Dipartimento di Chimica Industriale “Toso Montanari”

Corso di Laurea Magistrale in

Chimica Industriale

Classe LM-71 - Scienze e Tecnologie della Chimica Industriale

Sintesi e caratterizzazione di copolimeri bottle brush foto-elettro attivi Tesi di laurea sperimentale

CANDIDATO

Aurora Luzi

RELATORE

Dr. Stefano Scurti

CORRELATORE

Prof. Massimiliano Lanzi

Dr. Simone Gabellini

Dr. Riccardo Medri

**\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_** **Anno Accademico 2025-2026** **Riassunto** Il presente lavoro di tesi si concentra sulla progettazione, sintesi e caratterizzazione di nuove architetture macromolecolari potenzialmente semiconduttrici ed emissive a spazzola, note come copolimeri bottle brush. L'obiettivo principale è superare il fenomeno dello spegnimento dell'emissione indotto dall'aggregazione (Aggregation-Caused Quenching, ACQ), una criticità tipica dei materiali π-coniugati impiegati nel campo della soft optoelectronics. La naturale tendenza di questi sistemi planari a formare forti interazioni intermolecolari di π-stacking causa, infatti, una drastica dissipazione non radiativa dell'energia allo stato solido. Per risolvere questo problema, la strategia sintetica si è basata sulla realizzazione di un monomero ortogonale e multifunzionale derivato dal dichetopirrolopirrolo (DPP). Questo monomero è stato funzionalizzato con anelli tiofenici, che forniscono i siti reattivi per l'accrescimento della catena principale, e con gruppi ossidrilici terminali, che fungono da iniziatori indipendenti per l'innesto delle catene laterali. Successivamente, mediante polimerizzazione ossidativa diretta con 3-esiltiofene (3HT), è stato creato lo scheletro polimerico coniugato. L'architettura bottle brush finale è stata realizzata tramite polimerizzazione ad apertura d'anello (ROP) dell'ε-caprolattone, facendo crescere catene laterali flessibili di policaprolattone (PCL) con diversi pesi molecolari (1500, 5000 e 10000 Da). Le analisi spettroscopiche (1H-NMR e FT-IR) e cromatografiche (GPC) hanno confermato il successo della sintesi e l'ottenimento di macromolecole ramificate ad alta densità strutturale. La caratterizzazione ottica ha dimostrato che, mentre in soluzione il core di DPP mantiene intatta la sua integrità elettronica, allo stato solido l'introduzione delle catene laterali di PCL agisce efficacemente come spaziatore sterico. Questo ingombro limita l'eccessivo impaccamento intermolecolare, permettendo al materiale di conservare un'apprezzabile emissione nel rosso e attenuando così i percorsi di disattivazione non radiativa tipici dell'ACQ. Infine, le indagini elettrochimiche condotte tramite ciclovoltammetria hanno introdotto lo studio delle proprietà semiconduttrici dei materiali sintetizzati. I risultati hanno evidenziato una netta correlazione lineare tra la percentuale di DPP incorporata nello scheletro e l'allargamento del bandgap elettrochimico. In conclusione, il design macromolecolare proposto si è rivelato un approccio altamente efficace per combinare proprietà elettrochimiche modulabili e capacità emissive allo stato solido, confermandone il potenziale per future applicazioni in dispositivi optoelettronici. ## **Abstract** This thesis focuses on the design, synthesis, and characterization of novel semiconducting and emissive brush-like macromolecular architectures, known as bottle brush copolymers. The main objective is to overcome the phenomenon of Aggregation-Caused Quenching (ACQ), a typical critical issue of π-conjugated materials used in the field of soft optoelectronics. The natural tendency of these planar systems to form strong intermolecular π-stacking interactions causes, in fact, a drastic non-radiative energy dissipation in the solid state. To solve this problem, the synthetic strategy was based on the creation of an orthogonal and multifunctional monomer derived from diketopyrrolopyrrole (DPP). This monomer was functionalized with thiophene rings, which provide the reactive sites for the growth of the main chain, and with terminal hydroxyl groups, which act as independent initiators for the grafting of the side chains. Subsequently, the conjugated polymeric backbone was created through direct oxidative polymerization with 3-hexylthiophene (3HT). The final bottle brush architecture was achieved via ring-opening polymerization (ROP) of ε-caprolactone, growing flexible side chains of polycaprolactone (PCL) with different molecular weights (1500, 5000, and 10000 Da). Spectroscopic (1H-NMR and FT-IR) and chromatographic (GPC) analyses confirmed the success of the synthesis and the obtainment of branched macromolecules with high structural density. Optical characterization demonstrated that, while in solution the DPP core keeps its electronic integrity intact, in the solid state the introduction of the PCL side chains acts effectively as a steric spacer. This steric hindrance limits the excessive intermolecular packing, allowing the material to retain an appreciable emission in the red and thus attenuating the non-radiative deactivation pathways typical of ACQ. Finally, electrochemical investigations conducted via cyclic voltammetry were performed to assess the semiconducting properties of the synthesized materials. The results highlighted a clear linear correlation between the percentage of DPP incorporated into the backbone and the widening of the electrochemical bandgap. In conclusion, the proposed macromolecular design proved to be a highly effective approach for combining tunable electrochemical properties and solid-state emissive capabilities, confirming its potential for future applications in optoelectronic devices. - **Sommario** - [1. Introduzione](#_Toc242438062) - [1.1. Dichetopirrolopirroli](#_Toc242438063) - [1.1.1. Storia e sintesi](#_Toc242438064) - [1.1.2. Struttura e reattività](#_Toc242438065) - [1.2. Fluorescenza](#_Toc242438066) - [1.2.1. Shift di Stokes](#_Toc242438067) - [1.2.2. Resa quantica](#_Toc242438068) - [1.2.3. Tempi di vita](#_Toc242438069) - [1.3. Utilizzo di fluorofori in materiali polimerici](#_Toc242438070) - [1.4. Applicazioni](#_Toc242438071) - [2. Scopo](#_Toc242438072) - [3. Procedure sperimentali](#_Toc242438073) - [3.1. Materiali e metodi](#_Toc242438074) - [3.2. Sintesi e procedure](#_Toc242438075) - [3.3. Principi teorici della ciclovoltammetria](#_Toc242438076) - [3.4. Procedure sperimentali delle analisi voltammetriche](#_Toc242438077) - [4. Discussione dei risultati](#_Toc242438078) - [4.1. Dichetopirrolopirroli](#_Toc242438079) - [4.2. Copolimeri coniugati](#_Toc242438080) - [4.3. Polimeri bottle brush](#_Toc242438081) - [4.4. Ciclovoltammetrie](#_Toc242438082) - [4.4.1. Ciclovoltammetrie su polimeri elettroattivi](#_Toc242438083) - [4.4.2. Metodologie di analisi voltammetrica](#_Toc242438084) - [4.4.3. Proprietà elettrochimiche dei copolimeri lienari](#_Toc242438085) - [4.4.4. Effetto del design bottle brush](#_Toc242438086) - [4.5. Caratterizzazione spettroscopica allo stato solido](#_Toc242438087) - [5. Conclusioni](#_Toc242438088) # 1 **Introduzione** ## 1.1 **Dichetopirrolopirroli** I dichetopirrolopirroli (DPP) sono caratterizzati da un nucleo centrale costituito da due anelli lattamici a cinque termini condensati. Tale sistema biciclico presenta due insaturazioni che consentono l’introduzione di opportuni sostituenti aromatici o eteroaromatici periferici, come illustrato in **Figura 1**. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) Figura 1 - struttura generica di un dichetopirrolopirrolo Le particolari caratteristiche fisiche di questa molecola, tra cui un punto di fusione molto elevato (>350 °C), la fortissima insolubilità e la tipica colorazione rossa, rimasero inosservate finché i ricercatori della Ciba-Geigy Specialty Chemicals Co. non ne svilupparono i primi derivati, ispirandosi alle analogie strutturali con altri pigmenti già noti¹. Dal 1986, anno in cui il primo DPP fu immesso sul mercato, sono stati sintetizzati altri coloranti appartenenti a questa famiglia, impiegati con successo nella tintura di materiali plastici, fibre e inchiostri. Con il passare degli anni, l’interesse scientifico verso i DPP si è radicalmente evoluto: da tradizionali pigmenti industriali sono diventate molecole intensamente indagate in svariati settori. La loro architettura, caratterizzata da un’unità planare π-coniugata e dalla presenza di sostituenti ammidici reattivi, permette infatti di modulare finemente le proprietà ottiche ed elettroniche del materiale attraverso specifiche funzionalizzazioni chimiche. È proprio questa versatilità ad averne favorito l’impiego in numerosi campi tecnologici avanzati, come l’optoelettronica, il fotovoltaico² e il bio-imaging^3,4. ### 1.1.1 **Storia e sintesi** I DPP sono stati scoperti per la prima volta da Farnum et al. nel 1974 quando furono ottenuti come sottoprodotti della sintesi di derivati dell’azetinone mediante una reazione di Reformatskij modificata. I ricercatori hanno mostrato come, facendo reagire bromoacetato e benzonitrile in presenza di zinco, non si ottenga il prodotto desiderato ma un pigmento rosso con una resa del 5-20%. Per confermare la formazione del dichetopirrolopirrolo, Farnum et al. hanno ipotizzato uno schema di reazione riportato in Figura 2.² ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) Figura 2 - meccanismo di formazione del DPP proposto da Farnum et al² L’ipotesi prevedeva che il benzonitrile reagisse con l’organozinco, derivante dall’etilbromoacetato, per formare il β-amminocinnamato. Questo intermedio (**1**) in condizioni ossidative genera il dimero (**2**), che per ciclizzazioni consecutive mediante attacco nucleofilo delle due ammine sul carbonile estereo ed eliminazione di due molecole di alcol etilico, porta alla formazione del dichetopirrolopirrolo (**3**). Nel 1988, Iqbal in collaborazione con i ricercatori della Ciba-Geigy Specialty Chemicals Co.⁵, hanno intrapreso studi meccanicistici volti a rendere la produzione di DPP commercialmente sostenibile. Poiché i tentativi basati sull'ipotesi iniziale di Farnum. non avevano portato ai risultati sperati, i ricercatori hanno deciso di approfondire ulteriormente le indagini per chiarire l'effettivo meccanismo di reazione. Inizialmente l’attenzione è stata focalizzata sull’intermedio **1** per comprenderne l’effettiva partecipazione alla reazione attraverso esperimenti di crossover. Quest’ultimo è stato condotto replicando le condizioni della classica reazione di Reformatskij tra il 4-metilbenzonitrile (**A**), l’etil 2-bromoacetato (**B**) e quantità crescenti di β-amminocinnamato (**1**), sintetizzato separatamente con lo scopo di analizzare la distribuzione dei prodotti in funzione della concentrazione del reagente **1** aggiunto (**Figura 3**). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) Figura 3 - esperimento crossover in presenza di amminocinnamato Come è possibile osservare in **Tabella 1**, l’aggiunta progressiva di amminocinnamato ha mostrato un conseguente aumento del prodotto **4**, questo conferma la formazione e partecipazione dell’intermedio **1** alla reazione ed evidenzia la selettività verso il prodotto asimmetrico **4**.

A	B	Zn	1	5	4	3
1	1	1	0	100	-	-
1	1	1	0.2	60	35	⁓5
1	1	1	1	⁓5	85	10

Tabella 1 – descrizione degli esperimenti di crossover e risultati espressi in rapporto molare L’indagine meccanicistica si è successivamente concentrata sulla fase di dimerizzazione ossidativa. Nello studio, è stato evidenziato come né l’intermedio **1**, né il suo sale di zinco, diano luogo a dimerizzazione per via termica o in presenza di acidi di Lewis, basi, aria o agenti ossidanti. Al contrario, è stato osservato che ponendo il sale di zinco, visibile in **Figura 4** e sintetizzato precedentemente, a reagire con il bromuro B e il benzonitrile, è possibile isolare il DPP **3**. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) Figura 4 - sale di zinco derivato dall'intermedio 3 Le informazioni ottenute, insieme a quelle fornite precedentemente da Farnum sono state utilizzate per formulare un nuovo meccanismo di reazione, che tenesse conto di tutte le evidenze sperimentali. La sintesi proposta in **Figura 5** prevede come primo step la condensazione del reagente di Reformatskij con il benzonitrile per produrre il sale di Zn (**6**). Successivamente si ipotizza una C-alchilazione mediante una seconda molecola di bromoacetato, che porta alla formazione degli intermedi **7A** e **7B** in equilibrio tautomerico. Questi reagiscono con il carbonile estereo chiudendo l’anello lattamico a cinque termini e portando alla formazione dell’intermedio **8**. La condensazione con una seconda molecola di benzonitrile e la successiva ciclizzazione dell’intermedio **9**, isolato e menzionato anche da Farnum, porta alla formazione del DPP **3**. Con questo penultimo passaggio, inoltre, si spiegherebbe anche l’elevata selettività per il prodotto asimmetrico **4** menzionato in relazione all’esperimento di crossover. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) Figura 5 - meccanismo di formazione del DPP tramite la reazione di Reformtskij Tuttavia, nonostante l'approfondita ricerca condotta sulla base delle precedenti osservazioni, non sono state raggiunte svolte decisive. Sebbene sia stata messa a punto una procedura in grado di garantire rese riproducibili, i loro valori, pari al 25-30% rispetto al bromoacetato e al 60% rispetto a nitrile e zinco, sono risultate insufficienti per decretare la fattibilità commerciale del processo descritto. Sulla base di requisiti essenziali come la disponibilità di materie prime, minimizzazione degli stadi sintetici e fattibilità tecnologica, la ricerca si è orientata verso percorsi alternativi per la sintesi del DPP. Tali strategie sono state sviluppate con l'obiettivo di superare i limiti intrinseci e le criticità operative legati alla metodica di Reformatskij originale. Un’analisi dettagliata del meccanismo riportato in **Figura 5**, supportata da verifiche sperimentali, ha evidenziato come la bassa resa complessiva del DPP **3** risulti in netto contrasto con l'elevata efficienza dei singoli passaggi intermedi. In particolare, la formazione del sale di zinco **6** tramite reazione di Reformatskij procede con rese superiori all’80%, e la ciclizzazione del composto **9** (precursore immediato del DPP **3**) è risultata pressoché quantitativa. In base alle evidenze riportate in **Figura 5**, è stato quindi dedotto che la C-alchilazione del sale di zinco **6** rappresenti lo stadio determinante la resa dell'intero processo e che la bassa resa sia dovuta a probabili reazioni collaterali. La reazione in esame porta alla formazione del legame “**a**”, fondamentale nella molecola di DPP in quanto elemento strutturale condiviso da entrambi gli anelli del sistema biciclico condensato. A seguito di questa ipotesi, il gruppo di ricerca ha provato a sviluppare un processo sintetico che prevedesse l’utilizzo di un reagente che contenesse già al suo interno il legame “**a**”. Sono stati individuati come possibili candidati degli esteri succinici insieme a nitrili aromatici. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 6 - analisi retrosintetica del DPP proposta da Iqbal et al.* In **Figura 6** viene illustrata la strategia retrosintetica della molecola di DPP **3** individuata dal gruppo di Iqbal, che forma tre frammenti (**X**, **Y**, **X**) in maniera simmetrica. Tale approccio si basa sul preservare il legame C-C centrale “**a”** e prevede l’utilizzo di reagenti disponibili in commercio. L’utilizzo della reazione riportata in Figura 7 permette di superare la criticità data dalla formazione del legame C-C centrale, necessaria mediante il metodo Reformatskij, grazie alla preesistenza del legame nell’estere succinico. La reazione descritta, benché non fosse stata riportata in letteratura fino a quel momento, presenta evidenti analogie con la classica condensazione di Stobbe tra un'aldeide (o la corrispondente base di Schiff) ed esteri succinici, processo che conduce alla formazione del sistema dell'ottaidropirrolopirrolo⁶. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 7 - sintesi del DPP proposta da Iqbal et al.* L’efficienza della reazione descritta in **Figura 7** dipende strettamente dall'impiego di una base che coniughi un’elevata forza basica ad una ridotta reattività nucleofila, come un alcolato. Queste caratteristiche sono essenziali per favorire la corretta deprotonazione dell’estere succinico e minimizzare le reazioni indesiderate, quali l’attacco nucleofilo al nitrile o la condensazione di Claisen, preservando così l’integrità dei reagenti nel mezzo di reazione. Inoltre, è stato evidenziato come l’aggiunta graduale dell'estere succinico assicuri una bassa concentrazione locale del reagente nel mezzo di reazione, inibendo in questo modo la ciclizzazione competitiva riportata **Figura 8**. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) Figura 8 - reazione competitiva di ciclizzazione dell'estere succinico Allo stesso tempo, è diventato necessario l'impiego di un eccesso di base per compensare la porzione consumata dal DPP; quest'ultimo, data la sua natura relativamente acida, tende infatti a sottrarre base al sistema durante la sintesi^5,7. Un fattore determinante per limitare la reazione parassita di autocondensazione risiede nella natura chimica del residuo R del diestere. L'incremento dell'ingombro sterico di tale gruppo funge da inibitore per il processo secondario indesiderato. Nello specifico, la resa e la selettività nella sintesi dei dichetopirrolopirroli (DPP) migliorano proporzionalmente alla dimensione del sostituente, seguendo questo preciso ordine di efficacia: *t-Am > t-Bu > i-Pr > Et > Me*. In altre parole, l'impiego di gruppi più voluminosi (come il *terz*-amile o il *terz*-butile) permette di ottimizzare la formazione del prodotto principale rispetto a quanto avviene con residui più piccoli come il metile o l'etile. Grazie all'implementazione di queste strategie, il gruppo guidato da Iqbal riuscì a rivoluzionare la produzione di un composto che stava acquisendo una rilevanza strategica crescente. L'ottimizzazione dei parametri operativi e l’attenta selezione dei precursori permisero di superare le criticità legate alle basse rese delle sintesi precedenti. Questo progresso non ha solo ridefinito l'efficacia chimica del processo, ma ne ha confermato la fattibilità su scala industriale, garantendo un ottimo equilibrio tra efficienza sintetica (atom economy) e sostenibilità economica. Successivamente, nel 1987, il gruppo di ricerca di Closs e Gompper⁸ propose un nuovo metodo di sintesi dei DPP a partire da succindiammidi e della N,N-dimetilbenzammide dietilacetale, visibile in Figura 9. Un'attenta ottimizzazione del processo sintetico ha permesso di massimizzare la produzione del DPP **3** raggiungendo un'efficienza globale di circa il 60%. Nella fase iniziale, scaldando i reagenti sopra citati, si genera il prodotto desiderato in quota minoritaria (30%). Tuttavia, l'isolamento della fase liquida residua consente di recuperare l’intermedio **10**, la succinilbenzimmidina, con un'abbondanza del 35%. L'aggiunta di potassio ter-butossido a quest'ultimo composto, in presenza di THF, ne induce una conversione quantitativa verso l'analogo DPP, raddoppiando di fatto le rese finali. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 9 - sintesi del DPP3 proposta da Gloss e Gompper* Una variante metodologica all'approccio classico, anche questo descritto da Iqbal et al.⁵, prevede il passaggio attraverso i tetraidrodichetopirrolopirroli, i quali vengono sottoposti a un processo di deidrogenazione per generare il nucleo DPP finale. Il reagente selezionato per promuovere quest'ultima fase è solitamente il DDQ (2,3-dicloro-5,6-dicianobenzochinone). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 10 - DDQ (2,3-dicloro-5,6-dicianobenzochinone)* Le vie sintetiche per accedere ai precursori tetraidrati sono molteplici; un approccio ampiamente noto, ad esempio, è quello introdotto da Sprake⁶, che si basa sulla condensazione di una immina (11) con un estere succinico. L'intermedio 12 così isolato viene infine convertito nel dichetopirrolopirrolo 13 mediante l'azione ossidativa del DDQ. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) Figura 11 - esempio di sintesi proposta da Sprake et al.⁶ L'ottimizzazione di questi passaggi finali è stata oggetto di numerose indagini, tra cui spiccano i fondamentali contributi di ricercatori come Stas⁹, Avcibasi¹⁰, Riggs¹¹ e Qian¹². Infine, un’ulteriore via sintetica per la produzione di queste molecole è rappresentata dal metodo sviluppato nel 1996 da Langhals et al.¹³. In questo caso, gli autori hanno dimostrato la possibilità di generare con successo i DPP sfruttando abilmente la reattività dei composti basati sul nucleo del furo[3,4-c]furandione. L'intermedio furofurandionico (17) viene ottenuto per via termica in toluene¹⁴, oppure sottoponendo specifici benzoilacetati a un accoppiamento radicalico/ossidativo mediato da miscele di iodio/sodio, con successiva chiusura termica dell'anello¹⁵ (Figura 12). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 12 - metodi di sintesi per ottenere il nucleo furo[3,4-c]furandione* Il metodo che si basa sugli intermedi furofurandionici, mostrato in **Figura 13**, viene utilizzato nella preparazione di composti N-arilati simmetrici (**20**) asimmetrici (**19**), e con catene alchiliche (**21**). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 13 - sintesi dei N-aril-DPP proposta da Langhals et al.* Di seguito si riporta uno schema riassuntivo di tutte le sintesi per la formazione di dichetopirrolopirroli riportate in questo capitolo (**Figura 14**). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 14 - schema riassuntivo dei metodi sintetici analizzati per ottenere un dichetopirrolopirrolo* ### 1.1.2 **Struttura e reattività** Le particolari proprietà chimico-fisiche dei dichetopirrolopirroli derivano direttamente dal loro sistema biciclico lattamico, un core a otto elettroni π perfettamente planare nel caso del DPP non sostituito. Questa geometria favorisce l'instaurarsi di un fitto network di interazioni intermolecolari. Da un lato, la formazione di legami a idrogeno (0,182 nm)¹⁶ porta alla costituzione di aggregati stabili, limitando drasticamente la solubilità del composto nei solventi organici convenzionali. Dall'altro, l'estesa coniugazione elettronica e la vicinanza spaziale tra i piani molecolari (0,334 nm)¹⁶ provocano un'ottimale sovrapposizione degli orbitali, generando intense interazioni di π-π stacking¹⁷. Questo si traduce in una grande stabilità termica dei DPP, con un punto di fusione superiore a 350 °C ed una temperatura di degradazione che supera i 500 °C. Le interazioni intermolecolari influenzano in modo significativo anche le proprietà ottiche, le quali variano in funzione dello stato di aggregazione del campione. Mettendo a confronto le analisi spettroscopiche effettuate in soluzione con quelle allo stato solido, si osserva in quest'ultimo caso un allargamento della banda di assorbimento accompagnato da un marcato effetto batocromico, con uno spostamento del picco di assorbimento di circa 30 nm (Figura 15)¹⁸. ![](immagini/0cc8ba45ecb7b78a0f389ecdf2e753a48bf05e7d52a2f1ec0bd87a3a20cf2043.png) *Figura 15 - spettro di assorbimento del DPP non sostituito in film con spessore di 1200 Å (linea tratteggiata)* *e DPP non sostituito in DMSO (linea continua)* Le proprietà ottiche possono essere modulate agendo sulla natura elettronica dei sostituenti. Ad esempio, la funzionalizzazione del core dichetopirrolopirrolico con gruppi aventi caratteristiche elettroniche differenti (presenza simultanea di gruppi elettron-donatori ed elettron-attrattori) promuove un marcato effetto batocromico, ovvero una transizione dell’assorbimento verso lunghezze d'onda maggiori, insieme ad un aumento dell'intensità di assorbimento e a un allargamento della differenza tra i picchi di assorbimento e di emissione (Stokes shift)¹⁹. In **Tabella 2**, si riportano le proprietà fotofisiche di dichetopirrolopirroli con diversi sostituenti.

R	Colore ^a	λ _abs^max (nm)		ε _max^d (M^-1 cm^-1)
R	Colore ^a	Soluzione ^b	Solido ^c	ε _max^d (M^-1 cm^-1)
3-CF₃	Giallo-arancio	509	518	21000
3-Cl	Arancione	512	528	27000
H	Giallo-rosso	504	538	33000
4-Br	Blu-rosso	515	555	35000
4-NMe₂	Viola-blu	554	603	81500

Tabella 2 - proprietà foto-fisiche di DPP con diversi sostituenti in soluzione e allo stato solido²⁰ ^a soluzione in NMP, ^b soluzione in DMSO, ^c ottenuto mediante misure di riflettanza su un film di PVC pigmentato, ^d in DMSO I dati evidenziano uno shift batocromico tra lo spettro in soluzione e quello in fase solida. La spiegazione di questo fenomeno sta nella formazione di legami a idrogeno intermolecolari: l’atomo di idrogeno del gruppo ammidico, infatti, è in grado di interagire con il doppietto dell’atomo di ossigeno del gruppo carbonilico di una molecola adiacente. Questo provoca uno spostamento della densità elettronica sull’atomo di azoto, che allo stato solido porta alla formazione di una parziale carica negativa che influenza la struttura elettronica con variazione delle lunghezze d’onda di assorbimento ed i corrispettivi massimi²⁰. L'analisi dei diversi dichetopirrolopirroli in **Tabella 2** mostra come le proprietà ottiche siano strettamente dipendenti dai sostituenti aromatici, con un generale effetto batocromico dello spettro di emissione in soluzione rispetto al DPP avente gruppi aromatici non sostituiti. Rispetto alla molecola di base (DPP non sostituito), qualsiasi modifica strutturale si traduce, in Il comportamento allo stato solido appare, invece, fortemente dipendente dalla posizione dei sostituenti sull’anello aromatico portando ad effetti di natura prettamente sterica. L'ingombro generato modifica l'angolo di torsione dei gruppi aromatici rispetto al core, alterando di conseguenza la fotofisica del sistema. Mentre la funzionalizzazione in posizione para minimizza l'ingombro sterico e mantiene lo spostamento verso lunghezze d'onda maggiori, l'inserimento di gruppi in posizione meta provoca un aumento dell'angolo di torsione, riducendo la coniugazione effettiva e inducendo uno shift ipsocromico. Risulta essenziale specificare questa dinamica per distinguere chiaramente il contributo "strutturale" da quello elettronico, sebbene la posizione sull'anello influenzi inevitabilmente anche quest'ultimo. Per quanto riguarda gli effetti elettronici, i gruppi moderatamente elettron-attrattori provocano cambiamenti spettrali limitati, con picchi di assorbimento racchiusi in un range ristretto (504-515 nm). Al contrario, la presenza di un gruppo fortemente elettron-donatore (come il gruppo 4-NMe₂) produce un netto spostamento del massimo di assorbimento, di circa 50 nm. Questa marcata variazione è la diretta conseguenza di un'architettura elettronica di tipo donatore-accettore-donatore (push-pull-push): essendo il core DPP intrinsecamente elettron-povero, il collegamento con sostituenti ricchi di elettroni modifica la densità di carica lungo il sistema coniugato, alterandone l'assorbimento fotonico. La spiccata sensibilità del core centrale alla natura dei sostituenti periferici trova giustificazione, secondo Lenz²⁰, nella geometria di queste molecole. Analisi strutturali rivelano infatti che i gruppi fenilici subiscono una torsione di appena 7° rispetto al piano del nucleo del DPP. Questa piccola variazione risulta sorprendente se si considera la notevole repulsione sterica che si instaura tra i protoni in posizione orto dell'anello benzenico e gli eteroatomi (ossigeno e gruppi amminici) dell'anello lattamico. La conservazione della planarità si spiega mediante una delocalizzazione π che unisce le unità benzeniche allo scheletro centrale. Una prova tangibile di questa forte coniugazione elettronica è fornita dalla distanza interatomica del legame di giunzione tra il fenile e il nucleo: misurando solamente 1,46 Å, risulta nettamente più corto di un canonico legame singolo (generalmente atteso nel range di 1,50–1,54 Å), suggerendo un carattere di parziale doppio legame²⁰. ![](immagini/6f340ba76a30783ab8d6f8f0f47a136adeaf5193281bb3fae385c513191005ea.png) Figura 16 - struttura cristallina del DPP3 (distanze in Å)¹⁶ In conclusione, la straordinaria sensibilità dello spettro di assorbimento rispetto ai sostituenti non è altro che la conseguenza di un’elevata coniugazione della struttura, dove ogni minima variazione elettronica indotta sugli anelli periferici si traduce in una ridistribuzione della carica complessiva sull'intero scheletro molecolare. Per quanto riguarda la reattività dei DPP, invece, questa risulta essere varia per via dei diversi centri reattivi e del grande numero di sostituenti che posso essere introdotti nell’anello aromatico⁷. In **Figura 17** è possibile osservare i vari gruppi funzionali coinvolti nella reattività dei DPP. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) Figura 17 - reattività dei dichetopirrolopirroli² Si distinguono due macrocategorie di siti reattivi: quelli che possono essere coinvolti da un attacco nucleofilo e quelli che, invece, possiedono un carattere nucleofilo e che, quindi, possono attaccare un elettrofilo. I primi sono essenzialmente i carbonili ammidici (**a**) e i due atomi di carbonio in posizione 3 e 6 che possono subire addizione di Michael (**b**), oltre ad eventuali reazioni sugli anelli aromatici che possiedano gruppi elettron-attrattori in determinate posizioni (**c**, **d**). Al contrario, i gruppi nucleofili sono l’atomo di ossigeno del carbonile (**e**), che a seguito di tautomeria può risultare un ottimo nucleofilo, l’atomo di azoto del lattame (**f**), che a seguito della deprotonazione è in grado di attaccare un elettrofilo; si possono avere reazioni di SNAr sugli anelli aromatici in posizione 3 e 6 (**g**), grazie all’effetto elettron-attrattore che possiede il core dichetopirrolopirrolico, oppure ancora reazioni su elettrofili partendo da funzionalità nucleofile già presenti sugli anelli aromatici (**h**). Infine, è possibile effettuare sintesi di oligomeri o polimeri mediante reazioni di cross-coupling (**i**) partendo da DPP alogenati insieme ai corrispondenti reattivi organometallici, permettendo, in questo modo, di estendere ulteriormente la coniugazione. Nei paragrafi successivi sono riportate le reazioni che più comunemente vengono effettuate su questa famiglia di molecole, alcune delle quali utilizzate nel corso dell’attività sperimentale svolta. *Reazioni su gruppi ammidici come nucleofili* Una delle reazioni più comuni che viene effettuata sui dichetopirrolopirroli è la sostituzione nucleofila, favorita dalla presenza di gruppi ammidici, facilmente deprotonabili mediante l’utilizzo di basi forti. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 18 - deprotonazione stabilizzata per risonanza mesomerica del DPP* La carica negativa non è solo distribuita tra gli atomi di azoto e ossigeno dello stesso gruppo ammidico (**22** e **23**) ma può essere spostata anche al secondo atomo di ossigeno, dando la struttura mesomerica (**24**), che contiene un’unità pirrolica aromatica. Quindi, essendo l’anione fortemente stabilizzato, l’acidità dei protoni ammidici è relativamente elevata. La reazione viene influenzata dai sostituenti presenti sugli anelli aromatici, sia per effetto sterico, sia per effetti mesomerici sulla carica negativa generata dalla deprotonazione; inoltre vanno a modificare la solubilità del DPP.²¹ Proprio la scarsa solubilità della molecola rappresenta un ostacolo alla reazione, è quindi necessario l’utilizzo di solventi che siano in grado di solubilizzarla almeno parzialmente. I solventi polari aprotici sono particolarmente adatti a questo scopo e la N,N-dimetilformammide (DMF) è quella più utilizzata. Il più comune obiettivo di questa reazione è quello di introdurre catene alchiliche sull’azoto per modificarne la solubilità, eliminando i legami a idrogeno che tipicamente formano i gruppi ammidici. È stato studiato come l’aggiunta di un semplice gruppo metile al DPP aumenti la solubilità di 27 volte in DMF.⁵ In letteratura sono riportati molti studi in cui la reazione di sostituzione nucleofila viene utilizzata per la protezione delle funzionalità ammidiche, mediante l’utilizzo di gruppi ter-butossicarbonilici (Boc).²² L’introduzione di questi ultimi provoca un aumento della solubilità del prodotto e, mediante decomposizione termica, possono essere rimossi facilmente per ottenere il DPP non protetto in modo quantitativo (Figura 19). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 19 - reazione di protezione e deprotezione con gruppo Boc* Grazie a questa proprietà, i DPP protetti da Boc possono essere usati come pigmenti “latenti”, ad esempio per la colorazione dei polimeri^23,24. Grazie alla sua buona solubilità, questo pigmento riesce ad essere distribuito omogeneamente nel materiale polimerico. La matrice contenente il cromoforo viene poi riscaldata, portando alla formazione di un materiale colorato con pigmento di DPP non protetto di partenza. Sono inoltre riportati in letteratura alcuni esempi di reazioni di sostituzione nucleofila aromatico (SNAr) in cui l’azoto ammidico funge da nucleofilo. Questa tipologia di reazione, però, funziona in modo efficace solo quando l’agente arilante è un fluoroarene molto elettron-povero, ad esempio 1-fluoro-2,4-dinitrobenzene, mentre reazioni con arili meno elettron-poveri, come il 4-nitrofluorobenzene, o con un alogeno diverso dal fluoro, non portano alla formazione del prodotto desiderato. Recentemente Würthner ed i suoi collaboratori hanno dimostrato che la reazione SNAr dei DPP può essere eseguita anche utilizzando l’1-fluoro-2-nitro-4-(trifluorometil)benzene come agente arilante.²³ *Reazioni sugli anelli aromatici* Sebbene non strettamente parte del core dichetopirrolopirrolico, la maggior parte dei DPP presenti in letteratura contengono sostituenti aromatici derivanti dai benzonitrili di partenza e vengono quindi considerati parte integrante della struttura. I sostituenti arilici, in particolare, possono subire reazioni tipiche dei composti aromatici, come sostituzioni elettrofile aromatiche (S_eAr). Ad esempio, il DPP ottenuto mediante l’utilizzo di benzonitrile (**3**), può essere solfonato con acido solforico fumante, ottenendo il DPP **26** contenente gruppi solfonici nelle posizioni para degli anelli benzenici (**Figura 20**). Il DPP **3** può reagire anche con il bromo ed il cloro gassosi, producendo due molecole completamente diverse: mediante l’uso di bromo si provoca una sostituzione elettrofila aromatica ottenendo il DPP **27** para-dibromurato, mentre utilizzando il cloro si ottiene il prodotto in cui quest’ultimo viene addizionato ai doppi legami dell’unità centrale di DPP (**28**). Sebbene la bromurazione del DPP **3** abbia una buona resa, superiore all’80%, il DPP **26** si può ottenere più semplicemente partendo dal 4-bromobenzonitrile utilizzando il metodo di Iqbal riportato nella sezione precedente. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) Figura 20 - reazioni di sostituzione elettrofile aromatiche sugli anelli del DPP 3 Una delle reazioni più utili per le successive funzionalizzazioni è la bromurazione dei DPP N-N’-disostituiti che, nelle posizioni 3 e 6, possiedono sostituenti eteroaromatici come tiofene, furano o selenofene (**Figura 21**). A causa della loro alta densità elettronica, questi eterocicli reagiscono facilmente con NBS per dare i corrispondenti derivati bromurati con buone rese. La bromurazione del DPP **29** e **30** può essere effettuata anche utilizzando bromo elementare. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 21 - bromurazione del DPP con sostituenti eteroaromatici in posizione 3 e 6* La sintesi dei DPP **32**, **33** e **34** è difficile da realizzare mediante il metodo che sfrutta gli esteri succinici combinati con i corrispondenti nitrili: questo è dovuto al fatto che, in condizioni fortemente basiche, gli atomi di bromo in questi nitrili subiscono facilmente sostituzione nucleofila, riducendo le rese e complicando il processo di purificazione dei prodotti desiderati. Il gruppo di ricerca di Gryko et al.⁷ ha proposto un diverso esempio di sostituzione elettrofila aromatica: i DPP con sostituenti aromatici elettron-ricchi possono essere alchilati in DMF usando K₂CO₃ come base e tetrabutilammonio bisolfato (TBAHS) come catalizzatore a trasferimento di fase (Figura 22). Questa reazione porta alla formazione didiacetali (35) che possono essere trasformati nei rispettivi derivati carbonilici mediante un acido forte di Brønsted, attivando quindi una reazione di ciclizzazione elettrofila da parte dell’anello aromatico elettron-ricco adiacente. In questo modo sono riusciti ad ottenere dei pigmenti composti da almeno sei anelli fusi π coniugati con particolari caratteristiche fotofisiche (36). **35** **36** ![](immagini/44b209b21a14fccafd0091eceef379c4880287252f88a1e9934252c1085ed8ee.jpg) ![](immagini/922a3a6b2ebac21c6502b6fa7ed720a1df107fd86ca9b2a71411a92192b8be29.png) Figura 22 - reazione di ciclizzazione mediante sostituzione elettrofila aromatica sui DPP studiata da Gryko et al.⁷ Un’altra importante categoria di reazioni che viene utilizzata per la modifica degli anelli aromatici è quella del cross coupling catalizzato da palladio. In particolare, i composti **32**, **33 34** e **37** vengono utilizzati come descritto in **Figura 23**. Queste reazioni solitamente presentano alte rese e portano alla sostituzione degli atomi di bromo nei composti citati con i corrispondenti gruppi arilici, alchilici e amminici. Oltre a fornire un sistema π espanso, le reazioni di cross coupling possono essere utilizzate per la sintesi di polimeri π coniugati a base di DPP. In questo caso specifico, le reazioni più utilizzate sono quelle di Suzuki e Stille. alchil, aril, acil aril, alchil **32** **33** **34** **37** **Reagente Reazione** ![](immagini/ec1d0d99168054a309b5dc913893f65f3cfa6dc850c4c629c7b434cdf8638ac5.png) *Figura 23 - reazioni di cross coupling catalizzate da Pd sui DPP* Diversi composti aromatici bifunzionali possono essere polimerizzati con i DPP bromurati **32**-**34** e **37** in presenza di catalizzatori a base di palladio, fornendo i corrispettivi prodotti con buone rese (**Figura 24**). **32** **33** **34** **37** ![](immagini/8b3b485d4581689998b33430f9592ff5b7d3e41f929230ba0626ae4d6f15b6d5.png) X = S, O, Se, -CH=CH-; Y = B(OH)₂, B(OAlc)₂, SnAlc₃; R¹ = alchile, arile, acile; R² = H, alchile, OAlchile *Figura 24 - sintesi generica di polimeri a base di DPP mediante reazioni di cross coupling* In **Figura 24**, in particolare, sono stati utilizzati come co-monomeri i derivati di composti aromatici elencati: tiofene, 2,2'-bitienile, naftalene, 9,9-dialchilafluorene, tienotiofene, benzene, N-alchilcarbazolo. Per ottenere polimeri con buona solubilità e processabilità vengono utilizzati come materiali di partenza DPP con sostituenti alifatici a catena lunga o ramificati. Solitamente queste molecole sono polimerizzate con composti aromatici ricchi di elettroni, come quelli elencati in Figura 24, quindi, a causa del carattere elettron-accettore dell’unità dichetopirrolopirrolica, i polimeri che si ottengono sono di tipo donatore-accettore. Questa struttura generalmente garantisce buone proprietà conduttive, in particolare alta mobilità di carica e banda proibita a bassa energia, e consente l’applicazione del materiale in dispositivi semiconduttori come OFET e fotovoltaici organici (OPV).^25,26 Le reazioni di cross coupling di Suzuki e Stille sono particolarmente efficienti per la sintesi di composti biarilici ma entrambe richiedono una pre-attivazione dei substrati, ovvero la presenza di gruppi funzionali reattivi come atomi di bromo nel primo e gruppi boronici o trialchilstannici nel secondo componente della reazione. Mentre l’introduzione di atomi di bromo è relativamente semplice, la sintesi di acidi o esteri boronici e reagenti organostannici è più complessa e richiede condizioni di reazione più drastiche e utilizzo di reagenti altamente reattivi come il butillitio (BuLi). Inoltre, diventa più complicata anche la purificazione delle miscele di reazione e il trattamento dei composti organostannici, altamente tossici. Proprio per questi motivi sono state studiate procedure alternative per la sintesi dei legami biarilici: tra i vari metodi indagati da Marder et al. i più utilizzati sono l’arilazione diretta e l’accoppiamento ossidativo di composti aromatici.^27,28 L’arilazione diretta prevede l’accoppiamento di alogenuri arilici, spesso bromuri, con areni che non richiedono la pre-attivazione, in presenza di catalizzatori a base di palladio e basi. Durante la reazione uno dei gruppi CH del primo arene si condensa con l’unità legata al bromo (C-Br) del secondo componente, portando alla formazione di un nuovo legame arilico e acido bromidrico, che viene neutralizzato mediante l’azione della base. La regioselettività della reazione dipende dalla distribuzione della densità elettronica del reagente di partenza, dall’acidità degli atomi di idrogeno in ogni posizione e dalla presenza di eteroatomi o altri gruppi funzionali.²⁷ ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 25 - reazione di arilazione diretta del DPP 29 con diversi bromoarili* In due studi indipendenti, i gruppi di ricerca guidati da Marder e Chen²⁹ hanno esplorato con successo le potenzialità di un particolare precursore DPP (29), impiegandolo come molecola di partenza per reazioni di arilazione diretta condotte in presenza di diversi bromoareni (Figura 25). Le condizioni di reazione prevedono la presenza di un catalizzatore costituito da acetato di palladio e acido pivalico, insieme a K₂CO₃, come base per neutralizzare HBr che si libera come coprodotto, e l’utilizzo di DMA come solvente; in questo modo si ottengono i prodotti 38 (a-h). L’arilazione diretta ha luogo selettivamente nella posizione C5 dell’anello tiofenico, non sono stati identificati altri regioisomeri. Gryko et al. evidenziano come questo meccanismo di sintesi sia efficace sia con bromoareni elettron-ricchi sia con quelli elettron-poveri, anche quando il bromuro è il DPP stesso, in questo caso, però, si ottengono i prodotti con rese minori (Figura 26). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 26 - arilazione dei DPP di-brorumati con diversi areni* Diversamente dall’arilazione diretta, l’arilazione ossidativa procede mediante l’attivazione dei legami C-H dei due reagenti e non richiede pre-attivazione dei materiali di partenza²⁸. Il legame biarilico è formato attraverso l’ossidazione di due gruppi C-H aromatici, attivati mediante il catalizzatore a base di palladio. Questo metodo è stato utilizzato da Marder per l’arilazione del DPP 29. La reazione con polifluorurati poveri di elettroni in presenza di Pd(OAc)₂ come catalizzatore e carbonato d’argento come ossidante ha fornito i corrispondenti derivati coniugati 42 (a-c). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 27 - reazione di arilazione ossidativa* La resa migliore (79%) è stata ottenuta per il composto **45a**, sintetizzato da tetrafluoropiridina e DPP **29**. Dallo studio dell'accoppiamento ossidativo con il DPP 29 (Figura 27), emerge una minore reattività per substrati quali il pentafluorobenzene e il tetrafluorobenzonitrile, i quali restituiscono rese rispettivamente del 23% e del 45%. Questo approccio via attivazione C-H, seppur efficace, presenta una criticità rilevante: l'impiego massiccio di ossidanti, come Ag₂CO₃. In questo contesto, un'alternativa sintetica valida e notevolmente più economica per l'ottenimento di polimeri coniugati, in particolare per i derivati del DPP affiancati da anelli tiofenici (come il precursore 29), è rappresentata dalla polimerizzazione ossidativa mediata da ferro tricloruro (FeCl₃). A differenza dei tradizionali cross-coupling catalizzati da palladio, questo metodo non richiede alcuna complessa e costosa pre-attivazione dei monomeri (come nel caso di alogenazione, borilazione o stannilazione) né l'impiego di metalli di transizione pregiati. La reazione procede tipicamente in solventi poco polari, dove il ferro tricloruro agisce sia come acido di Lewis sia da ossidante, innescando la formazione di radical cationi sugli anelli tiofenici che portano alla formazione del legame C-C e alla successiva crescita della catena polimerica (Figura 28). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) Figura 28 - meccanismo di polimerizzazione ossidativa mediante FeCl₃ Sebbene l'ossidazione chimica possa offrire un controllo minore sulla polidispersione e sulla regioregolarità rispetto alle più controllate reazioni di Suzuki o Stille, essa si conferma un approccio estremamente diretto e scalabile per la sintesi di polimeri a base di DPP, permettendo di ottenere materiali semiconduttori con eccellenti proprietà optoelettroniche. Un' ulteriore alternativa sintetica si basa sulla litiazione in posizione C5. Al pari di altri sistemi tiofenici, i DPP 29, 30 e 31 (Figura 21) reagiscono prontamente con LDA, aprendo la strada a diverse funzionalizzazioni (Figura 29). Come è possibile osservare nello schema, la reazione dell'intermedio litiato con formammidi (es. N-formilpiperidina o DMF) genera la dialdeide 43³⁰. Se invece si impiega 2-isopropossi-4,4,5,5-tetrametil-1,3,2-diossaborolano o cloruro di trimetilstagno, si ottengono rispettivamente il diestere boronico 44³¹ e lo stannano 45³². Entrambi questi intermedi risultano di grande utilità per successivi step di cross coupling. Infine, è possibile isolare con buone rese il composto di-iodurato 46³¹ effettuando il quenching della reazione con iodio molecolare. ![](immagini/31ab95d1513571fe567fc67cef34b455944e7955aa5b495ee97b09788ef0f20b.png) *Figura 29 - reazione di litiazione e funzionalizzazione con successiva reazione con elettrofili* Un’ultima tipologia di reazione a cui possono andare incontro i dichetopirrolopirroli è quella della sostituzione nucleofila aromatica (SNAr); in particolare la reazione avviene in assenza di catalizzatori a base di palladio e su DPP che possiedono dei buoni gruppi uscenti sugli anelli aromatici. Essendo il core di-lattamico del DPP un elettron-attrattore, in letteratura solo riportati numerosi esempi in cui i composti **27** e **47** reagiscono con diverse ammine secondarie. La reazione procede a temperature elevate in autoclave per dare i corrispondenti sistemi amminici **48 (a-d)**, come mostrato in **Figura 30**. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 30 - sostituzione aromatica classica su derivati di DPP* ## 1.2 **Fluorescenza** La fluorescenza è il fenomeno fisico corrispondente all’'emissione di fotoni da parte di una sostanza, in seguito al rilassamento da uno stato elettronico eccitato ad uno fondamentale. Per molto tempo, in seguito all'introduzione del termine "fluorescenza" da parte di G. G. Stokes a metà del XIX secolo, la distinzione tra fluorescenza e fosforescenza si è basata esclusivamente sulla durata dell'emissione al termine dell'eccitazione. Nello specifico, la fluorescenza veniva considerata come un'emissione luminosa destinata a svanire simultaneamente all'interruzione della sorgente eccitante, mentre nella fosforescenza la luce emessa persisteva anche in assenza dello stimolo iniziale. Tuttavia, un simile criterio risultava insufficiente. Esistono infatti fenomeni di fluorescenza a vita lunga (ad esempio, nei sali di europio bivalente) e di fosforescenza a vita breve (come la luminescenza violetta del solfuro di zinco) che esibiscono durate del tutto comparabili, nell'ordine delle centinaia di nanosecondi³³. È stato poi determinato che ciò che distingue la fluorescenza dalla fosforescenza è la natura dello stato eccitato da cui decade l’elettrone. Negli stati eccitati di singoletto, l'elettrone promosso all'orbitale a maggiore energia mantiene uno spin opposto (accoppiato) rispetto a quello dell'elettrone rimasto nell'orbitale fondamentale. Di conseguenza, il rilassamento radiativo verso lo stato fondamentale è un processo permesso dalle regole di selezione dello spin e avviene rapidamente attraverso l'emissione di un fotone ad energia minore della radiazione incidente, e quindi a lunghezze d’onda maggiori. Si tratta di un fenomeno rapido, in cui il tempo di vita medio dello stato eccitato è nell’ordine delle decine di nanosecondi (10^-9 s). La fosforescenza, invece, consiste nell'emissione di radiazione luminosa a partire da stati eccitati di tripletto, nei quali l'elettrone promosso all'orbitale a maggiore energia presenta lo stesso orientamento di spin dell'elettrone rimasto nello stato fondamentale. Poiché le transizioni radiative verso lo stato fondamentale, che è uno stato di singoletto, sono proibite dalle regole di selezione dello spin, i tempi di vita medi della fosforescenza sono più lunghi, variando generalmente da pochi millisecondi a diversi secondi³⁴. I processi fotofisici che intercorrono tra l'assorbimento e la successiva emissione di luce vengono illustrati mediante il diagramma di Jablonski (**Figura 31**). Questo schema rappresenta il punto di partenza fondamentale per qualunque trattazione teorica sull'assorbimento e sulla luminescenza molecolare. ![](immagini/0423680b2667a6ca184d8ad3cdedd412ef8ade40cfcede7807f2fb580886520c.jpg) *Figura 31 - diagramma di Jablonski* In questo diagramma vengono rappresentati con delle frecce continue i fenomeni che coinvolgono l’interazione con una radiazione elettromagnetica, mentre con linee tratteggiate i fenomeni di rilassamento molecolare che non coinvolgono interazioni con la luce. In condizioni normali, l'assorbimento ottico coinvolge molecole che si trovano nel loro livello vibrazionale fondamentale. L'ampio divario energetico tra lo stato fondamentale (S₀) e il primo stato elettronico eccitato (S₁) impedisce la promozione di elettroni S₀ a livelli energetici superiori tramite semplice energia termica; per questo motivo, per indurre la fluorescenza è necessaria l'eccitazione mediante radiazione luminosa. A seguito dell'assorbimento di un fotone, il fluoroforo viene promosso a un livello vibrazionale superiore all'interno degli stati elettronici eccitati S₁ o S_2. Tuttavia, quando si trova in fase condensata (liquida o solida), la molecola va incontro a un processo di rilassamento non radiativo molto rapido, dissipando energia fino a raggiungere il livello vibrazionale fondamentale dello stato S_1. Questo fenomeno, definito conversione interna, avviene in intervalli temporali estremamente brevi, in genere nell'ordine dei picosecondi (10^-12 s). Poiché i tempi di vita medi della fluorescenza sono di diversi ordini di grandezza superiori, la conversione interna termina prima che la molecola possa decadere emettendo radiazione. Di conseguenza, l'emissione fluorescente si origina nella quasi totalità dei casi dal livello vibrazionale a minore energia dello stato S₁, come stabilito dalla regola di Kasha³⁵. ![](immagini/51d97cca166f20d62feb7eafcf0e6978cce78dc1fc3979bfacfca33e9f949e47.png) *Figura 32 - schema rappresentativo del fenomeno di intersystem crossing* Le molecole che si trovano nello stato eccitato S₁ possono, in alternativa, subire un'inversione di spin e transitare nel primo stato eccitato di tripletto, T₁, non raggiungibile direttamente. Questo processo non radiativo di conversione da S₁ a T₁ prende il nome di intersystem crossing (ISC) ed è mostrato in Figura 32. Dallo stato di tripletto a più bassa energia, la molecola può tornare allo stato fondamentale nuovamente tramite conversione interna oppure mediante fosforescenza. L'efficienza dell'emissione fluorescente dipende dunque in gran parte dalla struttura chimica del fluoroforo; in particolare, è necessaria una elevata rigidità strutturale per evitare fenomeni di rilassamento non radiativi. ![](immagini/969645e072498bad2c11541585f144818b6fac3d00dcac7d99a610e639f482c1.png) *Figura 33 - Stati elettronici per molecole rigide e flessibili* Nelle molecole poco flessibili, infatti, la geometria dello stato fondamentale e quella dello stato eccitato non presentano distorsioni significative; questo riduce significativamente la probabilità che l'energia assorbita venga dissipata sotto forma di calore attraverso movimenti vibrazionali. Di conseguenza, l'energia dello stato eccitato viene rilasciata quasi interamente sotto forma di luce. Le strutture molecolari ideali per massimizzare questo effetto sono quelle che presentano pochi gradi di libertà, come i sistemi coniugati e i composti aromatici. I dichetopirrolopirroli rientrano perfettamente in questa categoria: grazie al loro scheletro molecolare planare e al vasto sistema di elettroni delocalizzati, il rilassamento vibrazionale è fortemente limitato³⁴. La fluorescenza può essere caratterizzata mediante diversi parametri, tra cui gli shift di Stokes, i tempi di vita e la resa quantica. ### **1.2.1. Shift di Stokes** Lo shift di Stokes rappresenta la differenza tra la lunghezza d'onda della luce assorbita da una molecola e la lunghezza d'onda della luce emessa dalla stessa molecola sotto forma di fluorescenza o fosforescenza (Figura 34)³⁶. ![](immagini/3b55b8e6baa286d4a2e34a5ddcb6e51ee6a680299da1dd74559056416644ed73.png) Figura 34 - shift di Stokes³⁷ La minore energia registrata durante l'emissione è il risultato di una dissipazione energetica che avviene attraverso decadimenti di natura tipicamente vibrazionale. Questa differenza di energia, quantificata come la distanza in lunghezza d'onda tra i massimi degli spettri di assorbimento e di fluorescenza, rappresenta un parametro distintivo per ciascun fluoroforo. ### **1.2.2. Resa quantica** L'efficienza del processo radiativo di un cromoforo è quantificata dalla resa quantica di fluorescenza (ϕ). A livello macroscopico, questo parametro è definito come la frazione tra i quanti di luce riemessi dal sistema e quelli originariamente assorbiti per popolare lo stato eccitato (**Equazione 1**): $$ \phi =\frac{n\circ fotoni emessi}{n\circ fotoni assorbiti} $$ *Equazione 1 - resa quantica a livello macroscopico* Dal punto di vista della cinetica fotofisica, la resa quantica descrive la competizione tra il rilassamento emissivo e le vie di de-eccitazione non radiative. Matematicamente, si esprime rapportando la costante cinetica del decadimento fluorescente (K_f) alla somma di tutte le costanti di velocità non radiative che governano lo svuotamento dello stato eccitato (K_nr), quali l'intersystem crossing o la conversione interna (Equazione 2): $$ \phi =\frac{K_{f}}{K_{f}+\sum_{}^{}K_{nr}} $$ *Equazione 2 - resa quantica in cinetica fotofisica* Il valore ϕ di è strettamente legato alla topologia elettronica e all'architettura molecolare. Transizioni ad alta energia come le σ → σ\* inducono prevalentemente la fotodissociazione del legame spegnendo l'emissione, mentre le eccitazioni n → π\* e, in misura ancora maggiore, π → π\* garantiscono le efficienze radiative migliori. A tal fine, la progettazione molecolare gioca un ruolo cruciale: strutture rigide, ricche di insaturazioni, anelli aromatici e funzionalità carboniliche massimizzano la probabilità di emissione³⁴. Al contrario, un'eccessiva flessibilità conformazionale favorisce la dissipazione dell'energia termica tramite moti vibrazionali (conversione interna), abbattendo drasticamente la resa fluorescente^38,39. ### **1.2.3. Tempi di vita** Il tempo di vita dello stato eccitato è definito dal tempo medio che la molecola vi trascorre prima di tornare allo stato fondamentale. In generale, i fenomeni di fluorescenza avvengonoin tempi nell’ordine delle decine di nanosecondi. Il tempo di vita medio viene calcolato mediante la seguente equazione. $$ \tau =\frac{1}{K_{f}+\sum_{}^{}K_{nr}} $$ *Equazione 3 - tempo di vita medio* È bene ricordare che l’emissione è un processo casuale e che solamente poche molecole emettono fotoni esattamente a t = τ; quindi, è importante sottolineare che τ rappresenta un valore medio. Il tempo di vita di un fluoroforo in assenza di processi non radiativi è chiamato tempo di vita intrinseco o naturale e viene espresso mediante la seguente equazione. $$ \tau _{n}=\frac{1}{K_{f}} $$ *Equazione 4 - tempo di vita intrinseco* Questo parametro può anche essere calcolato mediante la misura del tempo di vita medio e della resa quantica, mediante l’equazione riportata successivamente. $$ \tau _{n}=\frac{\tau }{Q} $$ *Equazione 5 - correlazione tra tempo di vita intrinseco e resa quantica* Il tempo di vita, così come la resa quantica, dipende dalle costanti di velocità di decadimento radiativo (Γ) e non radiativo (K_nr). Ad esempio, esistono dei composti, noti come scintillatori, che presentano rese elevate e tempi di vita brevi (⁓1 ns) grazie ad alti valori di Γ; al contrario, i composti con valori di K_nr elevati hanno una fluorescenza debole, ne sono un esempio i composti aromatici con gruppi -NO_2.³⁴ ## 1.3 **Utilizzo di fluorofori in materiali polimerici** L'inserimento di fluorofori all'interno di un sistema macromolecolare richiede un accurato design molecolare, poiché l'architettura scelta ne influenza drasticamente le proprietà finali. La classificazione dei sistemi polimero-fluoroforo può essere suddivisa in diverse categorie strutturali ben distinte: ci sono le strutture host-guest, i sistemi polimerici main-chain, side-chain e cross-linked (**Figura 35**).

*Figura 35 - sistemi polimerici con inserimento di fluorofori, in verde il polimero e in rosso le unità di fluoroforo,* *a: sistema host-guest, b: sistema main-chain, c: sistema side-chain, d: sistema cross-linked* I sistemi polimerici di tipo host-guest rappresentano l’approccio più semplice e immediato per la fabbricazione di materiali fluorescenti. In questa architettura, la molecola d’interesse, ovvero il fluoroforo (guest), non forma legami covalenti con il polimero ma viene fisicamente mescolata e dispersa all’interno di quest’ultimo (host). Considerando che l’interazione tra le due specie è puramente di natura fisica, questa tipologia di struttura offre una notevole versatilità, data dalla possibilità di impiegare diverse tipologie di additivi, e facilità di preparazione, consentendo di ottenere materiali fluorescenti evitando di dover sviluppare complesse vie sintetiche. Tuttavia, l’assenza di un legame chimico diretto tra il fluoroforo e il polimero impone importanti limitazioni applicative. Il difetto principale risiede nella scarsa stabilità del sistema a lungo termine: all’aumentare della concentrazione le molecole del *guest* tendono a comportarsi in modo assimilabile a un comune additivo a basso peso molecolare, migrando gradualmente verso la superficie della matrice polimerica e aggregandosi. Questa progressiva migrazione innesca fenomeni di segregazione di fase e disomogeneità strutturale che portano alla perdita delle proprietà ottiche desiderate, come la diminuzione della resa quantica. Per via di queste problematiche, quindi, la stabilità del fluoroforo all'interno della matrice deve essere garantita dalla sinergia tra le interazioni secondarie (legami a idrogeno e dipolo-dipolo) con il polimero e l'impiego di host con elevata cristallinità e alta temperatura di transizione vetrosa (T_g), i quali immobilizzano la molecola guest riducendo la mobilità macromolecolare^40,41. Nei sistemi main-chain, il cromoforo è legato chimicamente come parte integrante della catena polimerica principale. La sintesi di queste architetture risulta più complessa, in quanto richiede l'impiego di monomeri fluorescenti opportunamente bifunzionalizzati e un controllo rigoroso della stechiometria e dei rapporti di reattività per evitare un'eccessiva vicinanza tra i cromofori, che porterebbe allo spegnimento della fluorescenza. Un approccio di grande successo in questo ambito è la strategia “grafting from”, ampiamente esplorata da Wang et al.⁴². Utilizzando un derivato dichetopirrolopirrolico bifunzionalizzato con gruppi idrossilici (DPP-OH) come iniziatore, è stato possibile far crescere simmetricamente due catene di policaprolattone (PCL) tramite polimerizzazione per apertura d'anello (ROP), ottenendo un copolimero PCL-DPP-PCL. Nei sistemi side-chain, invece, le unità luminescenti non costituiscono lo scheletro centrale, ma sono connesse chimicamente come catene laterali alla catena polimerica principale. Per minimizzare l'ingombro sterico e favorire la mobilità locale, la progettazione di queste macromolecole prevede spesso l'inserimento di uno spaziatore flessibile tra il core polimerico e il fluoroforo; ciò contribuisce ad abbassare la T_g e a limitare le interazioni indesiderate tra i cromofori adiacenti. La sintesi di questi sistemi può avvenire per polimerizzazione diretta, copolimerizzando un monomero funzionalizzato con altri co-monomeri (per garantire la giusta "diluizione" del fluoroforo e una buona processabilità), oppure per reazioni di post-polimerizzazione, ancorando il colorante a un polimero preformato. Un esempio classico di questa architettura è riportato nel lavoro di Lee et al.⁴³, i quali hanno sintetizzato copolimeri radicalici aventi una catena principale di polimetilmetacrilato (PMMA) a cui sono stati legati lateralmente dei cromofori a base di carbazolo e fenilenvinilene. Questa architettura side-chain non solo ha garantito un'eccellente solubilità nei comuni solventi organici senza formazione di gel, ma ha anche permesso di modulare finemente il colore dell'emissione e le proprietà di trasporto di carica. Per ovviare al problema della mobilità delle catene polimeriche, che nel tempo può portare all'avvicinamento dei cromofori e al conseguente spegnimento della fluorescenza, una soluzione è rappresentata dai sistemi reticolati (cross-linked). In questa architettura, i fluorofori fungono da unità multifunzionali in grado di creare veri e propri ponti chimici tra le macromolecole. Se da un lato questo approccio àncora permanentemente i cromofori nella loro posizione spaziale prevenendone l'aggregazione, dall'altro l'eccessiva rigidità conferita al reticolo comporta notevoli svantaggi applicativi: i materiali ottenuti possiedono un modulo elastico maggiore, ma risultano molto più fragili, insolubili e caratterizzati da una difficile lavorabilità. ## 1.4 **Applicazioni** Negli ultimi anni, i derivati del dichetopirrolopirrolo (DPP) hanno ampiamente trasceso il loro impiego originario come pigmenti commerciali, affermandosi in una vasta gamma di campi tecnologici avanzati che spaziano dai transistor organici a effetto di campo (OFET), al fotovoltaico, fino alle sonde fluorescenti per il bioimaging. Tra queste molteplici applicazioni, l'impiego del DPP ha assunto una rilevanza cruciale nel settore dell'optoelettronica organica; grazie all'elevata stabilità termica e fotochimica, unita a un nucleo fortemente elettron-deficiente, questo cromoforo è diventato un elemento chiave per la progettazione di semiconduttori innovativi e dispositivi a emissione di luce.⁴⁴ L'optoelettronica comprende lo studio e lo sviluppo di dispositivi basati sull'interazione tra la radiazione elettromagnetica e i materiali semiconduttori, con lo scopo di ottenere la conversione di segnali elettrici in fotoni, come nei diodi a emissione di luce (OLED), o viceversa, come nel caso delle celle fotovoltaiche (OSC) e dei fotorivelatori (**Figura 36**). ![](immagini/b5eeb7a523a478426c9115cb517438454b75741ad797e9ccacdccfb802d2dca1.jpg) *Figura 36 - rappresentazione schematica dei principi fisici alla base dei materiali optoelettronici: generazione di portatori di carica per assorbimento (sinistra) e ricombinazione radiativa per emissione (destra)* Storicamente, questo settore tecnologico è stato dominato dall'impiego di semiconduttori inorganici rigidi, caratterizzati da reticoli cristallini altamente ordinati quali il silicio.⁴⁵ Tuttavia, negli ultimi decenni, la ricerca si è orientata in modo significativo verso lo sviluppo dell'optoelettronica organica, che sfrutta le proprietà chimico-fisiche di piccole molecole e polimeri con estesi sistemi π-coniugati. L'impiego di materiali organici in sostituzione delle tradizionali controparti inorganiche offre una serie di vantaggi tecnologici. Tra i principali punti di forza spiccano la notevole leggerezza e la flessibilità meccanica, che consentono l'integrazione di tali semiconduttori in dispositivi deformabili o pieghevoli, spaziando dai display di nuova generazione fino all'elettronica indossabile (wearable electronics).⁴⁶ Inoltre, da un punto di vista chimico e ingegneristico, uno dei vantaggi più rilevanti risiede nella processabilità di questi materiali. A differenza del silicio, i polimeri coniugati possono essere depositati da soluzione a basse temperature impiegando tecniche ad alta resa e a basso costo, quali la deposizione per spin-coating o processi di stampa su larga scala. Questo approccio garantisce una drastica riduzione dei costi operativi rispetto ai complessi processi ad alta temperatura o in alto vuoto richiesti dalla tecnologia inorganica, promuovendo contestualmente un minor impatto ambientale e aprendo la strada a un'elettronica scalabile e sostenibile. Affinché tali materiali polimerici processabili possano essere impiegati efficacemente nei dispositivi optoelettronici, risulta indispensabile poter governare in modo preciso le loro proprietà ottiche ed elettroniche. Questo si traduce nella necessità di ingegnerizzare il band gap del materiale.⁴⁷ Negli attuali semiconduttori organici, la strategia sintetica d'elezione per ottenere un controllo accurato di tale parametro è l'approccio donatore-accettore (D-A). Questa architettura macromolecolare si basa sulla copolimerizzazione alternata di unità strutturali fortemente elettron-deficienti (accettori) e unità elettron-ricche (donatori) lungo lo scheletro $\pi$ -coniugato.⁴⁸ L'interazione tra questi due blocchi monomerici induce un'ibridazione dei rispettivi orbitali di frontiera: il livello HOMO del copolimero risultante è determinato principalmente dalla porzione elettron-donatrice, mentre il livello LUMO è governato dall'unità elettron-accettrice. Questo riposizionamento energetico intracatena promuove un marcato trasferimento di carica intramolecolare, il quale comporta una drastica riduzione del salto energetico e consente di centrare lo spettro di assorbimento e di emissione del polimero all'interno della regione visibile. ⁴⁹ Nel caso specifico delle architetture polimeriche sviluppate in questo progetto di tesi, il nucleo fortemente elettron-accettore del dichetopirrolopirrolo è stato combinato con unità di 3-esiltiofene (3HT), impiegate per il loro spiccato carattere elettron-donatore. L'introduzione del monomero tiofenico non solo funge da partner elettronico ideale per ibridare gli orbitali di frontiera del DPP, ma, grazie alla presenza della catena alchilica laterale esilica, garantisce anche l'adeguata solubilità della macromolecola finale, preservandone la processabilità.⁴⁹ La sinergia donatore-accettore (D-A) instaurata tra il nucleo di DPP e l'unità di 3HT permette di sintonizzare la struttura a bande del materiale, conferendogli i requisiti optoelettronici ottimali per un potenziale impiego come strato elettro-luminescente nei dispositivi OLED. Affinché le proprietà ottiche ed elettroniche dei polimeri D-A possano essere sfruttate tecnologicamente, è necessario implementare questi materiali all'interno di dispositivi a stato solido. Un diodo organico a emissione di luce (OLED) si basa su una complessa architettura multistrato, progettata con estrema precisione per ottimizzare l'iniezione, il trasporto e la ricombinazione delle cariche elettriche. Storicamente, i primi dispositivi organici a singolo strato presentavano efficienze estremamente ridotte a causa di un forte sbilanciamento tra la mobilità degli elettroni e quella delle lacune. Per ovviare a questo problema, i moderni OLED impiegano una struttura a sandwich comprendente molteplici film sottili specializzati. Il cuore del dispositivo è costituito dallo strato emissivo (EML, Emissive Layer) interposto tra due elettrodi asimmetrici. Da un lato, il dispositivo è delimitato da un anodo trasparente, tipicamente costituito da ossido di indio-stagno (ITO), caratterizzato da un elevato lavoro di estrazione e trasparente alla luce visibile; dall'altro lato, è presente un catodo metallico a basso lavoro di estrazione, come leghe di alluminio, calcio o bario. Per abbassare le barriere energetiche all'interfaccia tra gli elettrodi e il polimero luminescente, vengono frapposti degli strati ausiliari denominati HTL (Hole Transport Layer) ed ETL (Electron Transport Layer) (**Figura 37**). ![](immagini/a5b7997b8d326b7a48f255dfe64de8c53d58fa41be4e96680027c5d542706e8d.jpg) *Figura 37 - rappresentazione schematica dell'architettura OLED* Il meccanismo di elettroluminescenza si innesca quando viene applicata una differenza di potenziale ai capi degli elettrodi. Il campo elettrico generato forza il catodo a iniettare elettroni all'interno del livello LUMO dell'ETL, spingendoli verso il materiale emissivo. In modo simultaneo e speculare, l'anodo estrae elettroni dal livello HOMO dell'HTL, iniettando di fatto cariche positive, comunemente definite "lacune". A differenza dei classici semiconduttori inorganici, in cui le cariche si muovono liberamente all'interno di bande di conduzione delocalizzate nel reticolo cristallino, nei semiconduttori organici macromolecolari il trasporto di carica avviene attraverso un meccanismo quantistico, detto hopping, tra stati energetici localizzati lungo le catene polimeriche o tra catene adiacenti.⁴⁵ È in questa fase di conduzione che le caratteristiche chimico-strutturali del copolimero DPP-3HT si rivelano determinanti. La tendenza del nucleo fortemente planare del DPP a instaurare interazioni intermolecolari a corto raggio, promuove la formazione di domini microstrutturali ordinati durante la deposizione del film solido.⁴⁴ Una morfologia del film ordinata e omogenea incrementa sensibilmente l'integrità della sovrapposizione degli orbitali π tra molecole vicine, facilitando l'hopping dei portatori di carica e garantendo che elettroni e lacune possano convergere efficacemente all'interno del bulk dello strato emissivo. ![](immagini/c1e3df4eed389c56471304e53ef6eed99d2d012604f298652ded0b09061e1b5a.jpg) *Figura 38 - profilo energetico dell'elettroluminescenza in un polimero coniugato* L'interazione tra un elettrone, localizzato prevalentemente sull'unità accettrice del DPP, e una lacuna, situata sull'unità donatrice del tiofene, dà origine a uno stato eccitato transitorio definito "eccitone". Essendo termodinamicamente instabile, questo stato ha una vita brevissima: l'elettrone rilassa rapidamente dal livello energetico del LUMO per ricombinarsi con la lacuna nel livello HOMO. L'energia potenziale persa in questo salto energetico viene dissipata dal sistema e rilasciata verso l'esterno sotto forma di radiazione elettromagnetica, ovvero un fotone (Figura 38).⁴⁵ È in questo istante che la progettazione macromolecolare donatore-accettore si traduce in un fenomeno ottico macroscopico: l'entità del band gap corrisponde approssimativamente all'energia del fotone emesso ( $E=h\nu$ ). Conseguentemente, il controllo chimico della struttura polimerica consente di governare in modo assoluto la lunghezza d'onda, l'intensità e il colore della luce prodotta dal dispositivo OLED, rendendo materiali complessi come il copolimero DPP-3HT dei possibili candidati per la prossima generazione di display flessibili e sorgenti di illuminazione a stato solido. # 2 **Scopo** Il seguente progetto di tesi magistrale in Chimica Industriale è stato svolto all'interno di un gruppo di ricerca dell'Università di Bologna specializzato nella sintesi di materiali polimerici ingegnerizzati, con particolare riguardo verso le applicazioni nel campo della soft optoelectronics. Quest'ultima è una branca interdisciplinare che mira a combinare tecnologie di emissione e rilevamento della luce con dispositivi flessibili e adattabili, ideali per interfacce interattive, robotica biomimetica e sensori indossabili per il monitoraggio della salute. Si tratta di un campo di ricerca con numerose possibilità di innovazione, caratterizzato tuttavia dall'impiego di materiali semiconduttori π-coniugati che spesso perdono le loro proprietà ottiche allo stato solido. I principali problemi derivano infatti dalla natura altamente planare del loro scheletro molecolare, la quale induce il fenomeno noto come Aggregation-Caused Quenching (ACQ). Questo è causato dalle forti interazioni di π-stacking tra le catene polimeriche adiacenti, che smorzano drasticamente la fluorescenza del materiale limitandone le applicazioni pratiche. Per questo motivo, il progetto di tesi si pone come obiettivo lo sviluppo di nuovi semiconduttori polimerici emissivi in grado di superare le limitazioni imposte dall'ACQ, attraverso una strategia di design macromolecolare mirata all'ottenimento di architetture polimeriche a spazzola (bottle brush copolymers). L'intento è quello di promuovere la separazione fisica dei segmenti planari coniugati, ripristinando ed esaltando le proprietà emissive allo stato solido pur preservando l'integrità elettrochimica e la stabilità del sistema. Per fare ciò è stato scelto di utilizzare monomeri ortogonali a base di dichetopirrolopirrolo (DPP), una classe di molecole eteroaromatiche selezionata per le eccellenti proprietà fotofisiche. La reattività del monomero permette di far avvenire meccanismi di polimerizzazione indipendenti. In questa tesi è stata sviluppata una procedura sintetica che prevede inizialmente una condensazione pseudo-Stobbe per ottenere un fluoroforo contenente unità tiofeniche. Successivamente, attraverso l'N-alchilazione del core DPP impiegando una catena alchilica funzionalizzata con gruppi idrossilici, si è ottenuto un monomero in grado di subire due processi di polimerizzazione distinti. Sulla base di questa struttura, è stato deciso di sintetizzare inizialmente uno scheletro semiconduttore mediante copolimerizzazione ossidativa, con Fe(III) come ossidante stochiometrico, del monomero DPP con il 3-esiltiofene (3HT). La distribuzione statistica dei monomeri lungo la catena aumenta l'entropia conformazionale del sistema: ciò limita il packing molecolare e l'ordine costituzionale del polimero, una caratteristica di interesse in quanto riduce l'aggregazione delle catene principali e rende i gruppi idrossilici maggiormente accessibili per i successivi processi di funzionalizzazione. I materiali ottenuti sono stati infine strutturati e modificati per massimizzare l'emissione luminosa allo stato solido. Sfruttando i gruppi ossidrilici pendenti come iniziatori, è stata condotta una polimerizzazione ad apertura di anello (ROP) dell’ε-caprolattone. La crescita delle catene laterali di poli(ε-caprolattone) (PCL) ha permesso di ottenere la desiderata architettura bottle brush, favorendo la separazione sterica dei segmenti coniugati. Le proprietà foto-fisiche, termiche ed elettrochimiche di questi materiali sono state studiate per via spettroscopica (NMR, UV-Vis) e termica (DSC) e correlate con i parametri strutturali (come il peso molecolare del PCL) al fine di ottimizzarne l'emissione. Inoltre, per poter indagare approfonditamente l'aspetto semiconduttore dei materiali sintetizzati, tutti i polimeri sono stati caratterizzati mediante ciclovoltametria. Questa indagine elettrochimica ha permesso di confermare il mantenimento delle proprietà conduttive del core coniugato e di valutarne la stabilità ai processi di ossidoriduzione anche in seguito all'accrescimento delle catene laterali. # 3 **Procedure sperimentali** ## 3.1 **Materiali e metodi** Solventi e reagenti_ Le reazioni riportate sono state eseguite impiegando reagenti e solventi commerciali ad elevato grado di purezza, utilizzati senza ulteriori purificazioni ad eccezione di quelli menzionati di seguito. Il CHCl₃ è stato precedentemente anidrificato per distillazione in apparato Claisen con calcio idruro come anidrificante, e il THF purificato a pressione ridotta tramite evaporatore rotante per rimuovere lo stabilizzante. Strumenti di caratterizzazione_ La struttura molecolare dei composti sintetizzati è stata determinata mediante l’acquisizione di spettri ¹H-NMR in soluzione, effettuati con uno spettrometro “Varian Mercury 400” (400 MHz) con TMS come standard interno. I prodotti sono stati caratterizzati per spettroscopia infrarossa a riflettanza totale attenuata mediante uno spettrofotometro ATR-IR Bruker alpha I. I polimeri ottenuti sono stati caratterizzati per Gel Permeation Cromatography (GPC) in modo da determinare i loro pesi molecolari. Le analisi sono state effettuate impiegando una colonna del tipo 5MXL da 300 mm in grado di analizzare un range di Mw compreso tra 800-30000 Da. Lo strumento impiega un detector ad indice di rifrazione. I campioni sono stati solubilizzati in THF e l’analisi è stata eseguita con una velocità di flusso di 1 mL/min ad una temperatura di 20°C. La calibrazione della colonna è stata effettuata mediante standard monodispersi di polistirene. Le analisi UV-VIS sono state eseguite con uno spettrofotometro a doppio raggio “Agilent Cary 3500 UV-Vis” acquisendo uno spettro da 800 a 200 nm usando cuvette di quarzo con un cammino ottico di 1 cm. Le misure di fluorescenza sono state svolte con uno spettrometro Agilent Cary Eclipse, avente come sorgente una lampada allo xenon (80 Hz) e come detector un fotomoltiplicatore PMT 900. Le transizioni termiche dei polimeri sintetizzati sono state determinate mediante Calorimetria Differenziale a Scansione (DSC) con strumento “TA Q2000” operante in atmosfera inerte di azoto e utilizzando due cicli di riscaldamento da -50°C a 250°C a 20 °C/min, intervallati da un ciclo di raffreddamento da 250°C a -50°C a -10 °C/min. ## 3.2 **Sintesi e procedure** ***Sintesi di 3,6-di(tiofen-2-il)-2,5-diidropirrolo[3,4-c]pirrolo-1,4-dione (1)*** ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) In un pallone a tre colli da 25 mL con ancoretta magnetica e refrigerante si aggiungono sotto flusso di azoto: 475 mg (20,7 mmol, 3,5 eq) di Na_(s), 12 mL (109,7 mmol, 16,6 eq) di alcol tert-amilico (t-AmOH) e FeCl₃ in quantità catalitica. La soluzione viene scaldata a 80 °C mediante bagno d’olio e mantenuta sotto agitazione per favore la dissoluzione del sodio. Una volta solubilizzato, si aggiungono goccia a goccia 1,9 mL (20 mmol, 3eq) di 2-cianotiofene (2-CNTh) e si alza la temperatura fino a 110 °C. Successivamente, si sgocciolano 1,36 mL di diisopropil succinato (6,66 mmol, 1,13 eq) e si lascia reagire la soluzione per 16h. Si spegne la reazione lasciandola raffreddare e aggiungendo acido acetico diluito in acqua (rapporto 1:9 V/V). Il grezzo viene filtrato su imbuto buchner e lavato ripetutamente con acqua distillata e metanolo. Il prodotto ottenuta viene posto in stufa a 85 °C per eliminare eventuali tracce di acqua. Il prodotto **1** si presenta come un solido rosso scuro/violaceo. Caratterizzazione del prodotto 1 ¹H NMR (400 MHz, d₆-DMSO): δ = 8.24 – 8.18 (dd, J = 3.8, 1.2 Hz, 4H), 8.00 – 7.93 (dd, J = 5.0, 1.1 Hz, 4H), 7.38 – 7.25 (m, 4H) **UV-Vis** (in THF): 532 nm, 498 nm **Fluorescenza** (in THF): 490 nm ***Sintesi del 2,5-bis(6-idrossiesil)-3,6-di(tiofen-2-il)-2,5-diidropirrolo[3,4-c]pirrolo-1,4-dione (2)*** ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) In un pallone a 3 colli da 50 mL dotato di ancoretta magnetica e refrigerante si aggiungono: 1 g (3,32 mmol, 1 eq) di DPP (**1**) e 18,75 mL (6,25 mL/mmol di DPP) di dimetilsolfossido (DMSO). Il sistema viene inertizzato mediante cicli vuoto/azoto. Successivamente, si aggiungono 1,1 g (0,01 mol, 3 eq) di tert-butossido di potassio (t-BuOK) e la miscela di reazione scaldata a 40 °C. Dopo 10 min si sgocciolano all’interno 1,08 mL (8,3 mmol, 1,25 eq) di 6-bromoesanolo e si lascia reagire per 16 h. Al termine della reazione si trasferisce il grezzo di reazione in un imbuto separatore da 250 mL con 100 ml di DCM. Si lava la fase organica tre volte con 100 mL di soluzione satura di KCl in acqua. La fase organica viene anidrificata con sodio solfato (Na₂SO₄), filtrata su filtro a pieghe e evaporata tramite rotavapor. Il grezzo di reazione viene purificato mediante cristallizzazione in etanolo: il solido viene sciolto a caldo nella minima quantità di solvente e la soluzione ottenuta si ripone in freezer a -20 °C per 24 h. Al termine, si osserva nel pallone la formazione di un precipitato scuro costituito dal prodotto desiderato, il DPP bis-alchilato (**2**). Il composto cristallizzato viene posto in stufa a 85 °C fino a completa eliminazione delle tracce residue di solvente. Caratterizzazione del prodotto 2 ¹H NMR (400 MHz, CDCl₃): δ 8.96 – 8.84 (m, 1H), 7.67 – 7.58 (m, 1H), 7.33 – 7.19 (m, 2H), 4.17 – 4.04 (m, 2H), 3.73 – 3.59 (t, J = 6.4 Hz, 2H), 1.82 – 1.20 (m, 9H) **IR** (ATR): 3350, 3070, 2920, 2850, 1645, 1555, 1495, 1440, 1390, 820, 730 cm⁻¹ **UV-Vis** (in THF): 541 nm **Fluorescenza** (in THF): 540 nm ***Sintesi dei copolimeri coniugati (3a, 3b, 3c)*** ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) Sono stati sintetizzati tre copolimeri in base alla percentuale di DPP utilizzata (**Tabella 3**).

Copolimero	DPP (mmol)	DPP (eq)	3HT (mmol)	3HT (eq)
3a	0.2	0.2	0.8	0.8
3b	0.5	0.5	0.5	0.5
3c	0.8	0.8	0.2	0.2

*Tabella 3 - composizione dei copolimeri* La procedura sperimentale risulta analoga per ognuno dei copolimeri sintetizzati. In un pallone a tre colli posto in atmosfera d’azoto, vengono aggiunti 40 mL di cloroformio anidro (CHCl₃) ed i due monomeri nelle proporzioni corrette. La completa solubilizzazione del prodotto 2 viene favorita mediante sonicatore. In parallelo, si prepara una soluzione di 818 mg di tricloruro ferrico (FeCl₃) (5.05 mmol, 5 eq) in 10 mL di nitrometano (CH₃NO₂), lasciandola anch'essa in sonicatore per alcuni minuti per agevolarne la dissoluzione. La soluzione ossidante viene sgocciolata nel pallone mantenendo il sistema in agitazione per 1 h. Al termine, si aggiungono 30 mL di THF sbiancato e si lascia nuovamente in agitazione per 30 min. Successivamente, si trasferisce il grezzo di reazione in imbuto separatore e si lava con HCl 0.6 M finché la fase acquosa sottoposta al saggio con tiocianato non risulta trasparente (la persistenza del colore rosso indica la presenza di tracce residue di tricloruro ferrico; il test si esegue a partire dal terzo lavaggio). La fase organica viene estratta con una soluzione satura di NaCl in acqua, anidrificata e evaporata mediante rotavapor. Per separare il polimero dai possibili sottoprodotti (poli-3esiltiofene) e dalle molecole a basso peso molecolare viene effettuata una precipitazione in non-solvente. Il prodotto viene solubilizzato nella minima quantità di THF e si fa gocciolare in 150 mL di metanolo freddo. Il precipitato viene filtrato e la soluzione portata a secco mediante l’utilizzo del rotavapor. ***Sintesi dei polimeri bottle brush*** ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) A partire dai campioni **3b** e **3c** sono stati realizzati copolimeri con struttura bottle-brush a diverso peso molecolare. La quantità di $\varepsilon$ -caprolattone necessaria per l'innesto dei blocchi di PCL è stata determinata impostando il rapporto stechiometrico in funzione degli equivalenti di gruppi -OH del derivato DPP, considerandoli come iniziatori attivi per la ROP.

Copolimero	Mn teorico	Caprolattone
Copolimero	Mn teorico	V (ml)	mol
3b	1500 Da (3.1b)	1.06	0.01
	5000 Da (3.2b)	4.65	0.04
	10000 Da (3.3b)	9.29	0.09
3c	1500 Da (3.1c)	1.72	0.02
	5000 Da (3.2c)	7.43	0.07
	10000 Da (3.3c)	14.87	0.1

*Tabella 4 - composizione dei polimeri bottle brush* La procedura sintetica adottata è risultata analoga per tutti i polimeri descritti in Tabella 4. All'interno di un pallone da 30 mL dotato di rubinetto è stato introdotto il copolimero (nei quantitativi indicati in Tabella 4) sciolto in THF. Il sistema è stato riscaldato mediante bagno ad olio siliconico ed il solvente è stato rimosso a pressione ridotta utilizzando una pompa a membrana. Ottenuto un residuo secco, il pallone è stato posto in atmosfera inerte di azoto. Sono stati quindi aggiunti 2 mL di toluene e la quantità di caprolattone indicata in Tabella 4. La soluzione è stata portata alla temperatura di 110 °C, e successivamente, è stato aggiunto Sn(Oct)₂ in quantità catalitica. La miscela di reazione è stata mantenuta a reflusso per 24 h. Il prodotto è stato purificato mediante precipitazione in non-solvente usando metanolo freddo. Infine, il polimero precipitato è stato recuperato tramite filtrazione su imbuto Büchner ed essiccato all'aria sotto cappa aspirante in modo da allontanare ogni eventuale traccia di solvente residuo. ## 3.3 **Principi teorici della ciclovoltammetria** A differenza delle tecniche in stato stazionario, la CV prevede un'impostazione dinamica in cui il potenziale applicato varia in modo continuo nel tempo, rendendola uno strumento di indagine estremamente utile per caratterizzare i meccanismi di trasferimento elettronico. Per misurare accuratamente sia il potenziale che la corrente, l'analisi viene tipicamente condotta in una cella elettrochimica a tre elettrodi, controllata da un potenziostato. Il sistema comprende l'elettrodo di lavoro (Working Electrode, WE), ovvero la superficie su cui avviene la reazione di interesse, l'ossidazione o la riduzione della molecola (o in questo caso polimero) in esame. Il secondo componente è l'elettrodo di riferimento (Reference Electrode, RE), che possiede un potenziale noto e termodinamicamente stabile, come ad esempio un elettrodo ad Ag/AgCl o un filo di argento impiegato come pseudo-riferimento. Il potenziostato è progettato con un'impedenza d'ingresso molto elevata affinché attraverso questo elettrodo non passi alcuna corrente; in questo modo se ne impedisce la polarizzazione, garantendo che il potenziale di riferimento rimanga costante durante tutta l'analisi. Il circuito viene infine chiuso dal controelettrodo (Counter Electrode, CE), che è generalmente costituito da un materiale inerte dotato di un'ampia area superficiale, come un filo di platino. Il compito del controelettrodo è quello di permettere il passaggio della corrente necessaria a bilanciare la reazione faradica che si sviluppa sull'elettrodo di lavoro. Il principio fondamentale della tecnica consiste nell'imporre all'elettrodo di lavoro un potenziale che varia linearmente nel tempo secondo un'onda triangolare. Il potenziale viene scansionato da un valore iniziale ( $E_{i}$ ) a un valore finale o di inversione ( $E_{\lambda }$ ) con una velocità di scansione costante (scan rate, V/s), per poi invertire il senso della scansione e ritornare alle condizioni di partenza. La corrente misurata durante il ciclo rappresenta la somma di due contributi distinti: una corrente capacitiva, dovuta ai processi di carica e scarica del doppio strato elettrico all'interfaccia elettrodo/soluzione, e una corrente faradica, derivante dal reale trasferimento di elettroni tra l'elettrodo e la specie elettroattiva, descritto dalla legge di Faraday. Per minimizzare la caduta ohmica della soluzione e sopprimere la migrazione delle specie cariche per effetto del campo elettrico, l'analisi viene condotta in presenza di un elettrolita di supporto. In queste condizioni ottimali, il movimento delle specie elettroattive verso e dall'elettrodo è governato quasi esclusivamente dalla diffusione, a sua volta generata dal gradiente di concentrazione. In un tipico processo redox reversibile, all’avvicinarsi del potenziale applicato a quello del potenziale standard di riduzione (E⁰) della specie in esame, la corrente faradica inizia ad aumentare, seguendo il comportamento predetto dall'equazione di Nernst per l'equilibrio superficiale (Equazione 6). $$ E=E^{0}+\frac{RT}{nF}ln\left(\frac{C_{ox}}{C_{red}}\right) $$ *Equazione 6 - equazione di Nernst* Questa corrente continua a crescere fino a raggiungere un _picco massimo, definito corrente di picco (Ip). La formazione di tale picco si verifica poiché lo strato di soluzione immediatamente adiacente all'elettrodo si impoverisce rapidamente della specie reagente, rendendo il processo limitato dalla velocità di diffusione del materiale dal bulk della soluzione. Subito dopo il superamento del picco, lo strato di diffusione si espande verso l'interno della soluzione attenuando il gradiente di concentrazione, e conseguentemente la corrente decresce proporzionalmente a t^-1/2, seguendo l'equazione di Cottrell (Equazione 7) dove $I\left(t\right)$ è la corrente al tem_po $t$ , $n$ è il numero di elettroni scambiati, $F$ è la costante di Faraday, $A$ ra_ppresenta l'area attiva dell'elettrodo, $D$ è il coefficiente di diffusione della s_pecie elettroattiva, $C^{*}$ è la concentrazione della s_pecie reagente nel bulk della soluzione e $t$ è il tem_po. $$ I\left(t\right)=\frac{nFAD^{1/2}C^{*}}{\pi ^{1/2}t^{1/2}} $$ *Equazione 7 - equazione di Cottrell* Invertendo poi il potenziale applicato, le specie generate all'elettrodo durante la scansione di andata subiscono il processo inverso, originando nel voltammogramma un picco di corrente di segno opposto. Per un sistema diffusivo ideale e reversibile, il valore della corrente di picco in funzione della velocità di scansione è descritto quantitativamente dall'equazione di Randles-Sevcik (**Equazione 8**): $$ I_{p}=\left(2.69\times 10^{5}\right)\cdot n^{3/2}\cdot A\cdot D^{1/2}\cdot C\cdot v^{1/2} $$ *Equazione 8 - equazione di Randles-Sevcik* In questa equazione, $n$ rappresenta il numero di elettroni scambiati nella reazione redox, $A$ è l'area attiva dell'elettrodo (cm²), $D$ indica il coefficiente di diffusione della specie elettroattiva (cm²/s), $C$ è la concentrazione della specie nel bulk della soluzione (mol/cm³) e $v$ è la velocità di scansione (V/s, ²5 °C). La proporzionalità lineare tra la corrente di picco $I_{p}$ e la radice quadrata dello scan rate ( $v^{1/2}$ ) costituisce il criterio per confermare che il processo redox in esame è effettivamente controllato dal trasporto di materia per diffusione. ## 3.4 **Procedure sperimentali delle analisi voltammetriche** Le caratterizzazioni elettrochimiche sono state condotte a temperatura ambiente impiegando un potenziostato CHI660C (CH Instruments), interfacciato con una cella elettrochimica standard a tre elettrodi. Il sistema era costituito da un elettrodo di lavoro in glassy carbon (carbonio vetroso), un elettrodo di riferimento ad Ag/AgCl e un controelettrodo costituito da un filo di platino. Tutte le misurazioni sono state eseguite in fase omogenea, utilizzando tetraidrofurano (THF) come solvente. Come elettrolita di supporto è stato impiegato il tetrabutilammonio esafluorofosfato (TBAPF₆) ad una concentrazione di 0.1 M. Prima di procedere all'analisi dei materiali sintetizzati, è stata registrata la ciclovoltammetria del bianco sulla sola soluzione elettrolitica, al fine di verificare la pulizia del sistema e l'assenza di specie elettroattive interferenti all'interno della finestra di potenziale indagata. Successivamente, la soluzione è stata utilizzata per la preparazione delle soluzioni polimeriche a una concentrazione fissa di 10 mg/mL. ![](immagini/c9be0696a5ce4170a10898c5a8c55cd66b66323a81d276c8dd911fe7631ebaf6.jpg) *Figura 39 - schema della cella elettrochimica impiegata nelle misure voltammetriche* Inizialmente la soluzione è stata sottoposta a degasaggio tramite gorgogliamento di azoto, per rimuovere tutto l’ossigeno disciolto che potrebbe interferire con le analisi riducendosi al catodo. Successivamente, il flusso di azoto dentro la soluzione è stato rimosso per evitare perturbazioni meccaniche all’interfaccia elettrodo/soluzione durante le misure, mantenendolo solo come battente per impedire l’ingresso di ossigeno nella cella. Le scansioni voltammetriche di base per l'identificazione dei processi redox sono state registrate applicando una velocità di scansione di 0.05 V/s, variando in seguito le velocità di scansione (0.05, 0.1, 0.5 e 1.0 V/s) per investigare l’influenza della cinetica di trasferimento. Al termine delle misurazioni per ciascun campione, è stata aggiunta una piccola quantità di ferrocene direttamente nella cella elettrochimica per fungere da standard redox interno, in quanto i potenziali misurati sperimentalmente sono relativi e strettamente dipendenti dal particolare elettrodo di riferimento impiegato. Sfruttando il comportamento reversibile e il potenziale noto della coppia redox Fc/Fc⁺, è stato possibile calibrare l'asse dei potenziali e riferire i valori di onset sperimentali alla scala assoluta delle energie nel vuoto, passaggio indispensabile per un calcolo rigoroso dei livelli energetici HOMO e LUMO dei materiali.⁵⁰ # 4 **Discussione dei risultati** In seguito, verranno discussi i dati ottenuti durante il lavoro di tesi, attraverso l’analisi critica dei risultati delle varie sintesi e delle caratterizzazioni dei diversi prodotti con l’obiettivo di comparare i dati di questo lavoro di tesi con quelli già presenti in letteratura e delineare eventuali problemi riscontrati e possibili soluzioni. ## **4.1. Dichetopirrolopirroli** Il gruppo di ricerca all’interno del quale è stato svolto il lavoro di tesi si è precedentemente concentrato nella sintesi e caratterizzazione di fluorofori di natura dichetopirrolopirrolica. In particolare, è stato studiato l’effetto della presenza di gruppi funzionali elettron-attrattori (EWG) ed elettron-donatori (EDG), in posizione para sull’anello benzonitrilico, utilizzato nella formazione dei DPP, sulle proprietà foto-fisiche del fluoroforo finale (**Figura 40**). ![](immagini/06ea4ef401c2c94d92ce5ebdcab91b4639e8c1827ec33f15d85a9993333b8849.png) *Figura 40 - sostituenti del DPP precedentemente studiati dal gruppo di ricerca* L’impiego di benzonitrili con sostituenti in *para* di tipo EWG porta alla formazione di sistemi altamente emissivi; al contrario, la presenza di gruppi EDG porta alla formazione di un isomero strutturale (iso-DPP) in cui la fluorescenza nel visibile risulta inibita principalmente a causa dell'attivazione di processi di rilassamento non radiativo. Questo studio iniziale ha garantito solide fondamenta riguardo i possibili fluorofori da utilizzare in successive reazioni di polimerizzazione, sulla base di fattori come proprietà emissive e loro reattività. Con lo scopo di espandere ulteriormente le potenzialità fotofisiche di questi sistemi, il presente lavoro si è concentrato sulla sintesi e caratterizzazione di fluorofori dichetopirrolopirrolici, in cui i tradizionali anelli benzenici sono stati sostituiti da nuclei tiofenici. Successivamente, è stata sviluppata una strategia di funzionalizzazione basata su reazioni di N-alchilazione dei gruppi ammidici presenti nel core eteroaromatico. Questo approccio garantisce un notevole aumento della solubilità del fluoroforo finale, offrendo al contempo una procedura sintetica semplice e scalabile. In **Figura 41** è rappresentato lo schema di reazione del fluoroforo **2**, successivamente utilizzato nelle reazioni di polimerizzazione. In seguito, vengono analizzati i vari step di reazione e le rispettive caratterizzazioni. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 41 - schema di reazione del fluoroforo 2* La sintesi del composto 1 è stata eseguita sulla base delle procedure sintetiche descritte in letteratura, seguendo un meccanismo di ciclizzazione di tipo pseudo-Stobbe^5,7. In particolare, viene fatto reagire il derivato tiofenico con un estere succinico, in questo caso il diisopropil succinato. La reazione richiede la presenza di una base forte per la deprotonazione dell’estere succinico in posizione α al carbonile, azione eseguita dal teramilato di sodio (t-AmONa), ottenuto mediante salificazione dell’alcol ter-amilico con sodio in presenza di una quantità catalitica di FeCl₃. Una volta formatosi il carbanione, questo attacca il carbonio nitrilico del tiofene e porta al composto imminico che tautomerizza alla corrispondente enammina. Il gruppo amminico riesce ad attaccare il carbonile estereo in modo intramolecolare, portando alla chiusura del primo anello a cinque termini. Una seconda deprotonazione, con successivo attacco di una seconda molecola di tiofene, porta alla formazione di una nuova enammina, che nuovamente attacca il carbonile estereo, portando alla chiusura del secondo anello a cinque termini con formazione della struttura dichetopirrolopirrolica. Il meccanismo descritto è riportato in Figura 42. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 42 - meccanismo di reazione proposto per la formazione dei DPP* Il tiofene è stato introdotto direttamente nell’ambiente di reazione dopo la formazione dell’alcolato, mentre il succinato è stato gocciolato lentamente all’interno del pallone in quanto una concentrazione locale troppo elevata di quest’ultimo in condizioni basiche potrebbe indurre reazioni parassite di autocondensazione (Figura 43). In particolare, è stato scelto il diisopropil succinato per aumentare l’ingombro sterico intorno al carbonile e diminuire ulteriormente la possibilità dell’estere di subire autocondensazione di Claisen e successiva ciclizzazione, come riportato in letteratura.⁷ ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 43 - meccanismo di autocondensazione di Claisen* La purificazione della reazione è stata effettuata sfruttando la netta differenza di solubilità tra i reagenti ed il prodotto della reazione; una volta isolato il DPP dall’ambiente di reazione sono stati ripetuti numerosi lavaggi con acqua e metanolo per eliminare solvente e reagenti ancora presenti. Il prodotto, quindi, è stato sottoposto ad una serie di caratterizzazioni con lo scopo di determinarne l’effettiva struttura e proprietà fotofisiche. ![](immagini/7ee78c7f6eefe1816ac3830635c0335bfcb7376ab193625f3346fbd98ef4fe64.png) Figura 44 - spettro ¹H-NMR in DMSO del prodotto 1 Lo spettro ¹H-NMR del prodotto 1 viene riportato in Figura 44; la presenza di elementi di simmetria rende chimicamente equivalenti diversi gruppi di protoni, riducendo così il numero di segnali distinti rispetto al totale degli atomi di idrogeno presenti. Nella regione a circa 11 ppm si osserva un singoletto allargato attribuibile ai due protoni ammidici appartenenti ai due anelli lattamici fusi nel core dichetopirrolopirrolico. Tale segnale risulta marcatamente deschermato per effetto dell'azione sinergica tra il forte richiamo elettronico dei gruppi carbonilici adiacenti, l'esteso sistema π-coniugato del core molecolare e l'instaurarsi di legami a idrogeno intermolecolari con il solvente. Nella regione aromatica, invece, si identificano i segnali caratteristici dei due anelli tiofenici laterali. Il doppietto maggiormente deschermato è assegnabile ai protoni fisicamente più prossimi al core dichetopirrolopirrolico. Procedendo verso campi più alti, si osserva un secondo doppietto corrispondente ai protoni adiacenti all'eteroatomo di zolfo, il cui shift chimico risente del suo noto effetto induttivo. Infine, l'ulteriore segnale, che si risolve come un doppietto di doppietti a campi ancora maggiori, è attribuibile ai protoni centrali dell'anello tiofenico, i quali subiscono accoppiamento con entrambi i protoni vicinali.

Uv-Visibile X	Uv-Visibile Y	Emissione X	Emissione Y
700	-4.8807237255591763E-4	495	9.7185860062262036E-5
699	-3.5806465350884432E-4	496.05999759999997	-2.1471147226907533E-4
698	-3.0661120667882085E-4	496.9599915	-5.4001688259257296E-4
697	-3.831556347347063E-4	498.02999879999999	-5.3388871402922729E-4
696	-2.6650734920816231E-4	498.92999270000001	-7.7511852893581842E-4
695	-4.4065426620335267E-4	500	-6.9958309372477755E-4
694	-3.4855159821180171E-4	501.0400085	-4.533458900164179E-4
693	-4.1719581201490338E-4	501.94000240000003	-1.522795200024234E-4
692	-4.0142594450804281E-4	502.98001099999999	5.4741886578013317E-4
691	-2.9258060870527956E-4	504.01998900000001	1.2151126602887538E-3
690	-2.651234797052197E-4	505.07000729999999	2.0340297700280527E-3
689	-2.4084353964948143E-4	505.97000120000001	2.7844026821102199E-3
688	-3.4391624975770306E-4	507.01000979999998	3.8598725340081011E-3
687	-2.7041612287005934E-4	508.0499878	5.315943144308612E-3
686	-2.6366676481975681E-4	508.9500122	6.9554462968267946E-3
685	-3.0129522864554746E-4	510	8.6909514297538303E-3
684	-2.849823214021868E-4	511.0400085	1.1179674915453668E-2
683	-3.2022821690830575E-4	511.94000240000003	1.351033688038703E-2
682	-3.2811644326092871E-4	512.97998050000001	1.6985011719466977E-2
681	-3.1483977611890631E-4	514.02001949999999	2.1496965572643249E-2
680	-1.8982196655675842E-4	515.07000730000004	2.6145990117286407E-2
679	-1.9232355973138661E-4	515.96997069999998	3.0309592241537498E-2
678	-1.9628232894173834E-4	517.01000980000003	3.6599478675716147E-2
677	-2.3523446245651741E-4	518.04998780000005	4.4926850392710577E-2
676	-1.4490950520114091E-4	518.95001219999995	5.3914744519858962E-2
675	-2.2583709127363047E-4	520	6.5115551782352135E-2
674	-2.5276535145077583E-4	521.03997800000002	7.7750221344377576E-2
673	-2.7376644066441142E-4	521.94000240000003	9.2598582490112588E-2
672	-2.1325802002609046E-4	522.97998050000001	0.11361139944672297
671	-2.5626163658956256E-4	524.02001949999999	0.13995222427043885
670	-2.4941468861004225E-4	525.07000730000004	0.16901824785258762
669	-1.7949953423966191E-4	525.96997069999998	0.19633030444709645
668	-1.8914191650526606E-4	527.01000980000003	0.24550067935719239
667	-1.7595335455612216E-4	528.04998780000005	0.29630936856047291
666	-1.2853549328894985E-4	528.95001219999995	0.34165107202338346
665	-1.6842359047483947E-4	530	0.39933305710682893
664	-1.8251130965341137E-4	531.03997800000002	0.45618311855481064
663	-1.8579020811916155E-4	531.94000240000003	0.52245253878587683
662	-1.6354124002211176E-4	532.97998050000001	0.5948317020885372
661	-1.8253559798401053E-4	534.02001949999999	0.6584115430866786
660	-1.7906233733735744E-4	535.07000730000004	0.72141716726276595
659	-9.2673272092292882E-5	535.96997069999998	0.77390889576717548
658	-8.4654433100316129E-5	537.01000980000003	0.83848755825598376
657	-6.8129770503827039E-5	538.04998780000005	0.89595074917392381
656	-3.1333285003055694E-5	538.95001219999995	0.93591531341481649
655	-1.1777262990299905E-4	540	0.96551098909404232
654	-7.5250120185361798E-5	541.03997800000002	0.99108435480550128
653	1.7066389817583888E-5	541.94000240000003	1.0049261712208453
652	3.3246743513411517E-5	542.97998050000001	1.0076484734088158
651	6.4735860239319444E-5	544.02001949999999	1
650	2.6268732560848841E-5	545.07000730000004	0.98382712173103382
649	7.0961311473208838E-5	545.96997069999998	0.96415270645916284
648	6.1574571042017509E-5	547.01000980000003	0.9389771484787548
647	7.3028397855960057E-5	548.04998780000005	0.9113671137279642
646	7.0049368259439469E-5	548.95001219999995	0.88478903860029434
645	1.3513587603628891E-4	550	0.85863587027957766
644	1.6620279225135461E-4	551.02001949999999	0.82467087843959408
643	1.2579483142366918E-4	552.04998780000005	0.79088440929856885
642	1.9261460937698423E-4	552.94000240000003	0.76984589903177825
641	1.9367309987098244E-4	553.96997069999998	0.7441337913449958
640	1.2567320606046581E-4	555	0.72202135168166526
639	2.5898163943763525E-4	556.02001949999999	0.69322008328220608
638	2.1920020118503309E-4	557.04998780000005	0.67066462026064311
637	2.2036834328775548E-4	557.94000240000003	0.6519527181824023
636	2.5536703713226276E-4	558.96997069999998	0.63378717868997558
635	3.1918574909520859E-4	560	0.61410751724280532
634	3.4941622915248617E-4	561.02001949999999	0.59412799035688391
633	4.0562785787453637E-4	562.04998780000005	0.5746836165141046
632	4.3777140812501099E-4	562.94000240000003	0.56226715138509931
631	4.0205937147103424E-4	563.96997069999998	0.547586768619435
630	3.8353591129971435E-4	565	0.53009018010851461
629	4.5977177142793253E-4	566.02001949999999	0.51858701165553356
628	5.095066992073402E-4	567.04998780000005	0.50892632645885671
627	5.9832138617580007E-4	567.94000240000003	0.50179466321641775
626	6.6340602014194406E-4	568.96997069999998	0.49697628501190139
625	6.6956440943295704E-4	570	0.49343723177697441
624	7.4097872182026967E-4	571.02001949999999	0.49502298945834267
623	8.6820815607729657E-4	572.04998780000005	0.49634556757816561
622	9.2662653554892113E-4	572.94000240000003	0.50387269824718861
621	9.5378426584119969E-4	573.96997069999998	0.51065848778979317
620	1.0174799112089752E-3	575	0.52126938211253626
619	1.1021165803923097E-3	576.02001949999999	0.53473547039394365
618	1.1832673381457907E-3	577.04998780000005	0.54482294955636801
617	1.2401006494751291E-3	577.94000240000003	0.55456534765285992
616	1.4024587196475669E-3	578.96997069999998	0.56797176491065227
615	1.5497461138805396E-3	580	0.57832808498732946
614	1.6754223909924049E-3	581.02001949999999	0.58792751389258713
613	1.8101405251305517E-3	582.04998780000005	0.59346590866307036
612	1.8352330112770248E-3	582.94000240000003	0.59609660938260722
611	2.0267783696209952E-3	583.96997069999998	0.59740443009133115
610	2.200539554988991E-3	585	0.59499225936722422
609	2.4979890748749968E-3	586.02001949999999	0.58912825865338025
608	2.6039736492727431E-3	587.04998780000005	0.5822112002051254
607	2.781825541973352E-3	587.94000240000003	0.5737978719359802
606	2.9249216650240701E-3	588.96997069999998	0.55961123862477946
605	3.2083408742284571E-3	590	0.54251396729986023
604	3.4255799752446292E-3	591.02001949999999	0.52556902527096738
603	3.6476292232709004E-3	592.04998780000005	0.50928295680304037
602	3.8359928598132838E-3	592.94000240000003	0.49334276191127274
601	4.0127659433889622E-3	593.96997069999998	0.47088312757405437
600	4.1638743379306996E-3	595	0.45026767467633722
599	4.3770301089914709E-3	596.02001949999999	0.43316013732630565
598	4.5614698491983074E-3	597.04998780000005	0.41560995419821084
597	4.8697800462222576E-3	597.94000240000003	0.39761384147002599
596	5.1000134839162782E-3	598.96997069999998	0.37760329018328159
595	5.2112498914204499E-3	600	0.36188026659197603
594	5.4769268189670556E-3	601.02001949999999	0.34767521483850616
593	5.669738011353149E-3	602.04998780000005	0.33361075437456433
592	5.8537124855425494E-3	602.94000240000003	0.32013258847475434
591	6.0865754075781582E-3	603.96997069999998	0.30546530241055603
590	6.3143886553709873E-3	605	0.29331301700386481
589	6.619435926220627E-3	606.02001949999999	0.2825916877166858
588	6.8986226495406453E-3	607.04998780000005	0.27180766787761607
587	7.1848022429969365E-3	607.94000240000003	0.26150799941995329
586	7.3986956189935624E-3	608.96997069999998	0.2502518567015366
585	7.692899160046813E-3	610	0.24191388170972042
584	8.0169950790819518E-3	611.01000980000003	0.23327670170434231
583	8.3914274392976052E-3	612.02001949999999	0.22527858040177889
582	8.7561692551035211E-3	613.03997800000002	0.21519042189187074
581	9.1920469624148897E-3	614.04998780000005	0.20732779671086865
580	9.6583216354965539E-3	615.07000730000004	0.20175037600606285
579	1.0041438986349911E-2	615.94000240000003	0.19455247446698112
578	1.0519990211516894E-2	616.95001219999995	0.18802984556362728
577	1.1081491956573656E-2	617.96997069999998	0.17956915021475592
576	1.169082731091824E-2	618.97998050000001	0.17417227157641568
575	1.2296927819324361E-2	620	0.16943994652669328
574	1.3024169959388659E-2	621.02001949999999	0.16387739651940461
573	1.3717531363587093E-2	622.04998780000005	0.15821977261708403
572	1.4505665480207462E-2	622.94000240000003	0.15458109770527967
571	1.5476864793889005E-2	623.96997069999998	0.15073209233542639
570	1.6369664803294309E-2	625	0.14780894272727743
569	1.7545131400969735E-2	626.02001949999999	0.14370283444966953
568	1.8855711370280366E-2	627.04998780000005	0.14108790070131011
567	2.0319786014446891E-2	627.94000240000003	0.13957663762084982
566	2.1699030398025683E-2	628.96997069999998	0.1365982420852033
565	2.3596999892636208E-2	630	0.13482519598275483
564	2.5760954932648936E-2	631.01000980000003	0.1334072705221897
563	2.7974774864645141E-2	632.02001949999999	0.13086575577214091
562	3.0645537128443708E-2	633.03997800000002	0.12944167821595623
561	3.36066752917673E-2	634.04998780000005	0.12759670401887785
560	3.7407510665703178E-2	635.07000730000004	0.12586649588925458
559	4.1572152464376635E-2	635.94000240000003	0.12409524258147683
558	4.6432424610488E-2	636.95001219999995	0.122146910110847
557	5.2045831432217464E-2	637.96997069999998	0.12077397389013937
556	5.8844005280686736E-2	638.97998050000001	0.11893895435366836
555	6.7450872044594504E-2	640	0.11554133232317335
554	7.7600872717405206E-2	641	0.11317298077326297
553	8.8994957604043634E-2	642	0.10974937292853998
552	0.10289935896521243	643	0.10808512946433649
551	0.12083826726549068	644	0.10493098529997873
550	0.14297869077506126	645	0.10100339978316679
549	0.17018208104263285	646	9.742180119076993E-2
548	0.2015564108059012	647	9.3909148984581678E-2
547	0.23604272223032266	648	9.109344319603481E-2
546	0.2777524004484962	649	8.7515854744962415E-2
545	0.33080976201693391	650	8.3536637285804002E-2
544	0.39209903483002378	651.01000980000003	8.0256376039339147E-2
543	0.45969919290861688	652.02001949999999	7.6852314170669331E-2
542	0.52825325802943734	653.03997800000002	7.4346966220942085E-2
541	0.59324725179479698	654.04998780000005	7.0777723627295855E-2
540	0.67081386407330756	655.07000730000004	6.7466720985805723E-2
539	0.75310327044394254	655.94000240000003	6.4684728814823053E-2
538	0.82963405241342569	656.95001219999995	6.2012143175373007E-2
537	0.88354520546662296	657.96997069999998	5.944809124259981E-2
536	0.92446319368818652	658.97998050000001	5.6601559143684053E-2
535	0.95825885284497148	660	5.3844477134861929E-2
534	0.9776081115359363	661	5.1695839732639561E-2
533	0.99040067560079104	662	4.9984932195245919E-2
532	0.99753535687183448	663	4.7174590580438908E-2
531	1	664	4.5115110751894935E-2
530	0.99755163267701008	665	4.356266103366755E-2
529	0.99346737679325081	666	4.1577557832325994E-2
528	0.98446881671701736	667	4.0453982604704508E-2
527	0.97298939655216254	668	3.8501524443077126E-2
526	0.95782719892660118	669	3.6688508876379144E-2
525	0.94176398284561202	670	3.4832445447794437E-2
524	0.92435869073145904	671.01000980000003	3.3464451161568577E-2
523	0.90566429233353873	672.02001949999999	3.1892325719710131E-2
522	0.88544876869443379	673.03997800000002	3.0558667804793306E-2
521	0.86936937587260688	674.04998780000005	2.9458507185466807E-2
520	0.85375621470509866	675.07000730000004	2.8194710914551134E-2
519	0.83975855853570258	675.94000240000003	2.7285530480744558E-2
518	0.82815304761053976	676.95001219999995	2.6056589559081952E-2
517	0.81487728697676587	677.96997069999998	2.4844102079768053E-2
516	0.80040101100347827	678.97998050000001	2.3829124263882399E-2
515	0.78596324564000575	680	2.2903009167799984E-2
514	0.7709420128417479	681	2.1797191870685899E-2
513	0.75442702252506155	682	2.0743096155651827E-2
512	0.73735838505674645	683	1.9814898135413435E-2
511	0.72035530148332583	684	1.8877400091760737E-2
510	0.70434798298022294	685	1.8240856075345053E-2
509	0.69244772890954387	686	1.7637440680765653E-2
508	0.68257990251698053	687	1.7116832661423401E-2
507	0.67714205130581451	688	1.6716918569779356E-2
506	0.6760660584466478	689	1.6511249414976906E-2
505	0.67947066847411797	690	1.5913836271230684E-2
504	0.68845852405857344	690.97998050000001	1.5844467633396472E-2
503	0.70099904398509283	691.96997069999998	1.5077231420824679E-2
502	0.71755419210414528	692.95001219999995	1.4915473491617353E-2
501	0.73765082372133317	693.94000240000003	1.436760937842914E-2
500	0.75943845561294965	695.07000730000004	1.4259036738821661E-2
499	0.78181905084533065	696.04998780000005	1.3748068429003177E-2
498	0.80177317390109681	697.03997800000002	1.3471991530299739E-2
497	0.81946817035255581	698.02001949999999	1.3157410037412847E-2
496	0.83393558673377699	699.01000980000003	1.2917842086275465E-2
495	0.84460344128181364	700	1.2761509648936985E-2
494	0.85077726983476232
493	0.85148868904942998
492	0.84812423652440805
491	0.84014705009717006
490	0.82542592684376004
489	0.80801588764102039
488	0.79021655859028084
487	0.76983330645547865
486	0.7443487256051361
485	0.72026301989756703
484	0.70236058430654413
483	0.68242549212579806
482	0.65944378424247574
481	0.63784098330981753
480	0.61684151029476586
479	0.59644140824195568
478	0.57658614975224576
477	0.55659755606936356
476	0.53712861345181317
475	0.51738992925174299
474	0.4993915115964313
473	0.48328465240295904
472	0.46779619492419794
471	0.45460222403515171
470	0.44381067510480632
469	0.43508425478055585
468	0.42832692336938755
467	0.4233406469599601
466	0.4197488919229187
465	0.41701650124195938
464	0.41452951561630041
463	0.4116292159419972
462	0.40785406284544967
461	0.40299570617653219
460	0.39736831348141943
459	0.39033915601690028
458	0.38073911225476392
457	0.36963726350070897
456	0.35764978540817888
455	0.34481961278143547
454	0.3313863178823826
453	0.31855826762130346
452	0.30602900230711516
451	0.29307316160934682
450	0.28028998746853367
449	0.26805839852657515
448	0.25647451419999623
447	0.24579935189722402
446	0.23548100828780133
445	0.22506554063426601
444	0.21448302054415413
443	0.20450370839834017
442	0.19566005141537338
441	0.18792159871407271
440	0.18071913744438692
439	0.17381397665944101
438	0.16749028397599508
437	0.16193672520408967
436	0.1568625631306938
435	0.15220691373300466
434	0.14805443962631928
433	0.14386360095384973
432	0.13950704417105739
431	0.13522857975505612
430	0.13079082866973629
429	0.1263089896697436
428	0.12157633881406796
427	0.11679207139916736
426	0.11210020647809063
425	0.10765166052881306
424	0.10339225211973019
423	9.8984006377931269E-2
422	9.4644464897291933E-2
421	9.0846462352311821E-2
420	8.7064936174238564E-2
419	8.3425934095338522E-2
418	7.9967244898601991E-2
417	7.6711165845328985E-2
416	7.35867853936161E-2
415	7.0676002084699582E-2
414	6.8061840764851431E-2
413	6.5705054273471772E-2
412	6.3494742898040982E-2
411	6.159546912807836E-2
410	5.9953800274304657E-2
409	5.8373932120010033E-2
408	5.6854988201350133E-2
407	5.5740428299705033E-2
406	5.460183488285298E-2
405	5.3659033127623143E-2
404	5.2905784239760834E-2
403	5.2123161568271542E-2
402	5.1580837459095294E-2
401	5.1029273572721127E-2
400	5.0602696649873824E-2

*Figura 45 - spettro UV-Visibile e di emissione del prodotto 1 in THF* Dall’analisi dello spettro UV-visibile del prodotto **1** è possibile osservare una banda di assorbimento ben definita, con due massimi a lunghezze d’onda pari a circa 532 nm e 498 nm, caratteristici del sistema coniugato e planare del core dichetopirrolopirrolico. Lo spettro di emissione risulta essere pressoché simmetrico con quello di assorbimento, presentando un massimo principale a 543 nm e una spalla secondaria a circa 585 nm. È inoltre interessante notare uno Stokes Shift di soli 11 nm, indice del fatto che l'elevata rigidità molecolare del sistema minimizza i riarrangiamenti strutturali tra stato fondamentale ed eccitato, limitando così i decadimenti non radiativi in seguito all’eccitazione. Sfruttando la reattività del DPP ottenuto, descritta accuratamente nel **Capitolo 1.1.2**, è stata effettuata una reazione di N-alchilazione su entrambi gli azoti ammidici del DPP, utilizzando il 6-bromo-1-esanolo come agente alchilante. L’inserimento di una catena alchilica contente un gruppo ossidrilico, ha permesso di ottenere un monomero ortogonale e tetrafunzionale in grado di poter dare in maniera indipendente differenti tipi di polimerizzazione. La presenza degli anelli tiofenici può dare reazioni di polimerizzazione ossidativa mediante l’utilizzo stechiometrico di ferro tricloruro, mentre i gruppi ossidrilici assimilano la struttura ad un’unità monomerica di tipo diolica e per questo impiegabile nelle comuni reazioni di policondensazione con opportuni comonomeri. Inoltre, il gruppo -OH può agire da iniziatore per reazioni di tipo Ring Opening Polymerization (ROP) che coinvolgono monomeri ciclici. La reazione di N-alchilazione del lattame avviene mediante una tipica sostituzione nucleofila: l'azoto ammidico, deprotonato tramite l'impiego di una base forte come potassio ter-butossido (t-BuOK), agisce da nucleofilo attaccando il carbonio alifatico adiacente all'atomo di bromo (**Figura 46**). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 46 - meccanismo della reazione di N-alchilazione* Le condizioni operative hanno richiesto un controllo rigoroso della concentrazione della base, poiché un suo eccesso potrebbe favorire una reazione collaterale di ciclizzazione indesiderata a carico del 6-bromo-1-esanolo (**Figura 47**). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 47 - reazione di ciclizzazione del 6-bromo-1-esanolo* La fase di work-up è stata condotta mediante estrazioni liquido-liquido al fine di allontanare le impurezze idrosolubili, tra cui i sali inorganici generati, gli eccessi di base ed eventuali tracce di solvente di reazione. La fase organica in DCM è stata lavata con una soluzione acquosa satura di cloruro di potassio (KCl). Dopo aver rimosso l'umidità residua trattando la fase organica con sodio solfato anidro (Na₂SO₄) e aver filtrato l'agente essiccante, il grezzo isolato è stato sottoposto al processo di purificazione. Il prodotto è stato purificato per cristallizzazione, una tecnica che sfrutta la solubilità e capacità di cristallizzare del prodotto in uno specifico solvente, in questo caso etanolo. Sciogliendo il grezzo a caldo nella minima quantità di etanolo necessaria e inducendo successivamente una lenta precipitazione mediante prolungato raffreddamento a bassa temperatura (-20°C), è stato possibile isolare selettivamente il composto d’interesse, lasciando le impurezze maggiormente solubili nelle acque madri. Il precipitato scuro, corrispondente al DPP bis-alchilato, è infine stato recuperato mediante filtrazione. Il prodotto **2** ottenuto è stato caratterizzato mediante spettroscopia NMR e FT-IR. ![](immagini/b270db169fe23b49376d4aa1759d245f0a0c16a88ce5e4bb20c7b381daed37c0.png) Figura 48 - spettro ¹H-NMR in CDCl₃ del prodotto 2 Nella regione aromatica dello spettro 1H-NMR, riportato in **Figura 48**, si osservano chiaramente tre distinti segnali assegnabili ai protoni degli anelli tiofenici. Il segnale più indicativo è rappresentato da un doppietto a campi particolarmente bassi (circa 8.9 ppm), attribuibile ai protoni fortemente deschermati per effetto dei gruppi carbonilici adiacenti del core DPP. Gli altri due protoni tiofenici completano il pattern generando gli altri due segnali separati a campi progressivamente più alti (7.6 ppm e 7.3 ppm). L'avvenuta reazione di N-alchilazione è comprovata, nella regione alifatica, dalla comparsa di due multipletti: il segnale più deschermato (4.1 ppm) è relativo ai gruppi metilenici legati direttamente all'azoto lattamico, mentre il secondo (3.6 ppm) corrisponde ai metileni adiacenti all'ossidrile terminale. Infine, i restanti protoni metilenici della catena alifatica sono chiaramente visibili sotto forma di multipletti nella regione compresa tra 1 e 2 ppm. ![](immagini/0d8a5329d339fbc86b534f67282d254ffdea0186129f5383181c6e7cd8e71bea.png) Figura 49 - spettro FT-IR del prodotto 2 Dallo spettro FT-IR in **Figura 49** si possono osservare picchi coerenti con la struttura del DPP alchilato. A circa 3400 cm⁻¹ si osserva una banda larga attribuibile allo stretching del legame O-H dei gruppi alcolici terminali. I segnali deboli intorno a 3100 cm⁻¹ corrispondono allo stretching dei C-H aromatici degli anelli tiofenici, mentre i due picchi netti a 2930 e 2850 cm⁻¹ sono tipici dello stretching (asimmetrico e simmetrico) dei C-H alifatici dei gruppi metilenici. Il segnale più indicativo è la banda molto intensa a circa 1650 cm⁻¹, relativa allo stretching dei gruppi carbonilici (C=O) dei lattami in sistemi coniugati, tipica dei sistemi dichetopirrolopirrolici. Nella regione 1500-1400 cm⁻¹ compaiono gli stretching C=C degli anelli aromatici e del core. Infine, nella zona del fingerprint, sono presenti dei picchi compatibili lo stretching C-O degli alcol primari e ai bending dei C-H tiofenici. Per completare la caratterizzazione, il fluoroforo è stato analizzato mediante spettroscopia di assorbimento (UV-Visibile) e di emissione, in modo da poter confrontare le proprietà foto-fisiche con quelle del DPP di partenza (**Figura 50**).

Uv-Visibile X	Uv-Visibile Y	Emissione X	Emissione Y
660	5.9415327816413552E-3	524.91998290000004	-8.7761837159230731E-4
659	6.5059262938863948E-3	525.96997069999998	-1.5848693096365878E-2
658	8.1637234459518062E-3	526.85998540000003	-2.8617576581702841E-2
657	9.0936536112026321E-3	527.9099731	-4.0895077831421163E-2
656	8.7951241702173034E-3	528.95001219999995	-4.4427102583366455E-2
655	7.4042004120469015E-3	529.84997559999999	-3.7353883779261902E-2
654	7.9530497980955014E-3	530.89001459999997	-2.7189223000094735E-2
653	9.0345475239918E-3	531.94000240000003	-4.0141707210631953E-3
652	1.0304297037882918E-2	532.83001709999996	2.2253380982071087E-2
651	9.1300525858265397E-3	533.88000490000002	5.1129023926104369E-2
650	9.6483462533774253E-3	534.91998290000004	8.5724747349339617E-2
649	1.1256965401369921E-2	535.96997069999998	0.12879009112304829
648	1.214531115671795E-2	536.85998540000003	0.17690450806294322
647	1.1475447288044109E-2	537.9099731	0.23323038522975803
646	1.1651842560559008E-2	538.95001219999995	0.29134855130269277
645	1.2665220902769482E-2	539.84997559999999	0.33898766242489242
644	1.4035060283850157E-2	540.89001459999997	0.40228755558289087
643	1.4206522697099589E-2	541.94000240000003	0.4779061788953084
642	1.5944505645567639E-2	542.83001709999996	0.54092657475978922
641	1.5596798986393816E-2	543.88000490000002	0.60791197554607646
640	1.5572393465410731E-2	544.91998290000004	0.6657254787360064
639	1.2939562939010114E-2	545.96997069999998	0.73256866774855256
638	1.3376332530962006E-2	546.85998540000003	0.77920806804096165
637	1.5826483558247818E-2	547.9099731	0.8390453019613614
636	1.5900706789983829E-2	548.95001219999995	0.87536858016672736
635	1.501811592240802E-2	549.84997559999999	0.90710339325007106
634	1.8942700487713449E-2	550.88000490000002	0.94134008070255171
633	1.7440559495786965E-2	551.9099731	0.96785814916485968
632	1.7994408222404789E-2	552.94000240000003	0.98657321388707941
631	1.5574399394625597E-2	553.96997069999998	0.99313850561751926
630	1.7944907433034327E-2	554.84997559999999	0.998945299932266
629	1.7268663494807251E-2	555.88000490000002	1
628	1.7962634016716182E-2	556.9099731	0.99470037003663259
627	1.9225714090810513E-2	557.94000240000003	0.9820392562485718
626	2.0405760819926452E-2	558.96997069999998	0.96501263254398539
625	2.1863514080275905E-2	559.84997559999999	0.95148925412429408
624	2.2557385475334205E-2	560.88000490000002	0.92202982626268171
623	2.1978651278512677E-2	561.9099731	0.89933594262886907
622	2.2957078402671069E-2	562.94000240000003	0.86591493711291423
621	2.2426169234193306E-2	563.96997069999998	0.83895695516814306
620	2.142708528950767E-2	564.84997559999999	0.80167192858545899
619	2.2833886917868796E-2	565.88000490000002	0.7685435917796356
618	2.4710842724993451E-2	566.9099731	0.73331056676089024
617	2.4865888820344909E-2	567.94000240000003	0.70681123861251383
616	2.4990799491780898E-2	568.96997069999998	0.67581918109519679
615	2.3288168962964054E-2	569.84997559999999	0.64832897648053922
614	2.4803936841208216E-2	570.88000490000002	0.61142250241458396
613	2.4827378049914254E-2	571.9099731	0.5868767630397469
612	2.5720561283488552E-2	572.94000240000003	0.56557533217312594
611	2.4171396173549336E-2	573.96997069999998	0.54537143607673777
610	2.8418391735613006E-2	574.84997559999999	0.52167714580800961
609	2.9555133107974994E-2	575.88000490000002	0.50320313375132353
608	3.1091039207743695E-2	576.9099731	0.48313459594645708
607	2.8161718551540208E-2	577.94000240000003	0.47370665371414322
606	2.9498156490365562E-2	578.96997069999998	0.45663216230846732
605	3.1110148508967438E-2	579.84997559999999	0.45136508664881853
604	3.3463773704215515E-2	580.88000490000002	0.44205646610002358
603	3.4020553081837969E-2	581.9099731	0.43418176800910052
602	3.5763697950983164E-2	582.94000240000003	0.43261936811234314
601	3.6352249424702346E-2	583.96997069999998	0.43074941420947654
600	3.4017534249031478E-2	584.84997559999999	0.43077067119815499
599	3.611702273470474E-2	585.88000490000002	0.43054552074485924
598	3.6480101461360062E-2	586.9099731	0.43175142762822694
597	4.0445636429157758E-2	587.94000240000003	0.43123398322897
596	4.2765231418357856E-2	588.96997069999998	0.43634915588186707
595	4.4086681887655139E-2	589.84997559999999	0.4402351301283926
594	4.5584232691511677E-2	590.88000490000002	0.44557630978827428
593	4.8123188062336668E-2	591.9099731	0.44397889260117712
592	4.8555987817166336E-2	592.94000240000003	0.44765508312900043
591	5.1627911466873039E-2	593.96997069999998	0.44980397175804587
590	5.3452959224058606E-2	594.84997559999999	0.44751661969876805
589	5.5342576636505159E-2	595.88000490000002	0.44526425826121863
588	5.8471796932535978E-2	596.9099731	0.44650202360808994
587	5.7609074179089753E-2	597.94000240000003	0.43872905784787625
586	5.9713057548812051E-2	598.96997069999998	0.43276682693537116
585	6.3453666769055367E-2	599.84997559999999	0.42647075202948792
584	6.5198926577784061E-2	600.88000490000002	0.42057700330375841
583	6.9233150533161411E-2	601.9099731	0.41008857812587685
582	7.0499759987288205E-2	602.94000240000003	0.39877290595760723
581	7.0622992901167581E-2	603.96997069999998	0.38389669695826151
580	7.5677205590304497E-2	604.84997559999999	0.3778924875460436
579	7.6315260167062707E-2	605.88000490000002	0.36433366338371675
578	8.0842535762141149E-2	606.9099731	0.35094976566142055
577	8.639624015984973E-2	607.94000240000003	0.33473346950291205
576	8.7076153313302665E-2	608.96997069999998	0.32112966862223907
575	9.2185933511108181E-2	609.84997559999999	0.30952577154156863
574	9.7360432168910119E-2	610.85998540000003	0.29550368868564947
573	0.10130827294233724	611.88000490000002	0.2787619700724317
572	0.11015614746797554	612.89001459999997	0.26331959196287708
571	0.11661725252269589	613.9099731	0.24566126191289722
570	0.12131764709688839	614.91998290000004	0.23195018657807911
569	0.13086340195715432	615.94000240000003	0.21761950567500593
568	0.143779179864265	616.95001219999995	0.20033038493412242
567	0.15750972531303425	617.96997069999998	0.18488257211247341
566	0.17365543835304834	618.8400269	0.17247139949775459
565	0.19284313343027501	619.84997559999999	0.16006078902929124
564	0.21076075487979989	620.88000490000002	0.14744181399824358
563	0.238746695608992	621.9099731	0.1311107206264962
562	0.26551116067278935	622.94000240000003	0.120089725034072
561	0.30109797106925751	623.96997069999998	0.10861529616628973
560	0.33917822271484716	624.84997559999999	0.10041746272252292
559	0.38062589982028655	625.88000490000002	8.9467840650520422E-2
558	0.42732170779471612	626.9099731	7.6587385850338363E-2
557	0.47517496058838798	627.94000240000003	7.13898632976631E-2
556	0.52353889776212637	628.96997069999998	5.8942013341727287E-2
555	0.57259131911445371	629.84997559999999	5.4040907667240679E-2
554	0.61931996398955724	630.85998540000003	4.3005602575212347E-2
553	0.65909178849548722	631.88000490000002	3.6827510869279441E-2
552	0.6985315549920541	632.89001459999997	3.1067098701679886E-2
551	0.74039210833021396	633.9099731	2.6096118749431262E-2
550	0.77774687533661002	634.91998290000004	1.8667785941267806E-2
549	0.81674113784783486	635.94000240000003	1.3848494769622981E-2
548	0.85260865263341767	636.95001219999995	9.7837923567180816E-3
547	0.88483027411247073	637.96997069999998	3.3498964846445339E-3
546	0.9158101517207774	638.8400269	-2.1492367000411179E-4
545	0.94490515431145472	639.84997559999999	-2.8771875608788913E-3
544	0.96585025573802075	640.84997559999999	-7.9261000988607184E-3
543	0.98038343866186595	641.84997559999999	-1.3562866888705664E-2
542	0.99134945705354482	642.84997559999999	-1.5226035558189431E-2
541	1	643.84997559999999	-2.0138010555103024E-2
540	0.9962283819067993	644.84997559999999	-2.1797002828811543E-2
539	0.98297934924698471	645.84997559999999	-2.7251681509020916E-2
538	0.97103852573608795	646.84997559999999	-2.8414405713637694E-2
537	0.96090194160899289	647.84997559999999	-3.0868371943648835E-2
536	0.94535676599475027	648.84997559999999	-3.5555223215531492E-2
535	0.92341566480566062	649.84997559999999	-3.7844449446563587E-2
534	0.90719071543077001	650.85998540000003	-3.9806257065043697E-2
533	0.89159799854006416	651.88000490000002	-4.399168672712072E-2
532	0.87431921183803907	652.89001459999997	-4.5204848911482472E-2
531	0.85203789661896301	653.9099731	-5.1208482492236473E-2
530	0.8334770067882451	654.91998290000004	-5.2749879839922006E-2
529	0.82562406986077086	655.94000240000003	-5.4630368230272786E-2
528	0.81651621672809704	656.95001219999995	-5.8939670820030939E-2
527	0.80237093084322819	657.96997069999998	-6.1618479635273754E-2
526	0.79137059114692698	658.8400269	-6.4475574995218735E-2
525	0.78396771799686926	659.84997559999999	-6.7452755076780294E-2
524	0.77452953421167403	660.84997559999999	-7.0742040303342468E-2
523	0.76627365296259042	661.84997559999999	-7.3543497255198972E-2
522	0.75989065712991855	662.84997559999999	-7.6557013319751996E-2
521	0.75459727434418888	663.84997559999999	-7.8880708169535199E-2
520	0.75134745870035746	664.84997559999999	-8.1331127137367482E-2
519	0.7503225564506224	665.84997559999999	-8.4301801656817305E-2
518	0.75195989692436183	666.84997559999999	-8.7124783125632654E-2
517	0.7541703422408127	667.84997559999999	-9.1612887560827125E-2
516	0.754737684515977	668.84997559999999	-9.3938362750960944E-2
515	0.76279465906620669	669.84997559999999	-9.7121243621914294E-2
514	0.76675695401534572	670.85998540000003	-9.9201375728389746E-2
513	0.77233361268701395	671.88000490000002	-0.10138032237385872
512	0.77960036759363838	672.89001459999997	-0.1041191066502946
511	0.78543231630607913	673.9099731	-0.10802441672786192
510	0.79084291582428756	674.91998290000004	-0.11076642695883604
509	0.79600659539594176	675.94000240000003	-0.11276695326037239
508	0.79954439203104355	676.95001219999995	-0.11462903609804459
507	0.80553117392284623	677.96997069999998	-0.11790948661019465
506	0.80714470259454107	678.8400269	-0.11981374834815804
505	0.80834109377592622	679.84997559999999	-0.12167745088288762
504	0.80677805569193695	680.84997559999999	-0.12314921487213362
503	0.80663248196980408	681.84997559999999	-0.126186832167858
502	0.79952785326897535	682.84997559999999	-0.12813758308533499
501	0.79168245760919076	683.84997559999999	-0.12925566538900332
500	0.78128233882056752	684.84997559999999	-0.13172183954080793
499	0.76783344307440216	685.84997559999999	-0.13268990627360397
498	0.75467205758392752	686.84997559999999	-0.13444545088625628
497	0.74026956393129628	687.84997559999999	-0.1355081156751369
496	0.72684552845499328	688.84997559999999	-0.13671726209298052
495	0.70592161496282446	689.84997559999999	-0.13814071645417442
494	0.6831473907645782	690.8400269	-0.13948287836112119
493	0.663789451406396	691.96997069999998	-0.14040357248156174
492	0.65133066272050244	692.95001219999995	-0.1404457112385748
491	0.63937497246723407	693.94000240000003	-0.14181639845368724
490	0.61872969747328355	694.91998290000004	-0.14275978163214656
489	0.5998828905320388	695.9099731	-0.14325256939131009
488	0.58987156507116179	696.90002440000001	-0.14502079043711319
487	0.57894739050562516	697.88000490000002	-0.14500700297557662
486	0.56024019519179447	698.86999509999998	-0.14564830703838955
485	0.54561272905034941	699.84997559999999	-0.14700123120381578
484	0.54051710383788099	700.84997559999999	-0.14749182364499966
483	0.53331876912947007
482	0.51910054497666469
481	0.51084984513224685
480	0.4969541679461551
479	0.4884486261688184
478	0.47983539667165864
477	0.47369358475104489
476	0.46778541311845595
475	0.4600689696989701
474	0.45304494081412083
473	0.4460308046538084
472	0.44025420117512803
471	0.43192261735890375
470	0.42512519048435271
469	0.4206358975747031
468	0.41223404946600012
467	0.40505616814547474
466	0.39635665027514305
465	0.38996938714519125
464	0.38046102886567557
463	0.37285584184602133
462	0.36115551974250237
461	0.35251899066066661
460	0.3480946684490121
459	0.34094471300859863
458	0.3311064487755519
457	0.32300356763751631
456	0.31390060103949052
455	0.3100176537866019
454	0.30192729743069596
453	0.29491233935333194
452	0.28997711141570598
451	0.28230417653181683
450	0.27694144485099614
449	0.27096687073498354
448	0.26468406983174453
447	0.26256656160623298
446	0.26050259670959464
445	0.25516071692205605
444	0.25159869233980536
443	0.24609389584798821
442	0.24203177589644606
441	0.24020784651921337
440	0.23906227745562406
439	0.2355838581638531
438	0.23259866481952987
437	0.2294653524092122
436	0.22740071622373775
435	0.22547568251349173
434	0.22223083617084122
433	0.22005269916153336
432	0.21811285977317318
431	0.21741475157209075
430	0.21551255430524435
429	0.2124171921865779
428	0.20949175166662798
427	0.20965546667443197
426	0.20867740127673434
425	0.2087957567831186
424	0.20866494294806162
423	0.20821819177858517
422	0.20834207427489679
421	0.20938722577479901
420	0.21149196438470641
419	0.21399618091826975
418	0.21725531504935078
417	0.21584657892531575
416	0.21822101541251118
415	0.2187812396305118
414	0.22194603470930169
413	0.2228965858004523
412	0.22295036267906412
411	0.22770767192645175
410	0.23011806794737083
409	0.23119613590748495
408	0.23298758484052498
407	0.23427722719582483
406	0.23716731423837079
405	0.24077584624978077
404	0.24699420238395747
403	0.25007111113585545
402	0.25657799457316122
401	0.26084665441013027
400	0.26436668958797022

*Figura 50 - spettro UV-Visibile e di emissione del prodotto2 in THF* In seguito all’alchilazione si osserva uno spostamento batocromico del massimo di assorbimento, passando da 531 nm nel caso del prodotto **1** a 541 nm del prodotto **2**. Tale fenomeno è riconducibile all'effetto induttivo elettron-donatore delle catene alifatiche, le quali arricchiscono la densità elettronica sugli atomi di azoto determinando una destabilizzazione energetica dell'orbitale HOMO e un conseguente restringimento del bandgap ottico. Lo Stokes shift, invece, è simile per entrambi i fluorofori e vale circa 14 nm.

Prodotto	λ_{max, abs}(nm)		λ_{max, ex}(nm)	Stokes shift (nm)	ε (M^-1cm^-1)
1		531	542	11	28000⁵¹
2		541	555	14	13218

*Tabella 5 - dati spettroscopici dei fluorofori sintetizzati* Inoltre, è stato possibile calcolare il coefficiente di estinzione molare ε (M^-1 cm^-1) del prodotto 2 mediante una retta di calibrazione ottenuta valutando l’assorbanza per via spettrofotometrica di diverse soluzioni di fluoroforo in cloroformio (CHCl₃) a concentrazione nota. La pendenza della curva, secondo la legge di Lambert-Beer, rappresenta graficamente la ε; il valore calcolato risulta essere di 13218 M^-1 cm^-1 (Figura 51).

Concentrazione (mol/L)	Series1
9.9999999999999995E-7	1.9810000000000001E-2
4.9999999999999996E-6	5.8220000000000001E-2
1.0000000000000001E-5	0.15620000000000001
5.0000000000000002E-5	0.66590000000000005

Figura 51 - retta di calibrazione del fluoroforo 2 per il calcolo di ε ## **4.2. Copolimeri coniugati** Successivamente alla sintesi e alla caratterizzazione fotofisica del fluoroforo dichetopirrolopirrolico **2**, l'attenzione è stata rivolta alla sua integrazione in sistemi polimerici coniugati. In tale ottica, si è proceduto alla sintesi di copolimeri statistici, facendo reagire questo monomero con il 3-esiltiofene (3HT). La scelta del 3HT come comonomero è stata guidata dalla collaborazione con il gruppo di ricerca del Prof. Lanzi. L'esperienza pregressa di tale gruppo ha infatti ampiamente convalidato l'efficacia e la versatilità della polimerizzazione ossidativa applicata a questa classe di derivati tiofenici. La scelta di questa specifica via sintetica, inoltre, si giustifica alla luce di diversi vantaggi operativi: a differenza dei tradizionali e più complessi metodi di *cross-coupling* catalizzati da metalli di transizione, la polimerizzazione ossidativa diretta non richiede la pre-funzionalizzazione dei monomeri, diminuendo drasticamente gli step sintetici. Inoltre, richiedendo condizioni termodinamiche blande, temperatura ambiente e pressione atmosferica, il processo si distingue per una notevole semplicità esecutivo ed un basso costo energetico. Tali caratteristiche le conferiscono un grande potenziale di scale-up, aspetto di notevole rilevanza nell’ambito di ricerca di questa tesi. Sotto il profilo strutturale e funzionale, la selezione del 3HT è motivata dalle note proprietà elettroniche dei politiofeni, classificati in letteratura tra i più efficienti polimeri semiconduttori organici.⁵² L'inserimento di questa unità nella catena polimerica persegue quindi un duplice obiettivo: da un lato, la presenza della catena esilica assicura l'aumento di solubilità del materiale finale nei comuni solventi organici, requisito fondamentale per la successiva processabilità del polimero; dall'altro lato, l'anello tiofenico contribuisce attivamente all'estensione del sistema π-coniugato, agendo in sinergia con gli altri moduli strutturali della catena per modulare il band gap del materiale e ottimizzare le prestazioni di trasporto di carica del polimero semiconduttore. La reazione di polimerizzazione ossidativa del fluoroforo **2** con il 3HT è stata effettuata secondo lo schema di reazione riportato in **Figura 52**. ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 52 - schema di reazione dei copolimeri coniugati* Il primo stadio del meccanismo di polimerizzazione ossidativa è governato dalla reattività del tricloruro ferrico (FeCl₃). In questo caso, il sale inorganico funge da agente ossidante ed è impiegato in eccesso stechiometrico rispetto ai reagenti. Il centro metallico Fe³⁺ promuove l'attivazione dei monomeri attraverso un processo di trasferimento mono-elettronico (Single Electron Transfer, SET)⁵³. Durante questa fase, il ferro estrae un elettrone dagli anelli tiofenici dei monomeri, elettron-ricchi di natura, riducendosi a Fe²⁺. Questa reazione redox porta alla generazione di cationi radicalici fortemente delocalizzati sul sistema π-coniugato dei dichetopirrolopirroli e dei derivati tiofenici. Questi intermedi, altamente reattivi, rappresentano i veri centri attivi della polimerizzazione, che tendono a legarsi per formare i nuovi legami carbonio-carbonio necessari all'accrescimento della catena (Figura 53). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 53 - meccanismo di polimerizzazione ossidativa mediante tricloruro ferrico* Per garantire l'efficienza e il controllo di questa propagazione radicalica, l'impiego del nitrometano (CH₃NO₂) all'interno della miscela di solventi risulta determinante. Allo stato solido e in solventi non coordinanti come il cloroformio, il FeCl₃ tende a formare dimeri o aggregati, nei quali i siti attivi per l'ossidazione sono limitati alla superficie o ai difetti strutturali dei cluster. L'introduzione del nitrometano nella miscela di reazione risolve questa criticità: agendo come legante, esso rompe i ponti alogeno intermolecolari, spezzando i dimeri e solvatando il cloruro ferrico. La formazione di questi complessi di coordinazione con il nitrometano attiva di fatto il sistema, generando una soluzione omogenea di centri metallici discreti e stericamente accessibili per il trasferimento elettronico. Parallelamente, la coordinazione del ferro con il nitrometano ne modera sensibilmente sia la forte acidità di Lewis che il potenziale ossidante. Questa azione attenuatrice è essenziale per indirizzare la cinetica di reazione: controllando la forza dell'ossidante, si prevengono reazioni secondarie come l'iper-ossidazione della catena o l'insorgere di difetti di reticolazione (cross-linking). Di conseguenza si migliora la regioselettività della polimerizzazione, massimizzando la regolarità strutturale e l'estensione della π-coniugazione nel copolimero semiconduttore 3 sintetizzato. Come solvente di reazione, invece, è stato scelto di utilizzare il cloroformio anidro, necessario per prevenire reazioni secondarie indotte dall'umidità. L'acqua, agendo come nucleofilo e base di Lewis, potrebbe interferire con il processo di polimerizzazione attraverso due meccanismi competitivi. In primo luogo, si potrebbe coordinare al FeCl₃ formando specie idrate stabili; ciò saturerebbe la sfera di coordinazione del metallo, riducendone il potenziale ossidativo e inibendo l'innesco della reazione. In secondo luogo, l'acqua potrebbe causare il quenching degli intermedi cationico-radicalici in propagazione. Questo attacco nucleofilo porterebbe alla terminazione prematura della catena polimerica e all'introduzione di difetti strutturali, i quali interromperebbero la coniugazione della catena compromettendo le proprietà semiconduttrici del copolimero 3. Una volta completato il tempo di reazione, l'isolamento del materiale polimerico ha richiesto un accurato work-up, mirato non solo al recupero del prodotto, ma soprattutto alla completa rimozione delle impurità inorganiche e delle frazioni a basso peso molecolare. Inizialmente sono stati effettuati lavaggi con acido cloridrico, in questo modo si mantengono i sali di ferro disciolti nella fase acquosa, evitando che precipitino sotto forma di idrossidi insolubili all’interfaccia. La completa rimozione dell’ossidante inorganico è un requisito fondamentale per mantenere l’elettronica del copolimero realizzato: tracce di metalli di transizione all’interno del backbone polimerico abbatterebbero la mobilità dei portatori di carica e spegnerebbero la fluorescenza del materiale. Per monitorare l'efficacia dell'estrazione, le acque di lavaggio sono state sottoposte al saggio del tiocianato. L'aggiunta dello ione SCN^- genera, in presenza di ioni Fe³⁺, un complesso di coordinazione caratterizzato da un'intensa colorazione rossa. I lavaggi acidi sono stati ripetuti fino all'ottenimento di un saggio negativo (soluzione incolore), a riprova della totale purificazione del sistema organico dai residui inorganici. L'ultimo lavaggio con una soluzione acquosa mezza satura di cloruro di sodio (NaCl) sfrutta l'elevata forza ionica del sale per massimizzare l'effetto di salting-out: l'ambiente acquoso salino favorisce l'estrazione dell'acqua parzialmente disciolta nel solvente organico. Questa azione di pre-anidrificazione trascina nella fase acquosa anche le ultimissime tracce di impurità idrosolubili, come l'HCl residuo, garantendo l'isolamento di una fase organica di elevata purezza. Dopo aver isolato e anidrificato la fase organica, e rimosso il solvente, è stata necessaria una purificazione del solido grezzo. Al fine di allontanare i sottoprodotti di sintesi, primo fra tutti l'omopolimero del 3-esiltiofene, si è ricorsi a una purificazione mediante precipitazione selettiva in un sistema solvente/non-solvente. Il grezzo di reazione è stato solubilizzato nel minor volume possibile di THF e fatto gocciolare in un ampio eccesso di metanolo freddo. In queste condizioni, il copolimero d'interesse mantiene un'affinità sufficiente con la miscela, rimanendo disciolto nella fase liquida. Al contrario, la frazione contenente l’omopolimero (poli-3HT) risulta insolubile nel non-solvente, portando ad una precipitazione. La fase liquida contenente il copolimero purificato, è stata infine portata a secco, permettendo di isolare il materiale d'interesse idoneo per le successive caratterizzazioni. Al fine di indagare la relazione struttura-proprietà e di valutare l'incidenza del core fluorescente sulle caratteristiche finali del materiale, la reazione di polimerizzazione è stata condotta variando il rapporto stechiometrico tra i due monomeri. Nello specifico, sono stati sintetizzati tre differenti copolimeri, modulando la frazione molare del derivato dichetopirrolopirrolico (**2**) rispetto al 3-esiltiofene (**Tabella 6**). L'obiettivo era prepare una serie di materiali per studiare l'andamento delle proprietà al variare dell'architettura macromolecolare, ipotizzando di passare da un sistema a maggioranza tiofenica fino a uno equimolare o dominato dal DPP. Tuttavia, specifiche problematiche di reazione hanno limitato l'integrazione del monomero DPP a un massimo del 35%. Tale discrepanza è riconducibile ad una differenza nei rapporti di reattività dei due comonomeri, fortemente influenzata dall'ingombro sterico del nucleo DPP. Quest'ultimo, infatti, risulta svantaggiato nell'accoppiamento rispetto al derivato tiofenico, la cui maggiore reattività e minor volume ne favoriscono l’addizione preferenziale. Si è quindi ottenuta una libreria di materiali in cui si passa da un backbone con minime quantità di DPP (copolimero 3a), a uno in cui la sua percentuale aumenta (copolimero 3b), fino a giungere al sistema maggiormente arricchito (copolimero 3c), mantenendo però in tutti i casi un rapporto molare a favore delle unità di 3-esiltiofene.

Copolimero	moli DPP 2	moli 3HT	% DPP teorica (mol/mol)	% DPP reale (mol/mol)
3a	0.2	0.8	20	25.2
3b	0.5	0.5	50	32.6
3c	0.8	0.2	80	35.3

*Tabella 6 - composizione dei copolimeri coniugati* La composizione percentuale reale delle unità di DPP all'interno dei copolimeri è stata determinata mediante spettroscopia ¹H-NMR (**Figura 54**, **Figura 55**, **Figura 56**). L'analisi quantitativa si è basata sull'integrazione di due segnali: il picco relativo ai protoni del gruppo metilico (CH₃) del 3-esiltiofene e quello corrispondente ai protoni dei gruppi metilenici (CH₂) adiacenti alle funzioni idrossiliche del DPP. I valori delle aree ottenute sono stati normalizzati rispetto al numero di protoni magneticamente equivalenti. La percentuale molare di DPP nel copolimero è stata calcolata mediante l’**Equazione 9**. $$ \%DPP=\frac{\frac{A_{DPP}}{n_{DPP}}}{\frac{A_{DPP}}{n_{DPP}}+\frac{A_{3HT}}{n_{3HT}}}\times 100 $$ Equazione 9 - calcolo della percentuale di DPP nei copolimeri dagli spettri ¹H-NMR dove $A_{DPP}$ e $A_{3HT}$ rappresentano i valori delle aree integrate per i rispettivi segnali, mentre $n_{DPP}$ e $n_{3HT}$ indicano il numero di protoni magneticamente equivalenti che generano il segnale. La percentuale reale di DPP 2 presente nei tre copolimeri è riportata in **Tabella 6**. ![](immagini/dec925e1492a9c3c3e5aa39b3529b88ec72ca6de9cd925a787cad12199f30167.png) Figura 54 - Spettro ¹H-NMR del copolimero 3a in CDCl₃ ![](immagini/8b16419f042a8c9093868c26dde981bbd3b916bc37d4f110d9975493fa54977f.png) Figura 55 - Spettro ¹H-NMR del copolimero 3b in CDCl₃ ![](immagini/d89d66a28dc9ad9520ea6c139728786591c52e8edfc43669b6b14ee5347aeece.png) Figura 56 - Spettro ¹H-NMR del copolimero 3c in CDCl₃ In seguito all’analisi strutturale effettuata tramite spettroscopia NMR, i copolimeri sintetizzati sono stati caratterizzati mediante spettroscopia FT-IR, UV-Vis e di emissione, mentre la distribuzione dei pesi molecolari e il comportamento termico sono stati valutati rispettivamente tramite Cromatografia a Permeazione di Gel (GPC) e Calorimetria a Scansione Differenziale (DSC). ![](immagini/979f160dc1f93431a828dae823800239399ea6eb43ccdb12ebb1036bfe071e0e.png) *Figura 57 - spettro FT-IR dei copolimeri 3a (blu), 3b (verde), 3c (rosso)* L'analisi FT-IR (**Figura 57**) conferma l'avvenuta copolimerizzazione per i campioni **3a** (traccia verde), **3b** (traccia rossa) e **3c** (traccia blu). Tutti gli spettri mostrano gli stretching dei legami C-H alifatici (\~2920 e \~2850 cm⁻¹) e il segnale a \~820 cm⁻¹ caratteristico dell'anello del 3-esiltiofene. L'incorporazione del DPP è provata dall'intenso picco del carbonile lattamico (C=O) a \~1650 cm⁻¹ e dallo stretching C-O a \~1050 cm⁻¹. Come atteso dai dati NMR, la banda degli ossidrili terminali (3300-3400 cm⁻¹) risulta evidente nei polimeri **3b** e **3c**, mentre a minore intensità nel **3a**, confermando il minor contenuto di unità DPP in quest'ultimo campione. La caratterizzazione foto-fisica dei copolimeri sintetizzati è stata effettuata combinando spettroscopia di assorbimento (UV-Vis) ed emissione (**Figura 58**, **Figura 59**, **Figura 60**).

UV-Visibile X	UV-Visibile Y	Emissione X	Emissione Y
700	4.9098937286178687E-2	504.92001340000002	-1.2678678855713818E-2
699	5.1249626950878771E-2	505.97000120000001	-1.8844468957529621E-2
698	5.1879430772832413E-2	506.85998540000003	-2.2547852759309095E-2
697	5.2579595390031326E-2	507.9100037	-2.3138905564867859E-2
696	5.2177482518068218E-2	508.9500122	-2.2403132047543434E-2
695	5.2867257740675598E-2	509.85000609999997	-1.997970448167833E-2
694	5.4013911143591394E-2	510.89001459999997	-1.6765936465308752E-2
693	5.4486262934556461E-2	511.94000240000003	-1.2307685335295269E-2
692	5.4848255319458063E-2	512.97998050000001	-9.3127981721869667E-3
691	5.6601182305834288E-2	513.88000490000002	-5.6241982722040141E-3
690	5.6842877855508178E-2	514.91998290000004	2.0627448681398361E-3
689	5.6863958815068193E-2	515.96997069999998	9.081851218941641E-3
688	5.7496409818110078E-2	516.85998540000003	1.7529065971830363E-2
687	5.9047288002046186E-2	517.9099731	2.8660005490661632E-2
686	6.0088711705376101E-2	518.95001219999995	4.1216162555106871E-2
685	6.1171419219237695E-2	519.84997559999999	5.7322364533830661E-2
684	6.2122294073102866E-2	520.89001459999997	7.3660682012317152E-2
683	6.2669563564611716E-2	521.94000240000003	9.617552559992211E-2
682	6.4324483197368124E-2	522.97998050000001	0.12130649680721313
681	6.5477130928567134E-2	523.88000490000002	0.15353016751909992
680	6.6900303752311083E-2	524.91998290000004	0.17794141154273782
679	6.7534533146059963E-2	525.96997069999998	0.20921914993211194
678	6.8731775293858349E-2	526.85998540000003	0.25035270392860615
677	7.0551960190089788E-2	527.9099731	0.29355943226792369
676	7.1004686719136081E-2	528.95001219999995	0.31751392793006633
675	7.2845553627319398E-2	529.84997559999999	0.3555902172816644
674	7.4002277613124876E-2	530.89001459999997	0.39900121071829936
673	7.5557699256847355E-2	531.94000240000003	0.43858127164122968
672	7.6790161548618521E-2	532.97998050000001	0.47030994372564361
671	7.8164197669563992E-2	533.88000490000002	0.50554189614804823
670	8.0479972155164739E-2	534.91998290000004	0.53908197681833625
669	8.1411549943933154E-2	535.96997069999998	0.58259802987301657
668	8.3787613084456203E-2	536.85998540000003	0.62832851030805237
667	8.4975204590944486E-2	537.9099731	0.66647882138534553
666	8.6523971060511962E-2	538.95001219999995	0.70173028771887513
665	8.8411665107123741E-2	539.84997559999999	0.74491834572096449
664	9.0030877837056225E-2	540.89001459999997	0.80036926940966802
663	9.2286864045450376E-2	541.94000240000003	0.85039511772914322
662	9.404748066375454E-2	542.97998050000001	0.88819480823506336
661	9.5999186086799956E-2	543.88000490000002	0.92205386525915511
660	9.8002914278588177E-2	544.91998290000004	0.95303411903857693
659	0.10080970463326638	545.96997069999998	0.97715269103339397
658	0.10236975459399407	546.85998540000003	0.9919889907765117
657	0.10431411598806169	547.9099731	1
656	0.10682246968762053	548.95001219999995	0.99301817443426288
655	0.10893129375949934	549.84997559999999	0.98814830106529528
654	0.11091465894743216	550.88000490000002	0.9717580473695534
653	0.11384528083328148	551.9099731	0.95500462000668385
652	0.11605765243167897	552.94000240000003	0.93277079312270972
651	0.11892917618214016	553.96997069999998	0.9147618183826739
650	0.12118631972191032	554.84997559999999	0.88833594216435796
649	0.12344280988730574	555.88000490000002	0.86122174614605085
648	0.12638584777945228	556.9099731	0.83757836832090571
647	0.12938682051213474	557.94000240000003	0.80436496435544269
646	0.13200685252556738	558.96997069999998	0.79130465830278207
645	0.13423179798810397	559.84997559999999	0.76291139258575968
644	0.1375756267195625	560.88000490000002	0.73848792562361798
643	0.14050049071397067	561.9099731	0.72732823932817059
642	0.14336593922986787	562.94000240000003	0.69859078675107567
641	0.14612284195957928	563.96997069999998	0.68867261863825946
640	0.14980448219854012	564.84997559999999	0.67468365261662877
639	0.15242587167521027	565.88000490000002	0.66558723836597589
638	0.1551552103080821	566.9099731	0.64839959649613144
637	0.15884913625183977	567.94000240000003	0.63498408105960535
636	0.16180927263164036	568.96997069999998	0.62507804297671998
635	0.1655097564945828	569.84997559999999	0.61348799165852452
634	0.16827308974835636	570.88000490000002	0.61208477025215147
633	0.17194350227772734	571.9099731	0.60238410484184968
632	0.1761140596828325	572.94000240000003	0.59535138473401739
631	0.17909285155085608	573.96997069999998	0.59269762665361136
630	0.18208858900663663	574.84997559999999	0.5882611244942354
629	0.18709892406550091	575.88000490000002	0.57937461856891681
628	0.18956864866721979	576.9099731	0.57715581370159563
627	0.19318698333111628	577.94000240000003	0.57212550305732279
626	0.1980883649803783	578.96997069999998	0.56577429940861235
625	0.20152490884697757	579.84997559999999	0.5624346473821189
624	0.20637095039528436	580.88000490000002	0.5573849281092782
623	0.21062008676968816	581.9099731	0.55270682045464214
622	0.21525849652488047	582.94000240000003	0.55411906049067383
621	0.21963128870620433	583.96997069999998	0.54794564603760265
620	0.22344597083309395	584.84997559999999	0.54798456871555212
619	0.22875435729109614	585.88000490000002	0.54818181928473042
618	0.23356607329196666	586.9099731	0.54710785860287126
617	0.2385810867701742	587.94000240000003	0.54528513708478488
616	0.24306303679933461	588.96997069999998	0.53781814937936467
615	0.24733775823974849	589.84997559999999	0.53800622301484224
614	0.25299195503057914	590.88000490000002	0.53885608808017527
613	0.25768815353792912	591.9099731	0.53304895834886201
612	0.2630208610404613	592.94000240000003	0.52477735723782892
611	0.26769549035130952	593.96997069999998	0.52531578792720901
610	0.27292785237682005	594.84997559999999	0.51769954377431837
609	0.27807632098091467	595.88000490000002	0.51286210621225814
608	0.28323753205244889	596.9099731	0.49667617001316278
607	0.28749615658936883	597.94000240000003	0.48288007714287307
606	0.29253168315950379	598.96997069999998	0.47225644794397459
605	0.29777469451140892	599.84997559999999	0.45301982646482802
604	0.30305688156751309	600.88000490000002	0.4442465550059313
603	0.30731153011183487	601.9099731	0.42594320816226977
602	0.31204407141435625	602.94000240000003	0.41167608728374705
601	0.316226255326503	603.96997069999998	0.39867065784568434
600	0.32065065718883196	604.84997559999999	0.38481636542761249
599	0.32464715786201653	605.88000490000002	0.37385416674263588
598	0.32916645581046433	606.9099731	0.3584594214946078
597	0.33287170369312585	607.94000240000003	0.34470784178531338
596	0.33718773065208985	608.96997069999998	0.33387156172996463
595	0.34056062298759426	609.84997559999999	0.31954410537427669
594	0.3446748123987407	610.85998540000003	0.30833542266441244
593	0.34830974021912703	611.88000490000002	0.29740813838521807
592	0.35226871271591764	612.89001459999997	0.28862550541978599
591	0.35568824297628371	613.9099731	0.2760257580861713
590	0.35935502160527799	614.91998290000004	0.26837599723467032
589	0.3634590191607236	615.94000240000003	0.25692325649207898
588	0.36801778726096884	616.95001219999995	0.25094598503291965
587	0.37216445863925857	617.96997069999998	0.23832980891965921
586	0.37753023456261486	618.97998050000001	0.23294191578258841
585	0.38235399430011408	619.84997559999999	0.22730587718860221
584	0.38678550693241365	620.88000490000002	0.21728801548086332
583	0.39268743762594038	621.9099731	0.21098406759339258
582	0.39997733124520207	622.94000240000003	0.20390456642906116
581	0.40600843254436464	623.96997069999998	0.1989585882882432
580	0.41438668284629809	624.84997559999999	0.19190210847192732
579	0.42207958409863433	625.88000490000002	0.18449709126865033
578	0.43224856798708045	626.9099731	0.17706965911170533
577	0.44092015404907386	627.94000240000003	0.1758389133463065
576	0.45267282593329033	628.96997069999998	0.16773000434081434
575	0.46325246389390451	629.84997559999999	0.16311024119622053
574	0.47676212612981811	630.85998540000003	0.15827925110201302
573	0.48865198033046525	631.88000490000002	0.1524964217324199
572	0.50087158060386694	632.89001459999997	0.14783894890595678
571	0.51567023349539065	633.9099731	0.145246620605329
570	0.52962735007194539	634.91998290000004	0.13906649489042078
569	0.54297198728703211	635.94000240000003	0.1347786031044646
568	0.55585337081643404	636.95001219999995	0.13282164307698524
567	0.56837387557414609	637.96997069999998	0.13025261305275376
566	0.5805482313183572	638.97998050000001	0.12540526012739653
565	0.59306181901015231	639.84997559999999	0.12093198449210746
564	0.60405140435005633	640.84997559999999	0.11886767061315763
563	0.61625625245100724	641.84997559999999	0.11477275733022804
562	0.62684879310028085	642.84997559999999	0.11230956482595622
561	0.6393676423360114	643.84997559999999	0.10785513082807692
560	0.6510629902566526	644.84997559999999	0.10545207602461054
559	0.66464717829630293	645.84997559999999	0.10253659179782999
558	0.67854356092243184	646.84997559999999	9.7356853267648258E-2
557	0.69297605687912456	647.84997559999999	9.598037155693763E-2
556	0.7087164097960319	648.84997559999999	9.1538001986135042E-2
555	0.72605169254617863	649.84997559999999	9.0034929164696173E-2
554	0.74342435859644196	650.85998540000003	8.6053118520324795E-2
553	0.75945676000886764	651.88000490000002	8.3749335075498116E-2
552	0.77897500365835237	652.89001459999997	7.8576545124959443E-2
551	0.80012974257992564	653.9099731	7.5749691805706842E-2
550	0.82238120822600902	654.91998290000004	7.381513339011378E-2
549	0.84794043654785745	655.94000240000003	6.936054115732096E-2
548	0.87333653503191599	656.95001219999995	6.9183121176479956E-2
547	0.89726893921090134	657.96997069999998	6.4667244119256298E-2
546	0.92300524140904283	658.97998050000001	5.9935235348562557E-2
545	0.94585223204727586	659.84997559999999	5.8010473561322232E-2
544	0.9650138195537612	660.84997559999999	5.5020311642521573E-2
543	0.97894764212338381	661.84997559999999	5.211932450586905E-2
542	0.98954860188403904	662.84997559999999	4.9193338236864399E-2
541	0.99634000628441255	663.84997559999999	4.459289135837971E-2
540	1	664.84997559999999	4.3797362530921605E-2
539	0.99893919859948288	665.84997559999999	4.1866133401412826E-2
538	0.99528010042086024	666.84997559999999	3.9099424308686855E-2
537	0.99335414298785363	667.84997559999999	3.6292869542492785E-2
536	0.98820649583713327	668.84997559999999	3.3183200300849577E-2
535	0.98163335182223499	669.84997559999999	3.2681338764562973E-2
534	0.97751818015094971	670.85998540000003	2.9548588835083444E-2
533	0.97476722358865209	671.88000490000002	2.5725936694262021E-2
532	0.96867229819134681	672.89001459999997	2.4077206989665416E-2
531	0.96130690460863344	673.9099731	2.2801631531228574E-2
530	0.95649482595488455	674.91998290000004	2.1733861366949665E-2
529	0.95196940833612786	675.94000240000003	1.8834713564269041E-2
528	0.94798030413785761	676.95001219999995	1.6216657663095477E-2
527	0.94057717206347857	677.96997069999998	1.5014131494201678E-2
526	0.93379328855079913	678.97998050000001	1.1849150350235076E-2
525	0.92862075314260406	679.84997559999999	1.1203959138463917E-2
524	0.92041839311402296	680.84997559999999	9.5717570809544846E-3
523	0.9105488411253313	681.84997559999999	9.1705678111245852E-3
522	0.90091738332554216	682.84997559999999	7.8519921359114439E-3
521	0.89195931017479879	683.84997559999999	5.0225247966258811E-3
520	0.88204692815293351	684.84997559999999	3.7449979311770134E-3
519	0.87460775673085722	685.84997559999999	4.5341780842563994E-3
518	0.86653279780461456	686.84997559999999	3.4093259040255614E-3
517	0.85847836933119848	687.84997559999999	3.6177311186560996E-3
516	0.85138309211156094	688.84997559999999	2.4597544287465402E-3
515	0.84347848207932008	689.84997559999999	-2.4801024832716092E-4
514	0.83755289401953059	690.97998050000001	-7.7879351519313182E-4
513	0.83324897965541067	691.96997069999998	2.0183239417156178E-5
512	0.82808333923086108	692.95001219999995	-2.1549555395321291E-3
511	0.82492779248741943	693.94000240000003	-1.5479783186092889E-3
510	0.82069927683837229	694.91998290000004	-2.8747057450171703E-3
509	0.81939333010423765	695.9099731	-2.4789883338942353E-3
508	0.81757618301569335	696.90002440000001	-3.9315289048266113E-3
507	0.8155781622851016	697.88000490000002	-3.6408315827458288E-3
506	0.81314596521490468	698.86999509999998	-4.736623590673639E-3
505	0.8109004614107842	699.84997559999999	-6.3596850096590178E-3
504	0.80930340478607166	700.84997559999999	0
503	0.80500732072508852
502	0.8006513515802115
501	0.79437570565629867
500	0.78569614956547673
499	0.77705481515722008
498	0.76711473631378424
497	0.75773590604513719
496	0.7470461074589767
495	0.73460319130162244
494	0.72135909271645171
493	0.70817987739374821
492	0.69917901847406716
491	0.68890162743366312
490	0.6738358481775395
489	0.66004801005605629
488	0.64910722695559886
487	0.63780334755245605
486	0.62240934846295337
485	0.60841496178403565
484	0.59975905425020293
483	0.58880016841954985
482	0.57529800662852493
481	0.56304492605357681
480	0.55038170394384156
479	0.53931892128195014
478	0.52875995467513071
477	0.51894039670281544
476	0.50846787794149684
475	0.49870430117101666
474	0.49024755236550022
473	0.48189411394433357
472	0.47402540228807699
471	0.46601100867416267
470	0.45818711487969954
469	0.45037153371600386
468	0.4425036357279481
467	0.43577119940721326
466	0.42799165890134877
465	0.42063498688439122
464	0.41240105578254216
463	0.40430582401501286
462	0.39659561644645114
461	0.38938705784175659
460	0.38352300237024511
459	0.37695673324914486
458	0.36906988164534749
457	0.36199259691159624
456	0.35437754485792072
455	0.34786198138345847
454	0.3413166341102063
453	0.33532101591629776
452	0.32943454651388737
451	0.32322856654244764
450	0.31662773622419765
449	0.31130891454843068
448	0.30618880565542411
447	0.30171877449982737
446	0.29754042043664297
445	0.29326989329174807
444	0.28911179551927552
443	0.28469839655457513
442	0.28111043774313782
441	0.27817747020598421
440	0.27547533862651347
439	0.27281886333565181
438	0.26993401587873977
437	0.26773813724899276
436	0.2648681354989123
435	0.26237023109669255
434	0.26067603733912736
433	0.25967126746171021
432	0.25795937855477352
431	0.25630949602538894
430	0.25563865057520235
429	0.25419495706125933
428	0.2534785352079858
427	0.25274238463730342
426	0.25273109900008189
425	0.25269781833323818
424	0.25389910889876971
423	0.25424682524410636
422	0.25517946131242947
421	0.25723705715117595
420	0.25869102929789745
419	0.26062570339442237
418	0.26334940097997606
417	0.26591076549367909
416	0.26888432005086738
415	0.27226854889633828
414	0.2760608203017394
413	0.27931415660199277
412	0.28344058435592584
411	0.28767173934298468
410	0.29180818555651333
409	0.2955713415772529
408	0.30080596409225152
407	0.3053764731771636
406	0.31096739997723033
405	0.31680954149958823
404	0.32373486960269171
403	0.330315583199568
402	0.33586286618551425
401	0.34313988574706733
400	0.35102449325540691

Figura 58 - spettro UV-Visibile e di emissione del copolimero 3a in THF

UV-Visibile X	UV-Visibile Y	Emissione X	Emissione Y
750	9.417571988463682E-3	505.97000120000001	-1.3353837885542091E-2
749	9.7848519924912773E-3	506.85998540000003	-2.0883138137458165E-2
748	9.6102655675598409E-3	507.9100037	-2.6469533696026636E-2
747	9.9666740205747086E-3	508.9500122	-2.6322557747142875E-2
746	1.0488231829241553E-2	509.85000609999997	-2.5813926248611663E-2
745	1.0515415447601819E-2	510.89001459999997	-2.3188920555752345E-2
744	1.1153178735064589E-2	511.94000240000003	-2.0767090798315065E-2
743	1.2006438086825878E-2	512.97998050000001	-1.6975165320439363E-2
742	1.185672940089043E-2	513.88000490000002	-1.3365178968158583E-2
741	1.1941981998751934E-2	514.91998290000004	-7.7856702189445567E-3
740	1.2743051322230119E-2	515.96997069999998	-3.2702252806279396E-3
739	1.2637647434887725E-2	516.85998540000003	3.2483263780822861E-3
738	1.2873898250015703E-2	517.9099731	1.2895506769675593E-2
737	1.3534725419658399E-2	518.95001219999995	2.4506967588403851E-2
736	1.4057865220140769E-2	519.84997559999999	3.3614871613261793E-2
735	1.3659817433345243E-2	520.89001459999997	4.6725655031552238E-2
734	1.4083101278460996E-2	521.94000240000003	6.3783555259992894E-2
733	1.4712398496840879E-2	522.97998050000001	8.6907022969798853E-2
732	1.5143684000993474E-2	523.88000490000002	0.10655209721311136
731	1.5436356772983807E-2	524.91998290000004	0.13265022151792477
730	1.5961524874147152E-2	525.96997069999998	0.16042090297825698
729	1.5911180955824999E-2	526.85998540000003	0.1890427597693416
728	1.6198554181948599E-2	527.9099731	0.22352891154971441
727	1.6097329887115187E-2	528.95001219999995	0.25992872411512041
726	1.6085455443321562E-2	529.84997559999999	0.2943050769856787
725	1.6798530057782014E-2	530.89001459999997	0.32499080410250247
724	1.7311082532390668E-2	531.94000240000003	0.36714792653373546
723	1.7967996418736903E-2	532.97998050000001	0.40610545056295738
722	1.870688582146033E-2	533.88000490000002	0.43626766124276273
721	1.8901604617813882E-2	534.91998290000004	0.46805438092083207
720	1.9830293228236224E-2	535.96997069999998	0.50562867698484981
719	2.0448991470488675E-2	536.85998540000003	0.54970417757338175
718	2.1479796342484158E-2	537.9099731	0.59332114020541438
717	2.2015987737778669E-2	538.95001219999995	0.64287526190104938
716	2.2115724527376642E-2	539.84997559999999	0.67585055812199868
715	2.3051443623216306E-2	540.89001459999997	0.72286125051695971
714	2.3351590314960684E-2	541.94000240000003	0.7828559081908063
713	2.393846997639958E-2	542.97998050000001	0.83717464542304709
712	2.5028142274824902E-2	543.88000490000002	0.88039658199353499
711	2.5108716803385719E-2	544.91998290000004	0.9196097166381455
710	2.5928109750027246E-2	545.96997069999998	0.94528557537902136
709	2.640964104688177E-2	546.85998540000003	0.97675236809419241
708	2.6983645640553663E-2	547.9099731	0.9908343466457108
707	2.7832649800706457E-2	548.95001219999995	1
706	2.8231415493474726E-2	549.84997559999999	1.00001588945662
705	2.8815790534592423E-2	550.88000490000002	0.99371070834956476
704	2.9360230005080971E-2	551.9099731	0.97747242813404833
703	3.0127587033408131E-2	552.94000240000003	0.96650279519338322
702	3.0895164003068222E-2	553.96997069999998	0.94554104392280769
701	3.1393226600984106E-2	554.84997559999999	0.92507509651073649
700	3.1828449401604689E-2	555.88000490000002	0.90113700963402976
699	3.2414655285077011E-2	556.9099731	0.87563527786580642
698	3.2819260169811501E-2	557.94000240000003	0.84855013329387707
697	3.3605320283776309E-2	558.96997069999998	0.82776345490025327
696	3.4754051151850596E-2	559.84997559999999	0.81319569870388553
695	3.5119990870076237E-2	560.88000490000002	0.7840167249219433
694	3.6057008972139357E-2	561.9099731	0.76412565239727692
693	3.6537332057728009E-2	562.94000240000003	0.74093874308448726
692	3.7619612831081707E-2	563.96997069999998	0.72188870159384566
691	3.8313943031815456E-2	564.84997559999999	0.70315565519667633
690	3.9054413027321148E-2	565.88000490000002	0.68158143213217193
689	3.9962565618948044E-2	566.9099731	0.6718585909371817
688	4.1046037757094429E-2	567.94000240000003	0.64937835829614754
687	4.1700251484876959E-2	568.96997069999998	0.65052096729931541
686	4.2458713599011655E-2	569.84997559999999	0.6341879621445653
685	4.3296525280474736E-2	570.88000490000002	0.62032045034674754
684	4.4432732007535079E-2	571.9099731	0.61114737300739985
683	4.559729004686805E-2	572.94000240000003	0.60716354022763952
682	4.6155589901254256E-2	573.96997069999998	0.59875180793165006
681	4.7131922129297614E-2	574.84997559999999	0.58975560043947906
680	4.8398604616453234E-2	575.88000490000002	0.58276289567307771
679	4.9319130944343072E-2	576.9099731	0.57727003969804758
678	5.0522438232170785E-2	577.94000240000003	0.57497602546357507
677	5.1528385822670844E-2	578.96997069999998	0.5721941524708235
676	5.284581738964185E-2	579.84997559999999	0.57050201670794654
675	5.3990166073096715E-2	580.88000490000002	0.56864998846842851
674	5.5438602367701373E-2	581.9099731	0.55936501932852223
673	5.6476574668318132E-2	582.94000240000003	0.55930193247064364
672	5.7864329267268498E-2	583.96997069999998	0.56259110094338782
671	5.9266384521816533E-2	584.84997559999999	0.56078031090804425
670	6.080922862878519E-2	585.88000490000002	0.56090104598401125
669	6.1775113689456269E-2	586.9099731	0.55290959285293106
668	6.3467230098191371E-2	587.94000240000003	0.55601602711978781
667	6.5149642760900711E-2	588.96997069999998	0.55473712415465082
666	6.6253414560562968E-2	589.84997559999999	0.55713565250806429
665	6.768274113713342E-2	590.88000490000002	0.55606823688404339
664	6.9589071494233698E-2	591.9099731	0.55467209837891662
663	7.1527243384244529E-2	592.94000240000003	0.55307657905394214
662	7.298813433763475E-2	593.96997069999998	0.55516057185101853
661	7.4936543814985504E-2	594.84997559999999	0.54834029180144694
660	7.6564592533641659E-2	595.88000490000002	0.5383149275388307
659	7.7941509034126527E-2	596.9099731	0.52792333814100034
658	8.0158292900796568E-2	597.94000240000003	0.52020139905481599
657	8.2070236523270973E-2	598.96997069999998	0.50712204676567341
656	8.4127141512085182E-2	599.84997559999999	0.49661866034367197
655	8.6339054808122706E-2	600.88000490000002	0.48122231014317968
654	8.8602419602850313E-2	601.9099731	0.47289139892301552
653	9.0883661711633465E-2	602.94000240000003	0.45882810043175715
652	9.2979754584957747E-2	603.96997069999998	0.44153129553475823
651	9.5401059299322258E-2	604.84997559999999	0.4269039044733306
650	9.7830599189705186E-2	605.88000490000002	0.41625367812422748
649	0.10012322661811038	606.9099731	0.40482564905072205
648	0.1029640927250642	607.94000240000003	0.38596117947886505
647	0.10553434231165436	608.96997069999998	0.37730249115792241
646	0.10845778890439761	609.84997559999999	0.36430736489015242
645	0.11124727300883142	610.85998540000003	0.35721113914233826
644	0.11407488311803372	611.88000490000002	0.34360756098795292
643	0.11677002385877129	612.89001459999997	0.33183780384100331
642	0.12002763118792277	613.9099731	0.32344418412468023
641	0.12307970401704697	614.91998290000004	0.31013579927137686
640	0.12593985509697608	615.94000240000003	0.30462577643502176
639	0.12894766029884167	616.95001219999995	0.29081761542104478
638	0.13241316283050283	617.96997069999998	0.28488986711344438
637	0.13576297394095291	618.97998050000001	0.27656311750028101
636	0.13897531951156689	619.84997559999999	0.26894526700007487
635	0.14213613520141311	620.88000490000002	0.26420732460101382
634	0.14595915037268703	621.9099731	0.2515187416181125
633	0.14882968188396464	622.94000240000003	0.24517350425335568
632	0.15258730050686886	623.96997069999998	0.23925715322475694
631	0.15654260450637092	624.84997559999999	0.23421985585562741
630	0.1604256174176481	625.88000490000002	0.22415131447098133
629	0.16412426419688925	626.9099731	0.22045657440546101
628	0.1679305311772121	627.94000240000003	0.21154038409443277
627	0.17142120477434408	628.96997069999998	0.20839663681631343
626	0.17537904062257001	629.84997559999999	0.20366101169682754
625	0.17906927106856155	630.85998540000003	0.19677519752544342
624	0.18386640181073433	631.88000490000002	0.1904555448884287
623	0.18715390613296398	632.89001459999997	0.18605547634371541
622	0.19173497086229108	633.9099731	0.18070085324850998
621	0.19540448745118044	634.91998290000004	0.17894719130786199
620	0.19972292787615778	635.94000240000003	0.1706006266112656
619	0.20384883543071117	636.95001219999995	0.16966697487216448
618	0.20828076410540095	637.96997069999998	0.16280616604664283
617	0.21250026714961315	638.97998050000001	0.15989719729839294
616	0.21717440903225485	639.84997559999999	0.15778809266373814
615	0.22117535559185253	640.84997559999999	0.15076894020238296
614	0.22565598670900072	641.84997559999999	0.14700766110020766
613	0.22990288854912108	642.84997559999999	0.14267197987681954
612	0.23471931560187267	643.84997559999999	0.13859824602180748
611	0.23924396552855348	644.84997559999999	0.13302302013014455
610	0.24347206083161316	645.84997559999999	0.13329165930654255
609	0.24783539585603925	646.84997559999999	0.12634537110545901
608	0.25273975743083033	647.84997559999999	0.12428956396301784
607	0.257656369409271	648.84997559999999	0.12146097885634438
606	0.26234114452920321	649.84997559999999	0.11463469281036061
605	0.2663338009988005	650.85998540000003	0.11271040324707943
604	0.27033762700824654	651.88000490000002	0.10746864122540271
603	0.27530047845855132	652.89001459999997	0.10515043744103636
602	0.27991693649782362	653.9099731	0.10290656394463346
601	0.28440255873382358	654.91998290000004	9.6955855638756222E-2
600	0.2885674651171326	655.94000240000003	9.2966584405163311E-2
599	0.29384380477929689	656.95001219999995	9.1050913666473471E-2
598	0.29861149652610286	657.96997069999998	8.6804766995917784E-2
597	0.30203210838080374	658.97998050000001	8.2328098116895024E-2
596	0.30629036139588817	659.84997559999999	7.9961846175273812E-2
595	0.31071525348905704	660.84997559999999	7.7647224678014382E-2
594	0.31482289866112817	661.84997559999999	7.3157787082728035E-2
593	0.31914645843924166	662.84997559999999	7.0723530014774133E-2
592	0.32324058056327853	663.84997559999999	6.7464557150321888E-2
591	0.32717835477281132	664.84997559999999	6.346178415562656E-2
590	0.33116194427693452	665.84997559999999	5.9456173708374666E-2
589	0.33573137769615397	666.84997559999999	5.8317903690958683E-2
588	0.33934532176137261	667.84997559999999	5.5829356030454511E-2
587	0.34278078318429167	668.84997559999999	5.0017838329405505E-2
586	0.34653886374156051	669.84997559999999	4.8984443033699879E-2
585	0.35094604049282402	670.85998540000003	4.624572945361647E-2
584	0.35459607096216333	671.88000490000002	4.3642777829419228E-2
583	0.35798011971197324	672.89001459999997	4.0631712714691917E-2
582	0.3622998763223293	673.9099731	3.8430188760837397E-2
581	0.3661194509497826	674.91998290000004	3.8004128155708826E-2
580	0.3705963334571663	675.94000240000003	3.5045172326150002E-2
579	0.37551681466107323	676.95001219999995	3.155611466888384E-2
578	0.38002703131198168	677.96997069999998	3.1823199109618672E-2
577	0.38462464681723657	678.97998050000001	2.9098708434190452E-2
576	0.39013059502614489	679.84997559999999	2.612210697688306E-2
575	0.39586194474075209	680.84997559999999	2.4055251368498044E-2
574	0.40166166886309679	681.84997559999999	2.3419559533191813E-2
573	0.4081865882361651	682.84997559999999	2.0223496135469865E-2
572	0.41480159227330099	683.84997559999999	1.8531632261192279E-2
571	0.42287384157383584	684.84997559999999	1.6892569304165654E-2
570	0.43150840963007131	685.84997559999999	1.54018951336439E-2
569	0.44039444376055542	686.84997559999999	1.5125009537532591E-2
568	0.44993884379638194	687.84997559999999	1.4898069634768193E-2
567	0.4595495322443432	688.84997559999999	1.2370725238345211E-2
566	0.46995326185948899	689.84997559999999	1.3859330407475294E-2
565	0.48183256388516588	690.97998050000001	1.1332819522581061E-2
564	0.49412655119535209	691.96997069999998	1.0150698497605882E-2
563	0.50842991760478751	692.95001219999995	1.0779509418413425E-2
562	0.52387506761696423	693.94000240000003	1.0320752682803866E-2
561	0.53906709494622951	694.91998290000004	8.4799679973425798E-3
560	0.55613823276719809	695.9099731	6.9966121817670252E-3
559	0.57611986411672778	696.90002440000001	6.0974211904693178E-3
558	0.5952823461339003	697.88000490000002	5.9101883815086947E-3
557	0.61706602361360352	698.86999509999998	5.4139295145229187E-3
556	0.6384774814487284	699.84997559999999	2.1259078652008791E-3
555	0.66283592742090536	700.84997559999999	2.7316553339428438E-3
554	0.68554880359795556
553	0.70752293044887971
552	0.73275652613443454
551	0.7590536326508861
550	0.78723736498302099
549	0.82023068345760097
548	0.8508241085559104
547	0.87829195227440837
546	0.9073010724146372
545	0.93691049156803086
544	0.96045246322245836
543	0.9787838687999727
542	0.99001464511915194
541	0.99644828324987422
540	0.99981813982067691
539	1.0000000043368862
538	0.99583850648999295
537	0.99074465911318821
536	0.98332417511573922
535	0.97418590797313787
534	0.96521306840973553
533	0.95725479142432801
532	0.94748114896646662
531	0.93779082430121508
530	0.92897215873720129
529	0.9219152878909902
528	0.9147430576132215
527	0.90711324100210922
526	0.89992737181325444
525	0.8931337166278861
524	0.88616151127955545
523	0.87883292578332584
522	0.87207021613552216
521	0.86593190771614714
520	0.86023137342556566
519	0.85539072793993376
518	0.85152863278034285
517	0.84764248011626964
516	0.84544439998607257
515	0.84260032076443225
514	0.84173777908937586
513	0.84130210716614651
512	0.84131973040786945
511	0.84245077614289521
510	0.84325728008983281
509	0.84551403480636012
508	0.84786873696288134
507	0.85006418501942338
506	0.85292878156507523
505	0.85435555916365535
504	0.85537736367313555
503	0.8546495065184504
502	0.85222223807758857
501	0.84766650481187134
500	0.84158789123695033
499	0.83378546788329466
498	0.82426736882812435
497	0.8144936942377009
496	0.80339558536411471
495	0.79112826036205675
494	0.77789399602001308
493	0.76543659062908942
492	0.75464925121337056
491	0.74412139455144821
490	0.73100375200490397
489	0.71841269720548451
488	0.70778162788537546
487	0.69747040964634233
486	0.68591571310340471
485	0.67480006028981832
484	0.66590549546204925
483	0.65658028065289575
482	0.64666564303732765
481	0.6370811710265708
480	0.62797567650711617
479	0.61974201919859251
478	0.61178875861560578
477	0.60425752262408206
476	0.59716597448739273
475	0.59055207639640184
474	0.58430409456187637
473	0.57858128454901925
472	0.57308230596205834
471	0.56732508162015816
470	0.56204029577637094
469	0.5567733484723445
468	0.55129589231640552
467	0.54580161737250577
466	0.54001360611602456
465	0.5341695031671938
464	0.52812825862043178
463	0.52161130113108656
462	0.51548779430791658
461	0.50903056029001559
460	0.50302330494056724
459	0.49730421267889552
458	0.49117750148769124
457	0.48534389812188294
456	0.47966333873636324
455	0.4737126348565649
454	0.46866210521161322
453	0.46331561396210996
452	0.45872746623278504
451	0.45399876274186024
450	0.44921880709986578
449	0.44462235961425017
448	0.44056100641783902
447	0.43683692194455515
446	0.43342510865006106
445	0.43009960501916239
444	0.42681423992475059
443	0.42361360593534181
442	0.42060609369980856
441	0.41801601556549761
440	0.41561034369369365
439	0.41326685837220001
438	0.41109209823347309
437	0.40906844440197726
436	0.40699041742739356
435	0.40502913356223941
434	0.40335724648701016
433	0.40155892910333041
432	0.3999544632238286
431	0.39848579374493809
430	0.39714287771653334
429	0.39606901626485114
428	0.39495207068608762
427	0.39402618846352544
426	0.39300928818194514
425	0.39218498180440087
424	0.391681811455525
423	0.3912825640259267
422	0.39087609077808017
421	0.39068307531476781
420	0.39070126178531445

Figura 59 - spettro UV-Visibile e di emissione del copolimero 3b in THF

UV-Visibile X	UV-Visibile Y	Emissione X	Emissione Y
700	6.8547634768171883E-2	520.89001459999997	-1.2748958024005604E-2
699	6.9705535542605529E-2	521.94000240000003	-6.251101389020141E-3
698	7.011872383987959E-2	522.97998050000001	4.8581182728260142E-3
697	7.0915937753880526E-2	523.88000490000002	1.479581000400342E-2
696	7.2249442062024605E-2	524.91998290000004	2.8641472453585417E-2
695	7.3471490422503324E-2	525.96997069999998	4.1134645539068371E-2
694	7.4775042173274214E-2	526.85998540000003	5.7446155966524394E-2
693	7.4006340388481889E-2	527.9099731	7.6799209421476083E-2
692	7.4331318343943117E-2	528.95001219999995	9.7858120242891436E-2
691	7.6021619378520131E-2	529.84997559999999	0.11611409189695704
690	7.7268002831504506E-2	530.89001459999997	0.14425757805414566
689	7.6997673012224682E-2	531.94000240000003	0.17216154313838689
688	7.8171917710758515E-2	532.97998050000001	0.20299331481627364
687	7.9364859993905565E-2	533.88000490000002	0.22415784965863456
686	7.9522059036584478E-2	534.91998290000004	0.26246009244673901
685	8.1155832544443474E-2	535.96997069999998	0.30215038385012616
684	8.0959450123595816E-2	536.85998540000003	0.34945340950866893
683	8.1958971432771213E-2	537.9099731	0.40475578091448666
682	8.2905765922879099E-2	538.95001219999995	0.45824877867778979
681	8.4263176122421929E-2	539.84997559999999	0.50485204214492196
680	8.4970706848034497E-2	540.89001459999997	0.56832084758665091
679	8.6371448706067819E-2	541.94000240000003	0.64113666098148625
678	8.7751057283193878E-2	542.97998050000001	0.70747784555353121
677	8.865317201031038E-2	543.88000490000002	0.76873148814686187
676	8.9527030917085512E-2	544.91998290000004	0.82110995598062075
675	9.0344695332823008E-2	545.96997069999998	0.87094855584660902
674	9.1310270897718676E-2	546.85998540000003	0.9101431514343411
673	9.2147263804715607E-2	547.9099731	0.94496175351954537
672	9.3604013152603902E-2	548.95001219999995	0.97594604141417785
671	9.4618166899963441E-2	549.84997559999999	0.98256618569524823
670	9.6784631703317803E-2	550.88000490000002	0.99271576972064035
669	9.7733934172774525E-2	551.9099731	0.9992729408057921
668	9.8643025456273389E-2	552.94000240000003	1
667	9.9637957753550319E-2	553.96997069999998	0.98869118049909843
666	0.1007638047057316	554.84997559999999	0.9845763468643226
665	0.10211353611276212	555.88000490000002	0.96430278488898868
664	0.10365138027160167	556.9099731	0.95312532536691263
663	0.10410872616142847	557.94000240000003	0.93538215962858673
662	0.10610863935848946	558.96997069999998	0.91811925873188627
661	0.10771361057745216	559.84997559999999	0.89248762836772022
660	0.10923062515636799	560.88000490000002	0.86593335524335313
659	0.11142716375247266	561.9099731	0.83098183104295698
658	0.11281305835636245	562.94000240000003	0.80790687832531172
657	0.11394977022478149	563.96997069999998	0.78586547459262901
656	0.11571236299630602	564.84997559999999	0.75895506234512833
655	0.11744856179715074	565.88000490000002	0.73377142881536739
654	0.119674410881716	566.9099731	0.71241133755680708
653	0.12139879553719793	567.94000240000003	0.69222276398566673
652	0.12420407403843264	568.96997069999998	0.66952159386871768
651	0.126454008530856	569.84997559999999	0.64537307057348325
650	0.12829567742198963	570.88000490000002	0.62028436616066585
649	0.13079704164591177	571.9099731	0.60702456037590957
648	0.13375977599834479	572.94000240000003	0.59453771719659243
647	0.13523343645373057	573.96997069999998	0.57563953136340129
646	0.13870419742904269	574.84997559999999	0.55802304151413129
645	0.14144732664532175	575.88000490000002	0.5454498047582621
644	0.14345504691500305	576.9099731	0.53426516302432614
643	0.14703390854030646	577.94000240000003	0.53146908068060639
642	0.15007431733126692	578.96997069999998	0.52729163737064089
641	0.15319146794409189	579.84997559999999	0.51514625714561935
640	0.15607073084599316	580.88000490000002	0.51020204452107476
639	0.15966473694117114	581.9099731	0.51126983833202444
638	0.16405005109531257	582.94000240000003	0.50970085748912208
637	0.16657433857007903	583.96997069999998	0.50416849172286216
636	0.17111417961894121	584.84997559999999	0.50574626807566236
635	0.17445975657103102	585.88000490000002	0.51169774691134562
634	0.17868750225348023	586.9099731	0.51157382931853301
633	0.18287162926683612	587.94000240000003	0.51348463738683126
632	0.18548524718614393	588.96997069999998	0.51813740168379285
631	0.19139431153536088	589.84997559999999	0.52108467283764015
630	0.19461182897846549	590.88000490000002	0.52269986904153798
629	0.19823422036030194	591.9099731	0.52851660508868359
628	0.20292782974853657	592.94000240000003	0.52466641659114555
627	0.20726327780221199	593.96997069999998	0.52752864736054117
626	0.21113742243689379	594.84997559999999	0.52555424103713111
625	0.21639326192710859	595.88000490000002	0.51924011722374974
624	0.22049313010463994	596.9099731	0.51826256830354289
623	0.22483675794931354	597.94000240000003	0.51118198746642463
622	0.22994583752756259	598.96997069999998	0.49541775579121095
621	0.23387196571679514	599.84997559999999	0.4910448860156913
620	0.23958890073942768	600.88000490000002	0.47653841000475294
619	0.24444350628881564	601.9099731	0.46923986741836232
618	0.24756668219252534	602.94000240000003	0.45492043881908545
617	0.25277732011864029	603.96997069999998	0.44330403725985285
616	0.25793271792643668	604.84997559999999	0.43374619765264494
615	0.26324703733182431	605.88000490000002	0.41835215743808962
614	0.26714190869451621	606.9099731	0.4062890593012764
613	0.27170106171693775	607.94000240000003	0.39178107402103224
612	0.27580292499403469	608.96997069999998	0.377061398389194
611	0.28076737830348908	609.84997559999999	0.36208706976740174
610	0.28541186657361667	610.85998540000003	0.351144512374365
609	0.2904064702090372	611.88000490000002	0.34328810647040142
608	0.29488544023903829	612.89001459999997	0.32875256374034473
607	0.29903430814479909	613.9099731	0.31396333081477384
606	0.30421597146430002	614.91998290000004	0.30168424863425725
605	0.30795778373479077	615.94000240000003	0.28831400478814034
604	0.31305877518069125	616.95001219999995	0.27664795294151107
603	0.31742075804652969	617.96997069999998	0.26671729366447788
602	0.32186455332239444	618.97998050000001	0.2545294972759623
601	0.32592521189314422	619.84997559999999	0.2471545015529075
600	0.33047940372883128	620.88000490000002	0.23600129464131933
599	0.33441796359442982	621.9099731	0.22845913252280994
598	0.33825254780148162	622.94000240000003	0.21469512109927369
597	0.342431104954391	623.96997069999998	0.20599450389128235
596	0.34597622011076562	624.84997559999999	0.19931630386950006
595	0.34983540047767647	625.88000490000002	0.19362626976975492
594	0.35365887095363963	626.9099731	0.18758886572556724
593	0.35700147695972884	627.94000240000003	0.17875017489958442
592	0.35974890803808757	628.96997069999998	0.17482636966844375
591	0.36314534427655842	629.84997559999999	0.16817609143578982
590	0.36688958312680031	630.85998540000003	0.15819977630179949
589	0.36967073595967742	631.88000490000002	0.15362885171512769
588	0.3730254371856776	632.89001459999997	0.14932171390927898
587	0.37588365014573821	633.9099731	0.14438193802487687
586	0.37941611413978255	634.91998290000004	0.13611729629568856
585	0.38161078662411596	635.94000240000003	0.13406976773328369
584	0.38520458539960495	636.95001219999995	0.12778377390292558
583	0.38843704291842712	637.96997069999998	0.12507273201187319
582	0.39158714870202871	638.97998050000001	0.11837172350304738
581	0.39413271146921358	639.84997559999999	0.11912187768965858
580	0.39727928551075581	640.84997559999999	0.11664615424721936
579	0.40080537929194798	641.84997559999999	0.11113627164798856
578	0.40438142024269247	642.84997559999999	0.10351668050098725
577	0.40834144817018547	643.84997559999999	0.10322545339647131
576	0.41350346117913467	644.84997559999999	9.9399062170545685E-2
575	0.41938940312925194	645.84997559999999	9.7369046521118149E-2
574	0.42411755943016183	646.84997559999999	9.6156296278417749E-2
573	0.43014356604663379	647.84997559999999	9.3376555791125262E-2
572	0.43608571808762081	648.84997559999999	8.7383142257383445E-2
571	0.44421766892762138	649.84997559999999	8.6245856230347112E-2
570	0.45126392025306439	650.85998540000003	8.0377713413302743E-2
569	0.46160300258705883	651.88000490000002	7.8873657891052523E-2
568	0.47091243026293683	652.89001459999997	7.7145265261335222E-2
567	0.48143747330231063	653.9099731	7.2589095223181951E-2
566	0.49374545560855465	654.91998290000004	6.7396487970367805E-2
565	0.50793853244117559	655.94000240000003	6.6320848489825002E-2
564	0.52278665989534778	656.95001219999995	6.2375692087974804E-2
563	0.53838123803833748	657.96997069999998	5.9152390735583968E-2
562	0.55736444157353826	658.97998050000001	5.6109071729578734E-2
561	0.57863176212973089	659.84997559999999	5.3584751930173306E-2
560	0.60123014473887304	660.84997559999999	5.0566049894436353E-2
559	0.62629194639818297	661.84997559999999	4.8261623954590889E-2
558	0.65303717576035081	662.84997559999999	4.3597117139957904E-2
557	0.68141367503898276	663.84997559999999	4.2186930119095731E-2
556	0.70960170485504648	664.84997559999999	3.7312151147577917E-2
555	0.73589461924364374	665.84997559999999	3.5090189465598755E-2
554	0.7623945583261641	666.84997559999999	3.273930093109699E-2
553	0.7858231549629795	667.84997559999999	2.9565552297384768E-2
552	0.80912219355269865	668.84997559999999	2.652152419061414E-2
551	0.83127730523101673	669.84997559999999	2.2406429999678252E-2
550	0.85510972848023259	670.85998540000003	2.3189658330911921E-2
549	0.87969346633762791	671.88000490000002	2.0258137079310689E-2
548	0.90507138111268315	672.89001459999997	1.7290438509427707E-2
547	0.92690088512601632	673.9099731	1.1755067192799108E-2
546	0.94731608066790329	674.91998290000004	1.0494097804724854E-2
545	0.96681713274042003	675.94000240000003	1.0180693275328058E-2
544	0.98215655674465185	676.95001219999995	5.8949782105920563E-3
543	0.993007525232809	677.96997069999998	3.9838058302642844E-3
542	0.99892772253104989	678.97998050000001	2.4207255359134255E-3
541	1.0032710103195248	679.84997559999999	1.561395359058756E-3
540	1	680.84997559999999	-8.3237120672377985E-4
539	0.99419261611098542	681.84997559999999	-2.305606700741513E-3
538	0.98316531391377104	682.84997559999999	-5.164704994483264E-3
537	0.97460901778848741	683.84997559999999	-6.0176760027425983E-3
536	0.96485914192767386	684.84997559999999	-8.1602537946881114E-3
535	0.95041700963801068	685.84997559999999	-9.8780879447056564E-3
534	0.9382999445157405	686.84997559999999	-9.4993092157951153E-3
533	0.92814468191942623	687.84997559999999	-1.0411779923811157E-2
532	0.91407296509943248	688.84997559999999	-1.2637505058337396E-2
531	0.90077139319622301	689.84997559999999	-1.3624812276060504E-2
530	0.88772352833097667	690.97998050000001	-1.4703629714983063E-2
529	0.87960672905348292	691.96997069999998	-1.6510778466018679E-2
528	0.87157148809516116	692.95001219999995	-1.5290198741277993E-2
527	0.86020810576814799	693.94000240000003	-1.5710037208164565E-2
526	0.85083444706543132	694.91998290000004	-1.6908416764956084E-2
525	0.84313808713359895	695.9099731	-1.8993966969323695E-2
524	0.8334229713367507	696.90002440000001	-1.9010445509272084E-2
523	0.82641891245651422	697.88000490000002	-1.9666555539423487E-2
522	0.81790112216254918	698.86999509999998	-2.1610174310665819E-2
521	0.81048298247699124	699.84997559999999	-2.0921562594065423E-2
520	0.80424409188041246	700.84997559999999	-2.069905025287775E-2
519	0.79899994065192093
518	0.79641658136619242
517	0.79319109399339804
516	0.79027423063542379
515	0.78846874129980415
514	0.78695499597710505
513	0.78595433275254634
512	0.78487820794896179
511	0.78443961050206967
510	0.78392229020658322
509	0.78443691487316369
508	0.78325037731705094
507	0.782251547586167
506	0.77917613785146189
505	0.77729551494287563
504	0.77359091283833581
503	0.76831976592722073
502	0.76219179589586838
501	0.75370191492214333
500	0.74355943223742116
499	0.73192064183685412
498	0.71990780584795278
497	0.70763595833958204
496	0.69356079749080057
495	0.67800754606418112
494	0.66173242413005928
493	0.6455853572649074
492	0.63380666680513476
491	0.6217230800319824
490	0.60529987181046641
489	0.59048412362082536
488	0.5786962778754402
487	0.56785131440782755
486	0.55308783456690858
485	0.53977215078766227
484	0.53183027795076887
483	0.52244753299892377
482	0.50972114841933092
481	0.49909416128003992
480	0.48848969665639908
479	0.47863286391979265
478	0.47054614159068114
477	0.46158390114308029
476	0.45338343536157039
475	0.44473202100041187
474	0.43736405759194225
473	0.43024483840026168
472	0.42318298977031077
471	0.41571675919537332
470	0.40856431088928324
469	0.40174911792664558
468	0.39412452602677506
467	0.38706268044250686
466	0.37994984913815377
465	0.37230978714368734
464	0.36476211464449354
463	0.35637500482658585
462	0.34815030980455264
461	0.34102964726754348
460	0.33477054558481956
459	0.32885767692360895
458	0.32087913607094082
457	0.31375499309294413
456	0.30697571163164311
455	0.30047587799493947
454	0.29432256803562068
453	0.28870621132523833
452	0.28375693159228138
451	0.27809410283448188
450	0.27330306625718948
449	0.26859591860033738
448	0.26391813982472795
447	0.26056556746902376
446	0.25724579297235867
445	0.25411535017666592
444	0.25029713606862702
443	0.24734853585369013
442	0.24476927803233467
441	0.24258384349059717
440	0.24068260350953749
439	0.23883800577881112
438	0.2371064013512659
437	0.2350479136078622
436	0.23340164574574526
435	0.23184381474066312
434	0.23040441599832198
433	0.22980253166492423
432	0.22897848882315949
431	0.2281282488776043
430	0.22811565289654709
429	0.22702025542832385
428	0.2271846608107857
427	0.22693662493942104
426	0.22710787831299112
425	0.22827454313936033
424	0.22888241806988857
423	0.22912884332959854
422	0.23001687042022706
421	0.23176983759285819
420	0.23327345426229204

Figura 60 - spettro UV-Visibile e di emissione del copolimero 3c in THF I copolimeri 3a, 3b e 3c in soluzione (THF) mostrano profili pressoché identici tra loro e fortemente simili a quello del monomero DPP di partenza (Figura 58, Figura 59, Figura 60). Sia l'ampia banda di assorbimento, con λ_max a circa 540-545 nm, relativa alla transizione π→π\*, sia lo spettro di emissione, con λ_max a circa 550 nm, ricalcano infatti il comportamento foto-fisico del core dichetopirrolopirrolico. Si nota come tutti i campioni presentino uno Stokes shift estremamente ridotto: questa forte sovrapposizione tra le bande di assorbimento ed emissione è indicativa di una notevole rigidità strutturale dello scheletro polimerico, il quale subisce una minima riorganizzazione conformazionale nel passaggio dallo stato fondamentale a quello eccitato.

copolimero	λ_{max, asb}(nm)		λ_{max, ecc}(nm)	Stokes shift (nm)
3a		540	547	7
3b		544	550	6
3c		542	552	10

*Tabella 7 - dati spettroscopici dei copolimeri sintetizzati* Tuttavia, sebbene in soluzione diluita i copolimeri mantengano queste eccellenti caratteristiche emissive, il loro comportamento allo stato solido risulta drasticamente differente. Come tipicamente si osserva nei sistemi $\pi$ -coniugati altamente planari, la deposizione allo stato solido favorisce una forte interazione intermolecolare. L'intenso impaccamento delle catene porta alla formazione di aggregati che disattivano i fluorofori attraverso percorsi di decadimento non radiativo. Questo effetto è visivamente confermato osservando i campioni polimerici depositati su vetrino: esposti all'illuminazione di una lampada UV (**Figura 61**), i film non mostrano alcuna emissione apprezzabile allo stato solido. ![](immagini/4ee04a7d6b36bbfeef99d8c40233deaab3e5e81eefb4e3d9c7dbce387219c598.jpg) Figura 61 - film solidi dei copolimeri sotto lampada UV, in ordine copolimero 3a, 3b, 3c Proprio questa tendenza all'aggregazione, e al conseguente quenching emissivo nei film solidi, rappresenta la principale criticità per l'impiego di tali sistemi lineari in dispositivi optoelettronici. Per superare questo limite strutturale è necessario sfavorire l'avvicinamento incontrollato delle catene principali coniugate. È in quest'ottica che si è reso necessario il passaggio a un design macromolecolare più complesso, che giustifica la progettazione e la sintesi di un'architettura di tipo bottle-brush. Successivamente, i copolimeri sono stati caratterizzati mediante cromatografia a permeazione di gel (GPC) per determinare la distribuzione dei pesi molecolari I risultati dell'analisi cromatografica riportati in **Tabella 8** evidenziano masse molecolari medie numerali ( $\overbar{M_{n}}$ ) comprese tra circa 1400 e 2150 Da per i copolimeri sintetizzati. I campioni **3a** e **3c** presentano valori di $\overbar{M_{n}}$ del tutto equiparabili (rispettivamente 2149 e 2134 Da). Tuttavia, il copolimero **3c** si distingue per una distribuzione delle catene polimeriche maggiormente omogenea, confermata dal valore di polidispersità più contenuto della serie (PD = 1.979). L'ottenimento di indici di polidispersità di questa entità è del tutto normale e atteso per questo sistema, trattandosi di una polimerizzazione non controllata. Nei processi convenzionali, infatti, l'assenza di un rigoroso controllo sulla cinetica di crescita e sulle reazioni di terminazione o trasferimento di catena porta a distribuzioni dei pesi molecolari ampie, con valori teorici e sperimentali di PD che si assestano tipicamente attorno a 2 (distribuzione più probabile di Flory) o superiori.⁵⁴ Il campione **3b** mostra invece un andamento differente: pur registrando il valore più basso di $\overbar{M_{n}}$ (1402 Da), ad esso corrisponde la massa molecolare media ponderale ( $\overbar{M_{w}}$ ) più elevata (6439 Da). Questa discrepanza si traduce in un indice di polidispersità nettamente superiore (PD = 4.592), indicando una distribuzione dei pesi molecolari marcatamente ampia. Tale risultato suggerisce la presenza di una frazione significativa di specie oligomeriche a catena corta, che abbassano la media numerica, e di una porzione di macromolecole a peso molecolare più elevato che incrementano il valore ponderale.

Copolimero	Massa molecolare media numerica (Da)	Massa molecolare media ponderale (Da)	Polidispersità (PD)
3a	2149	5526	2,571
3b	1402	6439	4,592
3c	2134	4223	1,979

*Tabella 8 - Pesi molecolari e polidispersità determinati mediante GPC per i copolimeri 3a, 3b. 3c* Al fine di valutare le proprietà termiche dei materiali sintetizzati, i tre copolimeri sono stati analizzati mediante calorimetria a scansione differenziale (DSC). Dai termogrammi ottenuti è emerso che per tutti i campioni la temperatura di transizione vetrosa (Tg) si attesta intorno a -10 °C. A differenza di quanto si osserva per il 3HT, per i campioni in esame non si rilevano invece transizioni di fusione. Questo dato conferma l'ottenimento di un copolimero random: l'elevato disordine strutturale che lo caratterizza, infatti, impedisce al materiale di cristallizzare, nonostante i bassi pesi molecolari. ## **4.3. Polimeri bottle brush** In questa fase del progetto di ricerca, l'attenzione si è focalizzata sulla sintesi e caratterizzazione di architetture polimeriche di tipo bottle brush. Lo scopo principale di questa progettazione strutturale è limitare i fenomeni di impaccamento intermolecolare tra le catene dei copolimeri precedentemente sintetizzati. Ridurre l'aggregazione tra le catene principali è un passaggio fondamentale per ottimizzare le prestazioni del materiale: l'ingombro sterico generato dalle catene laterali permette di isolare i backbone polimerici, portando ad un miglioramento delle proprietà spettroscopiche, limitando lo smorzamento della fluorescenza o quenching da aggregazione e, allo stesso tempo, favorendo una maggiore mobilità e flessibilità delle catene stesse. ![](immagini/af07237d5d3b9056fb6ba8c4a035fa954b1cb19f09ee7b255a2dc1576c9cd544.png) *Figura 62 - Effetto dell'intensità dello stacking π-π sull'emissione luminosa* Dal punto di vista sintetico, la realizzazione di tale architettura mediante approccio “grafting from” richiede che la catena polimerica principale sia predisposta per comportarsi come macroiniziatore. Di conseguenza, al fine di innestare successivamente le catene laterali polimeriche, l'unità dichetopirrolopirrolica è stata progettata e sintetizzata introducendo una funzionalità ossidrilica terminale. Tale gruppo -OH costituisce il sito nucleofilo iniziatore per una reazione di polimerizzazione di tipo Ring Opening Polymerization (ROP), la quale permette di regolare il peso molecolare e mantenere una bassa dispersità delle catene laterali in accrescimento, parametri rilevanti per la sintesi di copolimeri bottle brush aventi un'architettura regolare e riproducibile. Stabilita la tecnica di polimerizzazione, per la costituzione delle catene laterali da accrescere la scelta è ricaduta sul policaprolattone (PCL). Tale decisione deriva da precedenti studi condotti all'interno del gruppo di ricerca. L'impiego del PCL offre infatti un duplice vantaggio, sia a livello sintetico che applicativo. La polimerizzazione del caprolattone via ROP, infatti, risulta essere un processo lineare ed efficiente. Per quanto riguarda le proprietà chimico-fisiche, invece, il PCL è caratterizzato da una bassa temperatura di transizione vetrosa (T_g) e da una buona solubilità nei comuni solventi organici⁵⁵. Queste caratteristiche garantiscono una notevole semplicità di lavorazione del prodotto e integrazione del sistema bottle brush all'interno di una matrice polimerica per l'ottenimento dei materiali finali. La reazione di polimerizzazione ROP presenta diversi possibili meccanismi⁵⁶, uno dei più sfruttati è quello di coordinazione-inserzione del monomero sul centro attivo dell’iniziatore. In particolare, la reazione di apertura dell’anello catalizzata da stagno ottanoato (Sn(Oct)₂) richiede generalmente l’aggiunta di co-iniziatori nucleofili come alcol⁵⁶. Si ha una prima reazione di scambio dei leganti, tra l’alcol e l’ottanoato del catalizzatore creando la specie attiva. A questo punto il centro metallico si coordina al carbonile del caprolattone, rendendo il carbonio più elettrofilo e favorendo l’attacco nucleofilo del gruppo alcolico con conseguente apertura dell’anello. La crescita del PCL prosegue quindi mediante attacchi successivi del terminale ossidrilico, che mantiene la reattività durante tutta la propagazione della catena (Figura 63). ![](immagini/5e383d1d45b7de4b9fa9143e4e9ea41713e055a9d72ac00614059c40393f341c.jpg) *Figura 63 - meccanismo di reazione della ROP con gruppo alcolico come iniziatore* La purificazione è stata condotta mediante precipitazione in non-solvente: la miscela di reazione è stata addizionata goccia a goccia all'interno di un largo eccesso di metanolo freddo. La scelta di questo specifico non-solvente è dettata dalle differenti solubilità delle specie in soluzione: mentre l'ε-caprolattone residuo e le altre specie a basso peso molecolare presentano un'elevata affinità per il metanolo, il copolimero ad alto peso molecolare vi risulta insolubile. Inoltre, l'impiego della bassa temperatura riduce ulteriormente la solubilità del polimero e ne favorisce la rapida coagulazione, massimizzando la resa del processo di precipitazione. Il polimero così precipitato è stato successivamente recuperato mediante filtrazione. Allo scopo di valutare in modo sistematico l'influenza della lunghezza delle catene laterali sulle proprietà finali del materiale, sono state preparate due serie di polimeri bottle brush. Queste serie sono state ottenute impiegando rispettivamente i copolimeri **3b** e **3c** in qualità di macroiniziatori. Sebbene fosse stato sintetizzato anche un terzo copolimero **3a**, il suo impiego per le successive fasi di grafting è stato scartato a causa della scarsa efficienza della sua via sintetica. Nello specifico, le basse rese di reazione e le difficoltà incontrate nel work-up per l'isolamento del prodotto puro portavano a notevoli perdite di materiale. Inoltre, dal punto di vista dell’efficienza di processo, l'isolamento di quantità utili di questo copolimero avrebbe richiesto volumi di solventi e costi di reagenti molto elevati. Di conseguenza, per garantire la fattibilità tecnica ed economica della ricerca, si è scelto di utilizzare esclusivamente i macroiniziatori **3b** e **3c**. Sfruttando l'elevato grado di controllo della reazione di ROP, è stato possibile modulare la lunghezza delle catene in accrescimento variando il rapporto molare tra il monomero (ε-caprolattone) e i siti iniziatori (-OH) presenti sul backbone. Seguendo questo approccio, per ciascuno dei due precursori copolimerici sono stati sintetizzati tre differenti polimeri dotate di catene laterali in PCL con pesi molecolari di circa 1500 Da, 5000 Da e 10000 Da (**Tabella 9**).

Copolimero	Polimero bottle brush	Lunghezza catene di PCL (Da)
3b	3.1b	1500
	3.2b	5000
	3.3b	10000
3c	3.1c	1500
	3.2c	5000
	3.3c	10000

*Tabella 9 - lunghezza delle catene in PCL nei polimeri bottle brush* Al fine di determinare la quantità esatta di monomero necessaria per raggiungere ciascuno di questi pesi molecolari target, è stata impiegata la seguente equazione: $$ V_{CL}=\frac{\frac{m_{backbone}}{MW_{backbone}}\times DP_{backbone}\times \chi _{DPP}\times 2\times Mn_{teorico}}{\rho _{CL}} $$ Il termine $V_{CL}$ rappresenta il volume di caprolattone da prelevare e inserire in reazione espresso in mL. Questo parametro è calcolato a partire dalla massa del copolimero lineare di partenza pesata ( $m_{backbone}$ , in g) e dal suo peso molecolare ricavato via GPC ( $MW_{backbone}$ , in g/mol), il cui rapporto restituisce le moli di backbone utilizzate. Tale valore viene moltiplicato per il grado di polimerizzazione del copolimero lineare di partenza ( $DP_{backbone}$ ), per la frazione molare delle unità di DPP al suo interno ( $\chi _{DPP}$ ) e per il valore $2$ , corrispondente al numero di gruppi idrossilici presenti per ogni unità di DPP. Il prodotto ottenuto viene a sua volta moltiplicato per il peso molecolare teorico desiderato per la singola catena laterale di PCL ( $Mn_{teorico}$ , espresso in Da). Infine, l'intero numeratore è diviso per la densità dell' $\varepsilon$ -caprolattone liquido alla temperatura di prelievo ( $\rho _{CL}$ , in g/mL) per convertire la massa totale del monomero nel volume da prelevare. Per confermare l'avvenuta formazione delle catene laterali, tutti i polimeri sintetizzati sono stati analizzati mediante spettroscopia ¹H-NMR. L'effettiva polimerizzazione dell'ε-caprolattone è stata verificata osservando la comparsa dei segnali caratteristici del PCL, in particolare il caratteristico tripletto a circa 4.0 ppm, attribuibile ai protoni metilenici adiacenti all'ossigeno del legame estereo (-CH₂-O-), e il segnale a 2.3 ppm relativo ai protoni in alfa al carbonile. Poiché gli spettri risultano del tutto analoghi per l'intera serie di campioni, differendo esclusivamente per i valori di integrazione dei segnali in funzione del peso molecolare, in Figura 64 riporta lo spettro del polimero 3.1b, rappresentativo per tutti i composti sintetizzati. ![](immagini/e5c7709e972d150950dac9ce997e72834c0dc9a43529a4cfdacf675b2fbf7dd2.png) Figura 64 - spettro ¹H-NMR del polimero 3.1b in CDCl₃ Entrambe le serie di polimeri bottle brush sintetizzati sono state sottoposte a spettroscopia FT-IR. Al fine di evidenziare l'accrescimento delle catene laterali, sono stati riportati gli spettri infrarossi sovrapposti delle due serie polimeriche (**Figura 65, Figura 66**). Ponendo alla base la traccia del relativo copolimero macroiniziatore, è possibile apprezzare in modo diretto le variazioni spettrali indotte dalle catene laterali di policaprolattone. L'analisi comparativa conferma chiaramente il successo della reazione. Per entrambe le serie, nello spettro del precursore (traccia rossa) è visibile un assorbimento largo nella regione tra 3600 e 3200 cm⁻¹, tipico dello stretching del gruppo ossidrilico (-OH) terminale. A seguito della polimerizzazione, tale banda risulta del tutto assente nei profili dei polimeri bottle brush, a conferma del coinvolgimento dell'ossidrile come sito iniziatore per la polimerizzazione. Parallelamente, gli spettri dei copolimeri innestati risultano dominati dai segnali caratteristici del PCL. Spicca in particolar modo la comparsa di un picco molto stretto e ad alta intensità centrato a circa 1720 cm⁻¹, attribuibile allo stretching del gruppo carbonilico (C=O) estereo delle unità di caprolattone. Rispetto al copolimero di riferimento, si osserva inoltre una maggiore definizione delle bande relative allo stretching simmetrico e asimmetrico dei legami C-H alifatici (nella regione 2950-2860 cm⁻¹), insieme ai forti segnali di stretching del legame C-O-C nella regione della fingerprint (1240-1160 cm⁻¹). Come atteso, all'aumentare del peso molecolare delle catene laterali, il profilo vibrazionale del materiale tende a coincidere quasi interamente con quello del PCL omopolimero. Questo fenomeno è dovuto al fatto che la massa delle lunghe catene di policaprolattone va a coprire progressivamente i segnali meno intensi provenienti dal backbone del fluoroforo. ![](immagini/aee89434079292419db42d834206a12f90edf335898d67af13028f6f3d04c928.png) *Figura 65 - spettri FT-IR dei polimeri bottle brush ottenuti a partire dal copolimero 3b (verde):* *polimero 3.1b (arancione), polimero 3.2b (rosa), polimero 3.3b (azzurro)* ![](immagini/cbe62cb1e190227f5fd74fe12b543905276918aa81971d52027734db5712c35a.png) *Figura 66 - spettri FT-IR dei polimeri bottle brush ottenuti a partire dal copolimero 3c (verde):* *polimero 3.1c (arancione), polimero 3.2c (rosa), polimero 3.3c (azzurro)* La caratterizzazione foto-fisica dei polimeri è stata effettuata mediante spettroscopia di assorbimento (UV-Vis) ed emissione (**Figura 67**).

UV-Visibile X	UV-Visibile Y	Emissione X	Emissione Y
700	8.6450089383341297E-2	500	2.8527803947757806E-5
699	9.125242140977928E-2	501.0400085	1.2620143289506983E-4
698	9.1867000893186251E-2	501.94000240000003	8.1623557476419846E-5
697	9.2191253719861602E-2	502.98001099999999	8.5427176895983307E-4
696	9.1922827566296675E-2	504.01998900000001	1.1820922406272239E-3
695	9.3725365740456548E-2	505.07000729999999	1.9405344800237931E-3
694	9.6577460504211815E-2	505.97000120000001	2.2328803959772714E-3
693	9.7662788291562996E-2	507.01000979999998	2.9148732642053643E-3
692	9.9715444811758924E-2	508.0499878	3.7648081972433776E-3
691	0.10150912229748925	508.9500122	4.781845208924048E-3
690	0.10309957646563887	510	5.429511147740488E-3
689	0.10370693109383647	511.0400085	6.4503241322589984E-3
688	0.10601666633124519	511.94000240000003	7.5528374744849398E-3
687	0.10725627402644401	512.97998050000001	8.9125179716722826E-3
686	0.10981958868753762	514.02001949999999	1.0633767450786107E-2
685	0.1102770884182363	515.07000730000004	1.1926829529905049E-2
684	0.11170136226265688	515.96997069999998	1.2880751124669741E-2
683	0.11359939553875727	517.01000980000003	1.4738182200207504E-2
682	0.11602351606990345	518.04998780000005	1.7150713510265612E-2
681	0.11799830611867659	518.95001219999995	1.8207708058943894E-2
680	0.12009120119804076	520	2.1185806454449563E-2
679	0.1224736876353876	521.03997800000002	2.3772850475874355E-2
678	0.12434003873824859	521.94000240000003	2.6151143490958671E-2
677	0.12604245216188389	522.97998050000001	2.9793746106594448E-2
676	0.12934928443999899	524.02001949999999	3.3455844720195319E-2
675	0.13121859668461602	525.07000730000004	3.7948906267890506E-2
674	0.13346259361179705	525.96997069999998	4.1581723989115249E-2
673	0.13533634000365985	527.01000980000003	4.7794732474030495E-2
672	0.13816904834677451	528.04998780000005	5.4418803935208648E-2
671	0.13939099279522676	528.95001219999995	5.9821212699591918E-2
670	0.14066679075479857	530	6.7251439068195543E-2
669	0.14601347975742743	531.03997800000002	7.3929574856374927E-2
668	0.14739264001578725	531.94000240000003	8.2433574365515377E-2
667	0.15006484402177739	532.97998050000001	9.3571618283689081E-2
666	0.15263737486913662	534.02001949999999	0.10343102814815942
665	0.15510789801903999	535.07000730000004	0.1142664256182421
664	0.15824161699909831	535.96997069999998	0.12550941729055337
663	0.1608037522900283	537.01000980000003	0.14027375569155406
662	0.16375805795019954	538.04998780000005	0.15826244687649355
661	0.1674593848061319	538.95001219999995	0.17294106315609847
660	0.17066843527505865	540	0.1930507582231514
659	0.17601800878745022	541.03997800000002	0.21537458027663733
658	0.17801166900286522	541.94000240000003	0.23987192917767544
657	0.1806303072841062	542.97998050000001	0.2712640784014711
656	0.18472135122101022	544.02001949999999	0.30091327727561457
655	0.18922749606708633	545.07000730000004	0.3339921744573825
654	0.19324135209920315	545.96997069999998	0.37145896417794338
653	0.19785468800917536	547.01000980000003	0.41706190949038818
652	0.20103596465572965	548.04998780000005	0.46470069845493545
651	0.20721366074656747	548.95001219999995	0.50797850225797569
650	0.21054061206017985	550	0.55851381031355196
649	0.2153475564595134	551.02001949999999	0.62723203255287296
648	0.22150302163220972	552.04998780000005	0.69297188940366727
647	0.22608552172039528	552.94000240000003	0.7413699312120291
646	0.23115339972059681	553.96997069999998	0.79953287645599325
645	0.23686835739089174	555	0.84867696989293373
644	0.24256737279922327	556.02001949999999	0.90205829646781899
643	0.24872334480292935	557.04998780000005	0.94584239994188313
642	0.25526255279013726	557.94000240000003	0.97173721263856194
641	0.26163899506324451	558.96997069999998	0.98911554127014123
640	0.26821519208240446	560	0.99935433176861355
639	0.2739001219226454	561.02001949999999	1
638	0.28142938088864572	562.04998780000005	0.99172281860906975
637	0.29059287706266224	562.94000240000003	0.98030852311895433
636	0.29828445988601898	563.96997069999998	0.96748537447728022
635	0.30417632517845478	565	0.94761279133089593
634	0.31366160734413456	566.02001949999999	0.92258615346841988
633	0.32091274048932278	567.04998780000005	0.89865272501670346
632	0.32823958491863908	567.94000240000003	0.87681415140303387
631	0.33583349561997933	568.96997069999998	0.85159292538671783
630	0.34525216964890104	570	0.82205964236239348
629	0.3539625772693073	571.02001949999999	0.79150128932646813
628	0.36042157697152338	572.04998780000005	0.76923011677700281
627	0.36985827032747076	572.94000240000003	0.75271299754094045
626	0.37687966785091515	573.96997069999998	0.7277879790099262
625	0.38818482365090573	575	0.70593418203764025
624	0.3935709397493109	576.02001949999999	0.68571994648720036
623	0.40356198070129246	577.04998780000005	0.66726615962996083
622	0.41028712045331978	577.94000240000003	0.6544956462083058
621	0.42088572791003132	578.96997069999998	0.63571621651473753
620	0.4279219709607669	580	0.61730916661572299
619	0.43687150655708262	581.02001949999999	0.60372002425961235
618	0.44544000605801037	582.04998780000005	0.59474453912276071
617	0.45367729209262792	582.94000240000003	0.58505356113770834
616	0.4612053849982477	583.96997069999998	0.57129286218114528
615	0.46978573046852851	585	0.55968324843328077
614	0.47728747566232244	586.02001949999999	0.55275060066070492
613	0.48695843192537047	587.04998780000005	0.54456981433814988
612	0.49517084706520048	587.94000240000003	0.54235289284145405
611	0.50149958517779847	588.96997069999998	0.53493725777176537
610	0.50997382117242462	590	0.52932335952235154
609	0.51807942576396371	591.02001949999999	0.52766969831849797
608	0.52641431412475415	592.04998780000005	0.52622500572375763
607	0.5325264669458103	592.94000240000003	0.52214315115567611
606	0.54017021764323347	593.96997069999998	0.521233912762463
605	0.54764587071071757	595	0.52333247496154556
604	0.55519448877333832	596.02001949999999	0.52571842523221068
603	0.56224698279683882	597.04998780000005	0.52753594705214835
602	0.56806860859412223	597.94000240000003	0.53364631448717637
601	0.5749875010421911	598.96997069999998	0.53635807605703267
600	0.58130627150654268	600	0.54140326503519576
599	0.58692847924569813	601.02001949999999	0.54831658890993518
598	0.5930535959968527	602.04998780000005	0.55424731058195853
597	0.60033232680754156	602.94000240000003	0.55786179438972783
596	0.60630716082586567	603.96997069999998	0.5610038517842183
595	0.60981348665534263	605	0.56452435584517702
594	0.61678758036255343	606.02001949999999	0.56426308879451192
593	0.62132194381743022	607.04998780000005	0.56222165597462603
592	0.62588037230772342	607.94000240000003	0.56108968626327504
591	0.63150718700040331	608.96997069999998	0.55817412394767529
590	0.63732005362627719	610	0.55300596930231816
589	0.64161673677069497	611.01000980000003	0.54669185752126359
588	0.64820061740769774	612.02001949999999	0.53859342288479328
587	0.65184699827103376	613.03997800000002	0.52724457065174879
586	0.65737606912903024	614.04998780000005	0.51990499568090898
585	0.6623090281513816	615.07000730000004	0.50908041872479393
584	0.6668414189512788	615.94000240000003	0.5002905899704021
583	0.67238334761396235	616.95001219999995	0.48922732823362391
582	0.67705872273534728	617.96997069999998	0.47488550544145802
581	0.68160261417737444	618.97998050000001	0.46212260377274006
580	0.68958946804349641	620	0.45465820930693057
579	0.69514888065085167	621.02001949999999	0.44250811383080207
578	0.6992308604808527	622.04998780000005	0.4298086892337184
577	0.7059934401822604	622.94000240000003	0.41949063666394881
576	0.71222639768915763	623.96997069999998	0.40987521309464237
575	0.71752216984248385	625	0.40159783511461994
574	0.72347782396691096	626.02001949999999	0.38928143542735527
573	0.73335926543075991	627.04998780000005	0.37747875042770146
572	0.73809539619895914	627.94000240000003	0.37346916407148611
571	0.74809310773291615	628.96997069999998	0.36462964908071455
570	0.75406542613891669	630	0.35589624743332454
569	0.76360496196163752	631.01000980000003	0.34758339535659061
568	0.7750983754925157	632.02001949999999	0.33858063764324081
567	0.78688506825438176	633.03997800000002	0.33130734839104181
566	0.79818365987237327	634.04998780000005	0.32377046099804441
565	0.81199850661108186	635.07000730000004	0.31832230517146226
564	0.824093429991543	635.94000240000003	0.31259541222415443
563	0.8395199328007058	636.95001219999995	0.30516446956441834
562	0.85646002160516377	637.96997069999998	0.29767288675354187
561	0.87185307110039467	638.97998050000001	0.29304726425331656
560	0.89219530518512147	640	0.28522888690327297
559	0.90912331603762087	641	0.28028691853731141
558	0.92746590913408111	642	0.27329466966425736
557	0.94674889432870069	643	0.26635707844911827
556	0.96210978983666451	644	0.26147103150705558
555	0.97440694701711184	645	0.25458455905165817
554	0.98669907711455151	646	0.2478767211403177
553	0.99458133343416177	647	0.24151660250494714
552	0.99940605316168596	648	0.2378872605377739
551	1	649	0.23154813702840915
550	0.99817153895664823	650	0.22620794837298427
549	0.99466718067193538	651.01000980000003	0.21971107323516528
548	0.98910639854875837	652.02001949999999	0.21672168383719068
547	0.98625905534031155	653.03997800000002	0.21253551350104388
546	0.97916239762393342	654.04998780000005	0.20845629896984863
545	0.97009883022230825	655.07000730000004	0.202382388871508
544	0.96171111640103712	655.94000240000003	0.20005870786443716
543	0.95103130030469818	656.95001219999995	0.19549899189415448
542	0.94482363931903512	657.96997069999998	0.19326256375275838
541	0.93921229808555584	658.97998050000001	0.18912287768054295
540	0.93034874181367955	660	0.18687983486841409
539	0.91829012020574141	661	0.18137365109586376
538	0.90873839408551305	662	0.17904629055947124
537	0.9017412616606959	663	0.17672909772872863
536	0.89575537047405518	664	0.17185866732346644
535	0.88413840579867453	665	0.16936953870357316
534	0.87655554109307621	666	0.16697111776335449
533	0.87240198888176013	667	0.16307851458110773
532	0.86369963425290386	668	0.1598339952463276
531	0.85491636856418063	669	0.15578476386497767
530	0.84654517352584779	670	0.15229788007295489
529	0.84267862028026852	671.01000980000003	0.15022150681843222
528	0.84053950380322218	672.02001949999999	0.14651578174254243
527	0.83179962916354955	673.03997800000002	0.14283944993141542
526	0.82651585431785068	674.04998780000005	0.13803515077141762
525	0.82207705693644151	675.07000730000004	0.13491547891057903
524	0.81793234647134194	675.94000240000003	0.13348013943581005
523	0.8155833645686632	676.95001219999995	0.12959504962359955
522	0.80914143595987731	677.96997069999998	0.1266358538951452
521	0.80621159727331171	678.97998050000001	0.12297716085255367
520	0.80418585476874338	680	0.1189469164580409
519	0.80328133099082999	681	0.11594421367860455
518	0.80221953015325576	682	0.1130829158427356
517	0.80029706752634422	683	0.10987967055718931
516	0.79977588586164794	684	0.10723072590248803
515	0.79814391761865322	685	0.10575466702478886
514	0.79532402595520602	686	0.10229241575765219
513	0.79312775375812206	687	0.10080353507430202
512	0.79041072392518641	688	9.9955976147955317E-2
511	0.78494933522187138	689	9.7939877918989615E-2
510	0.77928782354199544	690	9.7479241034556185E-2
509	0.77384611007441984	690.97998050000001	9.4755184223300259E-2
508	0.76521644407287293	691.96997069999998	9.3967661647154338E-2
507	0.75663567445891744	692.95001219999995	9.3055481117787123E-2
506	0.74653006588663262	693.94000240000003	9.2166746377849551E-2
505	0.73758579658594337	695.07000730000004	9.0552407262891738E-2
504	0.72831329896730368	696.04998780000005	8.9567305374647743E-2
503	0.71779005990347566	697.03997800000002	8.7799217008441635E-2
502	0.7086057474057631	698.02001949999999	8.563509228823904E-2
501	0.69712576877825172	699.01000980000003	8.3878498596691622E-2
500	0.68689921854127078	700	8.3088209430351681E-2
499	0.67697923203106136	701	8.0977675073366159E-2
498	0.66889563144960718	702	7.9325720189203308E-2
497	0.65949146828215088	703	7.827084973044357E-2
496	0.65224049741411738	704	7.6850887999312667E-2
495	0.64274409364313945	705	7.5108394075046922E-2
494	0.63245242977761151	706	7.4356535204687421E-2
493	0.62287990927478287	707	7.2222035444586552E-2
492	0.61739709484286442	708	7.0401754058649429E-2
491	0.61295085019430529	709	6.9045704707778432E-2
490	0.60398291005123805	710	6.6623535981942816E-2
489	0.59508314433843057	710.97998050000001	6.5930667224943965E-2
488	0.59002089184777884	711.96997069999998	6.3557264889972195E-2
487	0.58546765005802348	712.95001219999995	6.2969758182056024E-2
486	0.57768417489947221	713.94000240000003	6.1064765849493732E-2
485	0.57032408580916283	715.07000730000004	5.9451430855660452E-2
484	0.56936003119534673	716.04998780000005	5.7948485511275453E-2
483	0.56605979636987247	717.03997800000002	5.6984069846461621E-2
482	0.55988567480214402	718.02001949999999	5.5419079924352563E-2
481	0.55510090351585384	719.01000980000003	5.3797266094517009E-2
480	0.55067359551718331	720	5.2508566311153512E-2
479	0.54500370277490906	720.97998050000001	5.0900778531371538E-2
478	0.54248517269376872	721.96997069999998	4.9628836267283011E-2
477	0.53794559057459412	722.95001219999995	4.8311943958824925E-2
476	0.53532777764160444	723.94000240000003	4.7913383268353829E-2
475	0.53170581716588172	725.07000730000004	4.579073981848647E-2
474	0.52654716647886646	726.04998780000005	4.4802618557400149E-2
473	0.52311155201691784	727.03997800000002	4.2960390554251431E-2
472	0.51794311314890706	728.02001949999999	4.1975358893226941E-2
471	0.51393530239710772	729.01000980000003	4.1507461480308629E-2
470	0.51046561395619561	730	4.0129328577247193E-2
469	0.50650678693311435	730.97998050000001	3.9260869270529027E-2
468	0.50253642336398663	731.96997069999998	3.7951384954463568E-2
467	0.49973032826401664	732.95001219999995	3.745506330638592E-2
466	0.49575747641223095	733.94000240000003	3.5823580473986136E-2
465	0.49324518177173809	735.07000730000004	3.4801873976581944E-2
464	0.49189311390246898	736.04998780000005	3.454031906647323E-2
463	0.48678768792095567	737.03997800000002	3.3401973507003364E-2
462	0.48471802969436067	738.02001949999999	3.246735833352557E-2
461	0.48190913856343776	739.01000980000003	3.1502475714396329E-2
460	0.48212611776051811	740	3.0247677167749766E-2
459	0.48150005644289612	740.96997069999998	2.9634418025056588E-2
458	0.47890944294982934	741.94000240000003	2.9153758504777846E-2
457	0.47769325326748291	743.04998780000005	2.7902934282736463E-2
456	0.47676977366595608	744.02001949999999	2.7289236282505989E-2
455	0.47517982587572516	745	2.6799845143576657E-2
454	0.47556095870231302	745.96997069999998	2.5871251177385882E-2
453	0.47472840869328675	746.94000240000003	2.5425805961701582E-2
452	0.47544251886723615	748.04998780000005	2.4083715938399045E-2
451	0.47432869858757198	749.02001949999999	2.3628826406020736E-2
450	0.47414649542852499	750	2.3138525950504325E-2
449	0.47471014347052287
448	0.47492996334327114
447	0.47628955025984365
446	0.47870825215927221
445	0.47929441288810987
444	0.48130668770633073
443	0.4821656850045507
442	0.48338389519620345
441	0.4863265167568544
440	0.48779458509133999
439	0.49115777826657819
438	0.49339136484123625
437	0.49627084452267711
436	0.4986182726108197
435	0.50114480334482936
434	0.50476405850270323
433	0.50827557692505621
432	0.51105948389300693
431	0.51490877534700719
430	0.5190090721076599
429	0.5223169286154834
428	0.52610634136305978
427	0.53018109445834938
426	0.53478542629216907
425	0.53987542220216156
424	0.54476408958334677
423	0.54904583347666058
422	0.55341729758955749
421	0.55944511980891376
420	0.56539287036434049
419	0.571202600134739
418	0.57779171846093891
417	0.58334074889262022
416	0.58932944001310761
415	0.59570007857356533
414	0.60247128042442277
413	0.60805926419872158
412	0.61545121909225931
411	0.62320081895827417
410	0.63138841667323109
409	0.63627359060969657
408	0.6438063575860804
407	0.65100806162210945
406	0.65775065797509347
405	0.6656555575265195
404	0.67399334057324478
403	0.68220786061498706
402	0.69034788770620159
401	0.69686378128572168
400	0.7055128250000654

UV-Visibile X	UV-Visibile Y	Emissione X	Emissione Y
700	2.166706160410483E-2	500	1.2091207583757683E-5
699	2.2384901732899587E-2	501.0400085	-7.255121512058205E-5
698	2.3184969427691132E-2	501.94000240000003	1.0968645099363956E-5
697	2.2970452963631312E-2	502.98001099999999	6.979902534024714E-5
696	2.5575192276471613E-2	504.01998900000001	4.7048843622468433E-4
695	2.3309574839938226E-2	505.07000729999999	3.5757051792335159E-4
694	2.5496113426039014E-2	505.97000120000001	8.2427842761789575E-4
693	2.6219709583542479E-2	507.01000979999998	1.1432510150718015E-3
692	2.5515256755884296E-2	508.0499878	1.3152427129066743E-3
691	2.8713742404408903E-2	508.9500122	1.6205356237668925E-3
690	3.0200486107640315E-2	510	2.2246144268743993E-3
689	2.9154725651101568E-2	511.0400085	2.5544522402451398E-3
688	2.9811485509386382E-2	511.94000240000003	3.1325917648887674E-3
687	2.9561197407071301E-2	512.97998050000001	3.8083520217786038E-3
686	3.1596899231074428E-2	514.02001949999999	4.802927752963663E-3
685	3.1621639448047696E-2	515.07000730000004	5.4691653459312409E-3
684	3.3287954062451601E-2	515.96997069999998	6.3094830666588194E-3
683	3.3190194609666199E-2	517.01000980000003	7.2992860802718103E-3
682	3.4116796242940339E-2	518.04998780000005	8.8845398556444601E-3
681	3.6009825884282282E-2	518.95001219999995	1.0205795685376429E-2
680	3.714007925157773E-2	520	1.2111284591947215E-2
679	3.8019042857292205E-2	521.03997800000002	1.3966296832004756E-2
678	3.8429063168699373E-2	521.94000240000003	1.6437451927191662E-2
677	3.9926602287291009E-2	522.97998050000001	1.9264041266484719E-2
676	4.0681768551113794E-2	524.02001949999999	2.3091683061480229E-2
675	4.2388430837813122E-2	525.07000730000004	2.7281446424200124E-2
674	4.3182736641447651E-2	525.96997069999998	3.0923690121161904E-2
673	4.4817543014094414E-2	527.01000980000003	3.8069306529329605E-2
672	4.4015239716283211E-2	528.04998780000005	4.5514339779488246E-2
671	4.5741107749018795E-2	528.95001219999995	5.2106979364433689E-2
670	4.730144492242018E-2	530	6.0902056023241793E-2
669	4.8450238924634896E-2	531.03997800000002	7.1165217942139883E-2
668	4.9736917072871645E-2	531.94000240000003	8.4406101670953901E-2
667	5.0268521709385387E-2	532.97998050000001	0.1002085923001618
666	5.2675188848338828E-2	534.02001949999999	0.11744750158835791
665	5.3546291798370046E-2	535.07000730000004	0.13779665567360377
664	5.390499162360355E-2	535.96997069999998	0.15648986774390627
663	5.5539917138569657E-2	537.01000980000003	0.18762329676025669
662	5.6795312535548897E-2	538.04998780000005	0.22184041513111027
661	5.7994985541403345E-2	538.95001219999995	0.25296626259665533
660	6.0000282072821091E-2	540	0.2880120138280246
659	6.2615185479697966E-2	541.03997800000002	0.33309100075906295
658	6.3816844891267835E-2	541.94000240000003	0.37393978953697127
657	6.5173643407617027E-2	542.97998050000001	0.42293485605381564
656	6.724565381536865E-2	544.02001949999999	0.47174836711807094
655	6.96441234933209E-2	545.07000730000004	0.51663758856223441
654	7.1625307503817889E-2	545.96997069999998	0.56094061214227908
653	7.3550173373730321E-2	547.01000980000003	0.61037393641921101
652	7.6428524713421792E-2	548.04998780000005	0.6564051204094955
651	7.8139427323589625E-2	548.95001219999995	0.69527522411526377
650	8.0520817082055079E-2	550	0.73843794346226399
649	8.3436751447626453E-2	551.02001949999999	0.79220864998183582
648	8.6450684657166779E-2	552.04998780000005	0.83624045009624359
647	8.8561140811601824E-2	552.94000240000003	0.8723862315820996
646	9.1558868551200129E-2	553.96997069999998	0.91020091186748808
645	9.5963484541948377E-2	555	0.93968388094136523
644	9.802973572523703E-2	556.02001949999999	0.97244581412949116
643	0.10115300087524587	557.04998780000005	0.99104144223926427
642	0.1063379786000381	557.94000240000003	0.99738628477360458
641	0.10825342724372053	558.96997069999998	1
640	0.1127213438173104	560	0.99322342471710967
639	0.11619021264624887	561.02001949999999	0.98167917865810861
638	0.1188088273728075	562.04998780000005	0.95935531082929926
637	0.12516186079817945	562.94000240000003	0.93830599558132999
636	0.12804688748561235	563.96997069999998	0.9175487088805877
635	0.13289036263859641	565	0.88766107075561318
634	0.13768952811833113	566.02001949999999	0.85488036438385595
633	0.14132286580027595	567.04998780000005	0.82628343083011946
632	0.14740060524010609	567.94000240000003	0.80101488199458526
631	0.15249806996619503	568.96997069999998	0.77711774650626719
630	0.15739780700553846	570	0.74414197961297035
629	0.16394517556899349	571.02001949999999	0.71497815676394894
628	0.16866950783107906	572.04998780000005	0.69137775738495522
627	0.17345644376741789	572.94000240000003	0.67124287845055519
626	0.17981974642941095	573.96997069999998	0.64908315662624694
625	0.18593327040000995	575	0.62488115589447912
624	0.19020288243156727	576.02001949999999	0.60388655572429506
623	0.19773042148219189	577.04998780000005	0.58709690872110287
622	0.2030170708005547	577.94000240000003	0.57282470329997681
621	0.21080389538949723	578.96997069999998	0.55954935505133885
620	0.21633492062582724	580	0.54465704219052369
619	0.22067648699989456	581.02001949999999	0.53622788119777809
618	0.22722246577274624	582.04998780000005	0.52536155997409473
617	0.23373471348732675	582.94000240000003	0.52079247953232077
616	0.24022009159282071	583.96997069999998	0.51259357231331804
615	0.24666952818387647	585	0.50800999742307751
614	0.25358300132632089	586.02001949999999	0.50378996142369803
613	0.2596784217091973	587.04998780000005	0.50077532147762516
612	0.2661932954693646	587.94000240000003	0.50134098100634938
611	0.27181394533831882	588.96997069999998	0.50039883912195893
610	0.27981196182232526	590	0.50041862867519427
609	0.28783876068786807	591.02001949999999	0.50036289708759663
608	0.29384759757133977	592.04998780000005	0.50213737564373861
607	0.30008852625391014	592.94000240000003	0.50370262009645439
606	0.30588763753964354	593.96997069999998	0.50552470054523524
605	0.31345930090271878	595	0.5049141134560321
604	0.31933767156726189	596.02001949999999	0.50581715763897817
603	0.32683261125808138	597.04998780000005	0.50762372733979233
602	0.33273629328607379	597.94000240000003	0.50682776054787804
601	0.33792155047170414	598.96997069999998	0.50781359980556195
600	0.34347100180243911	600	0.5066373531876347
599	0.34816590674360121	601.02001949999999	0.5054654924239752
598	0.35427694042812108	602.04998780000005	0.50593910390460806
597	0.35939801946810229	602.94000240000003	0.50450981883106649
596	0.36592531806937761	603.96997069999998	0.50180362799152134
595	0.3696327482646512	605	0.49813668248219234
594	0.37461215348366589	606.02001949999999	0.49212061343198471
593	0.37803414056895496	607.04998780000005	0.48576143670720756
592	0.38269497180163492	607.94000240000003	0.47997139611492118
591	0.38603801690260098	608.96997069999998	0.47059971888175778
590	0.39074215513353239	610	0.46139448755912399
589	0.39434556913471402	611.01000980000003	0.45274871155015267
588	0.39893751701534114	612.02001949999999	0.440140216802685
587	0.40288413901790371	613.03997800000002	0.42593633871750192
586	0.40548228660047952	614.04998780000005	0.41317583901852373
585	0.40956848607407903	615.07000730000004	0.4011240717631111
584	0.4132479747473437	615.94000240000003	0.3909580055715744
583	0.41788716745864118	616.95001219999995	0.37615696512681168
582	0.42184920558741001	617.96997069999998	0.36158337057527346
581	0.42503724784055869	618.97998050000001	0.34865695979013517
580	0.42949854724130504	620	0.33827438549116334
579	0.43596924011814797	621.02001949999999	0.32615744649678591
578	0.4421525270205684	622.04998780000005	0.31594538302592723
577	0.44775090292590913	622.94000240000003	0.30485610874218172
576	0.45346993520275292	623.96997069999998	0.2964365750788171
575	0.46127876273203905	625	0.28658005449242713
574	0.46872002767990989	626.02001949999999	0.27623941262529794
573	0.47676618813015814	627.04998780000005	0.26628883824169647
572	0.4869557962721508	627.94000240000003	0.25969256172485056
571	0.49728732934845277	628.96997069999998	0.25158851050456155
570	0.50925771607382553	630	0.24484581822777843
569	0.52236082078729906	631.01000980000003	0.23730205123232589
568	0.53644193547482433	632.02001949999999	0.22918775765916746
567	0.5517339979021888	633.03997800000002	0.2234845101097632
566	0.56892493693411861	634.04998780000005	0.21698165883654416
565	0.58724994322436908	635.07000730000004	0.21293015476603752
564	0.60955805100193505	635.94000240000003	0.20764148443423608
563	0.63160232884291667	636.95001219999995	0.20302595208788959
562	0.65745485399123937	637.96997069999998	0.19728105294376738
561	0.68641237720348747	638.97998050000001	0.19279808371215584
560	0.71807707071818372	640	0.18785486092030373
559	0.75298269822496711	641	0.18382472416646958
558	0.78717812095530626	642	0.17900870257535248
557	0.82281090305431415	643	0.17508553623365525
556	0.85511745622290714	644	0.17169684745640695
555	0.88789570436148557	645	0.16697336863819129
554	0.9141575654785028	646	0.16242754089342737
553	0.93468418421381683	647	0.15966151351924576
552	0.95431185944530406	648	0.15676339111557172
551	0.96721409238806011	649	0.15308998726372794
550	0.97888417837517872	650	0.14943998318734833
549	0.98481989934759018	651.01000980000003	0.14651436931085091
548	0.99322201578140201	652.02001949999999	0.14347566100627382
547	0.99578094433905961	653.03997800000002	0.14103248366818374
546	1	654.04998780000005	0.13749386256788038
545	0.99773606249477309	655.07000730000004	0.13369689451730607
544	0.99313731739134781	655.94000240000003	0.13151587491961728
543	0.9869642967377229	656.95001219999995	0.12954228431424025
542	0.98123371176735541	657.96997069999998	0.12729242926591058
541	0.9763513054566505	658.97998050000001	0.12385724855463434
540	0.96508436478815152	660	0.12155928349896783
539	0.95325165615259733	661	0.11908044496364027
538	0.93596323214750243	662	0.11648182623993682
537	0.92395224766514072	663	0.11357045282466116
536	0.91181844560787095	664	0.11136457598674965
535	0.89460616331558485	665	0.10912166734585295
534	0.8825329608192839	666	0.10582310113679902
533	0.87068013188935034	667	0.10344325032699982
532	0.8566255477529775	668	0.10099305304224965
531	0.84296618983467975	669	9.7387074005843677E-2
530	0.82993206967824007	670	9.4776742074624387E-2
529	0.82276763620859394	671.01000980000003	9.3420825314341552E-2
528	0.81682104217895513	672.02001949999999	9.0387010908625984E-2
527	0.80516355352807301	673.03997800000002	8.7175812806591396E-2
526	0.79792877851564359	674.04998780000005	8.4183061681776847E-2
525	0.7919834163571059	675.07000730000004	8.2102661132604976E-2
524	0.78483322060916338	675.94000240000003	7.9980040654573856E-2
523	0.77894643094557547	676.95001219999995	7.713452761108272E-2
522	0.77461128197310092	677.96997069999998	7.4354106037333237E-2
521	0.77072135993618529	678.97998050000001	7.1869290424308965E-2
520	0.76826905750804075	680	6.9892357015898326E-2
519	0.76649569996206479	681	6.7309603374450827E-2
518	0.76732657866150711	682	6.4711653247808268E-2
517	0.76776047216331078	683	6.2983914058203458E-2
516	0.76831521334667285	684	6.0503932229753497E-2
515	0.76993364618373961	685	5.9394528780349433E-2
514	0.77025532439585542	686	5.7465859054528022E-2
513	0.77133756727741598	687	5.6169698650793888E-2
512	0.77024015878487762	688	5.4956607456968065E-2
511	0.76910778173344263	689	5.4197749365253595E-2
510	0.76633850177562124	690	5.3186755352450821E-2
509	0.7617347876349384	690.97998050000001	5.1799897414530775E-2
508	0.75725028461040744	691.96997069999998	5.1330270589268673E-2
507	0.74916929577230074	692.95001219999995	5.0151229410606894E-2
506	0.74007732375274426	693.94000240000003	4.9390385682645775E-2
505	0.7309309536050862	695.07000730000004	4.8002461390880491E-2
504	0.72219130318882818	696.04998780000005	4.6886980684985091E-2
503	0.70987125920750616	697.03997800000002	4.5831634063674249E-2
502	0.69768408096578782	698.02001949999999	4.4919544212282836E-2
501	0.68470810585803643	699.01000980000003	4.3872721796894068E-2
500	0.67141034802618227	700	4.3701719573916803E-2
499	0.65704294106768746	701	4.226103880846234E-2
498	0.64322121595175519	702	4.1208329679593966E-2
497	0.62896044711930987	703	4.046069011264776E-2
496	0.61550774461721569	704	3.9289912394625572E-2
495	0.6010807753338262	705	3.8507771531231506E-2
494	0.58369758074935385	706	3.7280195871766474E-2
493	0.56863525114320368	707	3.6697521384886522E-2
492	0.55868945907942102	708	3.5939555837860196E-2
491	0.54773861942756186	709	3.5119009256818566E-2
490	0.53200332596290623	710	3.4142396192712268E-2
489	0.51848974618657018	710.97998050000001	3.364266054309939E-2
488	0.50980735306663705	711.96997069999998	3.2845269712073286E-2
487	0.50064016448477255	712.95001219999995	3.1863729330469118E-2
486	0.48758177832433885	713.94000240000003	3.119486344131819E-2
485	0.47618306809971944	715.07000730000004	3.0187095248795631E-2
484	0.47177454095120114	716.04998780000005	2.9451215746962411E-2
483	0.46413241439759206	717.03997800000002	2.898908019241353E-2
482	0.4541242451433028	718.02001949999999	2.7759958477607184E-2
481	0.44501487384413246	719.01000980000003	2.752689336020242E-2
480	0.43653200295890687	720	2.6347838812684012E-2
479	0.42951473615749358	720.97998050000001	2.5730191684271826E-2
478	0.42211186653425792	721.96997069999998	2.5189155430263593E-2
477	0.41546560400125215	722.95001219999995	2.44136082944705E-2
476	0.40767521585982258	723.94000240000003	2.3699452140118923E-2
475	0.400881860541905	725.07000730000004	2.3438942428519127E-2
474	0.39394947402622088	726.04998780000005	2.2904657012466377E-2
473	0.38898776894235099	727.03997800000002	2.1874948184726767E-2
472	0.38088040522770994	728.02001949999999	2.1440121846297146E-2
471	0.37357546434794836	729.01000980000003	2.0862169096568527E-2
470	0.36504224562326454	730	2.0359851119449133E-2
469	0.35778203221718202	730.97998050000001	1.964594567146935E-2
468	0.35111666227480387	731.96997069999998	1.8964061151870291E-2
467	0.34490116307795315	732.95001219999995	1.8690952333937548E-2
466	0.33701973061018103	733.94000240000003	1.8184383950730371E-2
465	0.32973314901079565	735.07000730000004	1.7617776754444498E-2
464	0.32235326884995164	736.04998780000005	1.6676350275639077E-2
463	0.31505789981340371	737.03997800000002	1.664445470745466E-2
462	0.30788462920620213	738.02001949999999	1.6026391405904471E-2
461	0.30092525094853695	739.01000980000003	1.5636957285104471E-2
460	0.29735060423261889	740	1.5434905230106679E-2
459	0.29146107455922848	740.96997069999998	1.5048036731000207E-2
458	0.28490047191806389	741.94000240000003	1.4450767469640365E-2
457	0.27892582431283292	743.04998780000005	1.3966071194868061E-2
456	0.27334910057837103	744.02001949999999	1.3665031400321099E-2
455	0.26823428132852878	745	1.3022540400542792E-2
454	0.26341078355116077	745.96997069999998	1.2760173756859412E-2
453	0.25915954266235436	746.94000240000003	1.2203568295054746E-2
452	0.25515883310393406	748.04998780000005	1.2134792173534826E-2
451	0.25190356098555167	749.02001949999999	1.1391273474274242E-2
450	0.24749444986118943	750	1.1326915735335995E-2
449	0.24389153272065545
448	0.24045700823431446
447	0.23859314537772303
446	0.23700761826817873
445	0.23515436040791479
444	0.2319651815893638
443	0.22981323781575363
442	0.22736759356489805
441	0.22635452722480925
440	0.22535711253565857
439	0.22450788951992739
438	0.2233858481700185
437	0.22129302446376464
436	0.22017505939381399
435	0.22013322982301406
434	0.22027094492076371
433	0.22003009092768341
432	0.21970923722157629
431	0.21913216958343987
430	0.21922267511000817
429	0.21987844504356696
428	0.21987023270366141
427	0.22046864694405133
426	0.22265895602159885
425	0.22334282620091861
424	0.22581922685985859
423	0.22626074222767542
422	0.22861314992980619
421	0.23157190338806727
420	0.23366448762109579
419	0.2367638694020055
418	0.23908922838320798
417	0.24173633780766682
416	0.24545684597113654
415	0.24919801989192455
414	0.25270521765746012
413	0.25624748668021591
412	0.26020339253701524
411	0.2622966470509247
410	0.26787538709137809
409	0.27210314793264517
408	0.27589492254499598
407	0.28037226625194089
406	0.2863638829246406
405	0.29201301049300182
404	0.29896567550888564
403	0.30367589421014735
402	0.30949893379979615
401	0.31621465453113801
400	0.32148599384454685

UV-Visibile X	UV-Visibile Y	Emissione X	Emissione Y
700	5.2731595807159602E-2	500	-1.7214986206636617E-3
699	5.6479301103306484E-2	501.0400085	-2.3036905180172269E-2
698	5.9990533726995407E-2	501.94000240000003	-3.2974481086501049E-2
697	5.7956953033659157E-2	502.98001099999999	-3.7781624897877307E-2
696	6.0212191268087432E-2	504.01998900000001	-3.8114979745948144E-2
695	6.2766076034826243E-2	505.07000729999999	-3.7691066103112528E-2
694	6.3633453109443572E-2	505.97000120000001	-3.6958589735698592E-2
693	6.3376713330403692E-2	507.01000979999998	-3.6100117621732403E-2
692	6.9070635400828737E-2	508.0499878	-3.4605639069920494E-2
691	7.0536612904789589E-2	508.9500122	-3.3727320702666375E-2
690	7.1834908499925354E-2	510	-3.1967202433768362E-2
689	7.3537310624988514E-2	511.0400085	-3.0189180398634798E-2
688	7.5380655685541476E-2	511.94000240000003	-2.8910903750505458E-2
687	7.4099628807665047E-2	512.97998050000001	-2.6709159335538187E-2
686	7.7860834487333913E-2	514.02001949999999	-2.3938475125716077E-2
685	7.9527275277502779E-2	515.07000730000004	-2.1162256321899799E-2
684	8.2857718031412328E-2	515.96997069999998	-1.8980928947228099E-2
683	8.5878900061066271E-2	517.01000980000003	-1.5555928110413298E-2
682	8.86058527847019E-2	518.04998780000005	-1.1440253253372662E-2
681	8.9510706976069665E-2	518.95001219999995	-7.4978991262119226E-3
680	9.2941913739748638E-2	520	-2.493123592136924E-3
679	9.6175840423089617E-2	521.03997800000002	2.343555003987603E-3
678	9.9064782573548699E-2	521.94000240000003	7.9645265830231154E-3
677	9.9597040013315624E-2	522.97998050000001	1.4891134002418293E-2
676	0.10145096337155779	524.02001949999999	2.2683391783270366E-2
675	0.10569764623286534	525.07000730000004	3.1882536849559537E-2
674	0.10946862092685254	525.96997069999998	3.8479883588505272E-2
673	0.1100203092805966	527.01000980000003	5.0333976443426222E-2
672	0.11404349121730557	528.04998780000005	6.2335946421009814E-2
671	0.11763724358379378	528.95001219999995	7.1689354931607857E-2
670	0.12069306479052193	530	8.2718060693586531E-2
669	0.12421243298792634	531.03997800000002	9.3958910077724722E-2
668	0.12639234509271605	531.94000240000003	0.10645037507280714
667	0.12957304136950973	532.97998050000001	0.12042309179728566
666	0.13371356459893352	534.02001949999999	0.13280308790262244
665	0.1376667925606474	535.07000730000004	0.14583126534677909
664	0.14019047642664259	535.96997069999998	0.15858096767062199
663	0.144231793105699	537.01000980000003	0.17553703513253349
662	0.14814020050454044	538.04998780000005	0.19530682940910732
661	0.1530293864562679	538.95001219999995	0.21139517258011689
660	0.15789844787175944	540	0.22885090777191691
659	0.163059296727986	541.03997800000002	0.25284308519661258
658	0.16705496009524551	541.94000240000003	0.2757550241275632
657	0.17109329096445802	542.97998050000001	0.30614928343781361
656	0.1757012619329642	544.02001949999999	0.33628997938619404
655	0.18268826222062562	545.07000730000004	0.3684906927432931
654	0.18659091215127069	545.96997069999998	0.40459412157519337
653	0.19233949455802513	547.01000980000003	0.44999607913352968
652	0.19820265672245621	548.04998780000005	0.4966001558069601
651	0.20340475630859028	548.95001219999995	0.54016400572406953
650	0.20900476745785557	550	0.58674082782709691
649	0.21565613028748035	551.02001949999999	0.64844524453522234
648	0.22277312169483629	552.04998780000005	0.70919340727650726
647	0.22998880287222345	552.94000240000003	0.7501707000983513
646	0.2363511390571984	553.96997069999998	0.80033212352120631
645	0.24151735005153541	555	0.84632335419090898
644	0.25034750208998369	556.02001949999999	0.89463074797628517
643	0.2572527093378309	557.04998780000005	0.9327348798109607
642	0.26540706355023153	557.94000240000003	0.9577235232490271
641	0.27572892278216971	558.96997069999998	0.97742458386491948
640	0.28239893692846529	560	0.99404214432929605
639	0.2887130986485259	561.02001949999999	1
638	0.29908847437851571	562.04998780000005	0.9985497685624608
637	0.30681707873635888	562.94000240000003	0.99428858330415892
636	0.31607604434835024	563.96997069999998	0.98294713100994124
635	0.32227688781482272	565	0.9654460430222187
634	0.3323524282664525	566.02001949999999	0.94105489622746563
633	0.33999227485763822	567.04998780000005	0.91877784611365787
632	0.34876484978887962	567.94000240000003	0.89746417416568136
631	0.35849202082348813	568.96997069999998	0.87499911561700117
630	0.36782004838834992	570	0.84196223561224914
629	0.37576292065062367	571.02001949999999	0.8124808858033763
628	0.38394862505068861	572.04998780000005	0.78980180609894612
627	0.39435528249334278	572.94000240000003	0.77020517427989332
626	0.40300552849358667	573.96997069999998	0.74536743483091272
625	0.41139934459975569	575	0.72106044300493422
624	0.41900251026677521	576.02001949999999	0.69655544840929229
623	0.42678395913107908	577.04998780000005	0.67667924219964148
622	0.43652012232429194	577.94000240000003	0.66148398895000726
621	0.44540924004837762	578.96997069999998	0.64131591895922002
620	0.45200093957736964	580	0.62321580381053243
619	0.45840077892348302	581.02001949999999	0.60923653640031139
618	0.46702032068485549	582.04998780000005	0.59465761999561562
617	0.47501134401813766	582.94000240000003	0.58411377120794683
616	0.48134088590366314	583.96997069999998	0.57043698205501359
615	0.48669891160621315	585	0.55739823751488438
614	0.49692509988225581	586.02001949999999	0.55179244421057438
613	0.50306151867152438	587.04998780000005	0.54381841735020076
612	0.50918445623260911	587.94000240000003	0.5381005933625973
611	0.51564736109207077	588.96997069999998	0.53022205323041116
610	0.52335320819360087	590	0.52457972924425145
609	0.53117240194234128	591.02001949999999	0.5203598084866351
608	0.53616433601270219	592.04998780000005	0.51771137851844728
607	0.54147051390024536	592.94000240000003	0.51688838518995806
606	0.54648901211570033	593.96997069999998	0.51437541534077291
605	0.55459533135036576	595	0.51562740566629439
604	0.56258605638142034	596.02001949999999	0.51692386398170243
603	0.56986604908882876	597.04998780000005	0.51818790372593104
602	0.57184065346539814	597.94000240000003	0.52081529507726965
601	0.57927941381627202	598.96997069999998	0.52389147881417586
600	0.58351472969122975	600	0.52678367015040639
599	0.58784474900771033	601.02001949999999	0.5295922329016205
598	0.59295981880610904	602.04998780000005	0.53339702301049019
597	0.60278403900387756	602.94000240000003	0.53707108663117664
596	0.60776699545432333	603.96997069999998	0.5404438674040053
595	0.61034409963598724	605	0.5392744059545107
594	0.61698428815813278	606.02001949999999	0.54020201872865381
593	0.62062274145518259	607.04998780000005	0.53943764671431371
592	0.62694599544142049	607.94000240000003	0.53859108055613514
591	0.63052915512732699	608.96997069999998	0.53470132299616657
590	0.63511144024381172	610	0.52824781600580439
589	0.63957860314770665	611.01000980000003	0.52349633495484538
588	0.64527771349955987	612.02001949999999	0.51539765416586203
587	0.64997852436925985	613.03997800000002	0.50473350252933036
586	0.65414409368547077	614.04998780000005	0.49589287502782259
585	0.65819935611867697	615.07000730000004	0.48681967489973793
584	0.66266122898476021	615.94000240000003	0.4775015181195249
583	0.66749309092207076	616.95001219999995	0.46395296906081912
582	0.67496109007626193	617.96997069999998	0.45102764188894962
581	0.67756484567963859	618.97998050000001	0.44109826475905117
580	0.68397190614919545	620	0.42920144018470874
579	0.68774417796691445	621.02001949999999	0.41632598409792215
578	0.69100339207791861	622.04998780000005	0.40605678517052901
577	0.69885529391637113	622.94000240000003	0.39519704596267718
576	0.70346832735418474	623.96997069999998	0.38447307766523858
575	0.70937491615889459	625	0.37569092802122761
574	0.71690594857175727	626.02001949999999	0.36499148886848798
573	0.72319744554365328	627.04998780000005	0.35602348194999417
572	0.73070952737058015	627.94000240000003	0.34801789713301051
571	0.73923700227344125	628.96997069999998	0.34063175682438129
570	0.74534386515595008	630	0.33252243717976321
569	0.75494180514683995	631.01000980000003	0.32338922917790758
568	0.76558551421840715	632.02001949999999	0.31568114983029971
567	0.77687755463429564	633.03997800000002	0.30903633465137403
566	0.78927816124298611	634.04998780000005	0.30401876263099709
565	0.80179942455543318	635.07000730000004	0.29552331220329653
564	0.81827961457259535	635.94000240000003	0.29119738544040435
563	0.83057818954934803	636.95001219999995	0.28433135377379798
562	0.84747167552615421	637.96997069999998	0.2791749266816646
561	0.86640293580885241	638.97998050000001	0.27310798078166942
560	0.88622187740788283	640	0.26462178264998182
559	0.90454787627394917	641	0.25888638656992841
558	0.9225939438936468	642	0.25309062394313725
557	0.94291226921038895	643	0.24874504512301771
556	0.95665335519944827	644	0.24298990141064097
555	0.97288711636569603	645	0.2362367133483575
554	0.9831625709325903	646	0.23002696766336578
553	0.99126452937648879	647	0.22379474892034656
552	0.99594416784364204	648	0.22022071444580277
551	1	649	0.21367707600356559
550	0.99410821355950696	650	0.20787399765155881
549	0.99028935643557725	651.01000980000003	0.20387237674305497
548	0.98707978017993925	652.02001949999999	0.19824518621160112
547	0.98511694317431953	653.03997800000002	0.19433718722014964
546	0.9788207644401693	654.04998780000005	0.18852492839446436
545	0.970416002631728	655.07000730000004	0.18481447742323609
544	0.96034249482141865	655.94000240000003	0.18092393094568832
543	0.95104109899891709	656.95001219999995	0.17728228595885337
542	0.94630465390561502	657.96997069999998	0.17194576336040052
541	0.93960032569321339	658.97998050000001	0.16812646131697354
540	0.93318569755811465	660	0.16395261045052456
539	0.92230556470046943	661	0.16034625297989752
538	0.91309965885596167	662	0.15684975065269063
537	0.90809718179830756	663	0.15281392996657941
536	0.90159261102038823	664	0.1497317453670895
535	0.89108975229983789	665	0.14597618088237577
534	0.88437675882128652	666	0.14237719886356534
533	0.8811727273563178	667	0.1392860609144283
532	0.87433576280687364	668	0.135598788376772
531	0.86528140013927202	669	0.13127337558854352
530	0.85817334752303331	670	0.12781283024192175
529	0.85707218981951661	671.01000980000003	0.1238817365469496
528	0.85426192687912195	672.02001949999999	0.12030311177289438
527	0.84668452794881299	673.03997800000002	0.11651315629770913
526	0.84188105027023019	674.04998780000005	0.11309721042723696
525	0.83937331948183769	675.07000730000004	0.1090856798540764
524	0.83406470018564349	675.94000240000003	0.10651700545465498
523	0.82942609382508192	676.95001219999995	0.10196371788484605
522	0.82685107565710281	677.96997069999998	9.8259184046150222E-2
521	0.82289448081172833	678.97998050000001	9.4248657606883335E-2
520	0.82072577864558238	680	9.1436747784471972E-2
519	0.81808863932590459	681	8.7861661357150442E-2
518	0.82088533711877121	682	8.4997764636383824E-2
517	0.81811442050478	683	8.1989777146094706E-2
516	0.8177105325605154	684	7.864301968574415E-2
515	0.81589301396838587	685	7.687003616285247E-2
514	0.81380245109403848	686	7.356439974653535E-2
513	0.81233554175547351	687	7.1891433462069346E-2
512	0.81189530913418295	688	7.0337538643197001E-2
511	0.80764112839371061	689	6.8814843233312301E-2
510	0.80252378593609863	690	6.7292793284354516E-2
509	0.79729923382827916	690.97998050000001	6.5620663736351767E-2
508	0.78770426020043649	691.96997069999998	6.4223482932318124E-2
507	0.78011039407875671	692.95001219999995	6.2560665388127587E-2
506	0.77153660268268853	693.94000240000003	6.1261935838673218E-2
505	0.76129813308383365	695.07000730000004	5.9471392225056686E-2
504	0.75229669698991564	696.04998780000005	5.7455496103646808E-2
503	0.74277675206971183	697.03997800000002	5.66922955516913E-2
502	0.73489624670457088	698.02001949999999	5.4856674266817097E-2
501	0.72421666721591904	699.01000980000003	5.4041259636069969E-2
500	0.71365596994108615	700	5.2297228153691019E-2
499	0.70530091931456629	701	5.0699427169816152E-2
498	0.69677541613207472	702	4.9235619011001652E-2
497	0.68910990601336974	703	4.7974316719271229E-2
496	0.68215673482304751	704	4.5946389122203363E-2
495	0.67432163698510927	705	4.516479769065098E-2
494	0.66359287447594306	706	4.3245966195259021E-2
493	0.65409532049558472	707	4.1960636819509282E-2
492	0.6499386842594661	708	4.0542698276598572E-2
491	0.64647886148799638	709	3.8067902800363033E-2
490	0.63640791544423758	710	3.6842312409602757E-2
489	0.62755518482629324	710.97998050000001	3.539513493167646E-2
488	0.62602627168080349	711.96997069999998	3.3686869135544618E-2
487	0.6222573027315802	712.95001219999995	3.16877202465023E-2
486	0.61259964725414906	713.94000240000003	3.0758033530379661E-2
485	0.60740698187965214	715.07000730000004	2.8572077062108386E-2
484	0.60651284169084674	716.04998780000005	2.6847350921844641E-2
483	0.6059110828839086	717.03997800000002	2.5443129329243579E-2
482	0.59872935031268792	718.02001949999999	2.3472292948576647E-2
481	0.59354802419340458	719.01000980000003	2.2198612522481086E-2
480	0.59083729931952778	720	2.0555058474181771E-2
479	0.58740536244824104	720.97998050000001	1.928259733562215E-2
478	0.58356062056175928	721.96997069999998	1.7808464108314125E-2
477	0.58089309536343858	722.95001219999995	1.6027495471036195E-2
476	0.57900192811575979	723.94000240000003	1.4705539738065185E-2
475	0.57385529920349942	725.07000730000004	1.3329230197320964E-2
474	0.57138026548024334	726.04998780000005	1.1438137433833101E-2
473	0.56951390972274507	727.03997800000002	1.0183834078178884E-2
472	0.56644906862779965	728.02001949999999	8.7897193984309424E-3
471	0.56262572161204016	729.01000980000003	7.5574827029617087E-3
470	0.55909630197176463	730	6.6806017788839213E-3
469	0.55695808732677199	730.97998050000001	5.286188252418977E-3
468	0.55423060382106915	731.96997069999998	3.3624497341819366E-3
467	0.55217237438225053	732.95001219999995	2.3280599263347393E-3
466	0.55026342764906833	733.94000240000003	1.4669310841631581E-3
465	0.54931450478807664	735.07000730000004	4.5518172118229718E-4
464	0.54747626269610172	736.04998780000005	-7.4015965439363412E-4
463	0.54632015046335769	737.03997800000002	-1.9073379426964726E-3
462	0.54500121457569017	738.02001949999999	-2.902444665743722E-3
461	0.54492638882826816	739.01000980000003	-3.8782938617995125E-3
460	0.54650817412721842	740	-4.6614960621214757E-3
459	0.54677704981930741	740.96997069999998	-5.8501014872460733E-3
458	0.54595819738003415	741.94000240000003	-6.9072333446847092E-3
457	0.54648811389843888	743.04998780000005	-8.0610532935991869E-3
456	0.54747416639021274	744.02001949999999	-8.4709391821802468E-3
455	0.54864705436800232	745	-9.6365485416702798E-3
454	0.54850536886779389	745.96997069999998	-1.0568488542522986E-2
453	0.55192145796287251	746.94000240000003	-1.1219906379988182E-2
452	0.55467841903025306	748.04998780000005	-1.2670843312148921E-2
451	0.55545147891371704	749.02001949999999	-1.3258165024476879E-2
450	0.55760097444114165	750	-1.3802521889355846E-2
449	0.55987553679334268
448	0.56314981670603592
447	0.56628937097160414
446	0.57119540106491828
445	0.57459313691254799
444	0.58004168386241739
443	0.58297645310191137
442	0.58739478627860786
441	0.5912797474895406
440	0.59569757268363999
439	0.6006944028067287
438	0.60650737906571572
437	0.61221189348335792
436	0.61705820832161185
435	0.62226522122113237
434	0.62738412771858942
433	0.63321720187976238
432	0.64078738561874871
431	0.64685920597384372
430	0.65200379207564474
429	0.6583697618696811
428	0.66465969638752753
427	0.67132683215570854
426	0.67827847828373966
425	0.68676635458258473
424	0.6943894341894542
423	0.70079075849381722
422	0.70930689758273224
421	0.71778525096791612
420	0.72558025359566192
419	0.73472506618263766
418	0.74426531537775542
417	0.75235534158621631
416	0.76219412622469973
415	0.7701175890517411
414	0.77946256512237577
413	0.78855121397234895
412	0.7973331314472446
411	0.80780244035104731
410	0.81678099780036295
409	0.82547358182701358
408	0.83547905136367517
407	0.84331965962132238
406	0.85332086219059788
405	0.86419970504007027
404	0.8748663685689072
403	0.88639027052639574
402	0.89449684755505154
401	0.90617282827599221
400	0.91697961945561024

UV-Visibile X	UV-Visibile Y	Emissione X	Emissione Y
700	-4.2981952742674544E-2	500	7.8478457180007017E-5
699	-3.9023212647108577E-2	501.0400085	-2.8871419407981681E-4
698	-3.0913323869691554E-2	501.94000240000003	1.3727147240244277E-4
697	-3.6331205960295453E-2	502.98001099999999	3.1790488243942669E-4
696	-3.8873220273795493E-2	504.01998900000001	1.0877459037213269E-3
695	-3.3610326000998128E-2	505.07000729999999	1.6912397478423028E-3
694	-2.9259579804436955E-2	505.97000120000001	2.4765298606015877E-3
693	-3.0099388018494901E-2	507.01000979999998	2.4598711499212804E-3
692	-2.8514718026450437E-2	508.0499878	4.5950699112070684E-3
691	-2.6575467683919191E-2	508.9500122	4.8891813976551374E-3
690	-2.6397126680326163E-2	510	6.2178032775708006E-3
689	-2.2924701388714039E-2	511.0400085	7.9159960357900738E-3
688	-2.5305891140729612E-2	511.94000240000003	9.3619962091568924E-3
687	-2.9802648308651064E-2	512.97998050000001	1.198774234011042E-2
686	-2.0452538315037561E-2	514.02001949999999	1.4321077962739619E-2
685	-2.478839211015374E-2	515.07000730000004	1.6585016085747972E-2
684	-1.7742542763155431E-2	515.96997069999998	1.948801338632155E-2
683	-2.2423510397352433E-2	517.01000980000003	2.2955182334125579E-2
682	-2.0969090801142263E-2	518.04998780000005	2.6702714651808884E-2
681	-1.7941003565135512E-2	518.95001219999995	3.2308498111758684E-2
680	-1.4686447136222788E-2	520	3.8775064411026121E-2
679	-9.3518685111007045E-3	521.03997800000002	4.3638813142508934E-2
678	-8.3316250357901942E-3	521.94000240000003	5.1890789741121886E-2
677	-1.2783249960849813E-2	522.97998050000001	6.1710126287637425E-2
676	-8.7500786665978512E-3	524.02001949999999	7.2657042610235298E-2
675	-4.9574882296926854E-3	525.07000730000004	8.5589218572246925E-2
674	-2.8642382499870973E-3	525.96997069999998	9.5709981805750091E-2
673	-1.669240315205689E-3	527.01000980000003	0.11402142812826341
672	2.8862520443567086E-3	528.04998780000005	0.13413116895999333
671	9.247324387057803E-4	528.95001219999995	0.14961638050731429
670	3.3293246957507203E-3	530	0.16764693766995767
669	3.8942270437218626E-3	531.03997800000002	0.1908687819205119
668	7.8800612079537938E-3	531.94000240000003	0.21377414454781143
667	9.7493432799395513E-3	532.97998050000001	0.24560207570410228
666	1.2537733678417243E-2	534.02001949999999	0.27451296347415499
665	1.2413461282373205E-2	535.07000730000004	0.30563051549130693
664	1.3457751465807497E-2	535.96997069999998	0.33562860713422887
663	1.4731899806517084E-2	537.01000980000003	0.38251478648629167
662	1.4085085499753571E-2	538.04998780000005	0.43101192724315168
661	1.8710916933665441E-2	538.95001219999995	0.47623192896237743
660	2.203300157755498E-2	540	0.5303018914180142
659	2.6761060608701374E-2	541.03997800000002	0.58469211330128401
658	2.9297620632348687E-2	541.94000240000003	0.64482733071977927
657	2.6495644333650776E-2	542.97998050000001	0.70509716690177415
656	3.2087409608819263E-2	544.02001949999999	0.75806314721037171
655	3.3537490853423405E-2	545.07000730000004	0.80928487183281173
654	3.5502552225949863E-2	545.96997069999998	0.86180858217144285
653	3.7841184085734253E-2	547.01000980000003	0.89853724674800717
652	3.9031672575851016E-2	548.04998780000005	0.92411011270657539
651	4.3240870038863413E-2	548.95001219999995	0.94871297723455827
650	4.5873860089353631E-2	550	0.97068812578471486
649	4.8728635295618376E-2	551.02001949999999	0.97876172264313421
648	5.2551071407436686E-2	552.04998780000005	0.9834434551360044
647	5.8352887078038082E-2	552.94000240000003	0.99267416550375853
646	5.6513422696865573E-2	553.96997069999998	1
645	6.4645394025018801E-2	555	0.99708715094116795
644	6.6977913901330371E-2	556.02001949999999	0.9914414025066669
643	6.6703715035147618E-2	557.04998780000005	0.97825582271212497
642	7.2692222402006013E-2	557.94000240000003	0.96972940825391429
641	7.8294223466705587E-2	558.96997069999998	0.95827366080992782
640	8.1534414958918486E-2	560	0.93499422079684802
639	8.580569218458059E-2	561.02001949999999	0.9161586734837236
638	8.7756857155445678E-2	562.04998780000005	0.9004963823396428
637	9.2927410640835553E-2	562.94000240000003	0.87835747368604034
636	9.9842138356690188E-2	563.96997069999998	0.85319189844404553
635	9.8099486356611282E-2	565	0.82559150834610062
634	0.10663208750483673	566.02001949999999	0.80277077319885282
633	0.11171378496689754	567.04998780000005	0.78908312014800086
632	0.11583864007563206	567.94000240000003	0.76483206003572779
631	0.1175046610490489	568.96997069999998	0.74751676357851093
630	0.12391184907148274	570	0.72480999321481576
629	0.13036849903953807	571.02001949999999	0.70654740989830211
628	0.13626635548341326	572.04998780000005	0.68453620276800364
627	0.14186996010500139	572.94000240000003	0.67545674234468467
626	0.14653758470453462	573.96997069999998	0.65460848679792594
625	0.15501598295701338	575	0.64217513392654924
624	0.15645196943526676	576.02001949999999	0.63596745991831627
623	0.16375764064277964	577.04998780000005	0.61487905883191063
622	0.16591271052363007	577.94000240000003	0.6060409213371436
621	0.17247891443535759	578.96997069999998	0.59682164180165076
620	0.17684723411948847	580	0.58692387165415749
619	0.18181902890516477	581.02001949999999	0.58426568969348835
618	0.18727890781839299	582.04998780000005	0.57222049416518961
617	0.19191348432891286	582.94000240000003	0.56724921354367741
616	0.19491701732598851	583.96997069999998	0.56691747425270467
615	0.20212634640796043	585	0.57574158082125204
614	0.20449639604182687	586.02001949999999	0.56887665887541827
613	0.20880501508979593	587.04998780000005	0.5718695237600806
612	0.2149086572033265	587.94000240000003	0.57113221096557165
611	0.21913341463308966	588.96997069999998	0.57889011101950116
610	0.22794953429729403	590	0.57409637611150621
609	0.23361388767558372	591.02001949999999	0.57753690727836382
608	0.2376719172063364	592.04998780000005	0.57768207383244619
607	0.24130724635489337	592.94000240000003	0.57645941702471892
606	0.2429409287732921	593.96997069999998	0.58199110261351128
605	0.25340773336414629	595	0.57959661445286292
604	0.26005054860435717	596.02001949999999	0.57222402649266246
603	0.26465840889569575	597.04998780000005	0.5701533791181983
602	0.26747867356267863	597.94000240000003	0.56116227446595879
601	0.27237662109901761	598.96997069999998	0.55164618602256588
600	0.27810828649131802	600	0.54574042304799331
599	0.27699024153892898	601.02001949999999	0.52972995771707398
598	0.28410663028070021	602.04998780000005	0.52814421275460988
597	0.29442388161270772	602.94000240000003	0.52661429747131361
596	0.29921941365928229	603.96997069999998	0.5070287310803574
595	0.29893444144089332	605	0.50399769815389128
594	0.30466760320987551	606.02001949999999	0.4859424396163714
593	0.31460557151017621	607.04998780000005	0.47626607420516986
592	0.31311906526467514	607.94000240000003	0.46756388011679945
591	0.31949476850010022	608.96997069999998	0.44903990874699701
590	0.32417363289987	610	0.44039879355678924
589	0.32879329306047056	611.01000980000003	0.43184171683066547
588	0.33542316389333759	612.02001949999999	0.42288284424462647
587	0.34188089188259257	613.03997800000002	0.40455113643192731
586	0.34258974607851983	614.04998780000005	0.39130376654745397
585	0.34876270509433688	615.07000730000004	0.38062237158195344
584	0.35396151198282438	615.94000240000003	0.37883631746436297
583	0.35516514363584911	616.95001219999995	0.36128504552050278
582	0.36329319413790984	617.96997069999998	0.34986989468388391
581	0.37127097394124853	618.97998050000001	0.33607583197596369
580	0.37509089318888361	620	0.32794213748397449
579	0.38503890528064388	621.02001949999999	0.31735984236520609
578	0.38453554800684592	622.04998780000005	0.31191886764681859
577	0.39514940576167473	622.94000240000003	0.29940022513469922
576	0.40296242572982383	623.96997069999998	0.29186154672840331
575	0.41156414329503815	625	0.2839467303449858
574	0.41980385821845684	626.02001949999999	0.27111952914956061
573	0.42935900385112374	627.04998780000005	0.26670438505865351
572	0.44234696574349675	627.94000240000003	0.2604894502711626
571	0.45131374690091619	628.96997069999998	0.25405958654711541
570	0.46037496645427523	630	0.24855216089273899
569	0.47590229481576835	631.01000980000003	0.23844525069105874
568	0.48358061133846592	632.02001949999999	0.23157407366571994
567	0.49833709857583064	633.03997800000002	0.22789722363391451
566	0.51624648928753403	634.04998780000005	0.22328473845606164
565	0.53425115559720826	635.07000730000004	0.21632437148828509
564	0.55565414595055651	635.94000240000003	0.21002294507522845
563	0.57097883484093737	636.95001219999995	0.20497316939509544
562	0.5884468511571308	637.96997069999998	0.20137557464475786
561	0.61441025237763902	638.97998050000001	0.19757808774459437
560	0.6401427489001873	640	0.19448553431874741
559	0.66679964468453079	641	0.19180098296200035
558	0.68625037730937799	642	0.18780789646233079
557	0.7189169285753646	643	0.18436243469810734
556	0.74286232845053557	644	0.18006078935437439
555	0.76950089591985871	645	0.17517148692711998
554	0.79259675227137627	646	0.17074922931094683
553	0.81737614925940894	647	0.16930659047198118
552	0.83986709256560321	648	0.16463516045354562
551	0.86014618495403627	649	0.16134389226677776
550	0.87522638070403924	650	0.15677457921040872
549	0.89966408005643872	651.01000980000003	0.15456526558106087
548	0.91361421507953777	652.02001949999999	0.15150668578923296
547	0.93943984070636566	653.03997800000002	0.14648475136991523
546	0.95645626405311457	654.04998780000005	0.14464365260090675
545	0.96883213045442529	655.07000730000004	0.1385157244903622
544	0.98499651098031382	655.94000240000003	0.13479337188189275
543	0.98442520838835357	656.95001219999995	0.1338248915239563
542	0.99501950775325687	657.96997069999998	0.12838475078401795
541	0.99950984398242115	658.97998050000001	0.12655731503131001
540	1	660	0.12286032610308978
539	0.98768838263714631	661	0.12069845285506725
538	0.97652525578445104	662	0.11600175729891748
537	0.97255428040339253	663	0.1144718419030909
536	0.96335562675700481	664	0.10902338560483626
535	0.94452116804695807	665	0.10749347019293391
534	0.94010689075909071	666	0.10578066159345435
533	0.93181240838429291	667	0.10365474883126606
532	0.92061799369474828	668	9.9475083485915994E-2
531	0.90212072060557391	669	9.6582054428581879E-2
530	0.89028008596849939	670	9.4789959810774982E-2
529	0.88753227152773406	671.01000980000003	9.1763612004768791E-2
528	0.88642988501004116	672.02001949999999	8.9303200434304633E-2
527	0.87494163531320912	673.03997800000002	8.5011784050540551E-2
526	0.87222828894913329	674.04998780000005	8.3746255545194298E-2
525	0.8683016203671039	675.07000730000004	7.6742127681102584E-2
524	0.85899166519941483	675.94000240000003	7.7276445189041795E-2
523	0.85669393747809086	676.95001219999995	7.483555309975623E-2
522	0.85062912055398054	677.96997069999998	7.3174336511780638E-2
521	0.84652260600874585	678.97998050000001	6.9216805710225079E-2
520	0.8427778469190611	680	6.7902726856399781E-2
519	0.84041535566410763	681	6.4778033478476077E-2
518	0.84405862019300459	682	6.4162547319567956E-2
517	0.8418085677449676	683	6.1942986419956825E-2
516	0.84083682160300799	684	5.9133425699760864E-2
515	0.84005603493672554	685	5.7369981709224777E-2
514	0.84233003195321532	686	5.7881547944907748E-2
513	0.84393239353238669	687	5.4211044913822087E-2
512	0.84183675429502769	688	5.4445100890022836E-2
511	0.84230504716735299	689	5.320649981872632E-2
510	0.84334228929241006	690	5.2758729124448213E-2
509	0.84150877033073701	690.97998050000001	5.0927362493943404E-2
508	0.84391701577543021	691.96997069999998	5.2178737382844322E-2
507	0.84373376601582561	692.95001219999995	4.8704024047165909E-2
506	0.83850745465667509	693.94000240000003	4.8901671843599927E-2
505	0.83757893537709471	695.07000730000004	4.7885879887278049E-2
504	0.83183494416337689	696.04998780000005	4.590477803506033E-2
503	0.82645054852761413	697.03997800000002	4.4445612330787192E-2
502	0.8220599881411913	698.02001949999999	4.4668010565327314E-2
501	0.81478399167383275	699.01000980000003	4.3386798400610861E-2
500	0.80441642097997756	700	4.2099371024282281E-2
499	0.79691172699091872
498	0.7816660241584571
497	0.77394511146701905
496	0.76444530747306927
495	0.74738466024536865
494	0.72798985860358034
493	0.71122660008866201
492	0.70818121723765148
491	0.70018224136268381
490	0.6838746225724075
489	0.66553789375861594
488	0.66316523207356848
487	0.65933720681786978
486	0.64296567123596016
485	0.63070058556871922
484	0.62932369175701308
483	0.63074761402327639
482	0.61607370209221202
481	0.6067558628464228
480	0.59812426601292623
479	0.58830262376270726
478	0.58390938105672807
477	0.57855935773178224
476	0.57453767583745385
475	0.56822004222521383
474	0.56087719958973559
473	0.55651481653932477
472	0.5514464665175185
471	0.54673509911348928
470	0.54137411546298186
469	0.53505096669504038
468	0.53111525469276766
467	0.52579500864752726
466	0.52367217907047869
465	0.51723142345413742
464	0.51092433910174728
463	0.50588615402152903
462	0.50177080983624622
461	0.49466214222982041
460	0.49335480391465036
459	0.49276550698963556
458	0.486632230120561
457	0.48250081518166132
456	0.47729807646223882
455	0.47352541388020575
454	0.47016505775647838
453	0.46916753732019362
452	0.468090550533801
451	0.46432387176541001
450	0.46325974331406805
449	0.46048528749686424
448	0.46115833420057584
447	0.46197628332744789
446	0.46311240201037918
445	0.46161075585902911
444	0.4621624424859892
443	0.46284793297074472
442	0.46240839987156068
441	0.4645162409504468
440	0.46716971518116773
439	0.46586293025030312
438	0.46677377622736388
437	0.47202897003063199
436	0.47076226109772251
435	0.47349147140161835
434	0.47706594694366938
433	0.48032799085655487
432	0.48226609251962305
431	0.4825842048397993
430	0.48816920937187513
429	0.4894492810928926
428	0.49091065718464166
427	0.49312353314038299
426	0.49996377013885762
425	0.5067870787841372
424	0.51207601997159413
423	0.51852395001691687
422	0.52187228801142149
421	0.53219790016839319
420	0.5404526304015429
419	0.54648827452572113
418	0.55743718027326605
417	0.56459807796578099
416	0.57467234977730519
415	0.58338953729804921
414	0.58884458004429174
413	0.59686001622520146
412	0.60558244770056158
411	0.61672425794229913
410	0.62588668462142971
409	0.63277632136785633
408	0.64136673214506756
407	0.64806994735643408
406	0.65953655958483048
405	0.6720617207581937
404	0.68610345231802961
403	0.7006729095481341
402	0.71295071094574303
401	0.72521848307389813
400	0.73484027392134676

UV-Visibile X	UV-Visibile Y	Emissione X	Emissione Y
700	3.0442513089410674E-2	500	-2.4414848304932831E-4
699	3.3360735969207106E-2	501.0400085	2.3315195452844667E-4
698	3.5694709935189833E-2	501.94000240000003	1.2290014984083593E-4
697	3.5837424504081873E-2	502.98001099999999	9.8661766643960724E-4
696	3.8276604858806157E-2	504.01998900000001	1.3711802302274526E-3
695	3.7571241372987119E-2	505.07000729999999	1.8969060130148098E-3
694	4.0188937556503407E-2	505.97000120000001	2.4464688928505455E-3
693	3.8594364965370893E-2	507.01000979999998	3.3801599224570398E-3
692	4.1986493668170762E-2	508.0499878	3.8983918819535772E-3
691	4.4053397773935368E-2	508.9500122	4.522010466127731E-3
690	4.4584417829805635E-2	510	5.0869583299829463E-3
689	4.7433841673866259E-2	511.0400085	6.593215164485201E-3
688	4.8541354588479309E-2	511.94000240000003	7.6371100440245478E-3
687	5.1827540780933788E-2	512.97998050000001	9.1524210419470977E-3
686	5.3254167126276133E-2	514.02001949999999	1.0731817203151861E-2
685	5.2912607925186664E-2	515.07000730000004	1.237076741643894E-2
684	5.6082795321478314E-2	515.96997069999998	1.3425496019996907E-2
683	5.8723255112056179E-2	517.01000980000003	1.501657377476946E-2
682	5.9506526647550496E-2	518.04998780000005	1.7413343096471502E-2
681	6.2319257465307247E-2	518.95001219999995	1.9307152615631144E-2
680	6.5181845236258709E-2	520	2.1297906303693138E-2
679	6.6994160590151619E-2	521.03997800000002	2.3931400806227472E-2
678	7.0025956266828823E-2	521.94000240000003	2.7022698756051008E-2
677	6.9762361374465259E-2	522.97998050000001	2.984657730600199E-2
676	7.3392121527522669E-2	524.02001949999999	3.4163999471787977E-2
675	7.5878143054597808E-2	525.07000730000004	3.7952666245052682E-2
674	7.7826032342931742E-2	525.96997069999998	4.1547425303805216E-2
673	8.003711224155112E-2	527.01000980000003	4.7612563699987669E-2
672	8.3438348992754124E-2	528.04998780000005	5.3768234062301988E-2
671	8.6090627946673007E-2	528.95001219999995	5.9350614854399332E-2
670	8.7962432166993218E-2	530	6.6010752156598976E-2
669	9.0089802886251819E-2	531.03997800000002	7.3402224703875585E-2
668	9.3288536904767086E-2	531.94000240000003	8.164872490491501E-2
667	9.5792444296273094E-2	532.97998050000001	9.1447769876494486E-2
666	9.8943605985065575E-2	534.02001949999999	0.10197748597103901
665	0.10437385496591897	535.07000730000004	0.11299261610402929
664	0.10338196464315295	535.96997069999998	0.1232270668745255
663	0.10709917961904511	537.01000980000003	0.13961664633844298
662	0.11088622500046044	538.04998780000005	0.15750442311377549
661	0.11504381445508342	538.95001219999995	0.17380164602344303
660	0.11907825486704229	540	0.1918150881159591
659	0.12230182040564466	541.03997800000002	0.2162427140546038
658	0.12547654878345346	541.94000240000003	0.23996417664615383
657	0.12969295932686747	542.97998050000001	0.26956439435596968
656	0.13405013074901601	544.02001949999999	0.30228529205429733
655	0.13774060773296942	545.07000730000004	0.33525468365324751
654	0.14108741565877211	545.96997069999998	0.37351994655809428
653	0.14603543841656133	547.01000980000003	0.41796392385516745
652	0.15010949743834148	548.04998780000005	0.46837064395314326
651	0.15548461636007044	548.95001219999995	0.51206429117973506
650	0.16036722263336206	550	0.56375245013851394
649	0.16662405269251057	551.02001949999999	0.63046438816766048
648	0.17199082539696542	552.04998780000005	0.69841531357172526
647	0.17698387109034849	552.94000240000003	0.74756844858922655
646	0.18477320441035744	553.96997069999998	0.80493908229894706
645	0.18967396347760321	555	0.85647569485236308
644	0.19509565435837598	556.02001949999999	0.91000660248798715
643	0.20287268534306407	557.04998780000005	0.95075711310124422
642	0.20893516880168961	557.94000240000003	0.97359657082146434
641	0.21626702227029013	558.96997069999998	0.98837105658371149
640	0.22312372752744114	560	0.99695235938115323
639	0.23077927051691921	561.02001949999999	1
638	0.23810827674227564	562.04998780000005	0.99590453302852022
637	0.24687985844664007	562.94000240000003	0.98703860357129247
636	0.25238413800824716	563.96997069999998	0.97258299459088526
635	0.26048583107216244	565	0.95343285115176601
634	0.26947088062803404	566.02001949999999	0.92855303614315254
633	0.27720854414438756	567.04998780000005	0.90757989975006736
632	0.28434240493553214	567.94000240000003	0.88664875064023829
631	0.29443902638986313	568.96997069999998	0.8640958280435096
630	0.30406387324618095	570	0.83343625558382561
629	0.3108175620136619	571.02001949999999	0.80627566175226817
628	0.31928995544031197	572.04998780000005	0.78197288874240256
627	0.33027715147378628	572.94000240000003	0.76330926197509197
626	0.33896919521672586	573.96997069999998	0.7424875688162057
625	0.34773751092976479	575	0.71633606374286074
624	0.35805275352870264	576.02001949999999	0.69547908888549959
623	0.36631441461133174	577.04998780000005	0.67825819631564421
622	0.37240714556917465	577.94000240000003	0.66301328736619414
621	0.38390044236261939	578.96997069999998	0.64596163363652104
620	0.39309388675948204	580	0.62780314438109563
619	0.40172571995070439	581.02001949999999	0.61524851966975036
618	0.41027479249527976	582.04998780000005	0.60199718360436127
617	0.4186163723819355	582.94000240000003	0.58964419090951992
616	0.42866363972636462	583.96997069999998	0.57976788325735773
615	0.43553021179153506	585	0.568718664290078
614	0.44540590728741902	586.02001949999999	0.55922111948015918
613	0.45368579298552236	587.04998780000005	0.55367394309605533
612	0.46219949649444042	587.94000240000003	0.54772964075471475
611	0.47025525100266086	588.96997069999998	0.53880140091755901
610	0.47959399772054839	590	0.53429720224703892
609	0.4889325303263457	591.02001949999999	0.53109455919166604
608	0.4957685651727825	592.04998780000005	0.52838735637007994
607	0.50420893156971602	592.94000240000003	0.5287824189040391
606	0.51174132931366845	593.96997069999998	0.52592299913213381
605	0.52024826725088857	595	0.52936508339317401
604	0.5290178965961021	596.02001949999999	0.53001640295077124
603	0.5365017567251732	597.04998780000005	0.53168702413006319
602	0.54246143199618235	597.94000240000003	0.53795386549151725
601	0.54961621353243884	598.96997069999998	0.54303686007057095
600	0.55609457118747974	600	0.54736274164979359
599	0.56434149511240606	601.02001949999999	0.55134158288292057
598	0.56844872534707813	602.04998780000005	0.55558565621963685
597	0.57663025759751096	602.94000240000003	0.56106345560756665
596	0.58285136655537473	603.96997069999998	0.56485098112927135
595	0.58800563395186745	605	0.564814203516529
594	0.59534434890782062	606.02001949999999	0.56751093520867868
593	0.59970369115133582	607.04998780000005	0.56401262712550859
592	0.60538909060698587	607.94000240000003	0.5636315431349046
591	0.61110416963410952	608.96997069999998	0.560160882624953
590	0.61653829375250102	610	0.55405296393381731
589	0.62270226054161815	611.01000980000003	0.54722682439119019
588	0.62795027185353114	612.02001949999999	0.53855092120866277
587	0.63276445236209311	613.03997800000002	0.53126792460796812
586	0.63810502440283257	614.04998780000005	0.52194725276348775
585	0.64380326263753196	615.07000730000004	0.51192548539897853
584	0.64852876950141092	615.94000240000003	0.50406921207375566
583	0.6560229903309267	616.95001219999995	0.4921177296373539
582	0.66124919394088966	617.96997069999998	0.47806177396965416
581	0.6669380915767783	618.97998050000001	0.46724663171317321
580	0.67308587881894988	620	0.45705098307654257
579	0.67954788694382529	621.02001949999999	0.44503579751710937
578	0.6845102252009736	622.04998780000005	0.43322502946038716
577	0.6914830949818952	622.94000240000003	0.42350751548078408
576	0.69691962725531187	623.96997069999998	0.41512206765553994
575	0.70624155091950069	625	0.40560690775537023
574	0.7118980901851325	626.02001949999999	0.39276665049919535
573	0.71951848195479418	627.04998780000005	0.38387691622275477
572	0.72745848679199343	627.94000240000003	0.37491048033837548
571	0.73899530790237888	628.96997069999998	0.36540027238363659
570	0.74546288163363528	630	0.35873416443231737
569	0.75465671590885586	631.01000980000003	0.34852350567591051
568	0.76764439834143205	632.02001949999999	0.33983991685015369
567	0.77965051969125521	633.03997800000002	0.33248184328311153
566	0.7927110881688505	634.04998780000005	0.32567827077616629
565	0.80590128847315778	635.07000730000004	0.32009717947487792
564	0.8214818244151082	635.94000240000003	0.31535214685558705
563	0.83639692271701527	636.95001219999995	0.30686771407361879
562	0.85073696341122163	637.96997069999998	0.30100026816457154
561	0.87095035709916813	638.97998050000001	0.29412868544274257
560	0.88970349941559757	640	0.28764778095367
559	0.90921610021457389	641	0.27973659906963444
558	0.9247379151401669	642	0.27282759401670231
557	0.94604268672175973	643	0.2672081776704312
556	0.96331895190455019	644	0.26199295403286066
555	0.97561350215891773	645	0.2548417996326226
554	0.98626419134870968	646	0.24892455179933046
553	0.99653462929166503	647	0.24204773344517444
552	1	648	0.2370089699531692
551	0.9988375104621775	649	0.23139190071707194
550	0.99960521953320103	650	0.22598105414100927
549	0.99263747219135778	651.01000980000003	0.22073096121918384
548	0.98825618500726764	652.02001949999999	0.216066485942744
547	0.98362714065955115	653.03997800000002	0.21256064690548143
546	0.97928982200662795	654.04998780000005	0.20672800564659158
545	0.96964226391383235	655.07000730000004	0.20366273695658743
544	0.95838849272197335	655.94000240000003	0.19973770807175467
543	0.94797586979030934	656.95001219999995	0.19538408859383832
542	0.94001354938896398	657.96997069999998	0.19294972603928465
541	0.93524140739437334	658.97998050000001	0.18606566068836805
540	0.92700913970541976	660	0.18281397657918169
539	0.91543958343552956	661	0.17938709579933879
538	0.90412514613660944	662	0.17855525415415394
537	0.89724641597314203	663	0.17342807987080702
536	0.89027525064492175	664	0.17106437117389595
535	0.87667052802314149	665	0.16844615922791495
534	0.87148577449996389	666	0.16507266540123966
533	0.86631000917159129	667	0.16260677371195958
532	0.85808838316140934	668	0.15876236666885743
531	0.84779764831800586	669	0.15538906620360329
530	0.84028133896330592	670	0.15187064136608913
529	0.83947107115528197	671.01000980000003	0.14956972009742339
528	0.83462000083391208	672.02001949999999	0.14556708689077247
527	0.82599283494249165	673.03997800000002	0.14220851299361603
526	0.82117262635332422	674.04998780000005	0.13861017553161184
525	0.81663189978038186	675.07000730000004	0.13548367955607385
524	0.81414885130547976	675.94000240000003	0.1318663343148023
523	0.80899194787651985	676.95001219999995	0.12810942239529921
522	0.80652539454868621	677.96997069999998	0.12520254760649629
521	0.80232437034896031	678.97998050000001	0.12205179554945816
520	0.79864917516561063	680	0.11828393546572304
519	0.79728671915087435	681	0.11565505911001514
518	0.79627130707669824	682	0.11165946674710193
517	0.79645658023604005	683	0.10824246393687292
516	0.79373949319361603	684	0.10497216534284552
515	0.79189014473829844	685	0.10374015438039418
514	0.78960146797971431	686	0.10180853725411916
513	0.7864172810063117	687	9.9665623001550976E-2
512	0.78485322787177469	688	9.8687857197998455E-2
511	0.77933447206847184	689	9.6634649609859971E-2
510	0.77274572229939109	690	9.5948286972598967E-2
509	0.76689214443461096	690.97998050000001	9.4210977318672159E-2
508	0.75883436864828735	691.96997069999998	9.2306330851902096E-2
507	0.75027998227910131	692.95001219999995	9.0684563720237879E-2
506	0.73927211285437655	693.94000240000003	8.9246026939495848E-2
505	0.72907275954659556	695.07000730000004	8.8171932708232315E-2
504	0.72028524930309246	696.04998780000005	8.7119889562178685E-2
503	0.71062362126969314	697.03997800000002	8.6015929658803711E-2
502	0.69985228192410398	698.02001949999999	8.4209146165731011E-2
501	0.68865803888737798	699.01000980000003	8.2740137612713732E-2
500	0.67807078183363578	700	8.1152265967439491E-2
499	0.66987188796604191	701	7.9447246318670492E-2
498	0.6599678772825911	702	7.7779178362009968E-2
497	0.65113338494132	703	7.6626815673294546E-2
496	0.64347024580002232	704	7.5370870907392862E-2
495	0.63350741294078927	705	7.3517696317935893E-2
494	0.62287953031533905	706	7.1722305896147018E-2
493	0.61240298778486946	707	7.1224060961706998E-2
492	0.60941962656127546	708	6.9554548716926318E-2
491	0.60511333057014272	709	6.7528518117098743E-2
490	0.59441763961369243	710	6.5196770481059263E-2
489	0.58576006537624348	710.97998050000001	6.4486848012153888E-2
488	0.58237468258492242	711.96997069999998	6.2943123672993428E-2
487	0.57736334063444494	712.95001219999995	6.2090030323053005E-2
486	0.5689704547376625	713.94000240000003	6.0347220794219197E-2
485	0.56330682168134216	715.07000730000004	5.855067623461617E-2
484	0.56280283793723729	716.04998780000005	5.6902737945597331E-2
483	0.56069520884194246	717.03997800000002	5.6113554061016147E-2
482	0.55433401619852762	718.02001949999999	5.4019107065624489E-2
481	0.54891062658612144	719.01000980000003	5.2608772467335384E-2
480	0.54371190472515218	720	5.0807778999475646E-2
479	0.54070314353241855	720.97998050000001	4.9727733563408899E-2
478	0.53734884240557401	721.96997069999998	4.850429158135898E-2
477	0.5331281923827812	722.95001219999995	4.7776612178754577E-2
476	0.53139441327453474	723.94000240000003	4.5735352149438246E-2
475	0.52687509802193622	725.07000730000004	4.4412609355458772E-2
474	0.52496067361311793	726.04998780000005	4.3522731956409849E-2
473	0.5196672956404137	727.03997800000002	4.1913034904395574E-2
472	0.51595451174316276	728.02001949999999	4.0742328545002988E-2
471	0.51282970605615041	729.01000980000003	3.9687674086760882E-2
470	0.50902069373158965	730	3.8589742759801142E-2
469	0.50503640469692468	730.97998050000001	3.7843513371235357E-2
468	0.50314787697470953	731.96997069999998	3.676534420352108E-2
467	0.49930201221363701	732.95001219999995	3.5565797352637263E-2
466	0.49651031592053929	733.94000240000003	3.5137277681277765E-2
465	0.49358115875099434	735.07000730000004	3.3831524541243281E-2
464	0.49238243858361302	736.04998780000005	3.2394412698957514E-2
463	0.48920054481775993	737.03997800000002	3.1424957961418497E-2
462	0.48636180155351999	738.02001949999999	3.0868999781034415E-2
461	0.48494426565913862	739.01000980000003	2.9927218524440077E-2
460	0.48510086314638351	740	3.0030807037992536E-2
459	0.48481943001186634	740.96997069999998	2.9208050066767188E-2
458	0.48406091660061717	741.94000240000003	2.807227082427274E-2
457	0.48133077942385266	743.04998780000005	2.7417637254743273E-2
456	0.48062131961237214	744.02001949999999	2.6475377259609311E-2
455	0.48047665309719612	745	2.5666073375457503E-2
454	0.4801258102557352	745.96997069999998	2.4440813147003242E-2
453	0.48067081916361598	746.94000240000003	2.3836149144718589E-2
452	0.48101678584024576	748.04998780000005	2.3438272106817412E-2
451	0.48116229205609728	749.02001949999999	2.228461020513484E-2
450	0.48130643585121208	750	2.1794998722932321E-2
449	0.48357593613814182
448	0.48408281324185892
447	0.48522023170343276
446	0.48838532025989789
445	0.489894504669314
444	0.49173576977334615
443	0.49331340487543712
442	0.49694411870027277
441	0.49808760232470944
440	0.50083915338131124
439	0.5040931317358005
438	0.50709178422504331
437	0.51133873934807661
436	0.51408794379015077
435	0.51558432943995858
434	0.52113893813371648
433	0.5248683349660086
432	0.5287657930334615
431	0.53214516546657109
430	0.5368807746221006
429	0.5426793970946191
428	0.54601780081762996
427	0.55116548438878077
426	0.55671279790959838
425	0.5616859796628153
424	0.56765550041006818
423	0.57326027548729519
422	0.57874978224644846
421	0.58567279386186288
420	0.59232762164492936
419	0.59937650840113643
418	0.60555884174216856
417	0.61340583748994937
416	0.61905747882127105
415	0.62894107062720495
414	0.6342919695210073
413	0.64320328270935601
412	0.65013860577549076
411	0.6599152955936366
410	0.66598953378812542
409	0.67357414557136419
408	0.68135587966429512
407	0.68821832032552166
406	0.69904029723052208
405	0.7075765237282956
404	0.71622482056773851
403	0.72487262340877234
402	0.73398634617793801
401	0.74152891981143776
400	0.75031767252632764

UV-Visibile X	UV-Visibile Y	Emissione X	Emissione Y
700	-6.8109157198362434E-3	500	1.079236527377871E-4
699	-4.7083178500948331E-3	501.0400085	-1.702408944213608E-2
698	-5.857112123018864E-4	501.94000240000003	-2.5074749893178951E-2
697	-3.2444017030793665E-3	502.98001099999999	-2.8288650571646323E-2
696	-2.2837461753305397E-3	504.01998900000001	-2.8352775908038374E-2
695	-4.1858809020566337E-3	505.07000729999999	-2.7476908080661326E-2
694	1.7110233675642229E-3	505.97000120000001	-2.6492655801990169E-2
693	3.2372139005502395E-3	507.01000979999998	-2.5323957253001111E-2
692	2.928882308808385E-3	508.0499878	-2.3409324579729111E-2
691	8.5937568555500918E-3	508.9500122	-2.1882617765496895E-2
690	1.0853283293773478E-2	510	-1.9576557632604057E-2
689	7.1974240487641334E-3	511.0400085	-1.7341453537497976E-2
688	1.1644519347281123E-2	511.94000240000003	-1.5339527315589581E-2
687	1.0710978239011834E-2	512.97998050000001	-1.1517849173389667E-2
686	1.3282875932872279E-2	514.02001949999999	-7.3637360218323693E-3
685	1.6489744508765388E-2	515.07000730000004	-2.9388120478362444E-3
684	1.8719857361466058E-2	515.96997069999998	1.1607909994508002E-3
683	1.725629104227035E-2	517.01000980000003	6.4565139793932944E-3
682	2.1975778005080767E-2	518.04998780000005	1.4088002775900572E-2
681	2.4651203125503951E-2	518.95001219999995	2.1656053744225977E-2
680	2.814572782086644E-2	520	3.075146207001965E-2
679	3.0199019117548839E-2	521.03997800000002	4.0566997169933575E-2
678	3.2036513619673967E-2	521.94000240000003	5.1616691741654203E-2
677	3.2671177921748867E-2	522.97998050000001	6.5593909957828295E-2
676	3.7911349469315389E-2	524.02001949999999	8.1859966163700365E-2
675	3.9002264940915771E-2	525.07000730000004	9.7717811385398382E-2
674	4.3719039469114124E-2	525.96997069999998	0.11175813229030211
673	4.7835028333638313E-2	527.01000980000003	0.13319564289586611
672	4.7045917281514624E-2	528.04998780000005	0.1526639787375319
671	5.098277115409753E-2	528.95001219999995	0.16974282961062151
670	5.3879787275793629E-2	530	0.18932339401800566
669	5.7445012166316256E-2	531.03997800000002	0.20579773247898173
668	5.9632321261307367E-2	531.94000240000003	0.22469623177250242
667	6.549290608914167E-2	532.97998050000001	0.2437529314398853
666	6.7338084012517341E-2	534.02001949999999	0.26012602168432775
665	7.0056557134145256E-2	535.07000730000004	0.27516559679232661
664	7.3615858289800551E-2	535.96997069999998	0.28721840943273835
663	7.8416518640458871E-2	537.01000980000003	0.30616932674425495
662	8.1957889761174393E-2	538.04998780000005	0.32345134430864536
661	8.7086039190603828E-2	538.95001219999995	0.33792151659844155
660	9.0534467299788576E-2	540	0.35358770289942132
659	9.7526780714092445E-2	541.03997800000002	0.37214226194520367
658	0.10097114794201252	541.94000240000003	0.38908871743809603
657	0.10568812386503573	542.97998050000001	0.41145281855429083
656	0.11182258325640419	544.02001949999999	0.43494267496049754
655	0.11529257607326923	545.07000730000004	0.46072693842199064
654	0.11980518912520086	545.96997069999998	0.49012522611312664
653	0.12628199562777778	547.01000980000003	0.52699865045494287
652	0.13081314924292028	548.04998780000005	0.56524117242866267
651	0.13641809197974886	548.95001219999995	0.60003565763466382
650	0.14436388253180624	550	0.64035313683150319
649	0.14912564832853609	551.02001949999999	0.69228387864205621
648	0.15722412005449765	552.04998780000005	0.74238777608397222
647	0.16359298372989342	552.94000240000003	0.77882750495231046
646	0.16945152110907902	553.96997069999998	0.81986038481722512
645	0.17646381729790908	555	0.8625375228529959
644	0.18442705064974921	556.02001949999999	0.90672991372877876
643	0.19023591790015024	557.04998780000005	0.93992220941600657
642	0.19847026981050048	557.94000240000003	0.96105500967300195
641	0.20410873675237531	558.96997069999998	0.98212094172327769
640	0.21368452172608385	560	0.99478138128029103
639	0.22011519511258676	561.02001949999999	0.99862518512221055
638	0.22889661992869623	562.04998780000005	1
637	0.23640760082694615	562.94000240000003	0.99701877716245069
636	0.24454111713505738	563.96997069999998	0.9869896076119834
635	0.25330364350448203	565	0.96824047663188528
634	0.26137524676357937	566.02001949999999	0.94931715809456874
633	0.27043724934295754	567.04998780000005	0.92713686514424976
632	0.28023776105653325	567.94000240000003	0.91023732752098774
631	0.28966125914740182	568.96997069999998	0.88742825483133081
630	0.29585920268695493	570	0.86248823897696925
629	0.30577660193705786	571.02001949999999	0.83539086392851281
628	0.31382403923772118	572.04998780000005	0.81465974472815716
627	0.32118490158947743	572.94000240000003	0.79704539814512931
626	0.33448551503511159	573.96997069999998	0.77671564425138973
625	0.33951336270286298	575	0.75549492234092774
624	0.35017984417399189	576.02001949999999	0.73753093816014448
623	0.35687243318304773	577.04998780000005	0.71924010567831864
622	0.36279587780148576	577.94000240000003	0.70626448765174099
621	0.37066802164786133	578.96997069999998	0.69057669526395693
620	0.37915320886142484	580	0.67620292166308116
619	0.38705836610282146	581.02001949999999	0.66254364178872349
618	0.39424252052978226	582.04998780000005	0.64997967962558734
617	0.40272846387304462	582.94000240000003	0.6388471885400594
616	0.40890553521919332	583.96997069999998	0.62478922387524338
615	0.41709402406241286	585	0.61360405886433544
614	0.42967490902831118	586.02001949999999	0.60255393047482042
613	0.43405423831389023	587.04998780000005	0.59385880839156469
612	0.44122625095717993	587.94000240000003	0.58589379286578203
611	0.44534080352563582	588.96997069999998	0.57665532907208306
610	0.45639933085911388	590	0.56969155893829249
609	0.46473390910300139	591.02001949999999	0.5631955887429283
608	0.47083736830073947	592.04998780000005	0.55918981909184051
607	0.47595422430559059	592.94000240000003	0.55677338571142876
606	0.48167950994378417	593.96997069999998	0.5539801498957142
605	0.49138923292851466	595	0.55058313130366088
604	0.49908845547203345	596.02001949999999	0.55003963197659367
603	0.50785008514379093	597.04998780000005	0.55184782693958045
602	0.51072330037314706	597.94000240000003	0.55020218897729556
601	0.51977013828886431	598.96997069999998	0.55167265337410509
600	0.52506746061113829	600	0.55256902324843293
599	0.52935176766844561	601.02001949999999	0.55527287803577641
598	0.53581651870658631	602.04998780000005	0.55539245995961428
597	0.54476572760484987	602.94000240000003	0.55796569345813696
596	0.55205834874287707	603.96997069999998	0.55835806996620851
595	0.55606808955104181	605	0.55804048642199633
594	0.56219573346008866	606.02001949999999	0.55711076125262049
593	0.57124330798990242	607.04998780000005	0.55490849527366115
592	0.57420584531974295	607.94000240000003	0.55221161851016209
591	0.58148935571815497	608.96997069999998	0.54826562018351221
590	0.58485549324504549	610	0.54178971794341335
589	0.59122146218142624	611.01000980000003	0.53805520546850638
588	0.59863977500906651	612.02001949999999	0.52843796773976637
587	0.60529044886782202	613.03997800000002	0.51889662680802873
586	0.61084063363157748	614.04998780000005	0.51064284879039423
585	0.61517635075667831	615.07000730000004	0.50114550821873982
584	0.61975071965270223	615.94000240000003	0.49185019092021554
583	0.62570045355673776	616.95001219999995	0.48016659119043903
582	0.63220876526416481	617.96997069999998	0.46735668420240151
581	0.63907285532535707	618.97998050000001	0.45713897535178477
580	0.64383249281955357	620	0.44660845372793451
579	0.64798740325913406	621.02001949999999	0.43466727830667484
578	0.65481976510185702	622.04998780000005	0.42420315157457467
577	0.66187572739385936	622.94000240000003	0.41379922963846688
576	0.66654249883096561	623.96997069999998	0.40544033978158744
575	0.67615299704983145	625	0.39600292804763965
574	0.68375718485528703	626.02001949999999	0.3853081541400229
573	0.69178518672614708	627.04998780000005	0.37463163482133288
572	0.70369104492991763	627.94000240000003	0.36600046307350687
571	0.70971310732468851	628.96997069999998	0.3578241590526654
570	0.71973775066435552	630	0.34945939464334158
569	0.72867685236193602	631.01000980000003	0.3401509875684291
568	0.73884454287360102	632.02001949999999	0.33213948790295855
567	0.75473259713518637	633.03997800000002	0.32400777564044414
566	0.76715393882280647	634.04998780000005	0.31918977321248354
565	0.78104908673802642	635.07000730000004	0.31190877445611126
564	0.79989874820517515	635.94000240000003	0.30636543598326843
563	0.81375014543115776	636.95001219999995	0.29872525850060394
562	0.83185907789087565	637.96997069999998	0.29246372024347816
561	0.85245753500266264	638.97998050000001	0.28694843396393649
560	0.87234603280683209	640	0.28054158795936285
559	0.89514451208814649	641	0.27491864663175269
558	0.9141790449594277	642	0.26992328245447872
557	0.93218241433044191	643	0.26534613874383778
556	0.95223324954944388	644	0.25959935762140846
555	0.96880871776097732	645	0.25221299060163133
554	0.97911666156048704	646	0.24600109072874199
553	0.99217578645730253	647	0.24097071550670532
552	1	648	0.23554520419373934
551	0.99861341170434437	649	0.22974561080504396
550	0.99950875546277862	650	0.22390448119838915
549	0.99949153622575371	651.01000980000003	0.21901671289835276
548	0.99587644132968367	652.02001949999999	0.2137487908201689
547	0.99834033568268932	653.03997800000002	0.20884294528866584
546	0.99223981306635645	654.04998780000005	0.20456112851803554
545	0.98519278264283672	655.07000730000004	0.19880746745581176
544	0.98326416594513621	655.94000240000003	0.19486562855435016
543	0.9739684034946654	656.95001219999995	0.19074997629303864
542	0.96919016802875957	657.96997069999998	0.18569870482745868
541	0.96982929892445646	658.97998050000001	0.18108436183653948
540	0.96538136686030984	660	0.17693269314311511
539	0.95618125299424428	661	0.1729792824425474
538	0.94797270202767381	662	0.16969766614320914
537	0.9463885452812969	663	0.16551605277176756
536	0.9444208390386194	664	0.16240629812505472
535	0.9359152365612643	665	0.15818900345061704
534	0.93368184112540342	666	0.15554700915730313
533	0.93562660338851733	667	0.15152306377727806
532	0.9308850671864537	668	0.14766053203146193
531	0.92370738076725478	669	0.14263212810245321
530	0.91758075893896873	670	0.13919404629734489
529	0.92026530900754744	671.01000980000003	0.13615228327629852
528	0.92304172699661535	672.02001949999999	0.13226026021988865
527	0.91754199705430517	673.03997800000002	0.12827794965864872
526	0.91379068061301794	674.04998780000005	0.1238823469150233
525	0.91295591246832919	675.07000730000004	0.11931569075614878
524	0.90820196083940608	675.94000240000003	0.11657213290969824
523	0.90373808707588266	676.95001219999995	0.11275456748132066
522	0.90256348744962522	677.96997069999998	0.10827358587963166
521	0.89867363103853259	678.97998050000001	0.10524783019619829
520	0.89949867019397622	680	0.10222727885865338
519	0.89831064483641498	681	9.8578046434273925E-2
518	0.89969433670474197	682	9.521130749432169E-2
517	0.90155226431654845	683	9.2539743082102124E-2
516	0.90083827093527424	684	8.9586256842863088E-2
515	0.90016065814021418	685	8.7263561014306976E-2
514	0.89899514893645516	686	8.4482054769355205E-2
513	0.89739807756379308	687	8.2139197087367999E-2
512	0.8973377467604432	688	8.1103413862227983E-2
511	0.89279511645624143	689	7.8191867959636535E-2
510	0.8903335080387913	690	7.6755428961075775E-2
509	0.88340264573800442	690.97998050000001	7.4750346132953366E-2
508	0.87708491153990842	691.96997069999998	7.3888671966785238E-2
507	0.87037288367146748	692.95001219999995	7.2480935730600465E-2
506	0.86249338801791042	693.94000240000003	7.0789542902659264E-2
505	0.85473618026022247	695.07000730000004	6.8916155688601544E-2
504	0.84444769363646455	696.04998780000005	6.8269072059924163E-2
503	0.83896211066266146	697.03997800000002	6.7175055435174838E-2
502	0.8279035874261883	698.02001949999999	6.513885489961041E-2
501	0.82248839491680081	699.01000980000003	6.4298973996447115E-2
500	0.81217766310046502	700	6.2702806879679135E-2
499	0.80747398166593221	701	6.0573588557615618E-2
498	0.80105519266223668	702	5.9762765183426041E-2
497	0.7933481118478416	703	5.8192294589079235E-2
496	0.79028512223720515	704	5.6274394373328797E-2
495	0.78352421440640507	705	5.4965412600299669E-2
494	0.77376187541572305	706	5.2978002833278193E-2
493	0.7674106785320538	707	5.1427876478051256E-2
492	0.76662522367817132	708	4.9623545390995803E-2
491	0.76505966713844609	709	4.8185411031854058E-2
490	0.75475476162595234	710	4.6158801131949673E-2
489	0.74852055331611145	710.97998050000001	4.4498378105044201E-2
488	0.74643742280535541	711.96997069999998	4.2503822243179709E-2
487	0.74689634058134824	712.95001219999995	4.1745653466954663E-2
486	0.73804434425761756	713.94000240000003	4.0360922798161641E-2
485	0.73157151346201854	715.07000730000004	3.7739499484524652E-2
484	0.7347763260415332	716.04998780000005	3.6172518129481385E-2
483	0.73574146576347133	717.03997800000002	3.486331948114553E-2
482	0.72926847809108386	718.02001949999999	3.3490485870157252E-2
481	0.72739486273530285	719.01000980000003	3.1520946355552582E-2
480	0.72407989785262361	720	3.0157161210044692E-2
479	0.72188182933866263	720.97998050000001	2.8200297431044425E-2
478	0.71906791913316104	721.96997069999998	2.6690554025859233E-2
477	0.71896225887456833	722.95001219999995	2.533390514611833E-2
476	0.71834073343599514	723.94000240000003	2.4205286468490416E-2
475	0.71676075642581094	725.07000730000004	2.1702680942963088E-2
474	0.71483128336390811	726.04998780000005	2.083489562371103E-2
473	0.71339577603458615	727.03997800000002	1.900440481256719E-2
472	0.71159022145633566	728.02001949999999	1.7632413949244231E-2
471	0.70919470755923564	729.01000980000003	1.6472579051200458E-2
470	0.70869561228636002	730	1.5482910507214211E-2
469	0.70909149098311985	730.97998050000001	1.4267390090038126E-2
468	0.7082300364177786	731.96997069999998	1.2945461485979259E-2
467	0.70893735708326333	732.95001219999995	1.1491827443947443E-2
466	0.71010537355465564	733.94000240000003	1.0592840689235628E-2
465	0.70994754681884342	735.07000730000004	9.0587856949775319E-3
464	0.71088446617692047	736.04998780000005	7.5853248666182373E-3
463	0.71138784866685123	737.03997800000002	6.5038015762812736E-3
462	0.71295329374813732	738.02001949999999	5.8375565411461433E-3
461	0.71514348922645676	739.01000980000003	4.7309676274249644E-3
460	0.71905735303501439	740	3.425770803673621E-3
459	0.72334115527797327	740.96997069999998	2.8681615682204595E-3
458	0.72573511337842078	741.94000240000003	1.5568092251478246E-3
457	0.72664978905628641	743.04998780000005	5.6034693853968117E-4
456	0.72970371859569061	744.02001949999999	-2.9932383718944222E-4
455	0.73351668880287013	745	-1.2551912372239008E-3
454	0.73698400421147481	745.96997069999998	-2.1523372483647305E-3
453	0.74237305708718726	746.94000240000003	-3.1424148472817422E-3
452	0.74669478200705941	748.04998780000005	-3.8104439486002311E-3
451	0.75104734839817722	749.02001949999999	-5.0563304450152464E-3
450	0.75483603203020422	750	-5.8176410450820797E-3
449	0.75980502872300826
448	0.76613863775933311
447	0.7717799455952572
446	0.77846271134783507
445	0.78637687352078089
444	0.79315866684093539
443	0.79829361732527138
442	0.80310547271131671
441	0.81227683492061886
440	0.82054939300840701
439	0.82699368571982379
438	0.83524268231723953
437	0.84233842070747555
436	0.85045537944400362
435	0.85937634039932798
434	0.86741608718610685
433	0.8757174601033838
432	0.88624107748493441
431	0.89630607681198471
430	0.90402728603317128
429	0.91332580584547274
428	0.92353185393189463
427	0.9330104937777115
426	0.94330766591538506
425	0.95370707322094883
424	0.96412920336861141
423	0.9760050349426459
422	0.98576321356725904
421	0.99925047138695577
420	1.0127198657634569
419	1.0251951627960285
418	1.0387765542000429
417	1.0531176470575185
416	1.0655947532073415
415	1.0805309021641345
414	1.0948561864091899
413	1.1067590399910991
412	1.1229982075022666
411	1.1345411844744784
410	1.148652873297489
409	1.1641870539469514
408	1.1745438584679984
407	1.1879959256201953
406	1.2052514513991066
405	1.2205923346731891
404	1.2376697062623452
403	1.2547529214020383
402	1.2712355816418854
401	1.2864687467590121
400	1.3018317926642777

*Figura 67 - spettri UV-Visibile (linea continua) e di emissione (linea tratteggiata) dei polimeri bottle brush in THF* I massimi di assorbimento per l'intera libreria di polimeri (Tabella 10) rientrano in un range molto ristretto, compreso tra 544 e 554 nm, mentre i massimi di emissione ricadono nell'intervallo tra 557 e 564 nm. Le lievi fluttuazioni registrate all'interno delle due serie polimeriche (derivate rispettivamente dai copolimeri 3b e 3c) non seguono un andamento lineare in funzione del peso molecolare del PCL e risultano trascurabili. Tale costanza nei valori di λ_max rappresenta una conferma del fatto che l'incremento dell'ingombro sterico non perturba i livelli energetici e la natura delle transizioni elettroniche del core dichetopirrolopirrolico. Un ulteriore dato quantitativo di particolare rilevanza è rappresentato dai valori dello Stokes shift, i quali si mantengono estremamente ridotti, oscillando in un ristretto intervallo compreso tra gli 8 e i 14 nm. Questo parametro rappresenta una conferma della validità del design molecolare adottato: da un lato, i domini flessibili di policaprolattone generano l’ingombro sterico necessario per allontanare le catene principali tra di loro, limitando l'impaccamento e garantendo una maggiore mobilità al sistema; dall'altro lato, il grafting non introduce distorsioni alla geometria del backbone. Il mantenimento di un basso Stokes shift verifica che il core fluorescente conserva la sua conformazione planare e non subisce rilassamenti indesiderati nel passaggio allo stato eccitato, preservando così intatte le sue proprietà emissive.

Polimero	λ_{max, abs}(nm)		λ_{max, ex}(nm)	Stokes shift (nm)
3.1b		554	562	8
3.2b		550	564	14
3.3b		553	563	10
3.1c		547	561	14
3.2c		544	557	13
3.3c		553	564	11

*Tabella 10 - dati spettroscopici dei polimeri sintetizzati* A completamento della caratterizzazione strutturale, l'effettivo accrescimento delle catene laterali e le dimensioni macromolecolari dei sistemi bottle brush sono stati valutati mediante Cromatografia a Permeazione di Gel (GPC). Questa indagine risulta fondamentale non solo per determinare i pesi molecolari medi ( $\overbar{M_{n}}$ e $\overbar{M_{w}}$ ) e gli indici di dispersità (PD) dei materiali sintetizzati, ma anche per verificare a posteriori il grado di controllo esercitato dalla polimerizzazione per apertura di anello (ROP). Il confronto tra i valori sperimentali ricavati dai cromatogrammi e i pesi molecolari target previsti in fase di progettazione sintetica (rispettivamente 1500, 5000 e 10000 Da) permette infatti di confermare l'efficacia dell'approccio grafting-from e la corretta architettura finale dei copolimeri.

Polimero	Massa molecolare media numerale (Da)	Massa molecolare media ponderale (Da)	Polidispersità (PD)
3.1b	12188	18536	1,521
3.2b	17302	22737	1,314
3.3b	21269	26328	1,238
3.1c	13999	18219	1,301
3.2c	19119	24376	1,275
3.3c	14445	19521	1,351

*Tabella 11 - Pesi molecolari e polidispersità dei polimeri bottle brush determinati mediante GPC* I valori di peso molecolare ottenuti tramite GPC (**Tabella 11**) risultano significativamente sottostimati rispetto ai valori teorici a causa del principio di funzionamento della tecnica unito alla particolare architettura bottle brush dei polimeri. La GPC, infatti, separa le macromolecole in base al loro volume idrodinamico, restituendo valori relativi agli standard di calibrazione utilizzati, in questo caso un polimero lineare corrispondente a polistirene. A parità di peso molecolare reale, un polimero altamente ramificato assume una conformazione in soluzione molto più compatta rispetto a un polimero lineare, possedendo quindi un volume idrodinamico nettamente inferiore. Questo fa sì che il polimero ramificato penetri maggiormente nei pori della colonna, eluendo agli stessi tempi di polimeri lineari molto più corti. Tale sottostima è proporzionale all'ingombro delle catene laterali: con innesti in PCL a basso peso molecolare (circa 1500 Da), l'approssimazione a un comportamento lineare risulta più attendibile, restituendo valori GPC attorno ai 12000 Da. Al contrario, aumentando il peso molecolare dei segmenti laterali (ad esempio stimando tre catene per lato, per un peso teorico atteso di circa 62000 Da), la drastica compattazione strutturale porta a una sottostima del peso reale che si aggira intorno al 70%.⁵⁷ In questi sistemi, dunque, i dati ottenuti non indicano il peso molecolare assoluto o una bassa resa, ma confermano indirettamente la presenza di una struttura ramificata altamente impaccata e, sebbene non corrispondenti ai valori reali, permettono un confronto diretto tra i diversi polimeri sintetizzati. Tuttavia, il polimero 3.3c presenta un valore di peso molecolare che si discosta dall'andamento generale degli altri campioni; ciò potrebbe essere dovuto al fatto che, essendo il materiale di partenza di natura random, la presenza di possibili elevate concentrazioni locali di dichetopirrolopirroli e relativi ossidrili nel copolimero, abbia causato una ridotta crescita dei polimeri laterali per via dell’ingombro sterico delle catene in crescita. Tali discrepanze nei valori di peso molecolare saranno comunque maggiormente investigate in futuro attraverso ulteriori analisi. Al fine di superare le limitazioni associate all'analisi GPC, si è ricorsi all'utilizzo della spettroscopia H-NMR. Il calcolo si fonda sulla valutazione del grado di polimerizzazione delle singole catene laterali di PCL. L'equazione generale utilizzata per ricavare il peso molecolare totale ( $MW_{tot}$ ) del copolimero ramificato è la seguente: $$ MW_{tot}=MW_{backbone}+\left[\left(\frac{I_{4.05}}{I_{3.65}}\times MW_{CL}\right)\times \left(DP_{backbone}\times \chi _{DPP}\times 2\right)\right] $$ *Equazione 10 - calcolo del peso molecolare dei polimeri bottle brush mediante 1H-NMR* Nello specifico, il numero di unità ripetenti per catena laterale è stato ricavato dal rapporto tra l'area del segnale relativo ai protoni metilenici interni alla catena ( $I_{4.05}$ per il gruppo –CH2O–CO–, a circa 4.05 ppm) e l'integrale dei protoni metilenici terminali adiacenti al gruppo ossidrilico ( $I_{3.65}$ per il gruppo –CH2-OH, a circa 3.65 ppm), il cui valore è stato posto convenzionalmente pari a 1. Il peso molecolare della singola catena di PCL così ottenuto, pari al termine $\left(\frac{I_{4.05}}{I_{3.65}}\times MW_{CL}\right)$ dove $MW_{CL}$ è il peso molecolare dell'unità ripetente del caprolattone, è stato successivamente moltiplicato per il numero medio di siti di polimerizzazione presenti per macromolecola. Quest'ultimo parametro è stato stimato a partire dal grado di polimerizzazione del copolimero lineare di partenza ( $DP_{backbone}$ ), ricavato dai valori GPC, e dal rapporto molare tra le unità di 3HT e DPP ottenuto via NMR (che definisce la frazione molare $\chi _{DPP}$ ), considerando che ogni unità di DPP reca due gruppi idrossilici di innesco. Infine, il peso molecolare totale dei copolimeri ramificati è stato calcolato sommando la massa complessiva delle catene laterali di PCL al peso molecolare del backbone lineare ( $MW_{backbone}$ ). I valori calcolati con questo metodo offrono una stima molto più vicina ai valori teorici e sono riassunti in **Tabella 12.**

Polimero	Peso Molecolare teorico (Da)	Peso Molecolare da ¹H-NMR (Da)
3.1b	6500	8900
3.2b	18000	20500
3.3b	34500	88000
3.1c	10000	18200
3.2c	28500	35500
3.3c	55000	41300

Tabella 12 - pesi molecolari dei polimeri bottle brush determinati via ¹H-NMR Anche per i polimeri bottle brush è stata effettuata l’analisi termica mediante DSC. Dai termogrammi registrati è emerso che le principali transizioni termiche si mantengono pressoché costanti per tutti i polimeri sintetizzati, in quanto dominate dal comportamento del policaprolattone (PCL). Nello specifico, la temperatura di fusione (Tm) risulta compresa nel range tra 55 °C e 60 °C, mentre la temperatura di cristallizzazione (Tc) si attesta nell'intervallo tra 25 °C e 35 °C. Questo comportamento è strettamente legato alla struttura tridimensionale di queste macromolecole: le transizioni termiche osservate sono infatti fondamentalmente governate dai segmenti a base di caprolattone che costituiscono le catene laterali. Data l'elevata densità di grafting e rappresentando il caprolattone la frazione preponderante del sistema, la mobilità di queste catene e la loro propensione a cristallizzare dettano le proprietà termiche dell'intero materiale. Di conseguenza, l'influenza dello scheletro polimerico principale viene minimizzata, rendendo i profili termici essenzialmente indipendenti dalle lievi variazioni strutturali tra i diversi polimeri. ![](immagini/0173034d196ba93044667ab8a1fa2d4b9d69f60d679bad29840de373b8319dea.jpg) *Figura 68 - esempio di termogramma dei polimeri bottle brush realizzati (in figura l'analisi del campione 3.1c)* ## **4.4. Ciclovoltammetrie** La ciclovoltammetria (CV) è una tecnica elettrochimica dinamica, appartenente alla famiglia delle tecniche voltammetriche, ampiamente impiegata per studiare i processi di ossido-riduzione (redox). In ambito macromolecolare e dei materiali coniugati, questa tecnica risulta utile per investigare le proprietà di trasferimento elettronico, la stabilità elettrochimica e, in particolare, per determinare il gap energetico elettrochimico dei materiali. ### **4.4.1. Ciclovoltammetrie su polimeri elettroattivi** Alla luce dei principi teorici esposti nel **paragrafo 3.3**, l'impiego della ciclovoltammetria si è rivelato uno step analitico fondamentale per la caratterizzazione dei polimeri sintetizzati in questo progetto di tesi. L'obiettivo primario di tale indagine è stato quello di studiare il comportamento elettrochimico derivante dall'estesa coniugazione π presente lungo la catena macromolecolare. Infatti, il grado di delocalizzazione elettronica all'interno di questo sistema coniugato suggerisce un potenziale comportamento da semiconduttore; la tecnica della ciclovoltammetria ha permesso di supportare questa ipotesi verificando la loro elettroattività e stimando un band gap elettrochimico compatibile con i materiali semiconduttori. Nello specifico, l'analisi è stata condotta per identificare ed analizzare i processi redox a carico dello scheletro polimerico, individuando i potenziali di onsetnecessari per la stima del gap energetico. La tecnica è stata impiegata per indagare la cinetica dei processi redox e il loro grado di reversibilità, un parametro fondamentale per comprendere i limiti strutturali del materiale. In quest'ottica, l'osservazione del profilo voltammetrico e l'andamento delle correnti in scansioni multiple consecutive costituiscono uno strumento di caratterizzazione essenziale: queste due analisi consentono di discriminare tra un sistema in grado di tollerare ciclicamente il trasferimento di carica e l'eventuale presenza di reazioni secondarie di degradazione elettrochimica. Lo studio voltammetrico funge quindi da ponte tra la validazione dell'architettura elettronica dei polimeri bottle brush sintetizzati e l'indagine della loro effettiva stabilità operazionale. ### **4.4.2. Metodologie di analisi voltammetrica** L'analisi dei voltammogrammi è stata strutturata in due parti: una qualitativa, legata all'osservazione della forma del tracciato, e una quantitativa, basata sull'estrazione di valori numerici specifici. In primo luogo, si è studiato l'andamento delle curve per capire come il polimero risponde allo scambio di elettroni. I materiali coniugati, infatti, possono subire due processi principali: l'estrazione di elettroni dalla loro struttura, che corrisponde a un'ossidazione ed è nota in letteratura come p-doping, e l'iniezione di elettroni, che corrisponde a una riduzione ed è definita n-doping. Osservando la forma dei picchi di ossidazione e riduzione nel grafico, e verificando se sono presenti i rispettivi picchi di ritorno, è possibile capire se il processo è reversibile o meno, valutando così la stabilità del materiale quando viene sottoposto a stress elettrochimico. In secondo luogo, l'analisi si è concentrata sulla determinazione esatta del potenziale al quale questi due processi hanno inizio, chiamati potenziali di onset. Ricavare questi valori dal grafico è il passaggio fondamentale dell'intera analisi, poiché rappresentano i dati di partenza necessari per calcolare il gap energetico del polimero sintetizzato. Per illustrare nel dettaglio la procedura pratica di elaborazione dei dati che è stata applicata a tutti i materiali, si riporta a titolo esemplificativo il voltammogramma ciclico relativo al polimero 3.2.c (**Figura 69**). L'approccio di analisi descritto per questo specifico tracciato è stato ripetuto sistematicamente su tutti i voltammogrammi acquisiti per ricavare i parametri elettrochimici di ciascun polimero sintetizzato.

Scan rate 0.05 V/s X	Scan rate 0.05 V/s Y	baseline ox X	baseline ox Y	tangente ox X	tangente ox Y	baseline rid X	baseline rid Y	tangente rid X	tangente rid Y
0.63100000000000001	1.7629000000000001E-4	-0.21299999999999999	3.1132571428571337E-5	0.161	6.6507964285714272E-5	-0.92600000000000005	-3.5800666666666671E-5	-1.3859999999999999	-6.4801190476190449E-5
0.63	1.5401999999999999E-4	-0.214	3.1141107142857051E-5	0.16200000000000001	6.6711214285714273E-5	-0.92700000000000005	-3.5820466666666667E-5	-1.387	-6.498544761904761E-5
0.629	1.3040999999999999E-4	-0.215	3.1149642857142766E-5	0.16300000000000001	6.6914464285714275E-5	-0.92800000000000005	-3.5840266666666663E-5	-1.3879999999999999	-6.5169704761904718E-5
0.628	1.1476000000000001E-4	-0.216	3.115817857142848E-5	0.16400000000000001	6.7117714285714277E-5	-0.92900000000000005	-3.5860066666666666E-5	-1.389	-6.5353961904761879E-5
0.627	1.0465E-4	-0.217	3.1166714285714201E-5	0.16500000000000001	6.7320964285714265E-5	-0.93	-3.5879866666666668E-5	-1.39	-6.5538219047619041E-5
0.626	9.7492999999999996E-5	-0.218	3.1175249999999915E-5	0.16600000000000001	6.7524214285714267E-5	-0.93100000000000005	-3.5899666666666671E-5	-1.391	-6.5722476190476203E-5
0.625	9.2126000000000005E-5	-0.219	3.1183785714285629E-5	0.16700000000000001	6.7727464285714269E-5
0.624	8.7993999999999998E-5	-0.22	3.1192321428571343E-5
0.623	8.4336E-5
0.622	8.1178000000000001E-5
0.621	7.8522000000000005E-5
0.62	7.5999000000000002E-5
0.61899999999999999	7.3566999999999995E-5
0.61799999999999999	7.1384000000000006E-5
0.61699999999999999	6.9290999999999998E-5
0.61599999999999999	6.7279000000000004E-5
0.61499999999999999	6.5426999999999995E-5
0.61399999999999999	6.3646999999999996E-5
0.61299999999999999	6.1814000000000001E-5
0.61199999999999999	6.0222E-5
0.61099999999999999	5.8799999999999999E-5
0.61	5.7225000000000002E-5
0.60899999999999999	5.5705000000000003E-5
0.60799999999999998	5.3934000000000002E-5
0.60699999999999998	5.2601E-5
0.60599999999999998	5.1421000000000001E-5
0.60499999999999998	5.0365000000000003E-5
0.60399999999999998	4.9085999999999997E-5
0.60299999999999998	4.7843000000000003E-5
0.60199999999999998	4.6733999999999997E-5
0.60099999999999998	4.5571000000000001E-5
0.6	4.4515999999999999E-5
0.59899999999999998	4.3523000000000003E-5
0.59799999999999998	4.2503000000000003E-5
0.59699999999999998	4.1421000000000002E-5
0.59599999999999997	4.0491000000000002E-5
0.59499999999999997	3.9569E-5
0.59399999999999997	3.8612000000000002E-5
0.59299999999999997	3.7663999999999997E-5
0.59199999999999997	3.6876999999999999E-5
0.59099999999999997	3.5964999999999999E-5
0.59	3.5034999999999999E-5
0.58899999999999997	3.4158000000000001E-5
0.58799999999999997	3.3325999999999999E-5
0.58699999999999997	3.2486E-5
0.58599999999999997	3.1814999999999999E-5
0.58499999999999996	3.1000999999999997E-5
0.58399999999999996	3.0196E-5
0.58299999999999996	2.9471E-5
0.58199999999999996	2.8827E-5
0.58099999999999996	2.8076E-5
0.57999999999999996	2.7325E-5
0.57899999999999996	2.6743000000000001E-5
0.57799999999999996	2.5973999999999999E-5
0.57699999999999996	2.5284999999999999E-5
0.57599999999999996	2.4686E-5
0.57499999999999996	2.3980000000000001E-5
0.57399999999999995	2.3309E-5
0.57299999999999995	2.279E-5
0.57199999999999995	2.2164E-5
0.57099999999999995	2.1413E-5
0.56999999999999995	2.0876000000000001E-5
0.56899999999999995	2.0285999999999999E-5
0.56799999999999995	1.9660000000000002E-5
0.56699999999999995	1.9096000000000001E-5
0.56599999999999995	1.8524000000000001E-5
0.56499999999999995	1.7924E-5
0.56399999999999995	1.7379000000000001E-5
0.56299999999999994	1.6833E-5
0.56200000000000006	1.6198E-5
0.56100000000000005	1.5644000000000001E-5
0.56000000000000005	1.5160999999999999E-5
0.55900000000000005	1.4517E-5
0.55800000000000005	1.3953E-5
0.55700000000000005	1.3488E-5
0.55600000000000005	1.2969000000000001E-5
0.55500000000000005	1.2343E-5
0.55400000000000005	1.1887E-5
0.55300000000000005	1.1377E-5
0.55200000000000005	1.0823E-5
0.55100000000000005	1.0402E-5
0.55000000000000004	9.9459999999999993E-6
0.54900000000000004	9.3647000000000003E-6
0.54800000000000004	8.8199E-6
0.54700000000000004	8.4147999999999995E-6
0.54600000000000004	7.9147999999999992E-6
0.54500000000000004	7.5096000000000001E-6
0.54400000000000004	7.0883000000000004E-6
0.54300000000000004	6.5587999999999998E-6
0.54200000000000004	5.9784000000000002E-6
0.54100000000000004	5.5607E-6
0.54	5.0374000000000003E-6
0.53900000000000003	4.5401E-6
0.53800000000000003	4.0579999999999999E-6
0.53700000000000003	3.5706000000000002E-6
0.53600000000000003	3.0187E-6
0.53500000000000003	2.7056E-6
0.53400000000000003	2.2888E-6
0.53300000000000003	1.7343000000000001E-6
0.53200000000000003	1.3345000000000001E-6
0.53100000000000003	1.0143E-6
0.53	4.8245000000000004E-7
0.52900000000000003	6.1330999999999995E-8
0.52800000000000002	-3.9649999999999998E-7
0.52700000000000002	-8.5247999999999997E-7
0.52600000000000002	-1.3139E-6
0.52500000000000002	-1.7593E-6
0.52400000000000002	-2.2262E-6
0.52300000000000002	-2.6224999999999999E-6
0.52200000000000002	-3.0634000000000002E-6
0.52100000000000002	-3.4023999999999998E-6
0.52	-3.9203000000000004E-6
0.51900000000000002	-4.3201000000000004E-6
0.51800000000000002	-4.634E-6
0.51700000000000002	-5.1197000000000003E-6
0.51600000000000001	-5.6026999999999997E-6
0.51500000000000001	-5.9676000000000003E-6
0.51400000000000001	-6.4246999999999997E-6
0.51300000000000001	-6.8692000000000002E-6
0.51200000000000001	-7.1894000000000001E-6
0.51100000000000001	-7.6035000000000001E-6
0.51	-8.0382000000000004E-6
0.50900000000000001	-8.3387000000000003E-6
0.50800000000000001	-8.8118999999999994E-6
0.50700000000000001	-9.2752000000000006E-6
0.50600000000000001	-9.9012999999999995E-6
0.505	-1.0429E-5
0.504	-1.0688E-5
0.503	-1.1001E-5
0.502	-1.1234E-5
0.501	-1.1654000000000001E-5
0.5	-1.2111E-5
0.499	-1.2415000000000001E-5
0.498	-1.2826000000000001E-5
0.497	-1.3202E-5
0.496	-1.3577000000000001E-5
0.495	-1.3988999999999999E-5
0.49399999999999999	-1.432E-5
0.49299999999999999	-1.4579000000000001E-5
0.49199999999999999	-1.4963999999999999E-5
0.49099999999999999	-1.5447E-5
0.49	-1.5733E-5
0.48899999999999999	-1.6036999999999999E-5
0.48799999999999999	-1.6492999999999999E-5
0.48699999999999999	-1.6886999999999999E-5
0.48599999999999999	-1.7218E-5
0.48499999999999999	-1.7638E-5
0.48399999999999999	-1.7951000000000001E-5
0.48299999999999998	-1.8363E-5
0.48199999999999998	-1.8774E-5
0.48099999999999998	-1.9131999999999999E-5
0.48	-1.9202999999999999E-5
0.47899999999999998	-1.9525E-5
0.47799999999999998	-2.0035E-5
0.47699999999999998	-2.033E-5
0.47599999999999998	-2.0715000000000001E-5
0.47499999999999998	-2.1152999999999999E-5
0.47399999999999998	-2.1484E-5
0.47299999999999998	-2.1869E-5
0.47199999999999998	-2.2181999999999999E-5
0.47099999999999997	-2.2476999999999998E-5
0.47	-2.2710000000000001E-5
0.46899999999999997	-2.3057999999999998E-5
0.46800000000000003	-2.3416000000000001E-5
0.46700000000000003	-2.3612999999999999E-5
0.46600000000000003	-2.3997000000000001E-5
0.46500000000000002	-2.4372999999999999E-5
0.46400000000000002	-2.4624E-5
0.46300000000000002	-2.4955000000000001E-5
0.46200000000000002	-2.5276999999999999E-5
0.46100000000000002	-2.5491E-5
0.46	-2.5876000000000001E-5
0.45900000000000002	-2.6251E-5
0.45800000000000002	-2.6475E-5
0.45700000000000002	-2.6733999999999998E-5
0.45600000000000002	-2.7056E-5
0.45500000000000002	-2.7378000000000001E-5
0.45400000000000001	-2.7781E-5
0.45300000000000001	-2.8093999999999999E-5
0.45200000000000001	-2.8263999999999999E-5
0.45100000000000001	-2.8479E-5
0.45	-2.8747000000000001E-5
0.44900000000000001	-2.906E-5
0.44800000000000001	-2.9257000000000001E-5
0.44700000000000001	-2.957E-5
0.44600000000000001	-2.9882999999999998E-5
0.44500000000000001	-3.0114999999999999E-5
0.44400000000000001	-3.0232000000000001E-5
0.443	-3.0463999999999998E-5
0.442	-3.0660999999999997E-5
0.441	-3.0929000000000002E-5
0.44	-3.1269000000000002E-5
0.439	-3.1466E-5
0.438	-3.1724999999999999E-5
0.437	-3.1949000000000002E-5
0.436	-3.2181000000000002E-5
0.435	-3.2431999999999997E-5
0.434	-3.2709000000000001E-5
0.433	-3.2950999999999997E-5
0.432	-3.3058000000000001E-5
0.43099999999999999	-3.3246E-5
0.43	-3.3504999999999999E-5
0.42899999999999999	-3.3577000000000001E-5
0.42799999999999999	-3.3773999999999999E-5
0.42699999999999999	-3.4112999999999997E-5
0.42599999999999999	-3.4266E-5
0.42499999999999999	-3.4409000000000002E-5
0.42399999999999999	-3.4740000000000003E-5
0.42299999999999999	-3.4847E-5
0.42199999999999999	-3.5008000000000001E-5
0.42099999999999999	-3.5187E-5
0.42	-3.5339000000000002E-5
0.41899999999999998	-3.5509000000000002E-5
0.41799999999999998	-3.5750000000000002E-5
0.41699999999999998	-3.6010000000000003E-5
0.41599999999999998	-3.6028000000000001E-5
0.41499999999999998	-3.6295999999999999E-5
0.41399999999999998	-3.6501999999999997E-5
0.41299999999999998	-3.6554999999999998E-5
0.41199999999999998	-3.6806E-5
0.41099999999999998	-3.6984999999999999E-5
0.41	-3.7092000000000003E-5
0.40899999999999997	-3.7280000000000002E-5
0.40799999999999997	-3.7539000000000001E-5
0.40699999999999997	-3.7530000000000002E-5
0.40600000000000003	-3.7629000000000002E-5
0.40500000000000003	-3.7790000000000002E-5
0.40400000000000003	-3.8102999999999998E-5
0.40300000000000002	-3.8495999999999999E-5
0.40200000000000002	-3.8577E-5
0.40100000000000002	-3.8729000000000001E-5
0.4	-3.8674999999999998E-5
0.39900000000000002	-3.8702000000000003E-5
0.39800000000000002	-3.8908000000000001E-5
0.39700000000000002	-3.8943000000000003E-5
0.39600000000000002	-3.9167E-5
0.39500000000000002	-3.9328E-5
0.39400000000000002	-3.9363999999999998E-5
0.39300000000000002	-3.9524999999999999E-5
0.39200000000000002	-3.9623000000000003E-5
0.39100000000000001	-3.9694999999999999E-5
0.39	-3.9721999999999997E-5
0.38900000000000001	-3.9953999999999997E-5
0.38800000000000001	-4.0096999999999999E-5
0.38700000000000001	-4.0123999999999997E-5
0.38600000000000001	-4.0330000000000002E-5
0.38500000000000001	-4.0543999999999997E-5
0.38400000000000001	-4.0482000000000003E-5
0.38300000000000001	-4.0633999999999998E-5
0.38200000000000001	-4.0812999999999997E-5
0.38100000000000001	-4.0911000000000002E-5
0.38	-4.1081000000000002E-5
0.379	-4.1170000000000001E-5
0.378	-4.1125999999999999E-5
0.377	-4.1196999999999999E-5
0.376	-4.1366999999999999E-5
0.375	-4.1483999999999998E-5
0.374	-4.1554999999999998E-5
0.373	-4.1680000000000001E-5
0.372	-4.1885999999999998E-5
0.371	-4.1922000000000003E-5
0.37	-4.2082999999999997E-5
0.36899999999999999	-4.2262000000000003E-5
0.36799999999999999	-4.2234999999999998E-5
0.36699999999999999	-4.2342000000000002E-5
0.36599999999999999	-4.2475999999999998E-5
0.36499999999999999	-4.2493999999999997E-5
0.36399999999999999	-4.2512000000000002E-5
0.36299999999999999	-4.278E-5
0.36199999999999999	-4.2843000000000003E-5
0.36099999999999999	-4.2861000000000002E-5
0.36	-4.2967999999999999E-5
0.35899999999999999	-4.3075999999999999E-5
0.35799999999999998	-4.3173999999999997E-5
0.35699999999999998	-4.3343999999999997E-5
0.35599999999999998	-4.3398E-5
0.35499999999999998	-4.3389000000000001E-5
0.35399999999999998	-4.3504999999999998E-5
0.35299999999999998	-4.3594000000000003E-5
0.35199999999999998	-4.3656999999999999E-5
0.35099999999999998	-4.3782000000000002E-5
0.35	-4.3915999999999998E-5
0.34899999999999998	-4.3934000000000003E-5
0.34799999999999998	-4.4058999999999999E-5
0.34699999999999998	-4.4085999999999998E-5
0.34599999999999997	-4.4229E-5
0.34499999999999997	-4.4336999999999999E-5
0.34399999999999997	-4.439E-5
0.34300000000000003	-4.4471000000000002E-5
0.34200000000000003	-4.4569E-5
0.34100000000000003	-4.4595999999999998E-5
0.34	-4.4641000000000002E-5
0.33900000000000002	-4.4632000000000002E-5
0.33800000000000002	-4.4739E-5
0.33700000000000002	-4.4909E-5
0.33600000000000002	-4.4909E-5
0.33500000000000002	-4.4990000000000001E-5
0.33400000000000002	-4.5142000000000002E-5
0.33300000000000002	-4.5185999999999997E-5
0.33200000000000002	-4.5275999999999998E-5
0.33100000000000002	-4.5293999999999997E-5
0.33	-4.5346999999999998E-5
0.32900000000000001	-4.5419E-5
0.32800000000000001	-4.5553000000000002E-5
0.32700000000000001	-4.5597999999999999E-5
0.32600000000000001	-4.5516999999999998E-5
0.32500000000000001	-4.5597999999999999E-5
0.32400000000000001	-4.5741000000000001E-5
0.32300000000000001	-4.5704999999999997E-5
0.32200000000000001	-4.5847999999999999E-5
0.32100000000000001	-4.5973999999999997E-5
0.32	-4.6090000000000001E-5
0.31900000000000001	-4.6116999999999999E-5
0.318	-4.6161000000000001E-5
0.317	-4.6161000000000001E-5
0.316	-4.6278E-5
0.315	-4.6286999999999999E-5
0.314	-4.6205999999999998E-5
0.313	-4.6242000000000002E-5
0.312	-4.6384999999999997E-5
0.311	-4.6501000000000001E-5
0.31	-4.6483000000000002E-5
0.309	-4.6625999999999997E-5
0.308	-4.6743000000000003E-5
0.307	-4.6697999999999999E-5
0.30599999999999999	-4.6779000000000001E-5
0.30499999999999999	-4.6913000000000003E-5
0.30399999999999999	-4.6885999999999998E-5
0.30299999999999999	-4.6931000000000002E-5
0.30199999999999999	-4.7037999999999999E-5
0.30099999999999999	-4.7475999999999997E-5
0.3	-4.7539E-5
0.29899999999999999	-4.7369E-5
0.29799999999999999	-4.7234999999999998E-5
0.29699999999999999	-4.7243999999999997E-5
0.29599999999999999	-4.7305999999999997E-5
0.29499999999999998	-4.7305999999999997E-5
0.29399999999999998	-4.7395999999999998E-5
0.29299999999999998	-4.7503000000000002E-5
0.29199999999999998	-4.7475999999999997E-5
0.29099999999999998	-4.744E-5
0.28999999999999998	-4.7592000000000001E-5
0.28899999999999998	-4.7682000000000002E-5
0.28799999999999998	-4.7547999999999999E-5
0.28699999999999998	-4.7574999999999998E-5
0.28599999999999998	-4.7664000000000003E-5
0.28499999999999998	-4.7601E-5
0.28399999999999997	-4.7718E-5
0.28299999999999997	-4.7834000000000003E-5
0.28199999999999997	-4.7896999999999999E-5
0.28100000000000003	-4.7985999999999998E-5
0.28000000000000003	-4.8111000000000001E-5
0.27900000000000003	-4.812E-5
0.27800000000000002	-4.8058E-5
0.27700000000000002	-4.8075000000000003E-5
0.27600000000000002	-4.8146999999999998E-5
0.27500000000000002	-4.8066999999999999E-5
0.27400000000000002	-4.8219E-5
0.27300000000000002	-4.829E-5
0.27200000000000002	-4.8299E-5
0.27100000000000002	-4.8353000000000003E-5
0.27	-4.8451000000000001E-5
0.26900000000000002	-4.8451000000000001E-5
0.26800000000000002	-4.8557999999999998E-5
0.26700000000000002	-4.8621000000000001E-5
0.26600000000000001	-4.8683999999999997E-5
0.26500000000000001	-4.8639E-5
0.26400000000000001	-4.8674999999999997E-5
0.26300000000000001	-4.8718999999999999E-5
0.26200000000000001	-4.8621000000000001E-5
0.26100000000000001	-4.88E-5
0.26	-4.8925000000000003E-5
0.25900000000000001	-4.8853999999999997E-5
0.25800000000000001	-4.8844999999999997E-5
0.25700000000000001	-4.9005999999999998E-5
0.25600000000000001	-4.9014999999999997E-5
0.255	-4.914E-5
0.254	-4.9157999999999999E-5
0.253	-4.9104000000000003E-5
0.252	-4.9202000000000001E-5
0.251	-4.9345999999999998E-5
0.25	-4.9193000000000001E-5
0.249	-4.914E-5
0.248	-4.9301000000000001E-5
0.247	-4.9416999999999998E-5
0.246	-4.939E-5
0.245	-4.9506999999999999E-5
0.24399999999999999	-4.9595999999999997E-5
0.24299999999999999	-4.9659E-5
0.24199999999999999	-4.9650000000000001E-5
0.24099999999999999	-4.9685000000000003E-5
0.24	-4.9694000000000002E-5
0.23899999999999999	-4.9829E-5
0.23799999999999999	-4.99E-5
0.23699999999999999	-4.9836999999999997E-5
0.23599999999999999	-4.9864000000000002E-5
0.23499999999999999	-4.9917999999999999E-5
0.23400000000000001	-4.9963000000000003E-5
0.23300000000000001	-4.9944999999999997E-5
0.23200000000000001	-5.007E-5
0.23100000000000001	-5.0167999999999998E-5
0.23	-5.0195000000000003E-5
0.22900000000000001	-5.0284999999999997E-5
0.22800000000000001	-5.0294000000000003E-5
0.22700000000000001	-5.0266999999999998E-5
0.22600000000000001	-5.0319999999999999E-5
0.22500000000000001	-5.041E-5
0.224	-5.0257999999999999E-5
0.223	-5.0383000000000002E-5
0.222	-5.0516999999999998E-5
0.221	-5.0498999999999999E-5
0.22	-5.0498999999999999E-5
0.219	-5.0589E-5
0.218	-5.0659999999999999E-5
0.217	-5.075E-5
0.216	-5.0812000000000001E-5
0.215	-5.0794999999999997E-5
0.214	-5.0695999999999997E-5
0.21299999999999999	-5.0794999999999997E-5
0.21199999999999999	-5.0865999999999997E-5
0.21099999999999999	-5.0785999999999998E-5
0.21	-5.0856999999999998E-5
0.20899999999999999	-5.0937999999999999E-5
0.20799999999999999	-5.0856999999999998E-5
0.20699999999999999	-5.092E-5
0.20599999999999999	-5.1E-5
0.20499999999999999	-5.0973000000000001E-5
0.20399999999999999	-5.1E-5
0.20300000000000001	-5.1116999999999999E-5
0.20200000000000001	-5.1008999999999999E-5
0.20100000000000001	-5.1017999999999998E-5
0.2	-5.1125000000000003E-5
0.19900000000000001	-5.134E-5
0.19800000000000001	-5.1536999999999998E-5
0.19700000000000001	-5.1412000000000002E-5
0.19600000000000001	-5.1286000000000003E-5
0.19500000000000001	-5.117E-5
0.19400000000000001	-5.1107999999999999E-5
0.193	-5.1187999999999998E-5
0.192	-5.109E-5
0.191	-5.0973000000000001E-5
0.19	-5.1026999999999998E-5
0.189	-5.1017999999999998E-5
0.188	-5.0982000000000001E-5
0.187	-5.0964000000000002E-5
0.186	-5.0929E-5
0.185	-5.0776999999999999E-5
0.184	-5.0776999999999999E-5
0.183	-5.0686999999999998E-5
0.182	-5.0705000000000003E-5
0.18099999999999999	-5.0705000000000003E-5
0.18	-5.0695999999999997E-5
0.17899999999999999	-5.0633999999999997E-5
0.17799999999999999	-5.0544000000000003E-5
0.17699999999999999	-5.0481E-5
0.17599999999999999	-5.0312000000000002E-5
0.17499999999999999	-5.0319999999999999E-5
0.17399999999999999	-5.0257999999999999E-5
0.17299999999999999	-4.9981000000000001E-5
0.17199999999999999	-4.9836999999999997E-5
0.17100000000000001	-4.9926999999999998E-5
0.17	-4.9882000000000001E-5
0.16900000000000001	-4.9659E-5
0.16800000000000001	-4.9623000000000002E-5
0.16700000000000001	-4.9650000000000001E-5
0.16600000000000001	-4.9471000000000001E-5
0.16500000000000001	-4.9345999999999998E-5
0.16400000000000001	-4.9310000000000001E-5
0.16300000000000001	-4.9122000000000002E-5
0.16200000000000001	-4.8925000000000003E-5
0.161	-4.8888999999999999E-5
0.16	-4.8693000000000003E-5
0.159	-4.8603000000000002E-5
0.158	-4.8541000000000002E-5
0.157	-4.8325999999999998E-5
0.156	-4.8201000000000001E-5
0.155	-4.8128999999999999E-5
0.154	-4.8049E-5
0.153	-4.7976999999999998E-5
0.152	-4.7788999999999999E-5
0.151	-4.7565999999999998E-5
0.15	-4.7305999999999997E-5
0.14899999999999999	-4.7253000000000003E-5
0.14799999999999999	-4.7144999999999997E-5
0.14699999999999999	-4.7029E-5
0.14599999999999999	-4.6832000000000002E-5
0.14499999999999999	-4.6662000000000001E-5
0.14399999999999999	-4.651E-5
0.14299999999999999	-4.6439E-5
0.14199999999999999	-4.6357999999999999E-5
0.14099999999999999	-4.6152000000000001E-5
0.14000000000000001	-4.5920000000000001E-5
0.13900000000000001	-4.5794999999999998E-5
0.13800000000000001	-4.5695999999999998E-5
0.13700000000000001	-4.5544000000000003E-5
0.13600000000000001	-4.5445999999999998E-5
0.13500000000000001	-4.5178E-5
0.13400000000000001	-4.4944999999999997E-5
0.13300000000000001	-4.4873000000000002E-5
0.13200000000000001	-4.4756999999999999E-5
0.13100000000000001	-4.4480000000000001E-5
0.13	-4.4407999999999999E-5
0.129	-4.4354999999999998E-5
0.128	-4.4149E-5
0.127	-4.4005999999999998E-5
0.126	-4.3835999999999998E-5
0.125	-4.3621000000000001E-5
0.124	-4.3568E-5
0.123	-4.3414999999999997E-5
0.122	-4.3075999999999999E-5
0.121	-4.2967999999999999E-5
0.12	-4.2905999999999999E-5
0.11899999999999999	-4.2789E-5
0.11799999999999999	-4.2700000000000001E-5
0.11700000000000001	-4.2645999999999998E-5
0.11600000000000001	-4.2466999999999998E-5
0.115	-4.2324000000000003E-5
0.114	-4.2199E-5
0.113	-4.2128000000000001E-5
0.112	-4.1912999999999997E-5
0.111	-4.1797E-5
0.11	-4.1644999999999999E-5
0.109	-4.1474999999999998E-5
0.108	-4.1403000000000003E-5
0.107	-4.1340000000000001E-5
0.106	-4.1152999999999997E-5
0.105	-4.1001000000000003E-5
0.104	-4.0902000000000002E-5
0.10299999999999999	-4.0822000000000003E-5
0.10199999999999999	-4.0741000000000002E-5
0.10100000000000001	-4.0670000000000002E-5
0.1	-4.0562000000000002E-5
9.9000000000000005E-2	-4.0392000000000002E-5
9.8000000000000004E-2	-4.0330000000000002E-5
9.7000000000000003E-2	-4.0284999999999998E-5
9.6000000000000002E-2	-4.0419E-5
9.5000000000000001E-2	-4.0213000000000003E-5
9.4E-2	-4.0079E-5
9.2999999999999999E-2	-3.9802000000000003E-5
9.1999999999999998E-2	-3.9650000000000002E-5
9.0999999999999998E-2	-3.9659000000000001E-5
0.09	-3.9551999999999997E-5
8.8999999999999996E-2	-3.9533999999999998E-5
8.7999999999999995E-2	-3.9434999999999998E-5
8.6999999999999994E-2	-3.9273999999999997E-5
8.5999999999999993E-2	-3.9113000000000003E-5
8.5000000000000006E-2	-3.9113000000000003E-5
8.4000000000000005E-2	-3.9094999999999998E-5
8.3000000000000004E-2	-3.8890000000000002E-5
8.2000000000000003E-2	-3.8862999999999997E-5
8.1000000000000003E-2	-3.8818E-5
0.08	-3.8665999999999999E-5
7.9000000000000001E-2	-3.8711000000000003E-5
7.8E-2	-3.8603000000000003E-5
7.6999999999999999E-2	-3.8460000000000001E-5
7.5999999999999998E-2	-3.8451000000000002E-5
7.4999999999999997E-2	-3.8460000000000001E-5
7.3999999999999996E-2	-3.8325999999999999E-5
7.2999999999999995E-2	-3.8254999999999999E-5
7.1999999999999995E-2	-3.8219000000000001E-5
7.0999999999999994E-2	-3.8111999999999997E-5
7.0000000000000007E-2	-3.7941999999999997E-5
6.9000000000000006E-2	-3.7941999999999997E-5
6.8000000000000005E-2	-3.7932999999999997E-5
6.7000000000000004E-2	-3.7806999999999999E-5
6.6000000000000003E-2	-3.7842999999999997E-5
6.5000000000000002E-2	-3.7842999999999997E-5
6.4000000000000001E-2	-3.7781000000000003E-5
6.3E-2	-3.7709000000000001E-5
6.2E-2	-3.7636999999999999E-5
6.0999999999999999E-2	-3.7493999999999997E-5
0.06	-3.7512000000000003E-5
5.8999999999999997E-2	-3.7557E-5
5.8000000000000003E-2	-3.7422999999999997E-5
5.7000000000000002E-2	-3.7369000000000001E-5
5.6000000000000001E-2	-3.7387E-5
5.5E-2	-3.7261999999999997E-5
5.3999999999999999E-2	-3.7234999999999998E-5
5.2999999999999999E-2	-3.7289000000000002E-5
5.1999999999999998E-2	-3.7323999999999997E-5
5.0999999999999997E-2	-3.7119000000000002E-5
0.05	-3.7163000000000003E-5
4.9000000000000002E-2	-3.7225999999999999E-5
4.8000000000000001E-2	-3.7047E-5
4.7E-2	-3.7047E-5
4.5999999999999999E-2	-3.7064999999999998E-5
4.4999999999999998E-2	-3.7038E-5
4.3999999999999997E-2	-3.6967E-5
4.2999999999999997E-2	-3.6976E-5
4.2000000000000003E-2	-3.6823999999999998E-5
4.1000000000000002E-2	-3.6832999999999998E-5
0.04	-3.6859000000000001E-5
3.9E-2	-3.6814999999999999E-5
3.7999999999999999E-2	-3.6797E-5
3.6999999999999998E-2	-3.6752000000000003E-5
3.5999999999999997E-2	-3.6698E-5
3.5000000000000003E-2	-3.6600000000000002E-5
3.4000000000000002E-2	-3.6662999999999998E-5
3.3000000000000002E-2	-3.6644999999999999E-5
3.2000000000000001E-2	-3.6545999999999999E-5
3.1E-2	-3.6519000000000001E-5
0.03	-3.6536999999999999E-5
2.9000000000000001E-2	-3.6483999999999998E-5
2.8000000000000001E-2	-3.6465999999999999E-5
2.7E-2	-3.6474999999999999E-5
2.5999999999999999E-2	-3.6511000000000003E-5
2.5000000000000001E-2	-3.6430000000000002E-5
2.4E-2	-3.6465999999999999E-5
2.3E-2	-3.6457E-5
2.1999999999999999E-2	-3.6350000000000003E-5
2.1000000000000001E-2	-3.6313999999999998E-5
0.02	-3.6322999999999998E-5
1.9E-2	-3.6232999999999997E-5
1.7999999999999999E-2	-3.6322999999999998E-5
1.7000000000000001E-2	-3.6331999999999997E-5
1.6E-2	-3.6171000000000003E-5
1.4999999999999999E-2	-3.6214999999999998E-5
1.4E-2	-3.6260000000000002E-5
1.2999999999999999E-2	-3.6196999999999999E-5
1.2E-2	-3.6278000000000001E-5
1.0999999999999999E-2	-3.6171000000000003E-5
0.01	-3.6028000000000001E-5
8.9999999999999993E-3	-3.6117E-5
8.0000000000000002E-3	-3.6134999999999999E-5
7.0000000000000001E-3	-3.6019000000000002E-5
6.0000000000000001E-3	-3.6001000000000003E-5
5.0000000000000001E-3	-3.6053999999999997E-5
4.0000000000000001E-3	-3.6081000000000002E-5
3.0000000000000001E-3	-3.6001000000000003E-5
2E-3	-3.6001000000000003E-5
1E-3	-3.6072000000000003E-5
0	-3.5982999999999998E-5
-1E-3	-3.5955999999999999E-5
-2E-3	-3.6062999999999997E-5
-3.0000000000000001E-3	-3.5874999999999998E-5
-4.0000000000000001E-3	-3.5867000000000001E-5
-5.0000000000000001E-3	-3.5929000000000001E-5
-6.0000000000000001E-3	-3.6134999999999999E-5
-7.0000000000000001E-3	-3.6134999999999999E-5
-8.0000000000000002E-3	-3.5982999999999998E-5
-8.9999999999999993E-3	-3.5831000000000003E-5
-0.01	-3.5840000000000002E-5
-1.0999999999999999E-2	-3.5883999999999997E-5
-1.2E-2	-3.5812999999999997E-5
-1.2999999999999999E-2	-3.5741000000000002E-5
-1.4E-2	-3.5706E-5
-1.4999999999999999E-2	-3.5750000000000002E-5
-1.6E-2	-3.5624999999999999E-5
-1.7000000000000001E-2	-3.5661000000000003E-5
-1.7999999999999999E-2	-3.5670000000000002E-5
-1.9E-2	-3.5509000000000002E-5
-0.02	-3.5598E-5
-2.1000000000000001E-2	-3.5651999999999997E-5
-2.1999999999999999E-2	-3.5580000000000002E-5
-2.3E-2	-3.5509000000000002E-5
-2.4E-2	-3.5509000000000002E-5
-2.5000000000000001E-2	-3.5553000000000003E-5
-2.5999999999999999E-2	-3.5509000000000002E-5
-2.7E-2	-3.5472999999999997E-5
-2.8000000000000001E-2	-3.5472999999999997E-5
-2.9000000000000001E-2	-3.5311999999999997E-5
-0.03	-3.5410000000000001E-5
-3.1E-2	-3.5410000000000001E-5
-3.2000000000000001E-2	-3.5240000000000001E-5
-3.3000000000000002E-2	-3.5284999999999998E-5
-3.4000000000000002E-2	-3.5284999999999998E-5
-3.5000000000000003E-2	-3.5187E-5
-3.5999999999999997E-2	-3.5196E-5
-3.6999999999999998E-2	-3.5187E-5
-3.7999999999999999E-2	-3.5142000000000003E-5
-3.9E-2	-3.5151000000000003E-5
-0.04	-3.5160000000000002E-5
-4.1000000000000002E-2	-3.5079000000000001E-5
-4.2000000000000003E-2	-3.5008000000000001E-5
-4.2999999999999997E-2	-3.5034999999999999E-5
-4.3999999999999997E-2	-3.4999000000000002E-5
-4.4999999999999998E-2	-3.4882999999999998E-5
-4.5999999999999999E-2	-3.4873999999999998E-5
-4.7E-2	-3.4882999999999998E-5
-4.8000000000000001E-2	-3.4811000000000003E-5
-4.9000000000000002E-2	-3.4792999999999997E-5
-0.05	-3.4792999999999997E-5
-5.0999999999999997E-2	-3.4783999999999998E-5
-5.1999999999999998E-2	-3.4740000000000003E-5
-5.2999999999999999E-2	-3.4703999999999998E-5
-5.3999999999999999E-2	-3.4632000000000003E-5
-5.5E-2	-3.4595999999999999E-5
-5.6000000000000001E-2	-3.4613999999999998E-5
-5.7000000000000002E-2	-3.4570000000000003E-5
-5.8000000000000003E-2	-3.4443999999999998E-5
-5.8999999999999997E-2	-3.4452999999999997E-5
-0.06	-3.4381999999999997E-5
-6.0999999999999999E-2	-3.4301000000000002E-5
-6.2E-2	-3.4345999999999999E-5
-6.3E-2	-3.4292000000000003E-5
-6.4000000000000001E-2	-3.4239000000000002E-5
-6.5000000000000002E-2	-3.4248000000000001E-5
-6.6000000000000003E-2	-3.4167E-5
-6.7000000000000004E-2	-3.4032999999999998E-5
-6.8000000000000005E-2	-3.4060000000000003E-5
-6.9000000000000006E-2	-3.4069000000000002E-5
-7.0000000000000007E-2	-3.3988000000000001E-5
-7.0999999999999994E-2	-3.3908000000000001E-5
-7.1999999999999995E-2	-3.3899000000000002E-5
-7.2999999999999995E-2	-3.3890000000000002E-5
-7.3999999999999996E-2	-3.3747000000000001E-5
-7.4999999999999997E-2	-3.3782999999999998E-5
-7.5999999999999998E-2	-3.3773999999999999E-5
-7.6999999999999999E-2	-3.3701999999999997E-5
-7.8E-2	-3.3692999999999997E-5
-7.9000000000000001E-2	-3.3657E-5
-0.08	-3.3495999999999999E-5
-8.1000000000000003E-2	-3.3513999999999998E-5
-8.2000000000000003E-2	-3.3416E-5
-8.3000000000000004E-2	-3.3325999999999999E-5
-8.4000000000000005E-2	-3.3317E-5
-8.5000000000000006E-2	-3.3334999999999998E-5
-8.5999999999999993E-2	-3.3228000000000001E-5
-8.6999999999999994E-2	-3.3237E-5
-8.7999999999999995E-2	-3.3272999999999998E-5
-8.8999999999999996E-2	-3.3237E-5
-0.09	-3.3164999999999998E-5
-9.0999999999999998E-2	-3.3120999999999997E-5
-9.1999999999999998E-2	-3.2978000000000002E-5
-9.2999999999999999E-2	-3.2833999999999998E-5
-9.4E-2	-3.2888000000000001E-5
-9.5000000000000001E-2	-3.2833999999999998E-5
-9.6000000000000002E-2	-3.2727E-5
-9.7000000000000003E-2	-3.2771999999999997E-5
-9.8000000000000004E-2	-3.2790000000000003E-5
-9.9000000000000005E-2	-3.2656E-5
-0.1	-3.2611000000000003E-5
-0.10100000000000001	-3.2656E-5
-0.10199999999999999	-3.2539000000000001E-5
-0.10299999999999999	-3.2495E-5
-0.104	-3.2450000000000003E-5
-0.105	-3.2325E-5
-0.106	-3.2333999999999999E-5
-0.107	-3.2298000000000001E-5
-0.108	-3.2307000000000001E-5
-0.109	-3.2477000000000001E-5
-0.11	-3.2360000000000002E-5
-0.111	-3.2163999999999999E-5
-0.112	-3.2002999999999998E-5
-0.113	-3.1985E-5
-0.114	-3.2020000000000002E-5
-0.115	-3.1912999999999998E-5
-0.11600000000000001	-3.1832999999999998E-5
-0.11700000000000001	-3.1832999999999998E-5
-0.11799999999999999	-3.1742999999999997E-5
-0.11899999999999999	-3.1653999999999999E-5
-0.12	-3.1644999999999999E-5
-0.121	-3.1538000000000002E-5
-0.122	-3.1483999999999999E-5
-0.123	-3.1492999999999998E-5
-0.124	-3.1393999999999998E-5
-0.125	-3.1313999999999999E-5
-0.126	-3.1304999999999999E-5
-0.127	-3.1359000000000002E-5
-0.128	-3.1161999999999997E-5
-0.129	-3.1189000000000002E-5
-0.13	-3.1170999999999997E-5
-0.13100000000000001	-3.0982999999999998E-5
-0.13200000000000001	-3.1000999999999997E-5
-0.13300000000000001	-3.0938000000000001E-5
-0.13400000000000001	-3.0794999999999999E-5
-0.13500000000000001	-3.0794999999999999E-5
-0.13600000000000001	-3.0821999999999997E-5
-0.13700000000000001	-3.0768000000000001E-5
-0.13800000000000001	-3.0624999999999999E-5
-0.13900000000000001	-3.0642999999999998E-5
-0.14000000000000001	-3.0688000000000002E-5
-0.14099999999999999	-3.0518000000000002E-5
-0.14199999999999999	-3.0499999999999999E-5
-0.14299999999999999	-3.0482000000000001E-5
-0.14399999999999999	-3.025E-5
-0.14499999999999999	-3.0267E-5
-0.14599999999999999	-3.0303000000000001E-5
-0.14699999999999999	-3.0142E-5
-0.14799999999999999	-3.0114999999999999E-5
-0.14899999999999999	-3.0105999999999999E-5
-0.15	-2.9989999999999999E-5
-0.151	-2.9998999999999999E-5
-0.152	-2.9998999999999999E-5
-0.153	-2.9918999999999999E-5
-0.154	-2.9882999999999998E-5
-0.155	-2.9793000000000001E-5
-0.156	-2.9722000000000001E-5
-0.157	-2.9649999999999999E-5
-0.158	-2.9668000000000001E-5
-0.159	-2.9632E-5
-0.16	-2.9507000000000001E-5
-0.161	-2.9436000000000001E-5
-0.16200000000000001	-2.9453000000000001E-5
-0.16300000000000001	-2.9354999999999999E-5
-0.16400000000000001	-2.9283999999999999E-5
-0.16500000000000001	-2.9257000000000001E-5
-0.16600000000000001	-2.9184999999999999E-5
-0.16700000000000001	-2.9087000000000001E-5
-0.16800000000000001	-2.9149000000000002E-5
-0.16900000000000001	-2.9077999999999998E-5
-0.17	-2.8943999999999999E-5
-0.17100000000000001	-2.8969999999999999E-5
-0.17199999999999999	-2.8853999999999999E-5
-0.17299999999999999	-2.8792000000000001E-5
-0.17399999999999999	-2.8801000000000001E-5
-0.17499999999999999	-2.8756E-5
-0.17599999999999999	-2.8649E-5
-0.17699999999999999	-2.8631000000000001E-5
-0.17799999999999999	-2.8577000000000001E-5
-0.17899999999999999	-2.8523000000000001E-5
-0.18	-2.8461000000000001E-5
-0.18099999999999999	-2.8388999999999999E-5
-0.182	-2.8309E-5
-0.183	-2.8291000000000001E-5
-0.184	-2.8326999999999998E-5
-0.185	-2.8209999999999999E-5
-0.186	-2.8067000000000001E-5
-0.187	-2.8076E-5
-0.188	-2.8022E-5
-0.189	-2.7968999999999999E-5
-0.19	-2.7951000000000001E-5
-0.191	-2.7906E-5
-0.192	-2.7826000000000001E-5
-0.193	-2.7763000000000002E-5
-0.19400000000000001	-2.7718000000000001E-5
-0.19500000000000001	-2.7611E-5
-0.19600000000000001	-2.7611E-5
-0.19700000000000001	-2.7602000000000001E-5
-0.19800000000000001	-2.7495E-5
-0.19900000000000001	-2.7467999999999999E-5
-0.2	-2.745E-5
-0.20100000000000001	-2.7334E-5
-0.20200000000000001	-2.7288999999999999E-5
-0.20300000000000001	-2.7307000000000001E-5
-0.20399999999999999	-2.728E-5
-0.20499999999999999	-2.7191000000000001E-5
-0.20599999999999999	-2.72E-5
-0.20699999999999999	-2.7101E-5
-0.20799999999999999	-2.6993999999999999E-5
-0.20899999999999999	-2.6967000000000001E-5
-0.21	-2.6931E-5
-0.21099999999999999	-2.7083000000000001E-5
-0.21199999999999999	-2.7047E-5
-0.21299999999999999	-2.6851000000000001E-5
-0.214	-2.6707999999999999E-5
-0.215	-2.6707999999999999E-5
-0.216	-2.6662999999999999E-5
-0.217	-2.6591E-5
-0.218	-2.6618000000000002E-5
-0.219	-2.6573000000000001E-5
-0.22	-2.6448000000000002E-5
-0.221	-2.6403000000000001E-5
-0.222	-2.6376999999999998E-5
-0.223	-2.6359E-5
-0.224	-2.6234E-5
-0.22500000000000001	-2.6207000000000002E-5
-0.22600000000000001	-2.6242E-5
-0.22700000000000001	-2.6152999999999998E-5
-0.22800000000000001	-2.6098999999999999E-5
-0.22900000000000001	-2.6046000000000001E-5
-0.23	-2.5992000000000001E-5
-0.23100000000000001	-2.5973999999999999E-5
-0.23200000000000001	-2.6001000000000001E-5
-0.23300000000000001	-2.5876000000000001E-5
-0.23400000000000001	-2.5822000000000001E-5
-0.23499999999999999	-2.5803999999999999E-5
-0.23599999999999999	-2.5724E-5
-0.23699999999999999	-2.5687999999999999E-5
-0.23799999999999999	-2.5652000000000001E-5
-0.23899999999999999	-2.5581000000000001E-5
-0.24	-2.5554E-5
-0.24099999999999999	-2.5536000000000001E-5
-0.24199999999999999	-2.5527000000000001E-5
-0.24299999999999999	-2.5491E-5
-0.24399999999999999	-2.5491E-5
-0.245	-2.5411000000000001E-5
-0.246	-2.5222999999999999E-5
-0.247	-2.5276999999999999E-5
-0.248	-2.525E-5
-0.249	-2.516E-5
-0.25	-2.5142000000000001E-5
-0.251	-2.5168999999999999E-5
-0.252	-2.5116000000000001E-5
-0.253	-2.5052999999999999E-5
-0.254	-2.5007999999999998E-5
-0.255	-2.5052999999999999E-5
-0.25600000000000001	-2.4981E-5
-0.25700000000000001	-2.4955000000000001E-5
-0.25800000000000001	-2.4901000000000001E-5
-0.25900000000000001	-2.4794E-5
-0.26	-2.4828999999999999E-5
-0.26100000000000001	-2.4811E-5
-0.26200000000000001	-2.4802000000000001E-5
-0.26300000000000001	-2.4703999999999999E-5
-0.26400000000000001	-2.4757999999999999E-5
-0.26500000000000001	-2.4641E-5
-0.26600000000000001	-2.4587999999999999E-5
-0.26700000000000002	-2.4606000000000001E-5
-0.26800000000000002	-2.4587999999999999E-5
-0.26900000000000002	-2.4516E-5
-0.27	-2.4525E-5
-0.27100000000000002	-2.4498000000000002E-5
-0.27200000000000002	-2.4454E-5
-0.27300000000000002	-2.4417999999999999E-5
-0.27400000000000002	-2.4355E-5
-0.27500000000000002	-2.4284E-5
-0.27600000000000002	-2.4301999999999999E-5
-0.27700000000000002	-2.4275000000000001E-5
-0.27800000000000002	-2.4266000000000001E-5
-0.27900000000000003	-2.4239E-5
-0.28000000000000003	-2.4256999999999998E-5
-0.28100000000000003	-2.4167000000000001E-5
-0.28199999999999997	-2.4122999999999999E-5
-0.28299999999999997	-2.4193999999999999E-5
-0.28399999999999997	-2.4185E-5
-0.28499999999999998	-2.4051000000000001E-5
-0.28599999999999998	-2.4042000000000001E-5
-0.28699999999999998	-2.4032999999999998E-5
-0.28799999999999998	-2.3935E-5
-0.28899999999999998	-2.3944E-5
-0.28999999999999998	-2.3980000000000001E-5
-0.29099999999999998	-2.3907999999999999E-5
-0.29199999999999998	-2.3926000000000001E-5
-0.29299999999999998	-2.3935E-5
-0.29399999999999998	-2.3853999999999999E-5
-0.29499999999999998	-2.3845E-5
-0.29599999999999999	-2.3935E-5
-0.29699999999999999	-2.3845E-5
-0.29799999999999999	-2.3801000000000001E-5
-0.29899999999999999	-2.3791999999999999E-5
-0.3	-2.3782999999999999E-5
-0.30099999999999999	-2.3711E-5
-0.30199999999999999	-2.3711E-5
-0.30299999999999999	-2.3737999999999999E-5
-0.30399999999999999	-2.3666999999999999E-5
-0.30499999999999999	-2.3666999999999999E-5
-0.30599999999999999	-2.3657999999999999E-5
-0.307	-2.3693000000000002E-5
-0.308	-2.3649E-5
-0.309	-2.3621999999999998E-5
-0.31	-2.3586000000000001E-5
-0.311	-2.3631000000000001E-5
-0.312	-2.3604E-5
-0.313	-2.3711E-5
-0.314	-2.3728999999999999E-5
-0.315	-2.3604E-5
-0.316	-2.3541E-5
-0.317	-2.3461000000000001E-5
-0.318	-2.3506000000000002E-5
-0.31900000000000001	-2.3558999999999999E-5
-0.32	-2.3532000000000001E-5
-0.32100000000000001	-2.3513999999999999E-5
-0.32200000000000001	-2.3513999999999999E-5
-0.32300000000000001	-2.3434E-5
-0.32400000000000001	-2.3442999999999999E-5
-0.32500000000000001	-2.3425E-5
-0.32600000000000001	-2.3407000000000001E-5
-0.32700000000000001	-2.338E-5
-0.32800000000000001	-2.3425E-5
-0.32900000000000001	-2.3397999999999999E-5
-0.33	-2.3425E-5
-0.33100000000000002	-2.3451999999999998E-5
-0.33200000000000002	-2.3434E-5
-0.33300000000000002	-2.3451999999999998E-5
-0.33400000000000002	-2.3434E-5
-0.33500000000000002	-2.3425E-5
-0.33600000000000002	-2.338E-5
-0.33700000000000002	-2.3388999999999999E-5
-0.33800000000000002	-2.3371E-5
-0.33900000000000002	-2.3336000000000002E-5
-0.34	-2.3407000000000001E-5
-0.34100000000000003	-2.3451999999999998E-5
-0.34200000000000003	-2.3371E-5
-0.34300000000000003	-2.3416000000000001E-5
-0.34399999999999997	-2.3434E-5
-0.34499999999999997	-2.3353000000000002E-5
-0.34599999999999997	-2.3388999999999999E-5
-0.34699999999999998	-2.338E-5
-0.34799999999999998	-2.3407000000000001E-5
-0.34899999999999998	-2.3416000000000001E-5
-0.35	-2.3407000000000001E-5
-0.35099999999999998	-2.3434E-5
-0.35199999999999998	-2.3371E-5
-0.35299999999999998	-2.3461000000000001E-5
-0.35399999999999998	-2.3451999999999998E-5
-0.35499999999999998	-2.3416000000000001E-5
-0.35599999999999998	-2.3451999999999998E-5
-0.35699999999999998	-2.3461000000000001E-5
-0.35799999999999998	-2.3425E-5
-0.35899999999999999	-2.3434E-5
-0.36	-2.3513999999999999E-5
-0.36099999999999999	-2.3451999999999998E-5
-0.36199999999999999	-2.3461000000000001E-5
-0.36299999999999999	-2.3541E-5
-0.36399999999999999	-2.3513999999999999E-5
-0.36499999999999999	-2.3541E-5
-0.36599999999999999	-2.3595E-5
-0.36699999999999999	-2.3541E-5
-0.36799999999999999	-2.3532000000000001E-5
-0.36899999999999999	-2.3532000000000001E-5
-0.37	-2.3640000000000001E-5
-0.371	-2.3532000000000001E-5
-0.372	-2.3595E-5
-0.373	-2.3657999999999999E-5
-0.374	-2.3612999999999999E-5
-0.375	-2.3612999999999999E-5
-0.376	-2.3640000000000001E-5
-0.377	-2.3612999999999999E-5
-0.378	-2.3649E-5
-0.379	-2.3666999999999999E-5
-0.38	-2.3666999999999999E-5
-0.38100000000000001	-2.3683999999999999E-5
-0.38200000000000001	-2.3711E-5
-0.38300000000000001	-2.3756000000000001E-5
-0.38400000000000001	-2.3728999999999999E-5
-0.38500000000000001	-2.3853999999999999E-5
-0.38600000000000001	-2.3828E-5
-0.38700000000000001	-2.3791999999999999E-5
-0.38800000000000001	-2.3828E-5
-0.38900000000000001	-2.3853999999999999E-5
-0.39	-2.3765E-5
-0.39100000000000001	-2.3845E-5
-0.39200000000000002	-2.3898999999999999E-5
-0.39300000000000002	-2.3898999999999999E-5
-0.39400000000000002	-2.3917000000000002E-5
-0.39500000000000002	-2.3944E-5
-0.39600000000000002	-2.4006E-5
-0.39700000000000002	-2.3989E-5
-0.39800000000000002	-2.4042000000000001E-5
-0.39900000000000002	-2.4015E-5
-0.4	-2.4042000000000001E-5
-0.40100000000000002	-2.4096000000000001E-5
-0.40200000000000002	-2.4141000000000001E-5
-0.40300000000000002	-2.4068999999999999E-5
-0.40400000000000003	-2.4096000000000001E-5
-0.40500000000000003	-2.4150000000000001E-5
-0.40600000000000003	-2.4141000000000001E-5
-0.40699999999999997	-2.423E-5
-0.40799999999999997	-2.4266000000000001E-5
-0.40899999999999997	-2.4247999999999999E-5
-0.41	-2.4256999999999998E-5
-0.41099999999999998	-2.4311000000000002E-5
-0.41199999999999998	-2.4311000000000002E-5
-0.41299999999999998	-2.4284E-5
-0.41399999999999998	-2.4372999999999999E-5
-0.41499999999999998	-2.4445000000000001E-5
-0.41599999999999998	-2.4624E-5
-0.41699999999999998	-2.457E-5
-0.41799999999999998	-2.4488999999999999E-5
-0.41899999999999998	-2.4479999999999999E-5
-0.42	-2.4552000000000001E-5
-0.42099999999999999	-2.4579E-5
-0.42199999999999999	-2.4587999999999999E-5
-0.42299999999999999	-2.4579E-5
-0.42399999999999999	-2.4632999999999999E-5
-0.42499999999999999	-2.4641E-5
-0.42599999999999999	-2.4668000000000002E-5
-0.42699999999999999	-2.4722000000000001E-5
-0.42799999999999999	-2.4695E-5
-0.42899999999999999	-2.4677000000000001E-5
-0.43	-2.4766999999999999E-5
-0.43099999999999999	-2.482E-5
-0.432	-2.4837999999999998E-5
-0.433	-2.4873999999999999E-5
-0.434	-2.491E-5
-0.435	-2.4936999999999999E-5
-0.436	-2.4981E-5
-0.437	-2.5007999999999998E-5
-0.438	-2.4963000000000001E-5
-0.439	-2.5035E-5
-0.44	-2.5089E-5
-0.441	-2.5052999999999999E-5
-0.442	-2.5026000000000001E-5
-0.443	-2.5142000000000001E-5
-0.44400000000000001	-2.5168999999999999E-5
-0.44500000000000001	-2.5205E-5
-0.44600000000000001	-2.5222999999999999E-5
-0.44700000000000001	-2.5284999999999999E-5
-0.44800000000000001	-2.5321E-5
-0.44900000000000001	-2.5347999999999999E-5
-0.45	-2.5401999999999998E-5
-0.45100000000000001	-2.5375E-5
-0.45200000000000001	-2.5454999999999999E-5
-0.45300000000000001	-2.5482000000000001E-5
-0.45400000000000001	-2.5384E-5
-0.45500000000000002	-2.5491E-5
-0.45600000000000002	-2.5581000000000001E-5
-0.45700000000000002	-2.5571999999999998E-5
-0.45800000000000002	-2.5571999999999998E-5
-0.45900000000000002	-2.5624999999999999E-5
-0.46	-2.5678999999999999E-5
-0.46100000000000002	-2.5687999999999999E-5
-0.46200000000000002	-2.5795E-5
-0.46300000000000002	-2.5831000000000001E-5
-0.46400000000000002	-2.5732999999999999E-5
-0.46500000000000002	-2.5795E-5
-0.46600000000000003	-2.5857999999999999E-5
-0.46700000000000003	-2.5876000000000001E-5
-0.46800000000000003	-2.5956E-5
-0.46899999999999997	-2.5982999999999998E-5
-0.47	-2.5947000000000001E-5
-0.47099999999999997	-2.601E-5
-0.47199999999999998	-2.6046000000000001E-5
-0.47299999999999998	-2.6064E-5
-0.47399999999999998	-2.6098999999999999E-5
-0.47499999999999998	-2.6152999999999998E-5
-0.47599999999999998	-2.6251E-5
-0.47699999999999998	-2.6225E-5
-0.47799999999999998	-2.6268999999999999E-5
-0.47899999999999998	-2.6287000000000001E-5
-0.48	-2.6234E-5
-0.48099999999999998	-2.6332000000000001E-5
-0.48199999999999998	-2.6376999999999998E-5
-0.48299999999999998	-2.6359E-5
-0.48399999999999999	-2.6438999999999999E-5
-0.48499999999999999	-2.652E-5
-0.48599999999999999	-2.6511000000000001E-5
-0.48699999999999999	-2.6529E-5
-0.48799999999999999	-2.6627000000000001E-5
-0.48899999999999999	-2.6582000000000001E-5
-0.49	-2.6618000000000002E-5
-0.49099999999999999	-2.6653999999999999E-5
-0.49199999999999999	-2.6699E-5
-0.49299999999999999	-2.6672000000000001E-5
-0.49399999999999999	-2.6788000000000002E-5
-0.495	-2.6788000000000002E-5
-0.496	-2.6788000000000002E-5
-0.497	-2.6869E-5
-0.498	-2.6922000000000001E-5
-0.499	-2.6948999999999999E-5
-0.5	-2.7021000000000001E-5
-0.501	-2.7002999999999999E-5
-0.502	-2.6985E-5
-0.503	-2.7039E-5
-0.504	-2.7137000000000001E-5
-0.505	-2.7155E-5
-0.50600000000000001	-2.7056E-5
-0.50700000000000001	-2.7191000000000001E-5
-0.50800000000000001	-2.7325E-5
-0.50900000000000001	-2.7243999999999999E-5
-0.51	-2.7217E-5
-0.51100000000000001	-2.7316000000000001E-5
-0.51200000000000001	-2.7361000000000001E-5
-0.51300000000000001	-2.7432000000000001E-5
-0.51400000000000001	-2.7413999999999999E-5
-0.51500000000000001	-2.7432000000000001E-5
-0.51600000000000001	-2.7538999999999998E-5
-0.51700000000000002	-2.7512999999999999E-5
-0.51800000000000002	-2.7744999999999999E-5
-0.51900000000000002	-2.7798999999999999E-5
-0.52	-2.7744999999999999E-5
-0.52100000000000002	-2.7674E-5
-0.52200000000000002	-2.7656000000000001E-5
-0.52300000000000002	-2.7753999999999999E-5
-0.52400000000000002	-2.7763000000000002E-5
-0.52500000000000002	-2.7861E-5
-0.52600000000000002	-2.7826000000000001E-5
-0.52700000000000002	-2.7897000000000001E-5
-0.52800000000000002	-2.7869999999999999E-5
-0.52900000000000003	-2.7942000000000001E-5
-0.53	-2.7932999999999998E-5
-0.53100000000000003	-2.7951000000000001E-5
-0.53200000000000003	-2.8013000000000001E-5
-0.53300000000000003	-2.8121000000000001E-5
-0.53400000000000003	-2.8076E-5
-0.53500000000000003	-2.8093999999999999E-5
-0.53600000000000003	-2.8183000000000001E-5
-0.53700000000000003	-2.8255E-5
-0.53800000000000003	-2.8201E-5
-0.53900000000000003	-2.8246E-5
-0.54	-2.8282000000000001E-5
-0.54100000000000004	-2.83E-5
-0.54200000000000004	-2.8416E-5
-0.54300000000000004	-2.8407000000000001E-5
-0.54400000000000004	-2.8291000000000001E-5
-0.54500000000000004	-2.847E-5
-0.54600000000000004	-2.8504999999999999E-5
-0.54700000000000004	-2.8504999999999999E-5
-0.54800000000000004	-2.8577000000000001E-5
-0.54900000000000004	-2.8603999999999999E-5
-0.55000000000000004	-2.8595E-5
-0.55100000000000005	-2.8649E-5
-0.55200000000000005	-2.8719999999999999E-5
-0.55300000000000005	-2.8693000000000001E-5
-0.55400000000000005	-2.8674999999999999E-5
-0.55500000000000005	-2.8747000000000001E-5
-0.55600000000000005	-2.8818000000000001E-5
-0.55700000000000005	-2.8801000000000001E-5
-0.55800000000000005	-2.8872000000000001E-5
-0.55900000000000005	-2.8926000000000001E-5
-0.56000000000000005	-2.8917000000000001E-5
-0.56100000000000005	-2.8952999999999999E-5
-0.56200000000000006	-2.8997E-5
-0.56299999999999994	-2.9006E-5
-0.56399999999999995	-2.9087000000000001E-5
-0.56499999999999995	-2.9105E-5
-0.56599999999999995	-2.9068999999999999E-5
-0.56699999999999995	-2.9149000000000002E-5
-0.56799999999999995	-2.9184999999999999E-5
-0.56899999999999995	-2.8844999999999999E-5
-0.56999999999999995	-2.8702000000000001E-5
-0.57099999999999995	-2.9096000000000001E-5
-0.57199999999999995	-2.9257000000000001E-5
-0.57299999999999995	-2.9319000000000002E-5
-0.57399999999999995	-2.9328000000000001E-5
-0.57499999999999996	-2.9382000000000001E-5
-0.57599999999999996	-2.9382000000000001E-5
-0.57699999999999996	-2.9453000000000001E-5
-0.57799999999999996	-2.9516E-5
-0.57899999999999996	-2.9462E-5
-0.57999999999999996	-2.9516E-5
-0.58099999999999996	-2.9552000000000001E-5
-0.58199999999999996	-2.9543000000000002E-5
-0.58299999999999996	-2.9606000000000001E-5
-0.58399999999999996	-2.9649999999999999E-5
-0.58499999999999996	-2.9668000000000001E-5
-0.58599999999999997	-2.9658999999999998E-5
-0.58699999999999997	-2.9731E-5
-0.58799999999999997	-2.9774999999999999E-5
-0.58899999999999997	-2.9784000000000001E-5
-0.59	-2.9828999999999999E-5
-0.59099999999999997	-2.9865E-5
-0.59199999999999997	-2.9865E-5
-0.59299999999999997	-2.9963000000000001E-5
-0.59399999999999997	-2.9981E-5
-0.59499999999999997	-2.9828999999999999E-5
-0.59599999999999997	-3.0008000000000001E-5
-0.59699999999999998	-3.0088999999999999E-5
-0.59799999999999998	-3.008E-5
-0.59899999999999998	-3.0114999999999999E-5
-0.6	-3.0142E-5
-0.60099999999999998	-3.0159999999999999E-5
-0.60199999999999998	-3.0205E-5
-0.60299999999999998	-3.0222999999999998E-5
-0.60399999999999998	-3.0213999999999999E-5
-0.60499999999999998	-3.025E-5
-0.60599999999999998	-3.0329999999999999E-5
-0.60699999999999998	-3.0312E-5
-0.60799999999999998	-3.0258000000000001E-5
-0.60899999999999999	-3.0392999999999999E-5
-0.61	-3.0446E-5
-0.61099999999999999	-3.0402000000000001E-5
-0.61199999999999999	-3.0473000000000001E-5
-0.61299999999999999	-3.0527000000000001E-5
-0.61399999999999999	-3.0527000000000001E-5
-0.61499999999999999	-3.0598000000000001E-5
-0.61599999999999999	-3.0633999999999998E-5
-0.61699999999999999	-3.0580000000000002E-5
-0.61799999999999999	-3.0580000000000002E-5
-0.61899999999999999	-3.0679000000000002E-5
-0.62	-3.0741000000000003E-5
-0.621	-3.0929000000000002E-5
-0.622	-3.0821999999999997E-5
-0.623	-3.0849000000000002E-5
-0.624	-3.0777E-5
-0.625	-3.0840000000000003E-5
-0.626	-3.0876000000000001E-5
-0.627	-3.0830999999999997E-5
-0.628	-3.0920000000000002E-5
-0.629	-3.1010000000000003E-5
-0.63	-3.0991999999999997E-5
-0.63100000000000001	-3.1000999999999997E-5
-0.63200000000000001	-3.0991999999999997E-5
-0.63300000000000001	-3.0982999999999998E-5
-0.63400000000000001	-3.0973999999999999E-5
-0.63500000000000001	-3.1134999999999999E-5
-0.63600000000000001	-3.1126E-5
-0.63700000000000001	-3.1126E-5
-0.63800000000000001	-3.1170999999999997E-5
-0.63900000000000001	-3.1223999999999998E-5
-0.64	-3.1170999999999997E-5
-0.64100000000000001	-3.1223999999999998E-5
-0.64200000000000002	-3.1313999999999999E-5
-0.64300000000000002	-3.1304999999999999E-5
-0.64400000000000002	-3.1350000000000003E-5
-0.64500000000000002	-3.1448000000000001E-5
-0.64600000000000002	-3.1313999999999999E-5
-0.64700000000000002	-3.1331999999999997E-5
-0.64800000000000002	-3.1359000000000002E-5
-0.64900000000000002	-3.1430000000000002E-5
-0.65	-3.1448000000000001E-5
-0.65100000000000002	-3.1545999999999999E-5
-0.65200000000000002	-3.1572999999999997E-5
-0.65300000000000002	-3.1538000000000002E-5
-0.65400000000000003	-3.1572999999999997E-5
-0.65500000000000003	-3.1636E-5
-0.65600000000000003	-3.1563999999999998E-5
-0.65700000000000003	-3.1662999999999998E-5
-0.65800000000000003	-3.1715999999999999E-5
-0.65900000000000003	-3.1609000000000002E-5
-0.66	-3.1733999999999998E-5
-0.66100000000000003	-3.1823999999999999E-5
-0.66200000000000003	-3.1770000000000002E-5
-0.66300000000000003	-3.1770000000000002E-5
-0.66400000000000003	-3.1823999999999999E-5
-0.66500000000000004	-3.1850999999999997E-5
-0.66600000000000004	-3.1894999999999999E-5
-0.66700000000000004	-3.1940000000000003E-5
-0.66800000000000004	-3.1940000000000003E-5
-0.66900000000000004	-3.1903999999999998E-5
-0.67	-3.2020000000000002E-5
-0.67100000000000004	-3.2029000000000001E-5
-0.67200000000000004	-3.1976E-5
-0.67300000000000004	-3.2029000000000001E-5
-0.67400000000000004	-3.2064999999999999E-5
-0.67500000000000004	-3.2055999999999999E-5
-0.67600000000000005	-3.2101000000000003E-5
-0.67700000000000005	-3.2172999999999998E-5
-0.67800000000000005	-3.2128000000000001E-5
-0.67900000000000005	-3.2234999999999999E-5
-0.68	-3.2190000000000002E-5
-0.68100000000000005	-3.2172999999999998E-5
-0.68200000000000005	-3.2234999999999999E-5
-0.68300000000000005	-3.2316E-5
-0.68400000000000005	-3.2378000000000001E-5
-0.68500000000000005	-3.2261999999999997E-5
-0.68600000000000005	-3.2333999999999999E-5
-0.68700000000000006	-3.2333999999999999E-5
-0.68799999999999994	-3.2325E-5
-0.68899999999999995	-3.2422999999999998E-5
-0.69	-3.2477000000000001E-5
-0.69099999999999995	-3.2441000000000003E-5
-0.69199999999999995	-3.2468000000000002E-5
-0.69299999999999995	-3.2583999999999998E-5
-0.69399999999999995	-3.2512000000000003E-5
-0.69499999999999995	-3.2530000000000002E-5
-0.69599999999999995	-3.2583999999999998E-5
-0.69699999999999995	-3.2539000000000001E-5
-0.69799999999999995	-3.2530000000000002E-5
-0.69899999999999995	-3.2691000000000003E-5
-0.7	-3.2682000000000003E-5
-0.70099999999999996	-3.2638000000000002E-5
-0.70199999999999996	-3.2663999999999998E-5
-0.70299999999999996	-3.2753999999999998E-5
-0.70399999999999996	-3.2753999999999998E-5
-0.70499999999999996	-3.2736E-5
-0.70599999999999996	-3.2852000000000003E-5
-0.70699999999999996	-3.2833999999999998E-5
-0.70799999999999996	-3.2817000000000001E-5
-0.70899999999999996	-3.2879000000000001E-5
-0.71	-3.2824999999999998E-5
-0.71099999999999997	-3.2799000000000002E-5
-0.71199999999999997	-3.2879000000000001E-5
-0.71299999999999997	-3.2906E-5
-0.71399999999999997	-3.2923999999999999E-5
-0.71499999999999997	-3.2978000000000002E-5
-0.71599999999999997	-3.3049000000000002E-5
-0.71699999999999997	-3.3040000000000002E-5
-0.71799999999999997	-3.3031000000000003E-5
-0.71899999999999997	-3.3058000000000001E-5
-0.72	-3.3102999999999998E-5
-0.72099999999999997	-3.3111999999999997E-5
-0.72199999999999998	-3.3147E-5
-0.72299999999999998	-3.3317E-5
-0.72399999999999998	-3.3343999999999998E-5
-0.72499999999999998	-3.3300000000000003E-5
-0.72599999999999998	-3.3246E-5
-0.72699999999999998	-3.3317E-5
-0.72799999999999998	-3.3308E-5
-0.72899999999999998	-3.3325999999999999E-5
-0.73	-3.3325999999999999E-5
-0.73099999999999998	-3.3352999999999997E-5
-0.73199999999999998	-3.3343999999999998E-5
-0.73299999999999998	-3.3352999999999997E-5
-0.73399999999999999	-3.3361999999999997E-5
-0.73499999999999999	-3.3407E-5
-0.73599999999999999	-3.3281999999999997E-5
-0.73699999999999999	-3.3416E-5
-0.73799999999999999	-3.3451999999999998E-5
-0.73899999999999999	-3.3407E-5
-0.74	-3.3504999999999999E-5
-0.74099999999999999	-3.3612999999999998E-5
-0.74199999999999999	-3.3522999999999997E-5
-0.74299999999999999	-3.3568000000000001E-5
-0.74399999999999999	-3.3522999999999997E-5
-0.745	-3.3586E-5
-0.746	-3.3612999999999998E-5
-0.747	-3.3683999999999998E-5
-0.748	-3.3630000000000002E-5
-0.749	-3.3531999999999997E-5
-0.75	-3.3612999999999998E-5
-0.751	-3.3674999999999999E-5
-0.752	-3.3701999999999997E-5
-0.753	-3.3729000000000002E-5
-0.754	-3.3756E-5
-0.755	-3.3764999999999999E-5
-0.75600000000000001	-3.3747000000000001E-5
-0.75700000000000001	-3.3800000000000002E-5
-0.75800000000000001	-3.3844999999999999E-5
-0.75900000000000001	-3.3844999999999999E-5
-0.76	-3.3961000000000002E-5
-0.76100000000000001	-3.3890000000000002E-5
-0.76200000000000001	-3.3862999999999997E-5
-0.76300000000000001	-3.3917000000000001E-5
-0.76400000000000001	-3.3899000000000002E-5
-0.76500000000000001	-3.3862999999999997E-5
-0.76600000000000001	-3.3979000000000001E-5
-0.76700000000000002	-3.4014999999999999E-5
-0.76800000000000002	-3.4005999999999999E-5
-0.76900000000000002	-3.4096E-5
-0.77	-3.4041999999999997E-5
-0.77100000000000002	-3.4060000000000003E-5
-0.77200000000000002	-3.4041999999999997E-5
-0.77300000000000002	-3.4060000000000003E-5
-0.77400000000000002	-3.4122000000000003E-5
-0.77500000000000002	-3.4239000000000002E-5
-0.77600000000000002	-3.4239000000000002E-5
-0.77700000000000002	-3.4140000000000002E-5
-0.77800000000000002	-3.4087000000000001E-5
-0.77900000000000003	-3.4221000000000003E-5
-0.78	-3.4221000000000003E-5
-0.78100000000000003	-3.4221000000000003E-5
-0.78200000000000003	-3.4282999999999997E-5
-0.78300000000000003	-3.4266E-5
-0.78400000000000003	-3.4221000000000003E-5
-0.78500000000000003	-3.4301000000000002E-5
-0.78600000000000003	-3.4310000000000002E-5
-0.78700000000000003	-3.4230000000000003E-5
-0.78800000000000003	-3.4230000000000003E-5
-0.78900000000000003	-3.4363999999999998E-5
-0.79	-3.4354999999999999E-5
-0.79100000000000004	-3.4363999999999998E-5
-0.79200000000000004	-3.4443999999999998E-5
-0.79300000000000004	-3.4427000000000001E-5
-0.79400000000000004	-3.4400000000000003E-5
-0.79500000000000004	-3.4427000000000001E-5
-0.79600000000000004	-3.4434999999999998E-5
-0.79700000000000004	-3.4524999999999999E-5
-0.79800000000000004	-3.4489000000000001E-5
-0.79900000000000004	-3.4507E-5
-0.8	-3.4391000000000003E-5
-0.80100000000000005	-3.4471000000000003E-5
-0.80200000000000005	-3.4551999999999997E-5
-0.80300000000000005	-3.4489000000000001E-5
-0.80400000000000005	-3.4570000000000003E-5
-0.80500000000000005	-3.4570000000000003E-5
-0.80600000000000005	-3.4586999999999999E-5
-0.80700000000000005	-3.4677E-5
-0.80800000000000005	-3.4668000000000001E-5
-0.80900000000000005	-3.4604999999999998E-5
-0.81	-3.4604999999999998E-5
-0.81100000000000005	-3.4694999999999999E-5
-0.81200000000000006	-3.4694999999999999E-5
-0.81299999999999994	-3.4659000000000001E-5
-0.81399999999999995	-3.4730999999999997E-5
-0.81499999999999995	-3.4756999999999999E-5
-0.81599999999999995	-3.4740000000000003E-5
-0.81699999999999995	-3.4756999999999999E-5
-0.81799999999999995	-3.4792999999999997E-5
-0.81899999999999995	-3.4802000000000003E-5
-0.82	-3.4730999999999997E-5
-0.82099999999999995	-3.4847E-5
-0.82199999999999995	-3.4802000000000003E-5
-0.82299999999999995	-3.4811000000000003E-5
-0.82399999999999995	-3.4847E-5
-0.82499999999999996	-3.4953999999999998E-5
-0.82599999999999996	-3.5070000000000001E-5
-0.82699999999999996	-3.5008000000000001E-5
-0.82799999999999996	-3.4962999999999997E-5
-0.82899999999999996	-3.4900999999999997E-5
-0.83	-3.4918E-5
-0.83099999999999996	-3.4944999999999998E-5
-0.83199999999999996	-3.4990000000000002E-5
-0.83299999999999996	-3.4962999999999997E-5
-0.83399999999999996	-3.4972000000000003E-5
-0.83499999999999996	-3.5017E-5
-0.83599999999999997	-3.4972000000000003E-5
-0.83699999999999997	-3.5017E-5
-0.83799999999999997	-3.4935999999999999E-5
-0.83899999999999997	-3.5008000000000001E-5
-0.84	-3.5097E-5
-0.84099999999999997	-3.5061999999999997E-5
-0.84199999999999997	-3.4990000000000002E-5
-0.84299999999999997	-3.5017E-5
-0.84399999999999997	-3.5088E-5
-0.84499999999999997	-3.5097E-5
-0.84599999999999997	-3.5123999999999998E-5
-0.84699999999999998	-3.5132999999999997E-5
-0.84799999999999998	-3.5114999999999998E-5
-0.84899999999999998	-3.5187E-5
-0.85	-3.5196E-5
-0.85099999999999998	-3.5026E-5
-0.85199999999999998	-3.5079000000000001E-5
-0.85299999999999998	-3.5196E-5
-0.85399999999999998	-3.5178000000000001E-5
-0.85499999999999998	-3.5187E-5
-0.85599999999999998	-3.5204999999999999E-5
-0.85699999999999998	-3.5196E-5
-0.85799999999999998	-3.5249000000000001E-5
-0.85899999999999999	-3.5222999999999998E-5
-0.86	-3.5267E-5
-0.86099999999999999	-3.5231000000000002E-5
-0.86199999999999999	-3.5330000000000002E-5
-0.86299999999999999	-3.5302999999999997E-5
-0.86399999999999999	-3.5178000000000001E-5
-0.86499999999999999	-3.5249000000000001E-5
-0.86599999999999999	-3.5284999999999998E-5
-0.86699999999999999	-3.5284999999999998E-5
-0.86799999999999999	-3.5366E-5
-0.86899999999999999	-3.5401000000000002E-5
-0.87	-3.5321000000000003E-5
-0.871	-3.5348000000000001E-5
-0.872	-3.5374999999999999E-5
-0.873	-3.5348000000000001E-5
-0.874	-3.5321000000000003E-5
-0.875	-3.5383999999999999E-5
-0.876	-3.5383999999999999E-5
-0.877	-3.5419000000000001E-5
-0.878	-3.5419000000000001E-5
-0.879	-3.5401000000000002E-5
-0.88	-3.5383999999999999E-5
-0.88100000000000001	-3.5428E-5
-0.88200000000000001	-3.5500000000000002E-5
-0.88300000000000001	-3.5472999999999997E-5
-0.88400000000000001	-3.5437E-5
-0.88500000000000001	-3.5481999999999997E-5
-0.88600000000000001	-3.5481999999999997E-5
-0.88700000000000001	-3.5491000000000003E-5
-0.88800000000000001	-3.5500000000000002E-5
-0.88900000000000001	-3.5410000000000001E-5
-0.89	-3.5428E-5
-0.89100000000000001	-3.5481999999999997E-5
-0.89200000000000002	-3.5536E-5
-0.89300000000000002	-3.5463999999999998E-5
-0.89400000000000002	-3.5500000000000002E-5
-0.89500000000000002	-3.5527000000000001E-5
-0.89600000000000002	-3.5509000000000002E-5
-0.89700000000000002	-3.5553000000000003E-5
-0.89800000000000002	-3.5553000000000003E-5
-0.89900000000000002	-3.5509000000000002E-5
-0.9	-3.5598E-5
-0.90100000000000002	-3.5553000000000003E-5
-0.90200000000000002	-3.5500000000000002E-5
-0.90300000000000002	-3.5491000000000003E-5
-0.90400000000000003	-3.5562000000000003E-5
-0.90500000000000003	-3.5589000000000001E-5
-0.90600000000000003	-3.5607E-5
-0.90700000000000003	-3.5615999999999999E-5
-0.90800000000000003	-3.5679000000000002E-5
-0.90900000000000003	-3.5661000000000003E-5
-0.91	-3.5642999999999997E-5
-0.91100000000000003	-3.5642999999999997E-5
-0.91200000000000003	-3.5624999999999999E-5
-0.91300000000000003	-3.5679000000000002E-5
-0.91400000000000003	-3.5741000000000002E-5
-0.91500000000000004	-3.5553000000000003E-5
-0.91600000000000004	-3.5598E-5
-0.91700000000000004	-3.5688000000000001E-5
-0.91800000000000004	-3.5688000000000001E-5
-0.91900000000000004	-3.5651999999999997E-5
-0.92	-3.5759000000000001E-5
-0.92100000000000004	-3.5713999999999997E-5
-0.92200000000000004	-3.5713999999999997E-5
-0.92300000000000004	-3.5697000000000001E-5
-0.92400000000000004	-3.5768E-5
-0.92500000000000004	-3.5759000000000001E-5
-0.92600000000000005	-3.5713999999999997E-5
-0.92700000000000005	-3.5777E-5
-0.92800000000000005	-3.5982999999999998E-5
-0.92900000000000005	-3.5955999999999999E-5
-0.93	-3.5867000000000001E-5
-0.93100000000000005	-3.5803999999999998E-5
-0.93200000000000005	-3.5794999999999999E-5
-0.93300000000000005	-3.5849000000000002E-5
-0.93400000000000005	-3.5840000000000002E-5
-0.93500000000000005	-3.5867000000000001E-5
-0.93600000000000005	-3.5867000000000001E-5
-0.93700000000000006	-3.5821999999999997E-5
-0.93799999999999994	-3.5777E-5
-0.93899999999999995	-3.5785999999999999E-5
-0.94	-3.5849000000000002E-5
-0.94099999999999995	-3.5803999999999998E-5
-0.94199999999999995	-3.5902000000000003E-5
-0.94299999999999995	-3.5883999999999997E-5
-0.94399999999999995	-3.5741000000000002E-5
-0.94499999999999995	-3.5812999999999997E-5
-0.94599999999999995	-3.5911000000000002E-5
-0.94699999999999995	-3.5858000000000001E-5
-0.94799999999999995	-3.5883999999999997E-5
-0.94899999999999995	-3.5938E-5
-0.95	-3.5902000000000003E-5
-0.95099999999999996	-3.5867000000000001E-5
-0.95199999999999996	-3.5892999999999997E-5
-0.95299999999999996	-3.5902000000000003E-5
-0.95399999999999996	-3.5858000000000001E-5
-0.95499999999999996	-3.5911000000000002E-5
-0.95599999999999996	-3.5955999999999999E-5
-0.95699999999999996	-3.5883999999999997E-5
-0.95799999999999996	-3.5911000000000002E-5
-0.95899999999999996	-3.5973999999999998E-5
-0.96	-3.5973999999999998E-5
-0.96099999999999997	-3.5982999999999998E-5
-0.96199999999999997	-3.6044999999999998E-5
-0.96299999999999997	-3.5938E-5
-0.96399999999999997	-3.5947E-5
-0.96499999999999997	-3.5964999999999999E-5
-0.96599999999999997	-3.5955999999999999E-5
-0.96699999999999997	-3.5911000000000002E-5
-0.96799999999999997	-3.5973999999999998E-5
-0.96899999999999997	-3.5964999999999999E-5
-0.97	-3.6001000000000003E-5
-0.97099999999999997	-3.6125999999999999E-5
-0.97199999999999998	-3.6134999999999999E-5
-0.97299999999999998	-3.5973999999999998E-5
-0.97399999999999998	-3.6081000000000002E-5
-0.97499999999999998	-3.6152999999999998E-5
-0.97599999999999998	-3.6035999999999999E-5
-0.97699999999999998	-3.6072000000000003E-5
-0.97799999999999998	-3.6143999999999998E-5
-0.97899999999999998	-3.6180000000000003E-5
-0.98	-3.6125999999999999E-5
-0.98099999999999998	-3.6099000000000001E-5
-0.98199999999999998	-3.6090000000000002E-5
-0.98299999999999998	-3.6099000000000001E-5
-0.98399999999999999	-3.6196999999999999E-5
-0.98499999999999999	-3.6205999999999999E-5
-0.98599999999999999	-3.6196999999999999E-5
-0.98699999999999999	-3.6125999999999999E-5
-0.98799999999999999	-3.6143999999999998E-5
-0.98899999999999999	-3.6081000000000002E-5
-0.99	-3.6180000000000003E-5
-0.99099999999999999	-3.6214999999999998E-5
-0.99199999999999999	-3.6053999999999997E-5
-0.99299999999999999	-3.6161999999999997E-5
-0.99399999999999999	-3.6269000000000001E-5
-0.995	-3.6161999999999997E-5
-0.996	-3.6205999999999999E-5
-0.997	-3.6223999999999997E-5
-0.998	-3.6189000000000002E-5
-0.999	-3.6232999999999997E-5
-1	-3.6242000000000003E-5
-1.0009999999999999	-3.6196999999999999E-5
-1.002	-3.6260000000000002E-5
-1.0029999999999999	-3.6287E-5
-1.004	-3.6242000000000003E-5
-1.0049999999999999	-3.6180000000000003E-5
-1.006	-3.6269000000000001E-5
-1.0069999999999999	-3.6304999999999999E-5
-1.008	-3.6242000000000003E-5
-1.0089999999999999	-3.6251000000000002E-5
-1.01	-3.6304999999999999E-5
-1.0109999999999999	-3.6304999999999999E-5
-1.012	-3.6350000000000003E-5
-1.0129999999999999	-3.6421000000000002E-5
-1.014	-3.6313999999999998E-5
-1.0149999999999999	-3.6313999999999998E-5
-1.016	-3.6412000000000003E-5
-1.0169999999999999	-3.6322999999999998E-5
-1.018	-3.6322999999999998E-5
-1.0189999999999999	-3.6384999999999998E-5
-1.02	-3.6393999999999997E-5
-1.0209999999999999	-3.6393999999999997E-5
-1.022	-3.6412000000000003E-5
-1.0229999999999999	-3.6448000000000001E-5
-1.024	-3.6448000000000001E-5
-1.0249999999999999	-3.6474999999999999E-5
-1.026	-3.6421000000000002E-5
-1.0269999999999999	-3.6384999999999998E-5
-1.028	-3.6430000000000002E-5
-1.0289999999999999	-3.6448000000000001E-5
-1.03	-3.6698E-5
-1.0309999999999999	-3.6724999999999998E-5
-1.032	-3.6644999999999999E-5
-1.0329999999999999	-3.6563999999999998E-5
-1.034	-3.6501999999999997E-5
-1.0349999999999999	-3.6536999999999999E-5
-1.036	-3.6536999999999999E-5
-1.0369999999999999	-3.6519000000000001E-5
-1.038	-3.6572999999999997E-5
-1.0389999999999999	-3.6582000000000003E-5
-1.04	-3.6511000000000003E-5
-1.0409999999999999	-3.6591000000000003E-5
-1.042	-3.6733999999999998E-5
-1.0429999999999999	-3.6545999999999999E-5
-1.044	-3.6591000000000003E-5
-1.0449999999999999	-3.6653999999999998E-5
-1.046	-3.6644999999999999E-5
-1.0469999999999999	-3.6591000000000003E-5
-1.048	-3.6644999999999999E-5
-1.0489999999999999	-3.6671999999999997E-5
-1.05	-3.6698E-5
-1.0509999999999999	-3.6680000000000001E-5
-1.052	-3.6698E-5
-1.0529999999999999	-3.6636E-5
-1.054	-3.6733999999999998E-5
-1.0549999999999999	-3.6779000000000001E-5
-1.056	-3.6671999999999997E-5
-1.0569999999999999	-3.6733999999999998E-5
-1.0580000000000001	-3.6752000000000003E-5
-1.0589999999999999	-3.6698E-5
-1.06	-3.6742999999999997E-5
-1.0609999999999999	-3.6876999999999999E-5
-1.0620000000000001	-3.6850000000000001E-5
-1.0629999999999999	-3.6806E-5
-1.0640000000000001	-3.6797E-5
-1.0649999999999999	-3.6850000000000001E-5
-1.0660000000000001	-3.6806E-5
-1.0669999999999999	-3.6922000000000003E-5
-1.0680000000000001	-3.6832999999999998E-5
-1.069	-3.6797E-5
-1.07	-3.6912999999999997E-5
-1.071	-3.6958000000000001E-5
-1.0720000000000001	-3.6931000000000003E-5
-1.073	-3.6949000000000001E-5
-1.0740000000000001	-3.6967E-5
-1.075	-3.6958000000000001E-5
-1.0760000000000001	-3.6993999999999999E-5
-1.077	-3.7055999999999999E-5
-1.0780000000000001	-3.6967E-5
-1.079	-3.7011000000000002E-5
-1.08	-3.7055999999999999E-5
-1.081	-3.7101000000000003E-5
-1.0820000000000001	-3.7064999999999998E-5
-1.083	-3.7029000000000001E-5
-1.0840000000000001	-3.7082999999999997E-5
-1.085	-3.7101000000000003E-5
-1.0860000000000001	-3.7137E-5
-1.087	-3.7146E-5
-1.0880000000000001	-3.7128000000000001E-5
-1.089	-3.7208E-5
-1.0900000000000001	-3.7217E-5
-1.091	-3.7217E-5
-1.0920000000000001	-3.7280000000000002E-5
-1.093	-3.7234999999999998E-5
-1.0940000000000001	-3.7154999999999999E-5
-1.095	-3.7199000000000001E-5
-1.0960000000000001	-3.7333000000000003E-5
-1.097	-3.7298000000000001E-5
-1.0980000000000001	-3.7307E-5
-1.099	-3.7342000000000003E-5
-1.1000000000000001	-3.7271000000000003E-5
-1.101	-3.7369000000000001E-5
-1.1020000000000001	-3.7404999999999998E-5
-1.103	-3.7450000000000002E-5
-1.1040000000000001	-3.7387E-5
-1.105	-3.7378E-5
-1.1060000000000001	-3.7431999999999997E-5
-1.107	-3.7342000000000003E-5
-1.1080000000000001	-3.7475999999999998E-5
-1.109	-3.7512000000000003E-5
-1.1100000000000001	-3.7431999999999997E-5
-1.111	-3.7484999999999998E-5
-1.1120000000000001	-3.7557E-5
-1.113	-3.7601999999999997E-5
-1.1140000000000001	-3.7601999999999997E-5
-1.115	-3.7629000000000002E-5
-1.1160000000000001	-3.7557E-5
-1.117	-3.7548E-5
-1.1180000000000001	-3.7663999999999997E-5
-1.119	-3.7691000000000002E-5
-1.1200000000000001	-3.7629000000000002E-5
-1.121	-3.7636999999999999E-5
-1.1220000000000001	-3.7744999999999999E-5
-1.123	-3.7735999999999999E-5
-1.1240000000000001	-3.7798E-5
-1.125	-3.7790000000000002E-5
-1.1259999999999999	-3.7815999999999998E-5
-1.127	-3.7879000000000001E-5
-1.1279999999999999	-3.7951000000000003E-5
-1.129	-3.7923999999999998E-5
-1.1299999999999999	-3.7941999999999997E-5
-1.131	-3.7897E-5
-1.1319999999999999	-3.8003999999999997E-5
-1.133	-3.8281000000000002E-5
-1.1339999999999999	-3.8111999999999997E-5
-1.135	-3.8102999999999998E-5
-1.1359999999999999	-3.8003999999999997E-5
-1.137	-3.8022000000000003E-5
-1.1379999999999999	-3.8146999999999999E-5
-1.139	-3.8138E-5
-1.1399999999999999	-3.8129E-5
-1.141	-3.8146999999999999E-5
-1.1419999999999999	-3.8173999999999997E-5
-1.143	-3.8210000000000002E-5
-1.1439999999999999	-3.8325999999999999E-5
-1.145	-3.8263999999999998E-5
-1.1459999999999999	-3.8146999999999999E-5
-1.147	-3.8308E-5
-1.1479999999999999	-3.8316999999999999E-5
-1.149	-3.8299E-5
-1.1499999999999999	-3.8380000000000002E-5
-1.151	-3.8433999999999998E-5
-1.1519999999999999	-3.8433999999999998E-5
-1.153	-3.8478E-5
-1.1539999999999999	-3.8550000000000002E-5
-1.155	-3.8559000000000001E-5
-1.1559999999999999	-3.8532000000000003E-5
-1.157	-3.8559000000000001E-5
-1.1579999999999999	-3.8541000000000003E-5
-1.159	-3.8577E-5
-1.1599999999999999	-3.8630000000000001E-5
-1.161	-3.8683999999999998E-5
-1.1619999999999999	-3.8738000000000001E-5
-1.163	-3.8791000000000002E-5
-1.1639999999999999	-3.8756E-5
-1.165	-3.8763999999999997E-5
-1.1659999999999999	-3.8853999999999998E-5
-1.167	-3.8917E-5
-1.1679999999999999	-3.8924999999999997E-5
-1.169	-3.8996999999999999E-5
-1.17	-3.8943000000000003E-5
-1.171	-3.8961000000000002E-5
-1.1719999999999999	-3.8970000000000001E-5
-1.173	-3.9078000000000001E-5
-1.1739999999999999	-3.9094999999999998E-5
-1.175	-3.9131000000000002E-5
-1.1759999999999999	-3.9212000000000003E-5
-1.177	-3.9212000000000003E-5
-1.1779999999999999	-3.9239000000000002E-5
-1.179	-3.9292000000000003E-5
-1.18	-3.9381999999999997E-5
-1.181	-3.9363999999999998E-5
-1.1819999999999999	-3.9381999999999997E-5
-1.1830000000000001	-3.9443999999999997E-5
-1.1839999999999999	-3.9507E-5
-1.1850000000000001	-3.9613999999999997E-5
-1.1859999999999999	-3.9677E-5
-1.1870000000000001	-3.9586999999999999E-5
-1.1879999999999999	-3.9641000000000002E-5
-1.1890000000000001	-3.9659000000000001E-5
-1.19	-3.9739E-5
-1.1910000000000001	-3.9774999999999998E-5
-1.1919999999999999	-3.9739E-5
-1.1930000000000001	-3.9765999999999998E-5
-1.194	-3.9855999999999999E-5
-1.1950000000000001	-3.9972000000000003E-5
-1.196	-3.9953999999999997E-5
-1.1970000000000001	-3.9926999999999999E-5
-1.198	-4.0017E-5
-1.1990000000000001	-4.0114999999999998E-5
-1.2	-4.0061000000000002E-5
-1.2010000000000001	-4.0187E-5
-1.202	-4.0231000000000002E-5
-1.2030000000000001	-4.0240000000000001E-5
-1.204	-4.0373999999999997E-5
-1.2050000000000001	-4.0373999999999997E-5
-1.206	-4.0330000000000002E-5
-1.2070000000000001	-4.0428E-5
-1.208	-4.0615999999999999E-5
-1.2090000000000001	-4.0615999999999999E-5
-1.21	-4.0543999999999997E-5
-1.2110000000000001	-4.0633999999999998E-5
-1.212	-4.0615999999999999E-5
-1.2130000000000001	-4.0661000000000003E-5
-1.214	-4.0750000000000001E-5
-1.2150000000000001	-4.0883999999999997E-5
-1.216	-4.0929000000000001E-5
-1.2170000000000001	-4.0982999999999997E-5
-1.218	-4.1063000000000003E-5
-1.2190000000000001	-4.1026999999999999E-5
-1.22	-4.1152999999999997E-5
-1.2210000000000001	-4.1143999999999998E-5
-1.222	-4.1179E-5
-1.2230000000000001	-4.1242000000000003E-5
-1.224	-4.1340000000000001E-5
-1.2250000000000001	-4.1393999999999997E-5
-1.226	-4.1492000000000002E-5
-1.2270000000000001	-4.1554999999999998E-5
-1.228	-4.1653000000000003E-5
-1.2290000000000001	-4.1689E-5
-1.23	-4.1779000000000001E-5
-1.2310000000000001	-4.1814000000000003E-5
-1.232	-4.1779000000000001E-5
-1.2330000000000001	-4.1814000000000003E-5
-1.234	-4.1993000000000003E-5
-1.2350000000000001	-4.2314999999999997E-5
-1.236	-4.2333000000000003E-5
-1.2370000000000001	-4.2262000000000003E-5
-1.238	-4.2216999999999999E-5
-1.2390000000000001	-4.2289000000000001E-5
-1.24	-4.2386999999999999E-5
-1.2410000000000001	-4.2475999999999998E-5
-1.242	-4.2574999999999998E-5
-1.2430000000000001	-4.2718E-5
-1.244	-4.2726999999999999E-5
-1.2450000000000001	-4.2735999999999999E-5
-1.246	-4.2789E-5
-1.2470000000000001	-4.2896999999999999E-5
-1.248	-4.2870000000000001E-5
-1.2490000000000001	-4.3058E-5
-1.25	-4.3219000000000001E-5
-1.2509999999999999	-4.3173999999999997E-5
-1.252	-4.3281000000000001E-5
-1.2529999999999999	-4.3380000000000001E-5
-1.254	-4.3486999999999999E-5
-1.2549999999999999	-4.3603000000000002E-5
-1.256	-4.3594000000000003E-5
-1.2569999999999999	-4.3630000000000001E-5
-1.258	-4.3736999999999998E-5
-1.2589999999999999	-4.3897999999999999E-5
-1.26	-4.3943000000000003E-5
-1.2609999999999999	-4.3897999999999999E-5
-1.262	-4.4104000000000003E-5
-1.2629999999999999	-4.4255999999999998E-5
-1.264	-4.4264999999999997E-5
-1.2649999999999999	-4.4416999999999998E-5
-1.266	-4.4577999999999999E-5
-1.2669999999999999	-4.4613999999999997E-5
-1.268	-4.4685999999999999E-5
-1.2689999999999999	-4.4838E-5
-1.27	-4.4864000000000003E-5
-1.2709999999999999	-4.4935999999999998E-5
-1.272	-4.5034000000000003E-5
-1.2729999999999999	-4.5151000000000002E-5
-1.274	-4.5169000000000001E-5
-1.2749999999999999	-4.5436999999999999E-5
-1.276	-4.5534999999999997E-5
-1.2769999999999999	-4.5534999999999997E-5
-1.278	-4.5723000000000003E-5
-1.2789999999999999	-4.5838999999999999E-5
-1.28	-4.5964999999999998E-5
-1.2809999999999999	-4.6090000000000001E-5
-1.282	-4.6187999999999999E-5
-1.2829999999999999	-4.6286999999999999E-5
-1.284	-4.6421000000000002E-5
-1.2849999999999999	-4.6519E-5
-1.286	-4.6609E-5
-1.2869999999999999	-4.6689E-5
-1.288	-4.685E-5
-1.2889999999999999	-4.7011000000000001E-5
-1.29	-4.7181000000000001E-5
-1.2909999999999999	-4.7296999999999998E-5
-1.292	-4.7377999999999999E-5
-1.2929999999999999	-4.7503000000000002E-5
-1.294	-4.7627999999999999E-5
-1.2949999999999999	-4.778E-5
-1.296	-4.7896999999999999E-5
-1.2969999999999999	-4.8040000000000001E-5
-1.298	-4.8192000000000002E-5
-1.2989999999999999	-4.8254000000000003E-5
-1.3	-4.8451000000000001E-5
-1.3009999999999999	-4.8585000000000003E-5
-1.302	-4.8603000000000002E-5
-1.3029999999999999	-4.8736999999999998E-5
-1.304	-4.8934000000000003E-5
-1.3049999999999999	-4.9131000000000001E-5
-1.306	-4.9319E-5
-1.3069999999999999	-4.9506999999999999E-5
-1.3080000000000001	-4.9577999999999999E-5
-1.3089999999999999	-4.9703000000000002E-5
-1.31	-4.9873000000000002E-5
-1.3109999999999999	-4.9981000000000001E-5
-1.3120000000000001	-5.0096999999999998E-5
-1.3129999999999999	-5.0355999999999997E-5
-1.3140000000000001	-5.0535000000000003E-5
-1.3149999999999999	-5.0606999999999998E-5
-1.3160000000000001	-5.0741000000000001E-5
-1.3169999999999999	-5.1035999999999997E-5
-1.3180000000000001	-5.1242000000000002E-5
-1.319	-5.1421000000000001E-5
-1.32	-5.1554999999999997E-5
-1.321	-5.1653000000000002E-5
-1.3220000000000001	-5.1805000000000003E-5
-1.323	-5.202E-5
-1.3240000000000001	-5.2243000000000001E-5
-1.325	-5.2351000000000001E-5
-1.3260000000000001	-5.2512000000000001E-5
-1.327	-5.2691000000000001E-5
-1.3280000000000001	-5.2886999999999997E-5
-1.329	-5.3084000000000002E-5
-1.33	-5.3281E-5
-1.331	-5.346E-5
-1.3320000000000001	-5.3621E-5
-1.333	-5.3835999999999998E-5
-1.3340000000000001	-5.4058999999999999E-5
-1.335	-5.4193000000000001E-5
-1.3360000000000001	-5.4453000000000002E-5
-1.337	-5.4775000000000003E-5
-1.3380000000000001	-5.5034000000000002E-5
-1.339	-5.5043000000000001E-5
-1.34	-5.5266999999999998E-5
-1.341	-5.5401E-5
-1.3420000000000001	-5.5642E-5
-1.343	-5.5865999999999997E-5
-1.3440000000000001	-5.6081000000000001E-5
-1.345	-5.6196999999999997E-5
-1.3460000000000001	-5.6375999999999997E-5
-1.347	-5.6518999999999999E-5
-1.3480000000000001	-5.6742E-5
-1.349	-5.7028999999999999E-5
-1.35	-5.7207999999999998E-5
-1.351	-5.7404000000000001E-5
-1.3520000000000001	-5.7627999999999998E-5
-1.353	-5.7797999999999998E-5
-1.3540000000000001	-5.7958999999999999E-5
-1.355	-5.8272E-5
-1.3560000000000001	-5.8513E-5
-1.357	-5.8700999999999999E-5
-1.3580000000000001	-5.8925000000000002E-5
-1.359	-5.9131E-5
-1.36	-5.9246999999999997E-5
-1.361	-5.9462000000000001E-5
-1.3620000000000001	-5.9738999999999998E-5
-1.363	-5.9855000000000002E-5
-1.3640000000000001	-6.0096999999999997E-5
-1.365	-6.0365000000000002E-5
-1.3660000000000001	-6.0535000000000002E-5
-1.367	-6.0776000000000002E-5
-1.3680000000000001	-6.0982E-5
-1.369	-6.1231999999999999E-5
-1.37	-6.1402000000000006E-5
-1.371	-6.1599000000000004E-5
-1.3720000000000001	-6.1884999999999994E-5
-1.373	-6.2028999999999999E-5
-1.3740000000000001	-6.2252E-5
-1.375	-6.2476000000000003E-5
-1.3759999999999999	-6.2582999999999994E-5
-1.377	-6.2932E-5
-1.3779999999999999	-6.3200000000000005E-5
-1.379	-6.3307999999999998E-5
-1.38	-6.3513E-5
-1.381	-6.3719000000000004E-5
-1.3819999999999999	-6.3952E-5
-1.383	-6.4220000000000005E-5
-1.3839999999999999	-6.4308999999999997E-5
-1.385	-6.4533E-5
-1.3859999999999999	-6.4774E-5
-1.387	-6.5052E-5
-1.3879999999999999	-6.5149999999999998E-5
-1.389	-6.5328999999999997E-5
-1.39	-6.5517000000000003E-5
-1.391	-6.5748999999999997E-5
-1.3919999999999999	-6.5937000000000002E-5
-1.393	-6.6161000000000006E-5
-1.3939999999999999	-6.6392999999999999E-5
-1.395	-6.6571999999999999E-5
-1.3959999999999999	-6.6832E-5
-1.397	-6.7002000000000007E-5
-1.3979999999999999	-6.7126999999999996E-5
-1.399	-6.7269999999999998E-5
-1.4	-6.7538000000000003E-5
-1.401	-6.7753E-5
-1.4019999999999999	-6.7931999999999999E-5
-1.403	-6.8120000000000005E-5
-1.4039999999999999	-6.8369999999999998E-5
-1.405	-6.8477000000000002E-5
-1.4059999999999999	-6.8646999999999995E-5
-1.407	-6.8898000000000003E-5
-1.4079999999999999	-6.8978000000000003E-5
-1.409	-6.9202000000000006E-5
-1.41	-6.9363000000000007E-5
-1.411	-6.9497000000000002E-5
-1.4119999999999999	-6.9684999999999994E-5
-1.413	-6.9890999999999999E-5
-1.4139999999999999	-7.0034000000000001E-5
-1.415	-7.0185999999999995E-5
-1.4159999999999999	-7.0390999999999997E-5
-1.417	-7.0551999999999998E-5
-1.4179999999999999	-7.0730999999999998E-5
-1.419	-7.0945999999999995E-5
-1.42	-7.1035E-5
-1.421	-7.1241000000000005E-5
-1.4219999999999999	-7.1365999999999994E-5
-1.423	-7.1526999999999995E-5
-1.4239999999999999	-7.1662000000000006E-5
-1.425	-7.1876000000000001E-5
-1.4259999999999999	-7.1957000000000002E-5
-1.427	-7.1975000000000001E-5
-1.4279999999999999	-7.2162000000000005E-5
-1.429	-7.2349999999999997E-5
-1.43	-7.2484000000000006E-5
-1.431	-7.2653999999999999E-5
-1.4319999999999999	-7.2805999999999994E-5
-1.4330000000000001	-7.2966999999999994E-5
-1.4339999999999999	-7.3102000000000006E-5
-1.4350000000000001	-7.3263000000000007E-5
-1.4359999999999999	-7.3288999999999996E-5
-1.4370000000000001	-7.3316000000000001E-5
-1.4379999999999999	-7.3584999999999994E-5
-1.4390000000000001	-7.3737000000000002E-5
-1.44	-7.3960000000000003E-5
-1.4410000000000001	-7.4041000000000005E-5
-1.4419999999999999	-7.4111999999999998E-5
-1.4430000000000001	-7.4139000000000003E-5
-1.444	-7.4210999999999998E-5
-1.4450000000000001	-7.4326999999999995E-5
-1.446	-7.4443000000000005E-5
-1.4470000000000001	-7.4585999999999994E-5
-1.448	-7.4612999999999999E-5
-1.4490000000000001	-7.4532999999999999E-5
-1.45	-7.4773999999999999E-5
-1.4510000000000001	-7.4881000000000004E-5
-1.452	-7.4970999999999998E-5
-1.4530000000000001	-7.4998000000000003E-5
-1.454	-7.5086999999999994E-5
-1.4550000000000001	-7.5185999999999995E-5
-1.456	-7.5247999999999995E-5
-1.4570000000000001	-7.5292999999999999E-5
-1.458	-7.5364000000000006E-5
-1.4590000000000001	-7.5390999999999997E-5
-1.46	-7.5561000000000004E-5
-1.4610000000000001	-7.5632999999999999E-5
-1.462	-7.5668999999999997E-5
-1.4630000000000001	-7.5766999999999995E-5
-1.464	-7.5740000000000003E-5
-1.4650000000000001	-7.5740000000000003E-5
-1.466	-7.5829999999999997E-5
-1.4670000000000001	-7.5901000000000004E-5
-1.468	-7.5919000000000003E-5
-1.4690000000000001	-7.5982000000000005E-5
-1.47	-7.6052999999999998E-5
-1.4710000000000001	-7.6098000000000002E-5
-1.472	-7.6080000000000003E-5
-1.4730000000000001	-7.6143000000000006E-5
-1.474	-7.6249999999999997E-5
-1.4750000000000001	-7.6205000000000006E-5
-1.476	-7.6223000000000005E-5
-1.4770000000000001	-7.6304000000000007E-5
-1.478	-7.6329999999999996E-5
-1.4790000000000001	-7.6321000000000003E-5
-1.48	-7.6329999999999996E-5
-1.4810000000000001	-7.6375E-5
-1.482	-7.6420000000000004E-5
-1.4830000000000001	-7.6508999999999995E-5
-1.484	-7.6490999999999997E-5
-1.4850000000000001	-7.6536E-5
-1.486	-7.6490999999999997E-5
-1.4870000000000001	-7.6536E-5
-1.488	-7.6490999999999997E-5
-1.4890000000000001	-7.6581000000000004E-5
-1.49	-7.6617000000000002E-5
-1.4910000000000001	-7.6607999999999996E-5
-1.492	-7.6617000000000002E-5
-1.4930000000000001	-7.6669999999999996E-5
-1.494	-7.6625999999999994E-5
-1.4950000000000001	-7.6599000000000003E-5
-1.496	-7.6715E-5
-1.4970000000000001	-7.6715E-5
-1.498	-7.6697000000000001E-5
-1.4990000000000001	-7.6643000000000005E-5
-1.5	-7.6705999999999994E-5
-1.5009999999999999	-7.6661000000000003E-5
-1.502	-7.6705999999999994E-5
-1.5029999999999999	-7.6760000000000004E-5
-1.504	-7.6661000000000003E-5
-1.5049999999999999	-7.6679000000000002E-5
-1.506	-7.6724000000000006E-5
-1.5069999999999999	-7.6643000000000005E-5
-1.508	-7.6705999999999994E-5
-1.5089999999999999	-7.6742000000000005E-5
-1.51	-7.6812999999999998E-5
-1.5109999999999999	-7.6858000000000002E-5
-1.512	-7.6830999999999997E-5
-1.5129999999999999	-7.6760000000000004E-5
-1.514	-7.6715E-5
-1.5149999999999999	-7.6804000000000005E-5
-1.516	-7.6732999999999999E-5
-1.5169999999999999	-7.6715E-5
-1.518	-7.6732999999999999E-5
-1.5189999999999999	-7.6876000000000001E-5
-1.52	-7.6768999999999996E-5
-1.5209999999999999	-7.6742000000000005E-5
-1.522	-7.6750999999999998E-5
-1.5229999999999999	-7.6742000000000005E-5
-1.524	-7.6812999999999998E-5
-1.5249999999999999	-7.6840000000000003E-5
-1.526	-7.6778000000000002E-5
-1.5269999999999999	-7.6804000000000005E-5
-1.528	-7.6893999999999999E-5
-1.5289999999999999	-7.6866999999999994E-5
-1.53	-7.6732999999999999E-5
-1.5309999999999999	-7.6822000000000004E-5
-1.532	-7.6866999999999994E-5
-1.5329999999999999	-7.6812999999999998E-5
-1.534	-7.6858000000000002E-5
-1.5349999999999999	-7.6893999999999999E-5
-1.536	-7.6929999999999997E-5
-1.5369999999999999	-7.6921000000000004E-5
-1.538	-7.6911999999999998E-5
-1.5389999999999999	-7.6957000000000002E-5
-1.54	-7.6929999999999997E-5
-1.5409999999999999	-7.7045999999999994E-5
-1.542	-7.7224999999999993E-5
-1.5429999999999999	-7.7206999999999994E-5
-1.544	-7.7162000000000004E-5
-1.5449999999999999	-7.7045999999999994E-5
-1.546	-7.7055E-5
-1.5469999999999999	-7.7126000000000007E-5
-1.548	-7.7134999999999999E-5
-1.5489999999999999	-7.7134999999999999E-5
-1.55	-7.7216000000000001E-5
-1.5509999999999999	-7.7233999999999999E-5
-1.552	-7.7243000000000006E-5
-1.5529999999999999	-7.7233999999999999E-5
-1.554	-7.7188999999999996E-5
-1.5549999999999999	-7.7162000000000004E-5
-1.556	-7.7296E-5
-1.5569999999999999	-7.7349999999999996E-5
-1.5580000000000001	-7.7331999999999998E-5
-1.5589999999999999	-7.7341000000000004E-5
-1.56	-7.7447999999999994E-5
-1.5609999999999999	-7.7502000000000004E-5
-1.5620000000000001	-7.7484000000000006E-5
-1.5629999999999999	-7.7538000000000002E-5
-1.5640000000000001	-7.7608999999999995E-5
-1.5649999999999999	-7.7591999999999998E-5
-1.5660000000000001	-7.7707999999999995E-5
-1.5669999999999999	-7.7681000000000004E-5
-1.5680000000000001	-7.7583000000000006E-5
-1.569	-7.7707999999999995E-5
-1.57	-7.7797000000000001E-5
-1.571	-7.7815E-5
-1.5720000000000001	-7.7904999999999994E-5
-1.573	-7.7985000000000006E-5
-1.5740000000000001	-7.8003000000000005E-5
-1.575	-7.8057000000000002E-5
-1.5760000000000001	-7.8137000000000001E-5
-1.577	-7.8137000000000001E-5
-1.5780000000000001	-7.8236000000000001E-5
-1.579	-7.8361000000000004E-5
-1.58	-7.8361000000000004E-5
-1.581	-7.8333999999999999E-5
-1.5820000000000001	-7.8423000000000005E-5
-1.583	-7.8558000000000002E-5
-1.5840000000000001	-7.8610999999999997E-5
-1.585	-7.8646999999999994E-5
-1.5860000000000001	-7.8753999999999998E-5
-1.587	-7.8789999999999996E-5
-1.5880000000000001	-7.8942000000000004E-5
-1.589	-7.9048999999999995E-5
-1.59	-7.9013999999999999E-5
-1.591	-7.9041000000000004E-5
-1.5920000000000001	-7.9121000000000004E-5
-1.593	-7.9318000000000002E-5
-1.5940000000000001	-7.9461000000000004E-5
-1.595	-7.9469999999999996E-5
-1.5960000000000001	-7.9541000000000003E-5
-1.597	-7.9594999999999999E-5
-1.5980000000000001	-7.9710999999999996E-5
-1.599	-7.9819000000000003E-5
-1.6	-7.9837000000000001E-5
-1.601	-7.9899000000000002E-5
-1.6020000000000001	-8.0123000000000005E-5
-1.603	-8.0141000000000004E-5
-1.6040000000000001	-8.0185000000000006E-5
-1.605	-8.0247999999999995E-5
-1.6060000000000001	-8.0320000000000003E-5
-1.607	-8.0489999999999997E-5
-1.6080000000000001	-8.0632999999999999E-5
-1.609	-8.0649999999999995E-5
-1.61	-8.0712999999999998E-5
-1.611	-8.0909999999999996E-5
-1.6120000000000001	-8.0981000000000003E-5
-1.613	-8.1080000000000003E-5
-1.6140000000000001	-8.1205000000000006E-5
-1.615	-8.1366000000000007E-5
-1.6160000000000001	-8.1366000000000007E-5
-1.617	-8.1526999999999994E-5
-1.6180000000000001	-8.1651999999999997E-5
-1.619	-8.1633999999999998E-5
-1.62	-8.1786000000000006E-5
-1.621	-8.2001000000000003E-5
-1.6220000000000001	-8.2027999999999995E-5
-1.623	-8.2188999999999995E-5
-1.6240000000000001	-8.2323000000000004E-5
-1.625	-8.2377000000000001E-5
-1.6259999999999999	-8.2457E-5
-1.627	-8.2653999999999998E-5
-1.6279999999999999	-8.2779000000000001E-5
-1.629	-8.2896000000000001E-5
-1.63	-8.2966999999999994E-5
-1.631	-8.3109999999999995E-5
-1.6319999999999999	-8.3127999999999994E-5
-1.633	-8.3200000000000003E-5
-1.6339999999999999	-8.3361000000000004E-5
-1.635	-8.3467999999999994E-5
-1.6359999999999999	-8.3665000000000006E-5
-1.637	-8.3817000000000001E-5
-1.6379999999999999	-8.3950999999999996E-5
-1.639	-8.4067000000000007E-5
-1.64	-8.4175E-5
-1.641	-8.4201000000000002E-5
-1.6419999999999999	-8.4380000000000002E-5
-1.643	-8.4586000000000006E-5
-1.6439999999999999	-8.4783000000000005E-5
-1.645	-8.5050999999999996E-5
-1.6459999999999999	-8.5050999999999996E-5
-1.647	-8.5096E-5
-1.6479999999999999	-8.5167000000000006E-5
-1.649	-8.5354999999999998E-5
-1.65	-8.5498E-5
-1.651	-8.5551999999999997E-5
-1.6519999999999999	-8.5659000000000001E-5
-1.653	-8.5847000000000007E-5
-1.6539999999999999	-8.5953999999999997E-5
-1.655	-8.6034999999999999E-5
-1.6559999999999999	-8.6223000000000004E-5
-1.657	-8.6374999999999999E-5
-1.6579999999999999	-8.6402000000000004E-5
-1.659	-8.6625000000000005E-5
-1.66	-8.6776999999999999E-5
-1.661	-8.6786000000000006E-5
-1.6619999999999999	-8.6876E-5
-1.663	-8.7126000000000006E-5
-1.6639999999999999	-8.7216E-5
-1.665	-8.7295999999999999E-5
-1.6659999999999999	-8.7546999999999994E-5
-1.667	-8.7600000000000002E-5
-1.6679999999999999	-8.7725000000000005E-5
-1.669	-8.7850999999999996E-5
-1.67	-8.7850999999999996E-5
-1.671	-8.8038E-5
-1.6719999999999999	-8.8226000000000005E-5
-1.673	-8.8333999999999998E-5
-1.6739999999999999	-8.8441000000000002E-5
-1.675	-8.8566000000000006E-5
-1.6759999999999999	-8.8727000000000006E-5
-1.677	-8.8789999999999995E-5
-1.6779999999999999	-8.8996E-5
-1.679	-8.9165000000000004E-5
-1.68	-8.9165000000000004E-5
-1.681	-8.9362000000000003E-5
-1.6819999999999999	-8.9443000000000004E-5
-1.6830000000000001	-8.9531999999999996E-5
-1.6839999999999999	-8.9710999999999995E-5
-1.6850000000000001	-8.9979E-5
-1.6859999999999999	-8.9979E-5
-1.6870000000000001	-9.0068999999999994E-5
-1.6879999999999999	-9.0336999999999999E-5
-1.6890000000000001	-9.0426999999999993E-5
-1.69	-9.0515999999999999E-5
-1.6910000000000001	-9.0694999999999998E-5
-1.6919999999999999	-9.0784000000000004E-5
-1.6930000000000001	-9.0963000000000003E-5
-1.694	-9.1052999999999997E-5
-1.6950000000000001	-9.1231999999999997E-5
-1.696	-9.1231999999999997E-5
-1.6970000000000001	-9.1500000000000001E-5
-1.698	-9.1588999999999993E-5
-1.6990000000000001	-9.1679000000000001E-5
-1.7	-9.1947000000000006E-5
-1.7010000000000001	-9.2126000000000005E-5
-1.702	-9.2214999999999997E-5
-1.7030000000000001	-9.2305000000000005E-5
-1.704	-9.2484000000000004E-5
-1.7050000000000001	-9.2572999999999996E-5
-1.706	-9.2663000000000004E-5
-1.7070000000000001	-9.2842000000000003E-5
-1.708	-9.3109999999999995E-5
-1.7090000000000001	-9.302E-5
-1.71	-9.3199E-5
-1.7110000000000001	-9.3377999999999999E-5
-1.712	-9.3467999999999993E-5
-1.7130000000000001	-9.3735999999999998E-5
-1.714	-9.3914999999999998E-5
-1.7150000000000001	-9.3914999999999998E-5
-1.716	-9.4093999999999997E-5
-1.7170000000000001	-9.4272999999999997E-5
-1.718	-9.4362000000000002E-5
-1.7190000000000001	-9.4451999999999996E-5
-1.72	-9.4720000000000001E-5
-1.7210000000000001	-9.4809000000000007E-5
-1.722	-9.4899000000000001E-5
-1.7230000000000001	-9.4988000000000006E-5
-1.724	-9.5167000000000005E-5
-1.7250000000000001	-9.5346000000000005E-5
-1.726	-9.5525000000000004E-5
-1.7270000000000001	-9.5704000000000004E-5
-1.728	-9.5792999999999996E-5
-1.7290000000000001	-9.6061000000000001E-5
-1.73	-9.6150999999999995E-5
-1.7310000000000001	-9.6329999999999994E-5
-1.732	-9.6419E-5
-1.7330000000000001	-9.6688000000000007E-5
-1.734	-9.6688000000000007E-5
-1.7350000000000001	-9.6776999999999999E-5
-1.736	-9.7045000000000003E-5
-1.7370000000000001	-9.7134999999999997E-5
-1.738	-9.7313999999999997E-5
-1.7390000000000001	-9.7492999999999996E-5
-1.74	-9.7670999999999994E-5
-1.7410000000000001	-9.7761000000000001E-5
-1.742	-9.8029000000000006E-5
-1.7430000000000001	-9.8208000000000006E-5
-1.744	-9.8208000000000006E-5
-1.7450000000000001	-9.8387000000000005E-5
-1.746	-9.8566000000000005E-5
-1.7470000000000001	-9.9012999999999995E-5
-1.748	-9.9103000000000003E-5
-1.7490000000000001	-9.9191999999999995E-5
-1.75	-9.9281E-5
-1.7509999999999999	-9.9370999999999994E-5
-1.752	-9.9549999999999994E-5
-1.7529999999999999	-9.9638999999999999E-5
-1.754	-9.9817999999999999E-5
-1.7549999999999999	-9.9996999999999998E-5
-1.756	-1.0018000000000001E-4
-1.7569999999999999	-1.0027E-4
-1.758	-1.0043999999999999E-4
-1.7589999999999999	-1.0062E-4
-1.76	-1.0062E-4
-1.7609999999999999	-1.0089E-4
-1.762	-1.0107000000000001E-4
-1.7629999999999999	-1.0116E-4
-1.764	-1.0134E-4
-1.7649999999999999	-1.0152E-4
-1.766	-1.0161E-4
-1.7669999999999999	-1.0179E-4
-1.768	-1.0187999999999999E-4
-1.7689999999999999	-1.0196000000000001E-4
-1.77	-1.0205E-4
-1.7709999999999999	-1.0223E-4
-1.772	-1.0241E-4
-1.7729999999999999	-1.0241E-4
-1.774	-1.0268E-4
-1.7749999999999999	-1.0276999999999999E-4
-1.776	-1.0276999999999999E-4
-1.7769999999999999	-1.0304E-4
-1.778	-1.0313E-4
-1.7789999999999999	-1.0322E-4
-1.78	-1.0340000000000001E-4
-1.7809999999999999	-1.0357E-4
-1.782	-1.0349E-4
-1.7829999999999999	-1.0365999999999999E-4
-1.784	-1.0384E-4
-1.7849999999999999	-1.0384E-4
-1.786	-1.0384E-4
-1.7869999999999999	-1.0402E-4
-1.788	-1.0402E-4
-1.7889999999999999	-1.042E-4
-1.79	-1.0429000000000001E-4
-1.7909999999999999	-1.0438E-4
-1.792	-1.0438E-4
-1.7929999999999999	-1.0456E-4
-1.794	-1.0465E-4
-1.7949999999999999	-1.0465E-4
-1.796	-1.0474E-4
-1.7969999999999999	-1.0474E-4
-1.798	-1.0446999999999999E-4
-1.7989999999999999	-1.0446999999999999E-4
-1.8	-1.0483E-4
-1.8009999999999999	-1.0501E-4
-1.802	-1.0501E-4
-1.8029999999999999	-1.0510000000000001E-4
-1.804	-1.0510000000000001E-4
-1.8049999999999999	-1.0518000000000001E-4
-1.806	-1.0535999999999999E-4
-1.8069999999999999	-1.0535999999999999E-4
-1.8080000000000001	-1.0518000000000001E-4
-1.8089999999999999	-1.0535999999999999E-4
-1.81	-1.0527E-4
-1.8109999999999999	-1.0518000000000001E-4
-1.8120000000000001	-1.0527E-4
-1.8129999999999999	-1.0535999999999999E-4
-1.8140000000000001	-1.0535999999999999E-4
-1.8149999999999999	-1.0535999999999999E-4
-1.8160000000000001	-1.0535999999999999E-4
-1.8169999999999999	-1.0545E-4
-1.8180000000000001	-1.0545E-4
-1.819	-1.0545E-4
-1.82	-1.0545E-4
-1.821	-1.0535999999999999E-4
-1.8220000000000001	-1.0545E-4
-1.823	-1.0545E-4
-1.8240000000000001	-1.0535999999999999E-4
-1.825	-1.0545E-4
-1.8260000000000001	-1.0554E-4
-1.827	-1.0545E-4
-1.8280000000000001	-1.0545E-4
-1.829	-1.0545E-4
-1.83	-1.0535999999999999E-4
-1.831	-1.0535999999999999E-4
-1.8320000000000001	-1.0545E-4
-1.833	-1.0545E-4
-1.8340000000000001	-1.0527E-4
-1.835	-1.0535999999999999E-4
-1.8360000000000001	-1.0545E-4
-1.837	-1.0535999999999999E-4
-1.8380000000000001	-1.0535999999999999E-4
-1.839	-1.0527E-4
-1.84	-1.0527E-4
-1.841	-1.0527E-4
-1.8420000000000001	-1.0518000000000001E-4
-1.843	-1.0518000000000001E-4
-1.8440000000000001	-1.0527E-4
-1.845	-1.0518000000000001E-4
-1.8460000000000001	-1.0510000000000001E-4
-1.847	-1.0518000000000001E-4
-1.8480000000000001	-1.0518000000000001E-4
-1.849	-1.0535999999999999E-4
-1.85	-1.0535999999999999E-4
-1.851	-1.0527E-4
-1.8520000000000001	-1.0518000000000001E-4
-1.853	-1.0501E-4
-1.8540000000000001	-1.0510000000000001E-4
-1.855	-1.0510000000000001E-4
-1.8560000000000001	-1.0501E-4
-1.857	-1.0501E-4
-1.8580000000000001	-1.0501E-4
-1.859	-1.0492000000000001E-4
-1.86	-1.0492000000000001E-4
-1.861	-1.0501E-4
-1.8620000000000001	-1.0483E-4
-1.863	-1.0483E-4
-1.8640000000000001	-1.0501E-4
-1.865	-1.0501E-4
-1.8660000000000001	-1.0483E-4
-1.867	-1.0483E-4
-1.8680000000000001	-1.0492000000000001E-4
-1.869	-1.0492000000000001E-4
-1.87	-1.0492000000000001E-4
-1.871	-1.0483E-4
-1.8720000000000001	-1.0465E-4
-1.873	-1.0474E-4
-1.8740000000000001	-1.0483E-4
-1.875	-1.0474E-4
-1.8759999999999999	-1.0465E-4
-1.877	-1.0474E-4
-1.8779999999999999	-1.0474E-4
-1.879	-1.0465E-4
-1.88	-1.0474E-4
-1.881	-1.0474E-4
-1.8819999999999999	-1.0474E-4
-1.883	-1.0474E-4
-1.8839999999999999	-1.0465E-4
-1.885	-1.0465E-4
-1.8859999999999999	-1.0474E-4
-1.887	-1.0474E-4
-1.8879999999999999	-1.0465E-4
-1.889	-1.0465E-4
-1.89	-1.0474E-4
-1.891	-1.0465E-4
-1.8919999999999999	-1.0474E-4
-1.893	-1.0474E-4
-1.8939999999999999	-1.0474E-4
-1.895	-1.0474E-4
-1.8959999999999999	-1.0474E-4
-1.897	-1.0474E-4
-1.8979999999999999	-1.0474E-4
-1.899	-1.0483E-4
-1.9	-1.0474E-4
-1.901	-1.0474E-4
-1.9019999999999999	-1.0474E-4
-1.903	-1.0483E-4
-1.9039999999999999	-1.0474E-4
-1.905	-1.0483E-4
-1.9059999999999999	-1.0483E-4
-1.907	-1.0492000000000001E-4
-1.9079999999999999	-1.0492000000000001E-4
-1.909	-1.0492000000000001E-4
-1.91	-1.0492000000000001E-4
-1.911	-1.0483E-4
-1.9119999999999999	-1.0492000000000001E-4
-1.913	-1.0501E-4
-1.9139999999999999	-1.0492000000000001E-4
-1.915	-1.0492000000000001E-4
-1.9159999999999999	-1.0501E-4
-1.917	-1.0510000000000001E-4
-1.9179999999999999	-1.0518000000000001E-4
-1.919	-1.0518000000000001E-4
-1.92	-1.0501E-4
-1.921	-1.0510000000000001E-4
-1.9219999999999999	-1.0527E-4
-1.923	-1.0518000000000001E-4
-1.9239999999999999	-1.0518000000000001E-4
-1.925	-1.0518000000000001E-4
-1.9259999999999999	-1.0527E-4
-1.927	-1.0518000000000001E-4
-1.9279999999999999	-1.0535999999999999E-4
-1.929	-1.0535999999999999E-4
-1.93	-1.0535999999999999E-4
-1.931	-1.0554E-4
-1.9319999999999999	-1.0554E-4
-1.9330000000000001	-1.0554E-4
-1.9339999999999999	-1.0554E-4
-1.9350000000000001	-1.0563E-4
-1.9359999999999999	-1.0554E-4
-1.9370000000000001	-1.0572E-4
-1.9379999999999999	-1.0581000000000001E-4
-1.9390000000000001	-1.0563E-4
-1.94	-1.0572E-4
-1.9410000000000001	-1.059E-4
-1.9419999999999999	-1.059E-4
-1.9430000000000001	-1.0599000000000001E-4
-1.944	-1.0599000000000001E-4
-1.9450000000000001	-1.0599000000000001E-4
-1.946	-1.0608E-4
-1.9470000000000001	-1.0616999999999999E-4
-1.948	-1.0635E-4
-1.9490000000000001	-1.0626E-4
-1.95	-1.0626E-4
-1.9510000000000001	-1.0635E-4
-1.952	-1.0662000000000001E-4
-1.9530000000000001	-1.0662000000000001E-4
-1.954	-1.0671E-4
-1.9550000000000001	-1.0653E-4
-1.956	-1.0662000000000001E-4
-1.9570000000000001	-1.0671E-4
-1.958	-1.0671E-4
-1.9590000000000001	-1.0688000000000001E-4
-1.96	-1.0697E-4
-1.9610000000000001	-1.0697E-4
-1.962	-1.0697E-4
-1.9630000000000001	-1.0705999999999999E-4
-1.964	-1.0724E-4
-1.9650000000000001	-1.0705999999999999E-4
-1.966	-1.0724E-4
-1.9670000000000001	-1.0742E-4
-1.968	-1.0742E-4
-1.9690000000000001	-1.0751000000000001E-4
-1.97	-1.0768999999999999E-4
-1.9710000000000001	-1.0768999999999999E-4
-1.972	-1.0768999999999999E-4
-1.9730000000000001	-1.0778E-4
-1.974	-1.0796E-4
-1.9750000000000001	-1.0805E-4
-1.976	-1.0814E-4
-1.9770000000000001	-1.0823E-4
-1.978	-1.0823E-4
-1.9790000000000001	-1.0832000000000001E-4
-1.98	-1.0840000000000001E-4
-1.9810000000000001	-1.0840000000000001E-4
-1.982	-1.0857999999999999E-4
-1.9830000000000001	-1.0867E-4
-1.984	-1.0876E-4
-1.9850000000000001	-1.0885E-4
-1.986	-1.0894E-4
-1.9870000000000001	-1.0903E-4
-1.988	-1.0921000000000001E-4
-1.9890000000000001	-1.093E-4
-1.99	-1.0938999999999999E-4
-1.9910000000000001	-1.0948E-4
-1.992	-1.0957E-4
-1.9930000000000001	-1.0975E-4
-1.994	-1.0975E-4
-1.9950000000000001	-1.0993E-4
-1.996	-1.1010000000000001E-4
-1.9970000000000001	-1.1010000000000001E-4
-1.998	-1.1027999999999999E-4
-1.9990000000000001	-1.1027999999999999E-4
-2	-1.1037E-4
-2.0009999999999999	-1.1055E-4
-2.0019999999999998	-1.1073000000000001E-4
-2.0030000000000001	-1.1090999999999999E-4
-2.004	-1.1109E-4
-2.0049999999999999	-1.1109E-4
-2.0059999999999998	-1.1118E-4
-2.0070000000000001	-1.1127E-4
-2.008	-1.1145E-4
-2.0089999999999999	-1.1162000000000001E-4
-2.0099999999999998	-1.1171E-4
-2.0110000000000001	-1.1179999999999999E-4
-2.012	-1.1198E-4
-2.0129999999999999	-1.1207E-4
-2.0139999999999998	-1.1225E-4
-2.0150000000000001	-1.1234E-4
-2.016	-1.1243000000000001E-4
-2.0169999999999999	-1.1260999999999999E-4
-2.0179999999999998	-1.1297E-4
-2.0190000000000001	-1.1297E-4
-2.02	-1.1315E-4
-2.0209999999999999	-1.1332000000000001E-4
-2.0219999999999998	-1.1349999999999999E-4
-2.0230000000000001	-1.1368E-4
-2.024	-1.1377E-4
-2.0249999999999999	-1.1386E-4
-2.0259999999999998	-1.1404E-4
-2.0270000000000001	-1.1430999999999999E-4
-2.028	-1.144E-4
-2.0289999999999999	-1.1449E-4
-2.0299999999999998	-1.1476000000000001E-4
-2.0310000000000001	-1.1493E-4
-2.032	-1.1502000000000001E-4
-2.0329999999999999	-1.1519999999999999E-4
-2.0339999999999998	-1.1547E-4
-2.0350000000000001	-1.1565000000000001E-4
-2.036	-1.1582999999999999E-4
-2.0369999999999999	-1.1601E-4
-2.0379999999999998	-1.161E-4
-2.0390000000000001	-1.1628E-4
-2.04	-1.1663E-4
-2.0409999999999999	-1.1671999999999999E-4
-2.0419999999999998	-1.1681E-4
-2.0430000000000001	-1.1717E-4
-2.044	-1.1735000000000001E-4
-2.0449999999999999	-1.1752999999999999E-4
-2.0459999999999998	-1.178E-4
-2.0470000000000002	-1.1797E-4
-2.048	-1.1815E-4
-2.0489999999999999	-1.1833E-4
-2.0499999999999998	-1.1851E-4
-2.0510000000000002	-1.1869E-4
-2.052	-1.1896E-4
-2.0529999999999999	-1.1923E-4
-2.0539999999999998	-1.1967E-4
-2.0550000000000002	-1.1993999999999999E-4
-2.056	-1.2003E-4
-2.0569999999999999	-1.2012E-4
-2.0579999999999998	-1.203E-4
-2.0590000000000002	-1.2066E-4
-2.06	-1.2084E-4
-2.0609999999999999	-1.2102E-4
-2.0619999999999998	-1.2137E-4
-2.0630000000000002	-1.2155E-4
-2.0640000000000001	-1.2173E-4
-2.0649999999999999	-1.22E-4
-2.0659999999999998	-1.2235999999999999E-4
-2.0670000000000002	-1.2244999999999999E-4
-2.0680000000000001	-1.228E-4
-2.069	-1.2307E-4
-2.0699999999999998	-1.2333999999999999E-4
-2.0710000000000002	-1.2360999999999999E-4
-2.0720000000000001	-1.2388000000000001E-4
-2.073	-1.2415000000000001E-4
-2.0739999999999998	-1.2449999999999999E-4
-2.0750000000000002	-1.2468000000000001E-4
-2.0760000000000001	-1.2495E-4
-2.077	-1.2531E-4
-2.0779999999999998	-1.2567000000000001E-4
-2.0790000000000002	-1.2594E-4
-2.08	-1.2611E-4
-2.081	-1.2656000000000001E-4
-2.0819999999999999	-1.2692000000000001E-4
-2.0830000000000002	-1.271E-4
-2.0840000000000001	-1.2746E-4
-2.085	-1.2789999999999999E-4
-2.0859999999999999	-1.2816999999999999E-4
-2.0870000000000002	-1.2852999999999999E-4
-2.0880000000000001	-1.2898E-4
-2.089	-1.2933000000000001E-4
-2.09	-1.2951E-4
-2.0910000000000002	-1.2996000000000001E-4
-2.0920000000000001	-1.3040999999999999E-4
-2.093	-1.3067999999999999E-4
-2.0939999999999999	-1.3112E-4
-2.0950000000000002	-1.3156999999999999E-4
-2.0960000000000001	-1.3192999999999999E-4
-2.097	-1.3229E-4
-2.0979999999999999	-1.3273000000000001E-4
-2.0990000000000002	-1.3300000000000001E-4
-2.1	-1.3354E-4
-2.101	-1.3407E-4
-2.1019999999999999	-1.3443E-4
-2.1030000000000002	-1.3488000000000001E-4
-2.1040000000000001	-1.3542E-4
-2.105	-1.3577000000000001E-4
-2.1059999999999999	-1.3640000000000001E-4
-2.1070000000000002	-1.3684999999999999E-4
-2.1080000000000001	-1.3711999999999999E-4
-2.109	-1.3756E-4
-2.11	-1.381E-4
-2.1110000000000002	-1.3863999999999999E-4
-2.1120000000000001	-1.3899E-4
-2.113	-1.3944000000000001E-4
-2.1139999999999999	-1.3998E-4
-2.1150000000000002	-1.4043000000000001E-4
-2.1160000000000001	-1.4096000000000001E-4
-2.117	-1.415E-4
-2.1179999999999999	-1.4186E-4
-2.1190000000000002	-1.4239E-4
-2.12	-1.4292999999999999E-4
-2.121	-1.4347000000000001E-4
-2.1219999999999999	-1.44E-4
-2.1230000000000002	-1.4454E-4
-2.1240000000000001	-1.4507999999999999E-4
-2.125	-1.4561000000000001E-4
-2.1259999999999999	-1.4596999999999999E-4
-2.1269999999999998	-1.4651000000000001E-4
-2.1280000000000001	-1.4704E-4
-2.129	-1.4757999999999999E-4
-2.13	-1.4812000000000001E-4
-2.1309999999999998	-1.4846999999999999E-4
-2.1320000000000001	-1.4901000000000001E-4
-2.133	-1.4955E-4
-2.1339999999999999	-1.5008E-4
-2.1349999999999998	-1.5061999999999999E-4
-2.1360000000000001	-1.5116000000000001E-4
-2.137	-1.5160999999999999E-4
-2.1379999999999999	-1.5213999999999999E-4
-2.1389999999999998	-1.5268000000000001E-4
-2.14	-1.5312999999999999E-4
-2.141	-1.5357000000000001E-4
-2.1419999999999999	-1.5411E-4
-2.1429999999999998	-1.5464999999999999E-4
-2.1440000000000001	-1.55E-4
-2.145	-1.5563E-4
-2.1459999999999999	-1.5599E-4
-2.1469999999999998	-1.5652E-4
-2.1480000000000001	-1.5697000000000001E-4
-2.149	-1.5741999999999999E-4
-2.15	-1.5796000000000001E-4
-2.1509999999999998	-1.5849000000000001E-4
-2.1520000000000001	-1.5893999999999999E-4
-2.153	-1.593E-4
-2.1539999999999999	-1.5974000000000001E-4
-2.1549999999999998	-1.6028E-4
-2.1560000000000001	-1.6072999999999999E-4
-2.157	-1.6134999999999999E-4
-2.1579999999999999	-1.618E-4
-2.1589999999999998	-1.6225000000000001E-4
-2.16	-1.6260999999999999E-4
-2.161	-1.6296E-4
-2.1619999999999999	-1.6349999999999999E-4
-2.1629999999999998	-1.6385999999999999E-4
-2.1640000000000001	-1.6431E-4
-2.165	-1.6484E-4
-2.1659999999999999	-1.6511E-4
-2.1669999999999998	-1.6564999999999999E-4
-2.1680000000000001	-1.661E-4
-2.169	-1.6412999999999999E-4
-2.1680000000000001	-1.4846999999999999E-4
-2.1669999999999998	-1.3585999999999999E-4
-2.1659999999999999	-1.2951E-4
-2.165	-1.2540000000000001E-4
-2.1640000000000001	-1.2218E-4
-2.1629999999999998	-1.1932E-4
-2.1619999999999999	-1.1663E-4
-2.161	-1.1430999999999999E-4
-2.16	-1.1198E-4
-2.1589999999999998	-1.0993E-4
-2.1579999999999999	-1.0787E-4
-2.157	-1.059E-4
-2.1560000000000001	-1.0393E-4
-2.1549999999999998	-1.0213999999999999E-4
-2.1539999999999999	-1.0053E-4
-2.153	-9.8924000000000004E-5
-2.1520000000000001	-9.7224000000000003E-5
-2.1509999999999998	-9.5704000000000004E-5
-2.15	-9.4272999999999997E-5
-2.149	-9.2842000000000003E-5
-2.1480000000000001	-9.1321000000000002E-5
-2.1469999999999998	-8.9889999999999995E-5
-2.1459999999999999	-8.8646999999999993E-5
-2.145	-8.7331999999999997E-5
-2.1440000000000001	-8.6142000000000003E-5
-2.1429999999999998	-8.4899000000000001E-5
-2.1419999999999999	-8.3700000000000002E-5
-2.141	-8.2367999999999995E-5
-2.14	-8.1321000000000003E-5
-2.1389999999999998	-8.0265999999999993E-5
-2.1379999999999999	-7.8986999999999994E-5
-2.137	-7.7886999999999995E-5
-2.1360000000000001	-7.6903000000000006E-5
-2.1349999999999998	-7.5865000000000006E-5
-2.1339999999999999	-7.4845999999999995E-5
-2.133	-7.4014E-5
-2.1320000000000001	-7.2948999999999996E-5
-2.1309999999999998	-7.1975000000000001E-5
-2.13	-7.1052999999999999E-5
-2.129	-7.0086999999999995E-5
-2.1280000000000001	-6.9175000000000001E-5
-2.1269999999999998	-6.8351999999999999E-5
-2.1259999999999999	-6.7502000000000005E-5
-2.125	-6.6581000000000005E-5
-2.1240000000000001	-6.5758000000000003E-5
-2.1230000000000002	-6.4998000000000003E-5
-2.1219999999999999	-6.4228999999999998E-5
-2.121	-6.3441999999999993E-5
-2.12	-6.2707999999999997E-5
-2.1190000000000002	-6.1859000000000005E-5
-2.1179999999999999	-6.1142999999999994E-5
-2.117	-6.0553000000000001E-5
-2.1160000000000001	-5.9738999999999998E-5
-2.1150000000000002	-5.8996000000000002E-5
-2.1139999999999999	-5.8433000000000001E-5
-2.113	-5.7753000000000001E-5
-2.1120000000000001	-5.7090999999999999E-5
-2.1110000000000002	-5.6403000000000002E-5
-2.11	-5.5758999999999999E-5
-2.109	-5.5124000000000003E-5
-2.1080000000000001	-5.4506000000000003E-5
-2.1070000000000002	-5.3934000000000002E-5
-2.1059999999999999	-5.3263000000000001E-5
-2.105	-5.2744000000000002E-5
-2.1040000000000001	-5.2225999999999998E-5
-2.1030000000000002	-5.1688999999999999E-5
-2.1019999999999999	-5.1125000000000003E-5
-2.101	-5.0686999999999998E-5
-2.1	-4.9963000000000003E-5
-2.0990000000000002	-4.9425999999999997E-5
-2.0979999999999999	-4.8987999999999999E-5
-2.097	-4.8513999999999997E-5
-2.0960000000000001	-4.8031000000000001E-5
-2.0950000000000002	-4.7547999999999999E-5
-2.0939999999999999	-4.7055999999999998E-5
-2.093	-4.6554999999999997E-5
-2.0920000000000001	-4.6187999999999999E-5
-2.0910000000000002	-4.5759E-5
-2.09	-4.5151000000000002E-5
-2.089	-4.4829000000000001E-5
-2.0880000000000001	-4.4462000000000002E-5
-2.0870000000000002	-4.3952000000000002E-5
-2.0859999999999999	-4.3594000000000003E-5
-2.085	-4.3254000000000003E-5
-2.0840000000000001	-4.2753999999999998E-5
-2.0830000000000002	-4.2369E-5
-2.0819999999999999	-4.2128000000000001E-5
-2.081	-4.1582000000000003E-5
-2.08	-4.1295999999999999E-5
-2.0790000000000002	-4.0964999999999998E-5
-2.0779999999999998	-4.0589000000000001E-5
-2.077	-4.0187E-5
-2.0760000000000001	-3.9811000000000002E-5
-2.0750000000000002	-3.9551999999999997E-5
-2.0739999999999998	-3.9193999999999998E-5
-2.073	-3.8890000000000002E-5
-2.0720000000000001	-3.8504999999999998E-5
-2.0710000000000002	-3.8182999999999997E-5
-2.0699999999999998	-3.7914999999999999E-5
-2.069	-3.7700000000000002E-5
-2.0680000000000001	-3.7316E-5
-2.0670000000000002	-3.7038E-5
-2.0659999999999998	-3.6779000000000001E-5
-2.0649999999999999	-3.6457E-5
-2.0640000000000001	-3.6180000000000003E-5
-2.0630000000000002	-3.5867000000000001E-5
-2.0619999999999998	-3.5562000000000003E-5
-2.0609999999999999	-3.5348000000000001E-5
-2.06	-3.5097E-5
-2.0590000000000002	-3.4873999999999998E-5
-2.0579999999999998	-3.4427000000000001E-5
-2.0569999999999999	-3.4175999999999999E-5
-2.056	-3.3997E-5
-2.0550000000000002	-3.3738000000000001E-5
-2.0539999999999998	-3.3451999999999998E-5
-2.0529999999999999	-3.3067E-5
-2.052	-3.2978000000000002E-5
-2.0510000000000002	-3.2762999999999998E-5
-2.0499999999999998	-3.2583999999999998E-5
-2.0489999999999999	-3.2342000000000003E-5
-2.048	-3.2082999999999998E-5
-2.0470000000000002	-3.1931000000000003E-5
-2.0459999999999998	-3.1779000000000002E-5
-2.0449999999999999	-3.1483999999999999E-5
-2.044	-3.1313999999999999E-5
-2.0430000000000001	-3.1028000000000002E-5
-2.0419999999999998	-3.0723999999999999E-5
-2.0409999999999999	-3.0607E-5
-2.04	-3.0589000000000001E-5
-2.0390000000000001	-3.0294000000000002E-5
-2.0379999999999998	-2.9954000000000002E-5
-2.0369999999999999	-2.9819999999999999E-5
-2.036	-2.9658999999999998E-5
-2.0350000000000001	-2.9417999999999999E-5
-2.0339999999999998	-2.923E-5
-2.0329999999999999	-2.9113999999999999E-5
-2.032	-2.8853999999999999E-5
-2.0310000000000001	-2.8765E-5
-2.0299999999999998	-2.8586E-5
-2.0289999999999999	-2.83E-5
-2.028	-2.8255E-5
-2.0270000000000001	-2.813E-5
-2.0259999999999998	-2.7817000000000002E-5
-2.0249999999999999	-2.7699999999999999E-5
-2.024	-2.7486000000000001E-5
-2.0230000000000001	-2.7334E-5
-2.0219999999999998	-2.7146000000000001E-5
-2.0209999999999999	-2.6957999999999998E-5
-2.02	-2.6894999999999999E-5
-2.0190000000000001	-2.6733999999999998E-5
-2.0179999999999998	-2.6582000000000001E-5
-2.0169999999999999	-2.6367999999999999E-5
-2.016	-2.618E-5
-2.0150000000000001	-2.6089999999999999E-5
-2.0139999999999998	-2.5938000000000001E-5
-2.0129999999999999	-2.5803999999999999E-5
-2.012	-2.5741999999999998E-5
-2.0110000000000001	-2.5429E-5
-2.0099999999999998	-2.5276999999999999E-5
-2.0089999999999999	-2.5196000000000001E-5
-2.008	-2.5052999999999999E-5
-2.0070000000000001	-2.4865E-5
-2.0059999999999998	-2.4757999999999999E-5
-2.0049999999999999	-2.4785000000000001E-5
-2.004	-2.4488999999999999E-5
-2.0030000000000001	-2.4292999999999999E-5
-2.0019999999999998	-2.4114E-5
-2.0009999999999999	-2.3926000000000001E-5
-2	-2.3881000000000001E-5
-1.9990000000000001	-2.3853999999999999E-5
-1.998	-2.3640000000000001E-5
-1.9970000000000001	-2.3567999999999999E-5
-1.996	-2.3506000000000002E-5
-1.9950000000000001	-2.3309E-5
-1.994	-2.3237000000000001E-5
-1.9930000000000001	-2.3048999999999999E-5
-1.992	-2.2923999999999999E-5
-1.9910000000000001	-2.2781000000000001E-5
-1.99	-2.2753999999999999E-5
-1.9890000000000001	-2.2717999999999998E-5
-1.988	-2.2413999999999999E-5
-1.9870000000000001	-2.2289E-5
-1.986	-2.2271000000000001E-5
-1.9850000000000001	-2.2155E-5
-1.984	-2.1985E-5
-1.9830000000000001	-2.1869E-5
-1.982	-2.1806000000000001E-5
-1.9810000000000001	-2.16E-5
-1.98	-2.1583E-5
-1.9790000000000001	-2.1484E-5
-1.978	-2.1404E-5
-1.9770000000000001	-2.1296000000000001E-5
-1.976	-2.1243E-5
-1.9750000000000001	-2.1216000000000002E-5
-1.974	-2.0982999999999999E-5
-1.9730000000000001	-2.084E-5
-1.972	-2.0696999999999999E-5
-1.9710000000000001	-2.0571999999999999E-5
-1.97	-2.0545000000000001E-5
-1.9690000000000001	-2.0463999999999999E-5
-1.968	-2.0321000000000001E-5
-1.9670000000000001	-2.0259E-5
-1.966	-2.0106999999999999E-5
-1.9650000000000001	-1.9964000000000001E-5
-1.964	-1.9919E-5
-1.9630000000000001	-1.9910000000000001E-5
-1.962	-1.9820999999999999E-5
-1.9610000000000001	-1.9624E-5
-1.96	-1.9624E-5
-1.9590000000000001	-1.9490000000000001E-5
-1.958	-1.9275000000000001E-5
-1.9570000000000001	-1.9275000000000001E-5
-1.956	-1.9185E-5
-1.9550000000000001	-1.9114E-5
-1.954	-1.9051000000000001E-5
-1.9530000000000001	-1.8828E-5
-1.952	-1.8819000000000001E-5
-1.9510000000000001	-1.8496999999999999E-5
-1.95	-1.8425000000000001E-5
-1.9490000000000001	-1.8479E-5
-1.948	-1.8442999999999999E-5
-1.9470000000000001	-1.8372E-5
-1.946	-1.8272999999999999E-5
-1.9450000000000001	-1.8121000000000001E-5
-1.944	-1.8121000000000001E-5
-1.9430000000000001	-1.8023E-5
-1.9419999999999999	-1.7906000000000001E-5
-1.9410000000000001	-1.7853E-5
-1.94	-1.7808E-5
-1.9390000000000001	-1.7700999999999999E-5
-1.9379999999999999	-1.7700999999999999E-5
-1.9370000000000001	-1.7620000000000001E-5
-1.9359999999999999	-1.7495000000000001E-5
-1.9350000000000001	-1.7405999999999999E-5
-1.9339999999999999	-1.7271000000000001E-5
-1.9330000000000001	-1.7155000000000001E-5
-1.9319999999999999	-1.7227E-5
-1.931	-1.7146000000000002E-5
-1.93	-1.6994E-5
-1.929	-1.6957999999999999E-5
-1.9279999999999999	-1.6886999999999999E-5
-1.927	-1.6699000000000001E-5
-1.9259999999999999	-1.6690000000000001E-5
-1.925	-1.6735000000000002E-5
-1.9239999999999999	-1.6555999999999999E-5
-1.923	-1.6413E-5
-1.9219999999999999	-1.6385999999999999E-5
-1.921	-1.6376999999999999E-5
-1.92	-1.6234000000000001E-5
-1.919	-1.6180000000000001E-5
-1.9179999999999999	-1.5982999999999999E-5
-1.917	-1.5982999999999999E-5
-1.9159999999999999	-1.5974E-5
-1.915	-1.5875999999999998E-5
-1.9139999999999999	-1.5795999999999999E-5
-1.913	-1.5750999999999999E-5
-1.9119999999999999	-1.5715000000000001E-5
-1.911	-1.5644000000000001E-5
-1.91	-1.5536000000000002E-5
-1.909	-1.5517999999999999E-5
-1.9079999999999999	-1.5322E-5
-1.907	-1.5259000000000001E-5
-1.9059999999999999	-1.5169E-5
-1.905	-1.5152E-5
-1.9039999999999999	-1.5125E-5
-1.903	-1.5098E-5
-1.9019999999999999	-1.4973E-5
-1.901	-1.483E-5
-1.9	-1.483E-5
-1.899	-1.4739999999999999E-5
-1.8979999999999999	-1.4588E-5
-1.897	-1.4569999999999999E-5
-1.8959999999999999	-1.4623999999999999E-5
-1.895	-1.4481000000000001E-5
-1.8939999999999999	-1.4382000000000001E-5
-1.893	-1.4338000000000001E-5
-1.8919999999999999	-1.4266E-5
-1.891	-1.4212E-5
-1.89	-1.4204E-5
-1.889	-1.4042999999999999E-5
-1.8879999999999999	-1.3944000000000001E-5
-1.887	-1.3998E-5
-1.8859999999999999	-1.3882E-5
-1.885	-1.381E-5
-1.8839999999999999	-1.3828E-5
-1.883	-1.3738E-5
-1.8819999999999999	-1.3551E-5
-1.881	-1.3524E-5
-1.88	-1.347E-5
-1.879	-1.3399E-5
-1.8779999999999999	-1.3345E-5
-1.877	-1.3318E-5
-1.8759999999999999	-1.3166000000000001E-5
-1.875	-1.3077E-5
-1.8740000000000001	-1.3157E-5
-1.873	-1.3013999999999999E-5
-1.8720000000000001	-1.296E-5
-1.871	-1.2996000000000001E-5
-1.87	-1.2862E-5
-1.869	-1.2692E-5
-1.8680000000000001	-1.2692E-5
-1.867	-1.2629000000000001E-5
-1.8660000000000001	-1.2558000000000001E-5
-1.865	-1.2513E-5
-1.8640000000000001	-1.2459E-5
-1.863	-1.237E-5
-1.8620000000000001	-1.2218000000000001E-5
-1.861	-1.2298E-5
-1.86	-1.2235999999999999E-5
-1.859	-1.2065999999999999E-5
-1.8580000000000001	-1.2065999999999999E-5
-1.857	-1.1967000000000001E-5
-1.8560000000000001	-1.1815E-5
-1.855	-1.1753000000000001E-5
-1.8540000000000001	-1.169E-5
-1.853	-1.1644999999999999E-5
-1.8520000000000001	-1.1708E-5
-1.851	-1.1556000000000001E-5
-1.85	-1.1440000000000001E-5
-1.849	-1.1270000000000001E-5
-1.8480000000000001	-1.1063999999999999E-5
-1.847	-1.1090999999999999E-5
-1.8460000000000001	-1.1090999999999999E-5
-1.845	-1.1117999999999999E-5
-1.8440000000000001	-1.1037E-5
-1.843	-1.093E-5
-1.8420000000000001	-1.0920999999999999E-5
-1.841	-1.0742E-5
-1.84	-1.0696999999999999E-5
-1.839	-1.0715E-5
-1.8380000000000001	-1.059E-5
-1.837	-1.0429E-5
-1.8360000000000001	-1.0429E-5
-1.835	-1.0429E-5
-1.8340000000000001	-1.0322E-5
-1.833	-1.025E-5
-1.8320000000000001	-1.0142999999999999E-5
-1.831	-9.9638999999999996E-6
-1.83	-9.9371000000000001E-6
-1.829	-9.9729000000000007E-6
-1.8280000000000001	-9.8386999999999995E-6
-1.827	-9.6508999999999994E-6
-1.8260000000000001	-9.6687999999999997E-6
-1.825	-9.4540999999999998E-6
-1.8240000000000001	-9.4182999999999993E-6
-1.823	-9.5256000000000008E-6
-1.8220000000000001	-9.4361999999999995E-6
-1.821	-9.2930999999999992E-6
-1.82	-9.1768E-6
-1.819	-9.0605000000000007E-6
-1.8180000000000001	-8.9325999999999998E-6
-1.8169999999999999	-8.8888000000000003E-6
-1.8160000000000001	-8.7699000000000005E-6
-1.8149999999999999	-8.6956000000000002E-6
-1.8140000000000001	-8.6016999999999993E-6
-1.8129999999999999	-8.5292999999999998E-6
-1.8120000000000001	-8.4058000000000001E-6
-1.8109999999999999	-8.3073999999999994E-6
-1.81	-8.3173000000000008E-6
-1.8089999999999999	-8.1223000000000001E-6
-1.8080000000000001	-8.0337000000000007E-6
-1.8069999999999999	-8.0122999999999995E-6
-1.806	-7.8468000000000008E-6
-1.8049999999999999	-7.7770000000000002E-6
-1.804	-7.6437999999999996E-6
-1.8029999999999999	-7.5596999999999998E-6
-1.802	-7.4703000000000003E-6
-1.8009999999999999	-7.3950999999999997E-6
-1.8	-7.2841999999999996E-6
-1.7989999999999999	-7.1975000000000001E-6
-1.798	-7.1268000000000001E-6
-1.7969999999999999	-7.3763E-6
-1.796	-7.0025000000000003E-6
-1.7949999999999999	-6.6545000000000004E-6
-1.794	-6.6903000000000001E-6
-1.7929999999999999	-6.5687000000000003E-6
-1.792	-6.3691999999999999E-6
-1.7909999999999999	-6.2592000000000001E-6
-1.79	-6.2029000000000004E-6
-1.7889999999999999	-6.1160999999999998E-6
-1.788	-5.9479000000000003E-6
-1.7869999999999999	-5.9255999999999996E-6
-1.786	-5.7761999999999999E-6
-1.7849999999999999	-5.6376E-6
-1.784	-5.5373999999999997E-6
-1.7829999999999999	-5.3334999999999998E-6
-1.782	-5.2403999999999998E-6
-1.7809999999999999	-5.2457999999999998E-6
-1.78	-4.9908999999999999E-6
-1.7789999999999999	-4.9049999999999996E-6
-1.778	-4.8639000000000001E-6
-1.7769999999999999	-4.7762000000000001E-6
-1.776	-4.5338999999999999E-6
-1.7749999999999999	-4.3514000000000004E-6
-1.774	-4.2726999999999998E-6
-1.7729999999999999	-4.1376E-6
-1.772	-4.1296000000000002E-6
-1.7709999999999999	-4.0133000000000002E-6
-1.77	-3.8120000000000001E-6
-1.7689999999999999	-3.7181E-6
-1.768	-3.5839999999999999E-6
-1.7669999999999999	-3.4282999999999999E-6
-1.766	-3.2924E-6
-1.7649999999999999	-3.2548000000000002E-6
-1.764	-3.0732999999999999E-6
-1.7629999999999999	-2.9220999999999999E-6
-1.762	-2.8540999999999999E-6
-1.7609999999999999	-2.7307E-6
-1.76	-2.5857999999999999E-6
-1.7589999999999999	-2.4820000000000001E-6
-1.758	-2.3522999999999999E-6
-1.7569999999999999	-2.2039000000000002E-6
-1.756	-2.0947E-6
-1.7549999999999999	-2.0420000000000001E-6
-1.754	-1.9007000000000001E-6
-1.7529999999999999	-1.7871E-6
-1.752	-1.6224999999999999E-6
-1.7509999999999999	-1.4981999999999999E-6
-1.75	-1.432E-6
-1.7490000000000001	-1.3881999999999999E-6
-1.748	-1.1413E-6
-1.7470000000000001	-9.3735999999999997E-7
-1.746	-6.4023000000000001E-7
-1.7450000000000001	-7.7385999999999997E-7
-1.744	-6.9961999999999996E-7
-1.7430000000000001	-6.2010999999999996E-7
-1.742	-5.1269000000000002E-7
-1.7410000000000001	-3.3621999999999998E-7
-1.74	-2.4354999999999998E-7
-1.7390000000000001	-2.1645000000000001E-7
-1.738	-1.2039000000000001E-7
-1.7370000000000001	-1.5554000000000002E-8
-1.736	3.6868000000000003E-8
-1.7350000000000001	1.1466999999999999E-7
-1.734	1.7924000000000001E-7
-1.7330000000000001	2.4740000000000001E-7
-1.732	4.0643000000000002E-7
-1.7310000000000001	5.8897999999999997E-7
-1.73	5.7762000000000001E-7
-1.7290000000000001	7.5417999999999999E-7
-1.728	8.3101000000000003E-7
-1.7270000000000001	8.4236999999999999E-7
-1.726	8.8520999999999997E-7
-1.7250000000000001	9.7581999999999996E-7
-1.724	1.0152E-6
-1.7230000000000001	1.1233999999999999E-6
-1.722	1.2683E-6
-1.7210000000000001	1.2843999999999999E-6
-1.72	1.2683E-6
-1.7190000000000001	1.3792000000000001E-6
-1.718	1.4337999999999999E-6
-1.7170000000000001	1.4642000000000001E-6
-1.716	1.5796000000000001E-6
-1.7150000000000001	1.6564999999999999E-6
-1.714	1.6484E-6
-1.7130000000000001	1.7334E-6
-1.712	1.7397E-6
-1.7110000000000001	1.7504E-6
-1.71	1.8568E-6
-1.7090000000000001	1.9748999999999999E-6
-1.708	1.8694000000000001E-6
-1.7070000000000001	1.9551999999999999E-6
-1.706	2.0795000000000002E-6
-1.7050000000000001	2.1511E-6
-1.704	2.1735E-6
-1.7030000000000001	2.1905E-6
-1.702	2.3559000000000002E-6
-1.7010000000000001	2.3532000000000002E-6
-1.7	2.3192000000000002E-6
-1.6990000000000001	2.3327000000000001E-6
-1.698	2.3711E-6
-1.6970000000000001	2.4721999999999998E-6
-1.696	2.5053E-6
-1.6950000000000001	2.4623999999999999E-6
-1.694	2.6116999999999999E-6
-1.6930000000000001	2.7288999999999998E-6
-1.6919999999999999	2.5517999999999999E-6
-1.6910000000000001	2.7199999999999998E-6
-1.69	2.7638000000000001E-6
-1.6890000000000001	2.8845000000000001E-6
-1.6879999999999999	2.9023999999999999E-6
-1.6870000000000001	2.8227999999999999E-6
-1.6859999999999999	2.9337E-6
-1.6850000000000001	2.9758E-6
-1.6839999999999999	3.0097000000000002E-6
-1.6830000000000001	3.0974000000000002E-6
-1.6819999999999999	3.0527E-6
-1.681	3.0831000000000002E-6
-1.68	3.1493000000000001E-6
-1.679	3.1377E-6
-1.6779999999999999	3.2225999999999999E-6
-1.677	3.3291E-6
-1.6759999999999999	3.2834000000000002E-6
-1.675	3.4203000000000001E-6
-1.6739999999999999	3.5105999999999999E-6
-1.673	3.4945000000000002E-6
-1.6719999999999999	3.4686000000000001E-6
-1.671	3.5553000000000001E-6
-1.67	3.5329999999999999E-6
-1.669	3.4479999999999999E-6
-1.6679999999999999	3.6117000000000001E-6
-1.667	3.7181E-6
-1.6659999999999999	3.7467999999999999E-6
-1.665	3.7915E-6
-1.6639999999999999	3.8647999999999998E-6
-1.663	3.8738000000000001E-6
-1.6619999999999999	3.9373000000000004E-6
-1.661	3.9936000000000002E-6
-1.66	3.9488999999999996E-6
-1.659	4.0338999999999996E-6
-1.6579999999999999	4.1269000000000002E-6
-1.657	4.1331000000000003E-6
-1.6559999999999999	4.1743E-6
-1.655	4.2216999999999997E-6
-1.6539999999999999	4.2780000000000004E-6
-1.653	4.2672999999999998E-6
-1.6519999999999999	4.2432000000000003E-6
-1.651	4.4577999999999999E-6
-1.65	4.4550999999999999E-6
-1.649	4.5016999999999996E-6
-1.6479999999999999	4.5839000000000003E-6
-1.647	4.5347E-6
-1.6459999999999999	4.6268999999999997E-6
-1.645	4.8067000000000001E-6
-1.6439999999999999	4.9319000000000002E-6
-1.643	4.9659000000000002E-6
-1.6419999999999999	4.8996999999999999E-6
-1.641	4.8942999999999999E-6
-1.64	4.9292000000000002E-6
-1.639	4.9945000000000002E-6
-1.6379999999999999	5.0678E-6
-1.637	5.0956E-6
-1.6359999999999999	5.1259999999999997E-6
-1.635	5.2090999999999998E-6
-1.6339999999999999	5.1474E-6
-1.633	5.2341999999999998E-6
-1.6319999999999999	5.2565000000000004E-6
-1.631	5.1868E-6
-1.63	5.3147000000000001E-6
-1.629	5.3746000000000002E-6
-1.6279999999999999	5.3736999999999999E-6
-1.627	5.5276000000000002E-6
-1.6259999999999999	5.5338000000000003E-6
-1.625	5.5651000000000003E-6
-1.6240000000000001	5.6455999999999998E-6
-1.623	5.7046999999999998E-6
-1.6220000000000001	5.7664000000000004E-6
-1.621	5.7332999999999998E-6
-1.62	5.8128999999999999E-6
-1.619	5.8602999999999996E-6
-1.6180000000000001	5.8004000000000004E-6
-1.617	5.9380999999999999E-6
-1.6160000000000001	5.9264999999999999E-6
-1.615	5.9676000000000003E-6
-1.6140000000000001	6.0374E-6
-1.613	6.1689000000000003E-6
-1.6120000000000001	6.1850000000000001E-6
-1.611	6.1983999999999998E-6
-1.61	6.2698999999999999E-6
-1.609	6.3388000000000002E-6
-1.6080000000000001	6.3307999999999996E-6
-1.607	6.3388000000000002E-6
-1.6060000000000001	6.3782000000000002E-6
-1.605	6.3593999999999996E-6
-1.6040000000000001	6.5463000000000003E-6
-1.603	6.6008999999999998E-6
-1.6020000000000001	6.6510000000000004E-6
-1.601	6.7090999999999999E-6
-1.6	6.7734999999999996E-6
-1.599	6.6857999999999996E-6
-1.5980000000000001	6.7556000000000002E-6
-1.597	6.8522000000000002E-6
-1.5960000000000001	6.8933999999999999E-6
-1.595	6.9032000000000002E-6
-1.5940000000000001	7.0311000000000003E-6
-1.593	7.0874000000000001E-6
-1.5920000000000001	7.0874000000000001E-6
-1.591	7.0955000000000001E-6
-1.59	7.1778000000000001E-6
-1.589	7.0848000000000003E-6
-1.5880000000000001	7.2707999999999999E-6
-1.587	7.3424000000000002E-6
-1.5860000000000001	7.2931999999999999E-6
-1.585	7.4004999999999997E-6
-1.5840000000000001	7.4041E-6
-1.583	7.4273E-6
-1.5820000000000001	7.5293000000000001E-6
-1.581	7.6017000000000004E-6
-1.58	7.5426999999999998E-6
-1.579	7.5820999999999998E-6
-1.5780000000000001	7.6822000000000007E-6
-1.577	7.7493000000000005E-6
-1.5760000000000001	7.6992000000000008E-6
-1.575	7.8136999999999994E-6
-1.5740000000000001	7.9765000000000006E-6
-1.573	7.9801E-6
-1.5720000000000001	7.9640000000000003E-6
-1.571	8.0159000000000006E-6
-1.57	8.0606000000000004E-6
-1.569	8.1071000000000007E-6
-1.5680000000000001	8.1509000000000002E-6
-1.5669999999999999	8.0873999999999999E-6
-1.5660000000000001	8.1464000000000005E-6
-1.5649999999999999	8.2878000000000005E-6
-1.5640000000000001	8.2277999999999994E-6
-1.5629999999999999	8.3413999999999995E-6
-1.5620000000000001	8.4084999999999992E-6
-1.5609999999999999	8.4988000000000007E-6
-1.56	8.4835999999999995E-6
-1.5589999999999999	8.6186999999999993E-6
-1.5580000000000001	8.6410999999999993E-6
-1.5569999999999999	8.6098000000000001E-6
-1.556	8.7198000000000008E-6
-1.5549999999999999	8.6920000000000008E-6
-1.554	8.6786000000000002E-6
-1.5529999999999999	8.8101000000000006E-6
-1.552	8.9316999999999995E-6
-1.5509999999999999	8.8744999999999995E-6
-1.55	8.8933E-6
-1.5489999999999999	9.0157999999999993E-6
-1.548	9.0962999999999996E-6
-1.5469999999999999	9.1768E-6
-1.546	9.1768E-6
-1.5449999999999999	9.2214999999999997E-6
-1.544	9.2483999999999994E-6
-1.5429999999999999	9.2573000000000003E-6
-1.542	9.4452000000000006E-6
-1.5409999999999999	9.6865999999999997E-6
-1.54	9.5078000000000007E-6
-1.5389999999999999	9.6060999999999994E-6
-1.538	9.5256000000000008E-6
-1.5369999999999999	9.6060999999999994E-6
-1.536	9.7403000000000006E-6
-1.5349999999999999	9.6865999999999997E-6
-1.534	9.8029000000000006E-6
-1.5329999999999999	9.7760999999999995E-6
-1.532	9.8476000000000004E-6
-1.5309999999999999	9.9638999999999996E-6
-1.53	1.0009E-5
-1.5289999999999999	9.9997000000000002E-6
-1.528	9.9638999999999996E-6
-1.5269999999999999	1.0018E-5
-1.526	1.0142999999999999E-5
-1.5249999999999999	1.0223E-5
-1.524	1.0356999999999999E-5
-1.5229999999999999	1.0331E-5
-1.522	1.0383999999999999E-5
-1.5209999999999999	1.0429E-5
-1.52	1.0526999999999999E-5
-1.5189999999999999	1.0545E-5
-1.518	1.0563E-5
-1.5169999999999999	1.0679000000000001E-5
-1.516	1.0617E-5
-1.5149999999999999	1.0635000000000001E-5
-1.514	1.0778000000000001E-5
-1.5129999999999999	1.0858E-5
-1.512	1.0920999999999999E-5
-1.5109999999999999	1.0975000000000001E-5
-1.51	1.101E-5
-1.5089999999999999	1.1109E-5
-1.508	1.1198E-5
-1.5069999999999999	1.1297E-5
-1.506	1.1279E-5
-1.5049999999999999	1.1358999999999999E-5
-1.504	1.1430999999999999E-5
-1.5029999999999999	1.1297E-5
-1.502	1.1449E-5
-1.5009999999999999	1.1636E-5
-1.5	1.1663E-5
-1.4990000000000001	1.1671999999999999E-5
-1.498	1.1815E-5
-1.4970000000000001	1.1815E-5
-1.496	1.1797000000000001E-5
-1.4950000000000001	1.1932E-5
-1.494	1.2065999999999999E-5
-1.4930000000000001	1.2092999999999999E-5
-1.492	1.2173E-5
-1.4910000000000001	1.2262999999999999E-5
-1.49	1.2235999999999999E-5
-1.4890000000000001	1.2352E-5
-1.488	1.2379E-5
-1.4870000000000001	1.2405999999999999E-5
-1.486	1.2486E-5
-1.4850000000000001	1.2646999999999999E-5
-1.484	1.2719E-5
-1.4830000000000001	1.2763E-5
-1.482	1.2826000000000001E-5
-1.4810000000000001	1.2826000000000001E-5
-1.48	1.2916E-5
-1.4790000000000001	1.3040999999999999E-5
-1.478	1.3112000000000001E-5
-1.4770000000000001	1.3094E-5
-1.476	1.3229E-5
-1.4750000000000001	1.3363000000000001E-5
-1.474	1.3416E-5
-1.4730000000000001	1.3461E-5
-1.472	1.3594999999999999E-5
-1.4710000000000001	1.3621999999999999E-5
-1.47	1.3675999999999999E-5
-1.4690000000000001	1.3774000000000001E-5
-1.468	1.3774000000000001E-5
-1.4670000000000001	1.3890000000000001E-5
-1.466	1.4025E-5
-1.4650000000000001	1.4078E-5
-1.464	1.4015999999999999E-5
-1.4630000000000001	1.4168000000000001E-5
-1.462	1.4239E-5
-1.4610000000000001	1.4275E-5
-1.46	1.4355999999999999E-5
-1.4590000000000001	1.4534E-5
-1.458	1.4615E-5
-1.4570000000000001	1.4749000000000001E-5
-1.456	1.4820999999999999E-5
-1.4550000000000001	1.4803E-5
-1.454	1.4919000000000001E-5
-1.4530000000000001	1.508E-5
-1.452	1.5071E-5
-1.4510000000000001	1.5143000000000001E-5
-1.45	1.5322E-5
-1.4490000000000001	1.5285999999999999E-5
-1.448	1.5330000000000001E-5
-1.4470000000000001	1.5491000000000001E-5
-1.446	1.5617E-5
-1.4450000000000001	1.5625999999999999E-5
-1.444	1.5787E-5
-1.4430000000000001	1.5866999999999999E-5
-1.4419999999999999	1.5885000000000001E-5
-1.4410000000000001	1.5974E-5
-1.44	1.6082E-5
-1.4390000000000001	1.6341000000000002E-5
-1.4379999999999999	1.6422E-5
-1.4370000000000001	1.6314E-5
-1.4359999999999999	1.6252E-5
-1.4350000000000001	1.6636000000000001E-5
-1.4339999999999999	1.6592E-5
-1.4330000000000001	1.6636000000000001E-5
-1.4319999999999999	1.6878E-5
-1.431	1.6895999999999999E-5
-1.43	1.6957999999999999E-5
-1.429	1.7030000000000001E-5
-1.4279999999999999	1.7127999999999999E-5
-1.427	1.7306999999999999E-5
-1.4259999999999999	1.7306999999999999E-5
-1.425	1.7360999999999999E-5
-1.4239999999999999	1.7521999999999999E-5
-1.423	1.7513E-5
-1.4219999999999999	1.7674000000000001E-5
-1.421	1.7736000000000001E-5
-1.42	1.7825999999999998E-5
-1.419	1.7986999999999999E-5
-1.4179999999999999	1.8067000000000002E-5
-1.417	1.8121000000000001E-5
-1.4159999999999999	1.8202E-5
-1.415	1.8309E-5
-1.4139999999999999	1.8345000000000001E-5
-1.413	1.8363E-5
-1.4119999999999999	1.8515000000000001E-5
-1.411	1.8694000000000001E-5
-1.41	1.8729E-5
-1.409	1.8746999999999999E-5
-1.4079999999999999	1.8961999999999999E-5
-1.407	1.8980000000000001E-5
-1.4059999999999999	1.9051000000000001E-5
-1.405	1.9202999999999999E-5
-1.4039999999999999	1.9284E-5
-1.403	1.9436000000000002E-5
-1.4019999999999999	1.9454E-5
-1.401	1.9525E-5
-1.4	1.9596999999999999E-5
-1.399	1.9749E-5
-1.3979999999999999	1.9820999999999999E-5
-1.397	1.9775999999999998E-5
-1.3959999999999999	1.9973E-5
-1.395	2.0125000000000001E-5
-1.3939999999999999	2.0143E-5
-1.393	2.0205000000000001E-5
-1.3919999999999999	2.0366000000000001E-5
-1.391	2.0392999999999999E-5
-1.39	2.0536000000000001E-5
-1.389	2.0616999999999999E-5
-1.3879999999999999	2.0642999999999999E-5
-1.387	2.0750999999999998E-5
-1.3859999999999999	2.0930000000000001E-5
-1.385	2.0903E-5
-1.3839999999999999	2.1036999999999999E-5
-1.383	2.1225000000000001E-5
-1.3819999999999999	2.1268999999999999E-5
-1.381	2.1277999999999999E-5
-1.38	2.1466000000000001E-5
-1.379	2.1492999999999999E-5
-1.3779999999999999	2.1447999999999999E-5
-1.377	2.1654E-5
-1.3759999999999999	2.1851000000000001E-5
-1.375	2.1841999999999999E-5
-1.3740000000000001	2.1895999999999998E-5
-1.373	2.1957999999999999E-5
-1.3720000000000001	2.2082999999999998E-5
-1.371	2.2235E-5
-1.37	2.228E-5
-1.369	2.2361000000000002E-5
-1.3680000000000001	2.2405E-5
-1.367	2.2540000000000001E-5
-1.3660000000000001	2.2691999999999999E-5
-1.365	2.2682999999999999E-5
-1.3640000000000001	2.2710000000000001E-5
-1.363	2.2923999999999999E-5
-1.3620000000000001	2.2835000000000001E-5
-1.361	2.3023E-5
-1.36	2.3156999999999999E-5
-1.359	2.3112000000000002E-5
-1.3580000000000001	2.3281999999999998E-5
-1.357	2.3336000000000002E-5
-1.3560000000000001	2.3371E-5
-1.355	2.3541E-5
-1.3540000000000001	2.3693000000000002E-5
-1.353	2.3728999999999999E-5
-1.3520000000000001	2.3737999999999999E-5
-1.351	2.3791999999999999E-5
-1.35	2.3935E-5
-1.349	2.3935E-5
-1.3480000000000001	2.4087000000000002E-5
-1.347	2.4256999999999998E-5
-1.3460000000000001	2.4202999999999998E-5
-1.345	2.4284E-5
-1.3440000000000001	2.4426999999999998E-5
-1.343	2.4462999999999999E-5
-1.3420000000000001	2.4542999999999999E-5
-1.341	2.4686E-5
-1.34	2.4722000000000001E-5
-1.339	2.4749E-5
-1.3380000000000001	2.4811E-5
-1.337	2.5089E-5
-1.3360000000000001	2.5267999999999999E-5
-1.335	2.5142000000000001E-5
-1.3340000000000001	2.5196000000000001E-5
-1.333	2.5241000000000001E-5
-1.3320000000000001	2.5321E-5
-1.331	2.5437999999999999E-5
-1.33	2.5473000000000002E-5
-1.329	2.5536000000000001E-5
-1.3280000000000001	2.5633999999999999E-5
-1.327	2.5661E-5
-1.3260000000000001	2.5760000000000001E-5
-1.325	2.5768000000000001E-5
-1.3240000000000001	2.5867000000000002E-5
-1.323	2.5867000000000002E-5
-1.3220000000000001	2.6018999999999999E-5
-1.321	2.6081E-5
-1.32	2.6117000000000001E-5
-1.319	2.6216000000000001E-5
-1.3180000000000001	2.6341000000000001E-5
-1.3169999999999999	2.6359E-5
-1.3160000000000001	2.6429999999999999E-5
-1.3149999999999999	2.6511000000000001E-5
-1.3140000000000001	2.6511000000000001E-5
-1.3129999999999999	2.6618000000000002E-5
-1.3120000000000001	2.6707999999999999E-5
-1.3109999999999999	2.6672000000000001E-5
-1.31	2.6769999999999999E-5
-1.3089999999999999	2.6894999999999999E-5
-1.3080000000000001	2.6842000000000002E-5
-1.3069999999999999	2.6985E-5
-1.306	2.7137000000000001E-5
-1.3049999999999999	2.7146000000000001E-5
-1.304	2.7172999999999999E-5
-1.3029999999999999	2.7208000000000001E-5
-1.302	2.7316000000000001E-5
-1.3009999999999999	2.7342999999999999E-5
-1.3	2.7486000000000001E-5
-1.2989999999999999	2.7486000000000001E-5
-1.298	2.7432000000000001E-5
-1.2969999999999999	2.7593000000000002E-5
-1.296	2.7674E-5
-1.2949999999999999	2.7699999999999999E-5
-1.294	2.7727000000000001E-5
-1.2929999999999999	2.7852E-5
-1.292	2.7888000000000001E-5
-1.2909999999999999	2.7968999999999999E-5
-1.29	2.8005E-5
-1.2889999999999999	2.8058000000000001E-5
-1.288	2.8005E-5
-1.2869999999999999	2.8112000000000001E-5
-1.286	2.8263999999999999E-5
-1.2849999999999999	2.8272999999999998E-5
-1.284	2.8326999999999998E-5
-1.2829999999999999	2.8379999999999999E-5
-1.282	2.8371E-5
-1.2809999999999999	2.8407000000000001E-5
-1.28	2.8532000000000001E-5
-1.2789999999999999	2.8558999999999999E-5
-1.278	2.8622000000000001E-5
-1.2769999999999999	2.8631000000000001E-5
-1.276	2.8702000000000001E-5
-1.2749999999999999	2.8711E-5
-1.274	2.8792000000000001E-5
-1.2729999999999999	2.8818000000000001E-5
-1.272	2.8827E-5
-1.2709999999999999	2.8898999999999999E-5
-1.27	2.9006E-5
-1.2689999999999999	2.8962000000000002E-5
-1.268	2.9033000000000001E-5
-1.2669999999999999	2.9184999999999999E-5
-1.266	2.9203000000000001E-5
-1.2649999999999999	2.9328000000000001E-5
-1.264	2.9292E-5
-1.2629999999999999	2.9300999999999999E-5
-1.262	2.9319000000000002E-5
-1.2609999999999999	2.9337000000000001E-5
-1.26	2.9363999999999999E-5
-1.2589999999999999	2.9436000000000001E-5
-1.258	2.9587999999999999E-5
-1.2569999999999999	2.9606000000000001E-5
-1.256	2.957E-5
-1.2549999999999999	2.9686E-5
-1.254	2.9767000000000001E-5
-1.2529999999999999	2.9802E-5
-1.252	2.9802E-5
-1.2509999999999999	2.9901000000000001E-5
-1.25	2.9918999999999999E-5
-1.2490000000000001	2.9944999999999999E-5
-1.248	2.9989999999999999E-5
-1.2470000000000001	2.9963000000000001E-5
-1.246	3.0088999999999999E-5
-1.2450000000000001	3.0105999999999999E-5
-1.244	3.0052999999999998E-5
-1.2430000000000001	3.0178000000000001E-5
-1.242	3.0222999999999998E-5
-1.2410000000000001	3.0267E-5
-1.24	3.0329999999999999E-5
-1.2390000000000001	3.0312E-5
-1.238	3.0366E-5
-1.2370000000000001	3.0411000000000001E-5
-1.236	3.0518000000000002E-5
-1.2350000000000001	3.0589000000000001E-5
-1.234	3.0803999999999998E-5
-1.2330000000000001	3.0741000000000003E-5
-1.232	3.0741000000000003E-5
-1.2310000000000001	3.0670000000000003E-5
-1.23	3.0794999999999999E-5
-1.2290000000000001	3.0812999999999998E-5
-1.228	3.0840000000000003E-5
-1.2270000000000001	3.0803999999999998E-5
-1.226	3.0867000000000001E-5
-1.2250000000000001	3.0902000000000003E-5
-1.224	3.0902000000000003E-5
-1.2230000000000001	3.0902000000000003E-5
-1.222	3.0982999999999998E-5
-1.2210000000000001	3.0885E-5
-1.22	3.1108000000000001E-5
-1.2190000000000001	3.1099000000000002E-5
-1.218	3.1090000000000002E-5
-1.2170000000000001	3.1152999999999998E-5
-1.216	3.1241999999999997E-5
-1.2150000000000001	3.1260000000000002E-5
-1.214	3.1278000000000001E-5
-1.2130000000000001	3.1296E-5
-1.212	3.1350000000000003E-5
-1.2110000000000001	3.1287E-5
-1.21	3.1439000000000002E-5
-1.2090000000000001	3.1368000000000002E-5
-1.208	3.1402999999999997E-5
-1.2070000000000001	3.1492999999999998E-5
-1.206	3.1529000000000003E-5
-1.2050000000000001	3.1474999999999999E-5
-1.204	3.1563999999999998E-5
-1.2030000000000001	3.1698E-5
-1.202	3.1671999999999998E-5
-1.2010000000000001	3.1724999999999999E-5
-1.2	3.1698E-5
-1.1990000000000001	3.1690000000000003E-5
-1.198	3.1733999999999998E-5
-1.1970000000000001	3.1903999999999998E-5
-1.196	3.1832999999999998E-5
-1.1950000000000001	3.1788000000000001E-5
-1.194	3.1859000000000001E-5
-1.1930000000000001	3.1931000000000003E-5
-1.1919999999999999	3.1931000000000003E-5
-1.1910000000000001	3.1940000000000003E-5
-1.19	3.2064999999999999E-5
-1.1890000000000001	3.2064999999999999E-5
-1.1879999999999999	3.2064999999999999E-5
-1.1870000000000001	3.2146E-5
-1.1859999999999999	3.2110000000000003E-5
-1.1850000000000001	3.2190000000000002E-5
-1.1839999999999999	3.2234999999999999E-5
-1.1830000000000001	3.2298000000000001E-5
-1.1819999999999999	3.2271000000000003E-5
-1.181	3.2378000000000001E-5
-1.18	3.2289000000000002E-5
-1.179	3.2342000000000003E-5
-1.1779999999999999	3.2325E-5
-1.177	3.2404999999999999E-5
-1.1759999999999999	3.2459000000000002E-5
-1.175	3.2413999999999998E-5
-1.1739999999999999	3.2548000000000001E-5
-1.173	3.2486E-5
-1.1719999999999999	3.2530000000000002E-5
-1.171	3.2601999999999997E-5
-1.17	3.2548000000000001E-5
-1.169	3.2566E-5
-1.1679999999999999	3.2672999999999997E-5
-1.167	3.2638000000000002E-5
-1.1659999999999999	3.2700000000000002E-5
-1.165	3.2744999999999999E-5
-1.1639999999999999	3.2808000000000002E-5
-1.163	3.2780999999999997E-5
-1.1619999999999999	3.2799000000000002E-5
-1.161	3.2771999999999997E-5
-1.1599999999999999	3.2833999999999998E-5
-1.159	3.2950999999999997E-5
-1.1579999999999999	3.2914999999999999E-5
-1.157	3.2799000000000002E-5
-1.1559999999999999	3.2870000000000002E-5
-1.155	3.2941999999999997E-5
-1.1539999999999999	3.3012999999999997E-5
-1.153	3.3003999999999998E-5
-1.1519999999999999	3.3093999999999999E-5
-1.151	3.3093999999999999E-5
-1.1499999999999999	3.3201000000000003E-5
-1.149	3.3219000000000002E-5
-1.1479999999999999	3.3164999999999998E-5
-1.147	3.3147E-5
-1.1459999999999999	3.3210000000000002E-5
-1.145	3.3272999999999998E-5
-1.1439999999999999	3.3228000000000001E-5
-1.143	3.3343999999999998E-5
-1.1419999999999999	3.3317E-5
-1.141	3.3290999999999997E-5
-1.1399999999999999	3.3398000000000001E-5
-1.139	3.3371000000000003E-5
-1.1379999999999999	3.3352999999999997E-5
-1.137	3.3522999999999997E-5
-1.1359999999999999	3.3568000000000001E-5
-1.135	3.3504999999999999E-5
-1.1339999999999999	3.3541000000000003E-5
-1.133	3.3603999999999999E-5
-1.1319999999999999	3.3756E-5
-1.131	3.3835999999999999E-5
-1.1299999999999999	3.3747000000000001E-5
-1.129	3.3764999999999999E-5
-1.1279999999999999	3.3665999999999999E-5
-1.127	3.3756E-5
-1.1259999999999999	3.3756E-5
-1.125	3.3791000000000002E-5
-1.1240000000000001	3.3871999999999997E-5
-1.123	3.3899000000000002E-5
-1.1220000000000001	3.3827E-5
-1.121	3.3890000000000002E-5
-1.1200000000000001	3.3871999999999997E-5
-1.119	3.3853999999999998E-5
-1.1180000000000001	3.3926E-5
-1.117	3.3979000000000001E-5
-1.1160000000000001	3.3908000000000001E-5
-1.115	3.3988000000000001E-5
-1.1140000000000001	3.4096E-5
-1.113	3.4158000000000001E-5
-1.1120000000000001	3.4096E-5
-1.111	3.4149000000000001E-5
-1.1100000000000001	3.4248000000000001E-5
-1.109	3.4149000000000001E-5
-1.1080000000000001	3.4230000000000003E-5
-1.107	3.4282999999999997E-5
-1.1060000000000001	3.4193999999999998E-5
-1.105	3.4292000000000003E-5
-1.1040000000000001	3.4292000000000003E-5
-1.103	3.4310000000000002E-5
-1.1020000000000001	3.4372999999999998E-5
-1.101	3.4434999999999998E-5
-1.1000000000000001	3.4434999999999998E-5
-1.099	3.4418000000000001E-5
-1.0980000000000001	3.4434999999999998E-5
-1.097	3.4498000000000001E-5
-1.0960000000000001	3.4524999999999999E-5
-1.095	3.4551999999999997E-5
-1.0940000000000001	3.4659000000000001E-5
-1.093	3.4570000000000003E-5
-1.0920000000000001	3.4622999999999997E-5
-1.091	3.4668000000000001E-5
-1.0900000000000001	3.4632000000000003E-5
-1.089	3.4740000000000003E-5
-1.0880000000000001	3.4783999999999998E-5
-1.087	3.4712999999999998E-5
-1.0860000000000001	3.4730999999999997E-5
-1.085	3.4909000000000001E-5
-1.0840000000000001	3.4882999999999998E-5
-1.083	3.4856E-5
-1.0820000000000001	3.4981000000000003E-5
-1.081	3.4909000000000001E-5
-1.08	3.4891999999999997E-5
-1.079	3.5017E-5
-1.0780000000000001	3.5052999999999998E-5
-1.077	3.4999000000000002E-5
-1.0760000000000001	3.5105999999999999E-5
-1.075	3.5169000000000002E-5
-1.0740000000000001	3.5187E-5
-1.073	3.5222999999999998E-5
-1.0720000000000001	3.5293999999999998E-5
-1.071	3.5249000000000001E-5
-1.07	3.5249000000000001E-5
-1.069	3.5275999999999999E-5
-1.0680000000000001	3.5222999999999998E-5
-1.0669999999999999	3.5222999999999998E-5
-1.0660000000000001	3.5330000000000002E-5
-1.0649999999999999	3.5330000000000002E-5
-1.0640000000000001	3.5366E-5
-1.0629999999999999	3.5500000000000002E-5
-1.0620000000000001	3.5598E-5
-1.0609999999999999	3.5527000000000001E-5
-1.06	3.5527000000000001E-5
-1.0589999999999999	3.5580000000000002E-5
-1.0580000000000001	3.5553000000000003E-5
-1.0569999999999999	3.5651999999999997E-5
-1.056	3.5670000000000002E-5
-1.0549999999999999	3.5536E-5
-1.054	3.5633999999999998E-5
-1.0529999999999999	3.5732000000000003E-5
-1.052	3.5697000000000001E-5
-1.0509999999999999	3.5750000000000002E-5
-1.05	3.5831000000000003E-5
-1.0489999999999999	3.5849000000000002E-5
-1.048	3.5920000000000002E-5
-1.0469999999999999	3.5911000000000002E-5
-1.046	3.5831000000000003E-5
-1.0449999999999999	3.5867000000000001E-5
-1.044	3.6028000000000001E-5
-1.0429999999999999	3.6099000000000001E-5
-1.042	3.5964999999999999E-5
-1.0409999999999999	3.6010000000000003E-5
-1.04	3.6108000000000001E-5
-1.0389999999999999	3.6044999999999998E-5
-1.038	3.6062999999999997E-5
-1.0369999999999999	3.6196999999999999E-5
-1.036	3.6171000000000003E-5
-1.0349999999999999	3.6196999999999999E-5
-1.034	3.6313999999999998E-5
-1.0329999999999999	3.6260000000000002E-5
-1.032	3.6251000000000002E-5
-1.0309999999999999	3.6375999999999999E-5
-1.03	3.6457E-5
-1.0289999999999999	3.6689000000000001E-5
-1.028	3.6528E-5
-1.0269999999999999	3.6483999999999998E-5
-1.026	3.6536999999999999E-5
-1.0249999999999999	3.6536999999999999E-5
-1.024	3.6600000000000002E-5
-1.0229999999999999	3.6554999999999998E-5
-1.022	3.6600000000000002E-5
-1.0209999999999999	3.6636E-5
-1.02	3.6618000000000001E-5
-1.0189999999999999	3.6618000000000001E-5
-1.018	3.6742999999999997E-5
-1.0169999999999999	3.6706999999999999E-5
-1.016	3.6680000000000001E-5
-1.0149999999999999	3.6761000000000003E-5
-1.014	3.6724999999999998E-5
-1.0129999999999999	3.6788000000000001E-5
-1.012	3.6885999999999999E-5
-1.0109999999999999	3.6868E-5
-1.01	3.6885999999999999E-5
-1.0089999999999999	3.6949000000000001E-5
-1.008	3.6949000000000001E-5
-1.0069999999999999	3.6912999999999997E-5
-1.006	3.6993999999999999E-5
-1.0049999999999999	3.7038E-5
-1.004	3.6984999999999999E-5
-1.0029999999999999	3.6993999999999999E-5
-1.002	3.7055999999999999E-5
-1.0009999999999999	3.7092000000000003E-5
-1	3.7128000000000001E-5
-0.999	3.7154999999999999E-5
-0.998	3.7199000000000001E-5
-0.997	3.7208E-5
-0.996	3.7307E-5
-0.995	3.7298000000000001E-5
-0.99399999999999999	3.7271000000000003E-5
-0.99299999999999999	3.7351000000000002E-5
-0.99199999999999999	3.7387E-5
-0.99099999999999999	3.7271000000000003E-5
-0.99	3.7307E-5
-0.98899999999999999	3.7413999999999998E-5
-0.98799999999999999	3.7360000000000001E-5
-0.98699999999999999	3.7369000000000001E-5
-0.98599999999999999	3.7459000000000002E-5
-0.98499999999999999	3.7503000000000003E-5
-0.98399999999999999	3.7548E-5
-0.98299999999999998	3.7601999999999997E-5
-0.98199999999999998	3.7565999999999999E-5
-0.98099999999999998	3.7539000000000001E-5
-0.98	3.7654999999999998E-5
-0.97899999999999998	3.7735999999999999E-5
-0.97799999999999998	3.7682000000000003E-5
-0.97699999999999998	3.7727E-5
-0.97599999999999998	3.7753999999999998E-5
-0.97499999999999998	3.7620000000000002E-5
-0.97399999999999998	3.7700000000000002E-5
-0.97299999999999998	3.7709000000000001E-5
-0.97199999999999998	3.7790000000000002E-5
-0.97099999999999997	3.7861000000000002E-5
-0.97	3.7905999999999999E-5
-0.96899999999999997	3.7861000000000002E-5
-0.96799999999999997	3.7914999999999999E-5
-0.96699999999999997	3.7932999999999997E-5
-0.96599999999999997	3.7932999999999997E-5
-0.96499999999999997	3.7806999999999999E-5
-0.96399999999999997	3.7888E-5
-0.96299999999999997	3.7959E-5
-0.96199999999999997	3.8003999999999997E-5
-0.96099999999999997	3.7994999999999998E-5
-0.96	3.8012999999999997E-5
-0.95899999999999996	3.8022000000000003E-5
-0.95799999999999996	3.8102999999999998E-5
-0.95699999999999996	3.8102999999999998E-5
-0.95599999999999996	3.8102999999999998E-5
-0.95499999999999996	3.8192000000000003E-5
-0.95399999999999996	3.8219000000000001E-5
-0.95299999999999996	3.8182999999999997E-5
-0.95199999999999996	3.8084999999999999E-5
-0.95099999999999996	3.8164999999999998E-5
-0.95	3.8228000000000001E-5
-0.94899999999999995	3.8192000000000003E-5
-0.94799999999999995	3.8254999999999999E-5
-0.94699999999999995	3.8316999999999999E-5
-0.94599999999999995	3.8245999999999999E-5
-0.94499999999999995	3.8334999999999998E-5
-0.94399999999999995	3.8398000000000001E-5
-0.94299999999999995	3.8228000000000001E-5
-0.94199999999999995	3.8343999999999997E-5
-0.94099999999999995	3.8415999999999999E-5
-0.94	3.8371000000000002E-5
-0.93899999999999995	3.8343999999999997E-5
-0.93799999999999994	3.8433999999999998E-5
-0.93700000000000006	3.8398000000000001E-5
-0.93600000000000005	3.8433999999999998E-5
-0.93500000000000005	3.8469E-5
-0.93400000000000005	3.8504999999999998E-5
-0.93300000000000005	3.8522999999999997E-5
-0.93200000000000005	3.8495999999999999E-5
-0.93100000000000005	3.8513999999999998E-5
-0.93	3.8577E-5
-0.92900000000000005	3.8594999999999999E-5
-0.92800000000000005	3.8603000000000003E-5
-0.92700000000000005	3.8872000000000003E-5
-0.92600000000000005	3.8835999999999999E-5
-0.92500000000000004	3.8747E-5
-0.92400000000000004	3.8683999999999998E-5
-0.92300000000000004	3.8674999999999998E-5
-0.92200000000000004	3.8747E-5
-0.92100000000000004	3.8747E-5
-0.92	3.8692999999999997E-5
-0.91900000000000004	3.8756E-5
-0.91800000000000004	3.8835999999999999E-5
-0.91700000000000004	3.8738000000000001E-5
-0.91600000000000004	3.8800000000000001E-5
-0.91500000000000004	3.8818E-5
-0.91400000000000003	3.8683999999999998E-5
-0.91300000000000003	3.8763999999999997E-5
-0.91200000000000003	3.8844999999999998E-5
-0.91100000000000003	3.8747E-5
-0.91	3.8800000000000001E-5
-0.90900000000000003	3.8908000000000001E-5
-0.90800000000000003	3.8943000000000003E-5
-0.90700000000000003	3.8924999999999997E-5
-0.90600000000000003	3.8908000000000001E-5
-0.90500000000000003	3.8924999999999997E-5
-0.90400000000000003	3.8872000000000003E-5
-0.90300000000000002	3.8872000000000003E-5
-0.90200000000000002	3.8979000000000001E-5
-0.90100000000000002	3.8872000000000003E-5
-0.9	3.8961000000000002E-5
-0.89900000000000002	3.9042000000000003E-5
-0.89800000000000002	3.8881000000000003E-5
-0.89700000000000002	3.8933999999999997E-5
-0.89600000000000002	3.9069000000000002E-5
-0.89500000000000002	3.9005999999999999E-5
-0.89400000000000002	3.9078000000000001E-5
-0.89300000000000002	3.9023999999999998E-5
-0.89200000000000002	3.9032999999999997E-5
-0.89100000000000001	3.9051000000000003E-5
-0.89	3.9103999999999997E-5
-0.88900000000000001	3.9032999999999997E-5
-0.88800000000000001	3.8952000000000002E-5
-0.88700000000000001	3.9051000000000003E-5
-0.88600000000000001	3.9122000000000003E-5
-0.88500000000000001	3.9140000000000001E-5
-0.88400000000000001	3.9167E-5
-0.88300000000000001	3.9122000000000003E-5
-0.88200000000000001	3.9113000000000003E-5
-0.88100000000000001	3.9140000000000001E-5
-0.88	3.9212000000000003E-5
-0.879	3.9175999999999999E-5
-0.878	3.9202999999999997E-5
-0.877	3.9167E-5
-0.876	3.9158E-5
-0.875	3.9184999999999998E-5
-0.874	3.9140000000000001E-5
-0.873	3.9202999999999997E-5
-0.872	3.9255999999999998E-5
-0.871	3.9328E-5
-0.87	3.9264999999999998E-5
-0.86899999999999999	3.9239000000000002E-5
-0.86799999999999999	3.9301000000000002E-5
-0.86699999999999999	3.9337E-5
-0.86599999999999999	3.9301000000000002E-5
-0.86499999999999999	3.9239000000000002E-5
-0.86399999999999999	3.9273999999999997E-5
-0.86299999999999999	3.9255999999999998E-5
-0.86199999999999999	3.9273999999999997E-5
-0.86099999999999999	3.9283000000000003E-5
-0.86	3.9255999999999998E-5
-0.85899999999999999	3.9345999999999999E-5
-0.85799999999999998	3.9363999999999998E-5
-0.85699999999999998	3.9363999999999998E-5
-0.85599999999999998	3.9319000000000001E-5
-0.85499999999999998	3.9363999999999998E-5
-0.85399999999999998	3.9345999999999999E-5
-0.85299999999999998	3.9255999999999998E-5
-0.85199999999999998	3.9292000000000003E-5
-0.85099999999999998	3.9319000000000001E-5
-0.85	3.9246999999999999E-5
-0.84899999999999998	3.9283000000000003E-5
-0.84799999999999998	3.9328E-5
-0.84699999999999998	3.9310000000000001E-5
-0.84599999999999997	3.9381999999999997E-5
-0.84499999999999997	3.9425999999999998E-5
-0.84399999999999997	3.9443999999999997E-5
-0.84299999999999997	3.9391000000000003E-5
-0.84199999999999997	3.9337E-5
-0.84099999999999997	3.9337E-5
-0.84	3.9434999999999998E-5
-0.83899999999999997	3.9471000000000002E-5
-0.83799999999999997	3.9391000000000003E-5
-0.83699999999999997	3.9301000000000002E-5
-0.83599999999999997	3.9372999999999997E-5
-0.83499999999999996	3.9425999999999998E-5
-0.83399999999999996	3.9363999999999998E-5
-0.83299999999999996	3.9372999999999997E-5
-0.83199999999999996	3.9443999999999997E-5
-0.83099999999999996	3.9416999999999999E-5
-0.83	3.9416999999999999E-5
-0.82899999999999996	3.9434999999999998E-5
-0.82799999999999996	3.9434999999999998E-5
-0.82699999999999996	3.9400000000000002E-5
-0.82599999999999996	3.9434999999999998E-5
-0.82499999999999996	3.9542999999999997E-5
-0.82399999999999995	3.9703999999999998E-5
-0.82299999999999995	3.9578E-5
-0.82199999999999995	3.9524999999999999E-5
-0.82099999999999995	3.9425999999999998E-5
-0.82	3.9443999999999997E-5
-0.81899999999999995	3.9507E-5
-0.81799999999999995	3.9489000000000001E-5
-0.81699999999999995	3.9515999999999999E-5
-0.81599999999999995	3.9507E-5
-0.81499999999999995	3.9391000000000003E-5
-0.81399999999999995	3.9507E-5
-0.81299999999999994	3.9507E-5
-0.81200000000000006	3.9416999999999999E-5
-0.81100000000000005	3.9489000000000001E-5
-0.81	3.9489000000000001E-5
-0.80900000000000005	3.9471000000000002E-5
-0.80800000000000005	3.9434999999999998E-5
-0.80700000000000005	3.9480000000000001E-5
-0.80600000000000005	3.9425999999999998E-5
-0.80500000000000005	3.9443999999999997E-5
-0.80400000000000005	3.9489000000000001E-5
-0.80300000000000005	3.9498E-5
-0.80200000000000005	3.9416999999999999E-5
-0.80100000000000005	3.9480000000000001E-5
-0.8	3.9507E-5
-0.79900000000000004	3.9407999999999999E-5
-0.79800000000000004	3.9372999999999997E-5
-0.79700000000000004	3.9381999999999997E-5
-0.79600000000000004	3.9425999999999998E-5
-0.79500000000000004	3.9416999999999999E-5
-0.79400000000000004	3.9515999999999999E-5
-0.79300000000000004	3.9542999999999997E-5
-0.79200000000000004	3.9400000000000002E-5
-0.79100000000000004	3.9507E-5
-0.79	3.9480000000000001E-5
-0.78900000000000003	3.9400000000000002E-5
-0.78800000000000003	3.9425999999999998E-5
-0.78700000000000003	3.9400000000000002E-5
-0.78600000000000003	3.9363999999999998E-5
-0.78500000000000003	3.9453000000000003E-5
-0.78400000000000003	3.9471000000000002E-5
-0.78300000000000003	3.9434999999999998E-5
-0.78200000000000003	3.9453000000000003E-5
-0.78100000000000003	3.9425999999999998E-5
-0.78	3.9453000000000003E-5
-0.77900000000000003	3.9489000000000001E-5
-0.77800000000000002	3.9471000000000002E-5
-0.77700000000000002	3.9462000000000003E-5
-0.77600000000000002	3.9372999999999997E-5
-0.77500000000000002	3.9416999999999999E-5
-0.77400000000000002	3.9462000000000003E-5
-0.77300000000000002	3.9471000000000002E-5
-0.77200000000000002	3.9434999999999998E-5
-0.77100000000000002	3.9453000000000003E-5
-0.77	3.9372999999999997E-5
-0.76900000000000002	3.9345999999999999E-5
-0.76800000000000002	3.9462000000000003E-5
-0.76700000000000002	3.9381999999999997E-5
-0.76600000000000001	3.9372999999999997E-5
-0.76500000000000001	3.9434999999999998E-5
-0.76400000000000001	3.9443999999999997E-5
-0.76300000000000001	3.9391000000000003E-5
-0.76200000000000001	3.9345999999999999E-5
-0.76100000000000001	3.9337E-5
-0.76	3.9292000000000003E-5
-0.75900000000000001	3.9425999999999998E-5
-0.75800000000000001	3.9391000000000003E-5
-0.75700000000000001	3.9337E-5
-0.75600000000000001	3.9319000000000001E-5
-0.755	3.9425999999999998E-5
-0.754	3.9400000000000002E-5
-0.753	3.9345999999999999E-5
-0.752	3.9381999999999997E-5
-0.751	3.9337E-5
-0.75	3.9310000000000001E-5
-0.749	3.9354999999999998E-5
-0.748	3.9239000000000002E-5
-0.747	3.9255999999999998E-5
-0.746	3.9292000000000003E-5
-0.745	3.9319000000000001E-5
-0.74399999999999999	3.9255999999999998E-5
-0.74299999999999999	3.9310000000000001E-5
-0.74199999999999999	3.9264999999999998E-5
-0.74099999999999999	3.9283000000000003E-5
-0.74	3.9337E-5
-0.73899999999999999	3.9328E-5
-0.73799999999999999	3.9230000000000002E-5
-0.73699999999999999	3.9283000000000003E-5
-0.73599999999999999	3.9301000000000002E-5
-0.73499999999999999	3.9122000000000003E-5
-0.73399999999999999	3.9193999999999998E-5
-0.73299999999999998	3.9246999999999999E-5
-0.73199999999999998	3.9264999999999998E-5
-0.73099999999999998	3.9202999999999997E-5
-0.73	3.9264999999999998E-5
-0.72899999999999998	3.9255999999999998E-5
-0.72799999999999998	3.9255999999999998E-5
-0.72699999999999998	3.9255999999999998E-5
-0.72599999999999998	3.9131000000000002E-5
-0.72499999999999998	3.9140000000000001E-5
-0.72399999999999998	3.9212000000000003E-5
-0.72299999999999998	3.9184999999999998E-5
-0.72199999999999998	3.9416999999999999E-5
-0.72099999999999997	3.9292000000000003E-5
-0.72	3.9230000000000002E-5
-0.71899999999999997	3.9175999999999999E-5
-0.71799999999999997	3.9230000000000002E-5
-0.71699999999999997	3.9221000000000003E-5
-0.71599999999999997	3.9175999999999999E-5
-0.71499999999999997	3.9140000000000001E-5
-0.71399999999999997	3.9167E-5
-0.71299999999999997	3.9140000000000001E-5
-0.71199999999999997	3.9060000000000002E-5
-0.71099999999999997	3.9131000000000002E-5
-0.71	3.9131000000000002E-5
-0.70899999999999996	3.8996999999999999E-5
-0.70799999999999996	3.9069000000000002E-5
-0.70699999999999996	3.9113000000000003E-5
-0.70599999999999996	3.9032999999999997E-5
-0.70499999999999996	3.9149000000000001E-5
-0.70399999999999996	3.9122000000000003E-5
-0.70299999999999996	3.9051000000000003E-5
-0.70199999999999996	3.9051000000000003E-5
-0.70099999999999996	3.9032999999999997E-5
-0.7	3.9051000000000003E-5
-0.69899999999999995	3.9032999999999997E-5
-0.69799999999999995	3.9005999999999999E-5
-0.69699999999999995	3.8943000000000003E-5
-0.69599999999999995	3.8899000000000001E-5
-0.69499999999999995	3.8961000000000002E-5
-0.69399999999999995	3.8924999999999997E-5
-0.69299999999999995	3.8890000000000002E-5
-0.69199999999999995	3.8899000000000001E-5
-0.69099999999999995	3.8943000000000003E-5
-0.69	3.8943000000000003E-5
-0.68899999999999995	3.8970000000000001E-5
-0.68799999999999994	3.8933999999999997E-5
-0.68700000000000006	3.8917E-5
-0.68600000000000005	3.8924999999999997E-5
-0.68500000000000005	3.8908000000000001E-5
-0.68400000000000005	3.8800000000000001E-5
-0.68300000000000005	3.8738000000000001E-5
-0.68200000000000005	3.8826999999999999E-5
-0.68100000000000005	3.8782000000000002E-5
-0.68	3.8756E-5
-0.67900000000000005	3.8908000000000001E-5
-0.67800000000000005	3.8899000000000001E-5
-0.67700000000000005	3.8809000000000001E-5
-0.67600000000000005	3.8826999999999999E-5
-0.67500000000000004	3.8835999999999999E-5
-0.67400000000000004	3.8747E-5
-0.67300000000000004	3.8738000000000001E-5
-0.67200000000000004	3.8738000000000001E-5
-0.67100000000000004	3.8738000000000001E-5
-0.67	3.8756E-5
-0.66900000000000004	3.8756E-5
-0.66800000000000004	3.8711000000000003E-5
-0.66700000000000004	3.8692999999999997E-5
-0.66600000000000004	3.8674999999999998E-5
-0.66500000000000004	3.8702000000000003E-5
-0.66400000000000003	3.8711000000000003E-5
-0.66300000000000003	3.8674999999999998E-5
-0.66200000000000003	3.8665999999999999E-5
-0.66100000000000003	3.8594999999999999E-5
-0.66	3.8594999999999999E-5
-0.65900000000000003	3.8612000000000002E-5
-0.65800000000000003	3.8550000000000002E-5
-0.65700000000000003	3.8594999999999999E-5
-0.65600000000000003	3.8603000000000003E-5
-0.65500000000000003	3.8541000000000003E-5
-0.65400000000000003	3.8559000000000001E-5
-0.65300000000000002	3.8513999999999998E-5
-0.65200000000000002	3.8577E-5
-0.65100000000000002	3.8532000000000003E-5
-0.65	3.8478E-5
-0.64900000000000002	3.8495999999999999E-5
-0.64800000000000002	3.8478E-5
-0.64700000000000002	3.8460000000000001E-5
-0.64600000000000002	3.8415999999999999E-5
-0.64500000000000002	3.8325999999999999E-5
-0.64400000000000002	3.8424999999999999E-5
-0.64300000000000002	3.8495999999999999E-5
-0.64200000000000002	3.8325999999999999E-5
-0.64100000000000001	3.8424999999999999E-5
-0.64	3.8398000000000001E-5
-0.63900000000000001	3.8281000000000002E-5
-0.63800000000000001	3.8352999999999997E-5
-0.63700000000000001	3.8352999999999997E-5
-0.63600000000000001	3.8299E-5
-0.63500000000000001	3.8389000000000001E-5
-0.63400000000000001	3.8352999999999997E-5
-0.63300000000000001	3.8254999999999999E-5
-0.63200000000000001	3.8129E-5
-0.63100000000000001	3.8219000000000001E-5
-0.63	3.8272999999999998E-5
-0.629	3.8237E-5
-0.628	3.8245999999999999E-5
-0.627	3.8245999999999999E-5
-0.626	3.8146999999999999E-5
-0.625	3.8182999999999997E-5
-0.624	3.8210000000000002E-5
-0.623	3.8129E-5
-0.622	3.8120000000000001E-5
-0.621	3.8138E-5
-0.62	3.8308E-5
-0.61899999999999999	3.8325999999999999E-5
-0.61799999999999999	3.8164999999999998E-5
-0.61699999999999999	3.8146999999999999E-5
-0.61599999999999999	3.8067E-5
-0.61499999999999999	3.8058000000000001E-5
-0.61399999999999999	3.8003999999999997E-5
-0.61299999999999999	3.7951000000000003E-5
-0.61199999999999999	3.7985999999999998E-5
-0.61099999999999999	3.8003999999999997E-5
-0.61	3.7959E-5
-0.60899999999999999	3.7976999999999999E-5
-0.60799999999999998	3.7941999999999997E-5
-0.60699999999999998	3.7879000000000001E-5
-0.60599999999999998	3.7852000000000003E-5
-0.60499999999999998	3.7888E-5
-0.60399999999999998	3.7806999999999999E-5
-0.60299999999999998	3.7888E-5
-0.60199999999999998	3.7870000000000002E-5
-0.60099999999999998	3.7781000000000003E-5
-0.6	3.7833999999999997E-5
-0.59899999999999998	3.7815999999999998E-5
-0.59799999999999998	3.7824999999999998E-5
-0.59699999999999998	3.7663999999999997E-5
-0.59599999999999997	3.7654999999999998E-5
-0.59499999999999997	3.7735999999999999E-5
-0.59399999999999997	3.7645999999999998E-5
-0.59299999999999997	3.7682000000000003E-5
-0.59199999999999997	3.7645999999999998E-5
-0.59099999999999997	3.7565999999999999E-5
-0.59	3.7629000000000002E-5
-0.58899999999999997	3.7645999999999998E-5
-0.58799999999999997	3.7601999999999997E-5
-0.58699999999999997	3.7636999999999999E-5
-0.58599999999999997	3.7611000000000003E-5
-0.58499999999999996	3.7530000000000002E-5
-0.58399999999999996	3.7459000000000002E-5
-0.58299999999999996	3.7493999999999997E-5
-0.58199999999999996	3.7503000000000003E-5
-0.58099999999999996	3.7395999999999999E-5
-0.57999999999999996	3.7404999999999998E-5
-0.57899999999999996	3.7413999999999998E-5
-0.57799999999999996	3.7360000000000001E-5
-0.57699999999999996	3.7413999999999998E-5
-0.57599999999999996	3.7404999999999998E-5
-0.57499999999999996	3.7351000000000002E-5
-0.57399999999999995	3.7298000000000001E-5
-0.57299999999999995	3.7378E-5
-0.57199999999999995	3.7307E-5
-0.57099999999999995	3.7243999999999998E-5
-0.56999999999999995	3.7307E-5
-0.56899999999999995	3.6912999999999997E-5
-0.56799999999999995	3.6572999999999997E-5
-0.56699999999999995	3.6912999999999997E-5
-0.56599999999999995	3.7038E-5
-0.56499999999999995	3.7038E-5
-0.56399999999999995	3.7055999999999999E-5
-0.56299999999999994	3.7073999999999998E-5
-0.56200000000000006	3.7029000000000001E-5
-0.56100000000000005	3.7055999999999999E-5
-0.56000000000000005	3.7073999999999998E-5
-0.55900000000000005	3.6912999999999997E-5
-0.55800000000000005	3.6967E-5
-0.55700000000000005	3.7011000000000002E-5
-0.55600000000000005	3.6894999999999998E-5
-0.55500000000000005	3.6859000000000001E-5
-0.55400000000000005	3.6894999999999998E-5
-0.55300000000000005	3.6868E-5
-0.55200000000000005	3.6832999999999998E-5
-0.55100000000000005	3.6806E-5
-0.55000000000000004	3.6770000000000002E-5
-0.54900000000000004	3.6761000000000003E-5
-0.54800000000000004	3.6841000000000002E-5
-0.54700000000000004	3.6823999999999998E-5
-0.54600000000000004	3.6689000000000001E-5
-0.54500000000000004	3.6671999999999997E-5
-0.54400000000000004	3.6706999999999999E-5
-0.54300000000000004	3.6572999999999997E-5
-0.54200000000000004	3.6519000000000001E-5
-0.54100000000000004	3.6582000000000003E-5
-0.54	3.6582000000000003E-5
-0.53900000000000003	3.6545999999999999E-5
-0.53800000000000003	3.6572999999999997E-5
-0.53700000000000003	3.6511000000000003E-5
-0.53600000000000003	3.6430000000000002E-5
-0.53500000000000003	3.6511000000000003E-5
-0.53400000000000003	3.6536999999999999E-5
-0.53300000000000003	3.6402999999999997E-5
-0.53200000000000003	3.6366999999999999E-5
-0.53100000000000003	3.6350000000000003E-5
-0.53	3.6223999999999997E-5
-0.52900000000000003	3.6313999999999998E-5
-0.52800000000000002	3.6322999999999998E-5
-0.52700000000000002	3.6223999999999997E-5
-0.52600000000000002	3.6242000000000003E-5
-0.52500000000000002	3.6278000000000001E-5
-0.52400000000000002	3.6214999999999998E-5
-0.52300000000000002	3.6189000000000002E-5
-0.52200000000000002	3.6117E-5
-0.52100000000000002	3.6062999999999997E-5
-0.52	3.6062999999999997E-5
-0.51900000000000002	3.6090000000000002E-5
-0.51800000000000002	3.6171000000000003E-5
-0.51700000000000002	3.6223999999999997E-5
-0.51600000000000001	3.6108000000000001E-5
-0.51500000000000001	3.6019000000000002E-5
-0.51400000000000001	3.5920000000000002E-5
-0.51300000000000001	3.5964999999999999E-5
-0.51200000000000001	3.5920000000000002E-5
-0.51100000000000001	3.5883999999999997E-5
-0.51	3.5867000000000001E-5
-0.50900000000000001	3.5867000000000001E-5
-0.50800000000000001	3.5768E-5
-0.50700000000000001	3.5713999999999997E-5
-0.50600000000000001	3.5777E-5
-0.505	3.5697000000000001E-5
-0.504	3.5615999999999999E-5
-0.503	3.5633999999999998E-5
-0.502	3.5642999999999997E-5
-0.501	3.5544999999999999E-5
-0.5	3.5509000000000002E-5
-0.499	3.5562000000000003E-5
-0.498	3.5509000000000002E-5
-0.497	3.5454999999999999E-5
-0.496	3.5454999999999999E-5
-0.495	3.5392000000000003E-5
-0.49399999999999999	3.5410000000000001E-5
-0.49299999999999999	3.5419000000000001E-5
-0.49199999999999999	3.5311999999999997E-5
-0.49099999999999999	3.5258E-5
-0.49	3.5357E-5
-0.48899999999999999	3.5258E-5
-0.48799999999999999	3.5240000000000001E-5
-0.48699999999999999	3.5204999999999999E-5
-0.48599999999999999	3.5132999999999997E-5
-0.48499999999999999	3.5123999999999998E-5
-0.48399999999999999	3.5169000000000002E-5
-0.48299999999999998	3.5114999999999998E-5
-0.48199999999999998	3.5026E-5
-0.48099999999999998	3.5052999999999998E-5
-0.48	3.4999000000000002E-5
-0.47899999999999998	3.4953999999999998E-5
-0.47799999999999998	3.4918E-5
-0.47699999999999998	3.4909000000000001E-5
-0.47599999999999998	3.4909000000000001E-5
-0.47499999999999998	3.4829000000000001E-5
-0.47399999999999998	3.4829000000000001E-5
-0.47299999999999998	3.4829000000000001E-5
-0.47199999999999998	3.4802000000000003E-5
-0.47099999999999997	3.4774999999999998E-5
-0.47	3.4765999999999999E-5
-0.46899999999999997	3.4703999999999998E-5
-0.46800000000000003	3.4668000000000001E-5
-0.46700000000000003	3.4622999999999997E-5
-0.46600000000000003	3.4650000000000002E-5
-0.46500000000000002	3.4686E-5
-0.46400000000000002	3.4613999999999998E-5
-0.46300000000000002	3.4462000000000003E-5
-0.46200000000000002	3.4489000000000001E-5
-0.46100000000000002	3.4507E-5
-0.46	3.4471000000000003E-5
-0.45900000000000002	3.4452999999999997E-5
-0.45800000000000002	3.4443999999999998E-5
-0.45700000000000002	3.4409000000000002E-5
-0.45600000000000002	3.4337E-5
-0.45500000000000002	3.4372999999999998E-5
-0.45400000000000001	3.4310000000000002E-5
-0.45300000000000001	3.4175999999999999E-5
-0.45200000000000001	3.4202999999999998E-5
-0.45100000000000001	3.4273999999999997E-5
-0.45	3.4202999999999998E-5
-0.44900000000000001	3.4131000000000002E-5
-0.44800000000000001	3.4158000000000001E-5
-0.44700000000000001	3.4112999999999997E-5
-0.44600000000000001	3.4158000000000001E-5
-0.44500000000000001	3.4069000000000002E-5
-0.44400000000000001	3.3988000000000001E-5
-0.443	3.3961000000000002E-5
-0.442	3.3988000000000001E-5
-0.441	3.3899000000000002E-5
-0.44	3.3844999999999999E-5
-0.439	3.3871999999999997E-5
-0.438	3.3809000000000001E-5
-0.437	3.3827E-5
-0.436	3.3818E-5
-0.435	3.3844999999999999E-5
-0.434	3.3756E-5
-0.433	3.3756E-5
-0.432	3.3773999999999999E-5
-0.43099999999999999	3.3683999999999998E-5
-0.43	3.3701999999999997E-5
-0.42899999999999999	3.3639000000000001E-5
-0.42799999999999999	3.3577000000000001E-5
-0.42699999999999999	3.3568000000000001E-5
-0.42599999999999999	3.3586E-5
-0.42499999999999999	3.3513999999999998E-5
-0.42399999999999999	3.3469000000000001E-5
-0.42299999999999999	3.3541000000000003E-5
-0.42199999999999999	3.3495999999999999E-5
-0.42099999999999999	3.3451999999999998E-5
-0.42	3.3495999999999999E-5
-0.41899999999999998	3.3442999999999998E-5
-0.41799999999999998	3.3308E-5
-0.41699999999999998	3.3389000000000002E-5
-0.41599999999999998	3.3352999999999997E-5
-0.41499999999999998	3.3460999999999997E-5
-0.41399999999999998	3.3416E-5
-0.41299999999999998	3.3290999999999997E-5
-0.41199999999999998	3.3237E-5
-0.41099999999999998	3.3254999999999999E-5
-0.41	3.3237E-5
-0.40899999999999997	3.3210000000000002E-5
-0.40799999999999997	3.3182999999999997E-5
-0.40699999999999997	3.3173999999999998E-5
-0.40600000000000003	3.3120999999999997E-5
-0.40500000000000003	3.3076E-5
-0.40400000000000003	3.3076E-5
-0.40300000000000002	3.3084999999999999E-5
-0.40200000000000002	3.2985999999999999E-5
-0.40100000000000002	3.3022000000000003E-5
-0.4	3.3012999999999997E-5
-0.39900000000000002	3.2879000000000001E-5
-0.39800000000000002	3.2906E-5
-0.39700000000000002	3.2978000000000002E-5
-0.39600000000000002	3.2932999999999998E-5
-0.39500000000000002	3.2906E-5
-0.39400000000000002	3.2888000000000001E-5
-0.39300000000000002	3.2824999999999998E-5
-0.39200000000000002	3.2808000000000002E-5
-0.39100000000000001	3.2852000000000003E-5
-0.39	3.2808000000000002E-5
-0.38900000000000001	3.2647000000000001E-5
-0.38800000000000001	3.2691000000000003E-5
-0.38700000000000001	3.2744999999999999E-5
-0.38600000000000001	3.2672999999999997E-5
-0.38500000000000001	3.2647000000000001E-5
-0.38400000000000001	3.2663999999999998E-5
-0.38300000000000001	3.2691000000000003E-5
-0.38200000000000001	3.2709000000000001E-5
-0.38100000000000001	3.2672999999999997E-5
-0.38	3.2592999999999998E-5
-0.379	3.2530000000000002E-5
-0.378	3.2592999999999998E-5
-0.377	3.2539000000000001E-5
-0.376	3.2512000000000003E-5
-0.375	3.2512000000000003E-5
-0.374	3.2566E-5
-0.373	3.2468000000000002E-5
-0.372	3.2450000000000003E-5
-0.371	3.2502999999999997E-5
-0.37	3.2477000000000001E-5
-0.36899999999999999	3.2486E-5
-0.36799999999999999	3.2441000000000003E-5
-0.36699999999999999	3.2396E-5
-0.36599999999999999	3.2369000000000001E-5
-0.36499999999999999	3.2404999999999999E-5
-0.36399999999999999	3.2459000000000002E-5
-0.36299999999999999	3.2486E-5
-0.36199999999999999	3.2441000000000003E-5
-0.36099999999999999	3.2369000000000001E-5
-0.36	3.2342000000000003E-5
-0.35899999999999999	3.2316E-5
-0.35799999999999998	3.2333999999999999E-5
-0.35699999999999998	3.2316E-5
-0.35599999999999998	3.2360000000000002E-5
-0.35499999999999998	3.2333999999999999E-5
-0.35399999999999998	3.2225999999999999E-5
-0.35299999999999998	3.2325E-5
-0.35199999999999998	3.2325E-5
-0.35099999999999998	3.2199000000000001E-5
-0.35	3.2252999999999998E-5
-0.34899999999999998	3.2307000000000001E-5
-0.34799999999999998	3.2208000000000001E-5
-0.34699999999999998	3.2243999999999998E-5
-0.34599999999999997	3.2280000000000003E-5
-0.34499999999999997	3.2280000000000003E-5
-0.34399999999999997	3.2243999999999998E-5
-0.34300000000000003	3.2181000000000002E-5
-0.34200000000000003	3.2217E-5
-0.34100000000000003	3.2217E-5
-0.34	3.2271000000000003E-5
-0.33900000000000002	3.2243999999999998E-5
-0.33800000000000002	3.2128000000000001E-5
-0.33700000000000002	3.2190000000000002E-5
-0.33600000000000002	3.2217E-5
-0.33500000000000002	3.2146E-5
-0.33400000000000002	3.2163999999999999E-5
-0.33300000000000002	3.2217E-5
-0.33200000000000002	3.2217E-5
-0.33100000000000002	3.2261999999999997E-5
-0.33	3.2234999999999999E-5
-0.32900000000000001	3.2199000000000001E-5
-0.32800000000000001	3.2190000000000002E-5
-0.32700000000000001	3.2234999999999999E-5
-0.32600000000000001	3.2190000000000002E-5
-0.32500000000000001	3.2172999999999998E-5
-0.32400000000000001	3.2199000000000001E-5
-0.32300000000000001	3.2225999999999999E-5
-0.32200000000000001	3.2208000000000001E-5
-0.32100000000000001	3.2225999999999999E-5
-0.32	3.2289000000000002E-5
-0.31900000000000001	3.2261999999999997E-5
-0.318	3.2208000000000001E-5
-0.317	3.2307000000000001E-5
-0.316	3.2271000000000003E-5
-0.315	3.2243999999999998E-5
-0.314	3.2289000000000002E-5
-0.313	3.2387E-5
-0.312	3.2495E-5
-0.311	3.2378000000000001E-5
-0.31	3.2413999999999998E-5
-0.309	3.2378000000000001E-5
-0.308	3.2396E-5
-0.307	3.2378000000000001E-5
-0.30599999999999999	3.2360000000000002E-5
-0.30499999999999999	3.2404999999999999E-5
-0.30399999999999999	3.2459000000000002E-5
-0.30299999999999999	3.2378000000000001E-5
-0.30199999999999999	3.2396E-5
-0.30099999999999999	3.2404999999999999E-5
-0.3	3.2404999999999999E-5
-0.29899999999999999	3.2378000000000001E-5
-0.29799999999999999	3.2495E-5
-0.29699999999999999	3.2486E-5
-0.29599999999999999	3.2468000000000002E-5
-0.29499999999999998	3.2539000000000001E-5
-0.29399999999999998	3.2566E-5
-0.29299999999999998	3.2574999999999999E-5
-0.29199999999999998	3.2574999999999999E-5
-0.29099999999999998	3.2611000000000003E-5
-0.28999999999999998	3.2592999999999998E-5
-0.28899999999999998	3.2647000000000001E-5
-0.28799999999999998	3.2691000000000003E-5
-0.28699999999999998	3.2592999999999998E-5
-0.28599999999999998	3.2656E-5
-0.28499999999999998	3.2682000000000003E-5
-0.28399999999999997	3.2691000000000003E-5
-0.28299999999999997	3.2753999999999998E-5
-0.28199999999999997	3.2799000000000002E-5
-0.28100000000000003	3.2771999999999997E-5
-0.28000000000000003	3.2842999999999997E-5
-0.27900000000000003	3.2842999999999997E-5
-0.27800000000000002	3.2852000000000003E-5
-0.27700000000000002	3.2817000000000001E-5
-0.27600000000000002	3.2629000000000002E-5
-0.27500000000000002	3.2477000000000001E-5
-0.27400000000000002	3.3031000000000003E-5
-0.27300000000000002	3.2897E-5
-0.27200000000000002	3.2870000000000002E-5
-0.27100000000000002	3.2994999999999998E-5
-0.27	3.2932999999999998E-5
-0.26900000000000002	3.3254999999999999E-5
-0.26800000000000002	3.3272999999999998E-5
-0.26700000000000002	3.3451999999999998E-5
-0.26600000000000001	3.3352999999999997E-5
-0.26500000000000001	3.3139000000000002E-5
-0.26400000000000001	3.3139000000000002E-5
-0.26300000000000001	3.3343999999999998E-5
-0.26200000000000001	3.3371000000000003E-5
-0.26100000000000001	3.3371000000000003E-5
-0.26	3.3416E-5
-0.25900000000000001	3.3433999999999999E-5
-0.25800000000000001	3.3352999999999997E-5
-0.25700000000000001	3.3495999999999999E-5
-0.25600000000000001	3.3531999999999997E-5
-0.255	3.3504999999999999E-5
-0.254	3.2941999999999997E-5
-0.253	3.3380000000000002E-5
-0.252	3.3908000000000001E-5
-0.251	3.3943999999999999E-5
-0.25	3.3853999999999998E-5
-0.249	3.3747000000000001E-5
-0.248	3.3738000000000001E-5
-0.247	3.3756E-5
-0.246	3.3862999999999997E-5
-0.245	3.3862999999999997E-5
-0.24399999999999999	3.3881000000000003E-5
-0.24299999999999999	3.3961000000000002E-5
-0.24199999999999999	3.3935E-5
-0.24099999999999999	3.4078000000000001E-5
-0.24	3.4112999999999997E-5
-0.23899999999999999	3.4105E-5
-0.23799999999999999	3.4158000000000001E-5
-0.23699999999999999	3.4221000000000003E-5
-0.23599999999999999	3.4158000000000001E-5
-0.23499999999999999	3.4230000000000003E-5
-0.23400000000000001	3.4319000000000001E-5
-0.23300000000000001	3.4400000000000003E-5
-0.23200000000000001	3.4345999999999999E-5
-0.23100000000000001	3.4391000000000003E-5
-0.23	3.4462000000000003E-5
-0.22900000000000001	3.4551999999999997E-5
-0.22800000000000001	3.4579000000000002E-5
-0.22700000000000001	3.4595999999999999E-5
-0.22600000000000001	3.4622999999999997E-5
-0.22500000000000001	3.4668000000000001E-5
-0.224	3.4756999999999999E-5
-0.223	3.4730999999999997E-5
-0.222	3.4792999999999997E-5
-0.221	3.4847E-5
-0.22	3.4882999999999998E-5
-0.219	3.4972000000000003E-5
-0.218	3.4999000000000002E-5
-0.217	3.5105999999999999E-5
-0.216	3.5114999999999998E-5
-0.215	3.5160000000000002E-5
-0.214	3.5222999999999998E-5
-0.21299999999999999	3.5213999999999999E-5
-0.21199999999999999	3.5267E-5
-0.21099999999999999	3.5437E-5
-0.21	3.5651999999999997E-5
-0.20899999999999999	3.5607E-5
-0.20799999999999999	3.5562000000000003E-5
-0.20699999999999999	3.5527000000000001E-5
-0.20599999999999999	3.5598E-5
-0.20499999999999999	3.5670000000000002E-5
-0.20399999999999999	3.5697000000000001E-5
-0.20300000000000001	3.5741000000000002E-5
-0.20200000000000001	3.5840000000000002E-5
-0.20100000000000001	3.5892999999999997E-5
-0.2	3.5849000000000002E-5
-0.19900000000000001	3.5964999999999999E-5
-0.19800000000000001	3.5982999999999998E-5
-0.19700000000000001	3.6010000000000003E-5
-0.19600000000000001	3.6117E-5
-0.19500000000000001	3.6189000000000002E-5
-0.19400000000000001	3.6180000000000003E-5
-0.193	3.6260000000000002E-5
-0.192	3.6341000000000003E-5
-0.191	3.6341000000000003E-5
-0.19	3.6402999999999997E-5
-0.189	3.6572999999999997E-5
-0.188	3.6511000000000003E-5
-0.187	3.6536999999999999E-5
-0.186	3.6689000000000001E-5
-0.185	3.6689000000000001E-5
-0.184	3.6698E-5
-0.183	3.6761000000000003E-5
-0.182	3.6868E-5
-0.18099999999999999	3.6868E-5
-0.18	3.6984999999999999E-5
-0.17899999999999999	3.7073999999999998E-5
-0.17799999999999999	3.7092000000000003E-5
-0.17699999999999999	3.7119000000000002E-5
-0.17599999999999999	3.7234999999999998E-5
-0.17499999999999999	3.7163000000000003E-5
-0.17399999999999999	3.7280000000000002E-5
-0.17299999999999999	3.7360000000000001E-5
-0.17199999999999999	3.7395999999999999E-5
-0.17100000000000001	3.7459000000000002E-5
-0.17	3.7539000000000001E-5
-0.16900000000000001	3.7583999999999998E-5
-0.16800000000000001	3.7645999999999998E-5
-0.16700000000000001	3.7762999999999997E-5
-0.16600000000000001	3.7852000000000003E-5
-0.16500000000000001	3.7861000000000002E-5
-0.16400000000000001	3.7932999999999997E-5
-0.16300000000000001	3.7968E-5
-0.16200000000000001	3.7985999999999998E-5
-0.161	3.8084999999999999E-5
-0.16	3.8120000000000001E-5
-0.159	3.8146999999999999E-5
-0.158	3.8237E-5
-0.157	3.8334999999999998E-5
-0.156	3.8371000000000002E-5
-0.155	3.8433999999999998E-5
-0.154	3.8541000000000003E-5
-0.153	3.8612000000000002E-5
-0.152	3.8648E-5
-0.151	3.8729000000000001E-5
-0.15	3.8747E-5
-0.14899999999999999	3.8782000000000002E-5
-0.14799999999999999	3.8862999999999997E-5
-0.14699999999999999	3.8970000000000001E-5
-0.14599999999999999	3.8899000000000001E-5
-0.14499999999999999	3.9023999999999998E-5
-0.14399999999999999	3.9158E-5
-0.14299999999999999	3.9167E-5
-0.14199999999999999	3.9230000000000002E-5
-0.14099999999999999	3.9363999999999998E-5
-0.14000000000000001	3.9372999999999997E-5
-0.13900000000000001	3.9453000000000003E-5
-0.13800000000000001	3.9551999999999997E-5
-0.13700000000000001	3.9561000000000003E-5
-0.13600000000000001	3.9613999999999997E-5
-0.13500000000000001	3.9641000000000002E-5
-0.13400000000000001	3.9765999999999998E-5
-0.13300000000000001	3.9694999999999999E-5
-0.13200000000000001	3.9838E-5
-0.13100000000000001	3.9891000000000001E-5
-0.13	3.9972000000000003E-5
-0.129	4.0105999999999999E-5
-0.128	4.0178000000000001E-5
-0.127	4.0213000000000003E-5
-0.126	4.0321000000000002E-5
-0.125	4.0348000000000001E-5
-0.124	4.0419E-5
-0.123	4.0553000000000003E-5
-0.122	4.0642999999999997E-5
-0.121	4.0606999999999999E-5
-0.12	4.0615999999999999E-5
-0.11899999999999999	4.0768E-5
-0.11799999999999999	4.0902000000000002E-5
-0.11700000000000001	4.0902000000000002E-5
-0.11600000000000001	4.0964999999999998E-5
-0.115	4.1099000000000001E-5
-0.114	4.1134999999999998E-5
-0.113	4.1233000000000003E-5
-0.112	4.1295999999999999E-5
-0.111	4.1278E-5
-0.11	4.1375999999999998E-5
-0.109	4.1457E-5
-0.108	4.1770000000000002E-5
-0.107	4.1885999999999998E-5
-0.106	4.1832000000000002E-5
-0.105	4.1859E-5
-0.104	4.1832000000000002E-5
-0.10299999999999999	4.1931000000000002E-5
-0.10199999999999999	4.2029E-5
-0.10100000000000001	4.2110000000000002E-5
-0.1	4.2172000000000002E-5
-9.9000000000000005E-2	4.2271000000000002E-5
-9.8000000000000004E-2	4.2333000000000003E-5
-9.7000000000000003E-2	4.2422999999999997E-5
-9.6000000000000002E-2	4.2475999999999998E-5
-9.5000000000000001E-2	4.2441000000000002E-5
-9.4E-2	4.2556999999999999E-5
-9.2999999999999999E-2	4.2753999999999998E-5
-9.1999999999999998E-2	4.2772000000000003E-5
-9.0999999999999998E-2	4.2815999999999998E-5
-0.09	4.2959E-5
-8.8999999999999996E-2	4.3102000000000002E-5
-8.7999999999999995E-2	4.3102000000000002E-5
-8.6999999999999994E-2	4.3192000000000003E-5
-8.5999999999999993E-2	4.3299E-5
-8.5000000000000006E-2	4.3334999999999998E-5
-8.4000000000000005E-2	4.3389000000000001E-5
-8.3000000000000004E-2	4.3504999999999998E-5
-8.2000000000000003E-2	4.3541000000000002E-5
-8.1000000000000003E-2	4.3594000000000003E-5
-0.08	4.3745999999999998E-5
-7.9000000000000001E-2	4.3809E-5
-7.8E-2	4.3934000000000003E-5
-7.6999999999999999E-2	4.4051000000000002E-5
-7.5999999999999998E-2	4.4067999999999999E-5
-7.4999999999999997E-2	4.4113000000000003E-5
-7.3999999999999996E-2	4.4319E-5
-7.2999999999999995E-2	4.4407999999999999E-5
-7.1999999999999995E-2	4.4416999999999998E-5
-7.0999999999999994E-2	4.4498E-5
-7.0000000000000007E-2	4.4586999999999998E-5
-6.9000000000000006E-2	4.4569E-5
-6.8000000000000005E-2	4.473E-5
-6.7000000000000004E-2	4.4829000000000001E-5
-6.6000000000000003E-2	4.4829000000000001E-5
-6.5000000000000002E-2	4.4981000000000002E-5
-6.4000000000000001E-2	4.5114999999999997E-5
-6.3E-2	4.5231000000000001E-5
-6.2E-2	4.5266999999999999E-5
-6.0999999999999999E-2	4.5364999999999997E-5
-0.06	4.5410000000000001E-5
-5.8999999999999997E-2	4.5482000000000003E-5
-5.8000000000000003E-2	4.5597999999999999E-5
-5.7000000000000002E-2	4.5652000000000003E-5
-5.6000000000000001E-2	4.5723000000000003E-5
-5.5E-2	4.5856999999999998E-5
-5.3999999999999999E-2	4.5946999999999999E-5
-5.2999999999999999E-2	4.5964999999999998E-5
-5.1999999999999998E-2	4.6063000000000003E-5
-5.0999999999999997E-2	4.617E-5
-0.05	4.6205999999999998E-5
-4.9000000000000002E-2	4.6286999999999999E-5
-4.8000000000000001E-2	4.6421000000000002E-5
-4.7E-2	4.6439E-5
-4.5999999999999999E-2	4.6591000000000002E-5
-4.4999999999999998E-2	4.668E-5
-4.3999999999999997E-2	4.668E-5
-4.2999999999999997E-2	4.6671000000000001E-5
-4.2000000000000003E-2	4.6805000000000003E-5
-4.1000000000000002E-2	4.6876999999999999E-5
-0.04	4.7002000000000002E-5
-3.9E-2	4.7092000000000002E-5
-3.7999999999999999E-2	4.7190000000000001E-5
-3.6999999999999998E-2	4.7207999999999999E-5
-3.5999999999999997E-2	4.7278999999999999E-5
-3.5000000000000003E-2	4.7423000000000003E-5
-3.4000000000000002E-2	4.7395999999999998E-5
-3.3000000000000002E-2	4.7503000000000002E-5
-3.2000000000000001E-2	4.7627999999999999E-5
-3.1E-2	4.7601E-5
-0.03	4.7682000000000002E-5
-2.9000000000000001E-2	4.7788999999999999E-5
-2.8000000000000001E-2	4.7852000000000002E-5
-2.7E-2	4.7896999999999999E-5
-2.5999999999999999E-2	4.7914000000000002E-5
-2.5000000000000001E-2	4.8075000000000003E-5
-2.4E-2	4.8128999999999999E-5
-2.3E-2	4.8192000000000002E-5
-2.1999999999999999E-2	4.8299E-5
-2.1000000000000001E-2	4.8307999999999999E-5
-0.02	4.8415000000000003E-5
-1.9E-2	4.8477999999999999E-5
-1.7999999999999999E-2	4.8405999999999997E-5
-1.7000000000000001E-2	4.8504999999999997E-5
-1.6E-2	4.8612000000000001E-5
-1.4999999999999999E-2	4.8647999999999999E-5
-1.4E-2	4.8727999999999998E-5
-1.2999999999999999E-2	4.8863000000000003E-5
-1.2E-2	4.8888999999999999E-5
-1.0999999999999999E-2	4.8961000000000001E-5
-0.01	4.9005999999999998E-5
-8.9999999999999993E-3	4.9085999999999997E-5
-8.0000000000000002E-3	4.9067999999999998E-5
-7.0000000000000001E-3	4.9166999999999999E-5
-6.0000000000000001E-3	4.9336999999999999E-5
-5.0000000000000001E-3	4.9577999999999999E-5
-4.0000000000000001E-3	4.9444000000000003E-5
-3.0000000000000001E-3	4.9497999999999999E-5
-2E-3	4.9444000000000003E-5
-1E-3	4.9497999999999999E-5
0	4.9577999999999999E-5
1E-3	4.9641000000000001E-5
2E-3	4.9756999999999998E-5
3.0000000000000001E-3	4.9820000000000001E-5
4.0000000000000001E-3	4.9855000000000003E-5
5.0000000000000001E-3	4.9836999999999997E-5
6.0000000000000001E-3	4.9864000000000002E-5
7.0000000000000001E-3	4.9908999999999999E-5
8.0000000000000002E-3	4.9864000000000002E-5
8.9999999999999993E-3	5.0034000000000002E-5
0.01	5.0142000000000002E-5
1.0999999999999999E-2	5.0034000000000002E-5
1.2E-2	5.0167999999999998E-5
1.2999999999999999E-2	5.0275999999999998E-5
1.4E-2	5.0346999999999998E-5
1.4999999999999999E-2	5.0392000000000001E-5
1.6E-2	5.0454999999999997E-5
1.7000000000000001E-2	5.0445999999999998E-5
1.7999999999999999E-2	5.0553000000000002E-5
1.9E-2	5.058E-5
0.02	5.0544000000000003E-5
2.1000000000000001E-2	5.0571000000000001E-5
2.1999999999999999E-2	5.0741000000000001E-5
2.3E-2	5.0732000000000001E-5
2.4E-2	5.0714000000000003E-5
2.5000000000000001E-2	5.0865999999999997E-5
2.5999999999999999E-2	5.0946999999999999E-5
2.7E-2	5.0991E-5
2.8000000000000001E-2	5.1044999999999997E-5
2.9000000000000001E-2	5.1107999999999999E-5
0.03	5.1072000000000002E-5
3.1E-2	5.1196999999999998E-5
3.2000000000000001E-2	5.1242000000000002E-5
3.3000000000000002E-2	5.1125000000000003E-5
3.4000000000000002E-2	5.1286000000000003E-5
3.5000000000000003E-2	5.134E-5
3.5999999999999997E-2	5.1322000000000001E-5
3.6999999999999998E-2	5.1465000000000003E-5
3.7999999999999999E-2	5.1616999999999997E-5
3.9E-2	5.1635000000000003E-5
0.04	5.1662000000000001E-5
4.1000000000000002E-2	5.1761000000000001E-5
4.2000000000000003E-2	5.1814000000000002E-5
4.2999999999999997E-2	5.1786999999999997E-5
4.3999999999999997E-2	5.1823000000000002E-5
4.4999999999999998E-2	5.1956999999999997E-5
4.5999999999999999E-2	5.2117999999999998E-5
4.7E-2	5.2145000000000003E-5
4.8000000000000001E-2	5.2163000000000002E-5
4.9000000000000002E-2	5.2135999999999997E-5
0.05	5.2198999999999999E-5
5.0999999999999997E-2	5.2287999999999998E-5
5.1999999999999998E-2	5.2324000000000003E-5
5.2999999999999999E-2	5.2439999999999999E-5
5.3999999999999999E-2	5.2448999999999999E-5
5.5E-2	5.2475999999999997E-5
5.6000000000000001E-2	5.2583000000000001E-5
5.7000000000000002E-2	5.2664000000000003E-5
5.8000000000000003E-2	5.27E-5
5.8999999999999997E-2	5.2664000000000003E-5
0.06	5.2788999999999999E-5
6.0999999999999999E-2	5.2886999999999997E-5
6.2E-2	5.2914000000000002E-5
6.3E-2	5.2985999999999997E-5
6.4000000000000001E-2	5.3128999999999999E-5
6.5000000000000002E-2	5.3208999999999998E-5
6.6000000000000003E-2	5.3226999999999997E-5
6.7000000000000004E-2	5.3307999999999999E-5
6.8000000000000005E-2	5.3369999999999999E-5
6.9000000000000006E-2	5.3442000000000001E-5
7.0000000000000007E-2	5.3566999999999997E-5
7.0999999999999994E-2	5.3603000000000002E-5
7.1999999999999995E-2	5.3539999999999999E-5
7.2999999999999995E-2	5.3701E-5
7.3999999999999996E-2	5.3791E-5
7.4999999999999997E-2	5.3826999999999998E-5
7.5999999999999998E-2	5.3961000000000001E-5
7.6999999999999999E-2	5.4113000000000002E-5
7.8E-2	5.414E-5
7.9000000000000001E-2	5.4274000000000002E-5
0.08	5.4407999999999998E-5
8.1000000000000003E-2	5.4381E-5
8.2000000000000003E-2	5.4453000000000002E-5
8.3000000000000004E-2	5.4605000000000003E-5
8.4000000000000005E-2	5.4623000000000002E-5
8.5000000000000006E-2	5.4676000000000003E-5
8.5999999999999993E-2	5.4818999999999998E-5
8.6999999999999994E-2	5.49E-5
8.7999999999999995E-2	5.4988999999999998E-5
8.8999999999999996E-2	5.5176999999999997E-5
0.09	5.5266999999999998E-5
9.0999999999999998E-2	5.5266999999999998E-5
9.1999999999999998E-2	5.5374000000000002E-5
9.2999999999999999E-2	5.5553000000000002E-5
9.4E-2	5.5642E-5
9.5000000000000001E-2	5.5686999999999997E-5
9.6000000000000002E-2	5.5812E-5
9.7000000000000003E-2	5.6276999999999997E-5
9.8000000000000004E-2	5.6428999999999998E-5
9.9000000000000005E-2	5.6412000000000001E-5
0.1	5.6348999999999999E-5
0.10100000000000001	5.6412000000000001E-5
0.10199999999999999	5.6573000000000002E-5
0.10299999999999999	5.6777999999999997E-5
0.104	5.6805000000000002E-5
0.105	5.6938999999999998E-5
0.106	5.7082E-5
0.107	5.7172000000000001E-5
0.108	5.7243000000000001E-5
0.109	5.7457999999999998E-5
0.11	5.7538999999999999E-5
0.111	5.7547000000000003E-5
0.112	5.7788999999999998E-5
0.113	5.7914000000000002E-5
0.114	5.8093000000000001E-5
0.115	5.8298999999999999E-5
0.11600000000000001	5.8325999999999997E-5
0.11700000000000001	5.8424000000000002E-5
0.11799999999999999	5.8594000000000002E-5
0.11899999999999999	5.8853E-5
0.12	5.8987000000000003E-5
0.121	5.9104000000000002E-5
0.122	5.9256000000000003E-5
0.123	5.9265000000000003E-5
0.124	5.9444000000000002E-5
0.125	5.9809999999999998E-5
0.126	5.9891E-5
0.127	6.0061E-5
0.128	6.0302E-5
0.129	6.0454000000000001E-5
0.13	6.0633E-5
0.13100000000000001	6.0838999999999998E-5
0.13200000000000001	6.0999999999999999E-5
0.13300000000000001	6.1161000000000006E-5
0.13400000000000001	6.1358000000000004E-5
0.13500000000000001	6.1509999999999999E-5
0.13600000000000001	6.1554000000000001E-5
0.13700000000000001	6.1760000000000005E-5
0.13800000000000001	6.2001999999999994E-5
0.13900000000000001	6.2198000000000003E-5
0.14000000000000001	6.2466999999999997E-5
0.14099999999999999	6.2655000000000002E-5
0.14199999999999999	6.2806999999999997E-5
0.14299999999999999	6.3021000000000005E-5
0.14399999999999999	6.3200000000000005E-5
0.14499999999999999	6.3397000000000003E-5
0.14599999999999999	6.3621000000000006E-5
0.14699999999999999	6.3791E-5
0.14799999999999999	6.3898000000000004E-5
0.14899999999999999	6.4264999999999995E-5
0.15	6.4407999999999997E-5
0.151	6.4505999999999995E-5
0.152	6.4658000000000003E-5
0.153	6.5024999999999995E-5
0.154	6.5320000000000005E-5
0.155	6.5471999999999999E-5
0.156	6.5605999999999995E-5
0.157	6.5811999999999999E-5
0.158	6.5919000000000004E-5
0.159	6.6231999999999999E-5
0.16	6.6446999999999996E-5
0.161	6.6544999999999994E-5
0.16200000000000001	6.6687999999999996E-5
0.16300000000000001	6.6921000000000005E-5
0.16400000000000001	6.7100000000000005E-5
0.16500000000000001	6.7269999999999998E-5
0.16600000000000001	6.7546999999999996E-5
0.16700000000000001	6.7753E-5
0.16800000000000001	6.7949999999999998E-5
0.16900000000000001	6.8155000000000001E-5
0.17	6.8324999999999994E-5
0.17100000000000001	6.8433E-5
0.17199999999999999	6.8763999999999994E-5
0.17299999999999999	6.8968999999999996E-5
0.17399999999999999	6.8934000000000001E-5
0.17499999999999999	6.9059000000000004E-5
0.17599999999999999	6.9344999999999994E-5
0.17699999999999999	6.9461000000000005E-5
0.17799999999999999	6.9640000000000004E-5
0.17899999999999999	6.9819000000000004E-5
0.18	7.0034000000000001E-5
0.18099999999999999	7.0247999999999996E-5
0.182	7.0463000000000006E-5
0.183	7.0543000000000005E-5
0.184	7.0650999999999998E-5
0.185	7.0803000000000006E-5
0.186	7.1008999999999997E-5
0.187	7.1008999999999997E-5
0.188	7.1151999999999999E-5
0.189	7.1330999999999999E-5
0.19	7.1365999999999994E-5
0.191	7.1501000000000005E-5
0.192	7.1669999999999997E-5
0.193	7.1823000000000007E-5
0.19400000000000001	7.1983999999999994E-5
0.19500000000000001	7.2144000000000006E-5
0.19600000000000001	7.2216000000000001E-5
0.19700000000000001	7.2243000000000006E-5
0.19800000000000001	7.2367999999999996E-5
0.19900000000000001	7.2619000000000004E-5
0.2	7.3021000000000004E-5
0.20100000000000001	7.2993999999999999E-5
0.20200000000000001	7.2948999999999996E-5
0.20300000000000001	7.2914E-5
0.20399999999999999	7.3003000000000006E-5
0.20499999999999999	7.3109999999999996E-5
0.20599999999999999	7.3127999999999995E-5
0.20699999999999999	7.3236000000000002E-5
0.20799999999999999	7.3316000000000001E-5
0.20899999999999999	7.3361000000000005E-5
0.21	7.3397000000000002E-5
0.21099999999999999	7.3415000000000001E-5
0.21199999999999999	7.3415000000000001E-5
0.21299999999999999	7.3449999999999996E-5
0.214	7.3558000000000003E-5
0.215	7.3674E-5
0.216	7.3620000000000003E-5
0.217	7.3862000000000005E-5
0.218	7.3906999999999996E-5
0.219	7.3844000000000007E-5
0.22	7.3898000000000003E-5
0.221	7.4014E-5
0.222	7.3986999999999995E-5
0.223	7.4147999999999995E-5
0.224	7.4255E-5
0.22500000000000001	7.4085000000000006E-5
0.22600000000000001	7.4023000000000006E-5
0.22700000000000001	7.4121000000000004E-5
0.22800000000000001	7.4085000000000006E-5
0.22900000000000001	7.4129999999999997E-5
0.23	7.4220000000000004E-5
0.23100000000000001	7.4344999999999994E-5
0.23200000000000001	7.4344999999999994E-5
0.23300000000000001	7.4443000000000005E-5
0.23400000000000001	7.4515000000000001E-5
0.23499999999999999	7.4433999999999999E-5
0.23599999999999999	7.4479000000000003E-5
0.23699999999999999	7.4542000000000006E-5
0.23799999999999999	7.4461000000000004E-5
0.23899999999999999	7.4542000000000006E-5
0.24	7.4595E-5
0.24099999999999999	7.4577000000000001E-5
0.24199999999999999	7.4648999999999996E-5
0.24299999999999999	7.4819000000000003E-5
0.24399999999999999	7.4738000000000002E-5
0.245	7.4746999999999994E-5
0.246	7.4845999999999995E-5
0.247	7.4873E-5
0.248	7.4819000000000003E-5
0.249	7.4855000000000001E-5
0.25	7.4873E-5
0.251	7.4720000000000003E-5
0.252	7.4863999999999993E-5
0.253	7.4944000000000006E-5
0.254	7.4899000000000002E-5
0.255	7.5060000000000003E-5
0.25600000000000001	7.5185999999999995E-5
0.25700000000000001	7.5131999999999998E-5
0.25800000000000001	7.5292999999999999E-5
0.25900000000000001	7.5346999999999995E-5
0.26	7.5382000000000004E-5
0.26100000000000001	7.5354999999999999E-5
0.26200000000000001	7.5408999999999996E-5
0.26300000000000001	7.5436000000000001E-5
0.26400000000000001	7.5338000000000003E-5
0.26500000000000001	7.5525000000000006E-5
0.26600000000000001	7.5543000000000005E-5
0.26700000000000002	7.5561000000000004E-5
0.26800000000000002	7.5650999999999998E-5
0.26900000000000002	7.5704000000000006E-5
0.27	7.5704000000000006E-5
0.27100000000000002	7.5794E-5
0.27200000000000002	7.5945999999999994E-5
0.27300000000000002	7.5937000000000002E-5
0.27400000000000002	7.5955E-5
0.27500000000000002	7.6044000000000006E-5
0.27600000000000002	7.6017000000000001E-5
0.27700000000000002	7.5999000000000002E-5
0.27800000000000002	7.6168999999999995E-5
0.27900000000000003	7.6241000000000004E-5
0.28000000000000003	7.6267999999999996E-5
0.28100000000000003	7.6339000000000002E-5
0.28199999999999997	7.6402000000000005E-5
0.28299999999999997	7.6474E-5
0.28399999999999997	7.6563000000000005E-5
0.28499999999999998	7.6742000000000005E-5
0.28599999999999998	7.6687999999999995E-5
0.28699999999999998	7.6768999999999996E-5
0.28799999999999998	7.6812999999999998E-5
0.28899999999999998	7.6812999999999998E-5
0.28999999999999998	7.6911999999999998E-5
0.29099999999999998	7.7118000000000003E-5
0.29199999999999998	7.7198000000000002E-5
0.29299999999999998	7.7162000000000004E-5
0.29399999999999998	7.7349999999999996E-5
0.29499999999999998	7.7484000000000006E-5
0.29599999999999999	7.7538000000000002E-5
0.29699999999999999	7.7583000000000006E-5
0.29799999999999999	7.7663000000000005E-5
0.29899999999999999	7.7689999999999996E-5
0.3	7.7832999999999998E-5
0.30099999999999999	7.8029999999999997E-5
0.30199999999999999	7.8431999999999997E-5
0.30299999999999999	7.8512999999999999E-5
0.30399999999999999	7.8522000000000005E-5
0.30499999999999999	7.8495E-5
0.30599999999999999	7.8512999999999999E-5
0.307	7.8592999999999998E-5
0.308	7.8701000000000004E-5
0.309	7.8880000000000004E-5
0.31	7.8996000000000001E-5
0.311	7.9085000000000006E-5
0.312	7.9058000000000001E-5
0.313	7.9202000000000005E-5
0.314	7.9406999999999994E-5
0.315	7.9416E-5
0.316	7.9648999999999996E-5
0.317	7.9827999999999995E-5
0.318	7.9773999999999999E-5
0.31900000000000001	7.9998000000000002E-5
0.32	8.0193999999999998E-5
0.32100000000000001	8.0229999999999996E-5
0.32200000000000001	8.0481000000000004E-5
0.32300000000000001	8.0587999999999995E-5
0.32400000000000001	8.0597000000000001E-5
0.32500000000000001	8.0785000000000007E-5
0.32600000000000001	8.0981000000000003E-5
0.32700000000000001	8.1062000000000004E-5
0.32800000000000001	8.1142000000000003E-5
0.32900000000000001	8.1374999999999999E-5
0.33	8.1526999999999994E-5
0.33100000000000002	8.1633999999999998E-5
0.33200000000000002	8.1812999999999997E-5
0.33300000000000002	8.2064000000000006E-5
0.33400000000000002	8.2198000000000001E-5
0.33500000000000002	8.2341000000000003E-5
0.33600000000000002	8.2510999999999997E-5
0.33700000000000002	8.2502000000000004E-5
0.33800000000000002	8.2707999999999995E-5
0.33900000000000002	8.2896000000000001E-5
0.34	8.3039000000000002E-5
0.34100000000000003	8.3226000000000006E-5
0.34200000000000003	8.3423000000000004E-5
0.34300000000000003	8.3557E-5
0.34399999999999997	8.3718E-5
0.34499999999999997	8.3942000000000004E-5
0.34599999999999997	8.4191999999999996E-5
0.34699999999999998	8.4300000000000003E-5
0.34799999999999998	8.4497000000000001E-5
0.34899999999999998	8.4710999999999996E-5
0.35	8.4773999999999998E-5
0.35099999999999998	8.4987999999999993E-5
0.35199999999999998	8.5211999999999997E-5
0.35299999999999998	8.5372999999999997E-5
0.35399999999999998	8.5614999999999999E-5
0.35499999999999998	8.5828999999999994E-5
0.35599999999999998	8.5891999999999997E-5
0.35699999999999998	8.6088999999999995E-5
0.35799999999999998	8.6366000000000006E-5
0.35899999999999999	8.6500000000000002E-5
0.36	8.6724000000000005E-5
0.36099999999999999	8.6955999999999999E-5
0.36199999999999999	8.7117E-5
0.36299999999999999	8.7188999999999995E-5
0.36399999999999999	8.7439000000000001E-5
0.36499999999999999	8.7618E-5
0.36599999999999999	8.7733999999999997E-5
0.36699999999999999	8.8038E-5
0.36799999999999999	8.8199E-5
0.36899999999999999	8.8315999999999999E-5
0.37	8.8504000000000005E-5
0.371	8.8745000000000005E-5
0.372	8.8978000000000001E-5
0.373	8.9121000000000003E-5
0.374	8.9443000000000004E-5
0.375	8.9531999999999996E-5
0.376	8.9710999999999995E-5
0.377	8.9979E-5
0.378	9.0247999999999994E-5
0.379	9.0158E-5
0.38	9.0426999999999993E-5
0.38100000000000001	9.0694999999999998E-5
0.38200000000000001	9.0873999999999998E-5
0.38300000000000001	9.1052999999999997E-5
0.38400000000000001	9.1321000000000002E-5
0.38500000000000001	9.1500000000000001E-5
0.38600000000000001	9.1768000000000006E-5
0.38700000000000001	9.2037E-5
0.38800000000000001	9.2126000000000005E-5
0.38900000000000001	9.2214999999999997E-5
0.39	9.2484000000000004E-5
0.39100000000000001	9.2751999999999996E-5
0.39200000000000002	9.2930999999999995E-5
0.39300000000000002	9.3109999999999995E-5
0.39400000000000002	9.3377999999999999E-5
0.39500000000000002	9.3556999999999999E-5
0.39600000000000002	9.3735999999999998E-5
0.39700000000000002	9.4004000000000003E-5
0.39800000000000002	9.4183000000000003E-5
0.39900000000000002	9.4451999999999996E-5
0.4	9.4720000000000001E-5
0.40100000000000002	9.4809000000000007E-5
0.40200000000000002	9.5078E-5
0.40300000000000002	9.5346000000000005E-5
0.40400000000000003	9.5883000000000003E-5
0.40500000000000003	9.6329999999999994E-5
0.40600000000000003	9.6419E-5
0.40699999999999997	9.6597999999999999E-5
0.40799999999999997	9.6688000000000007E-5
0.40899999999999997	9.6866000000000004E-5
0.41	9.7134999999999997E-5
0.41099999999999998	9.7403000000000002E-5
0.41199999999999998	9.7670999999999994E-5
0.41299999999999998	9.7940000000000001E-5
0.41399999999999998	9.8208000000000006E-5
0.41499999999999998	9.8475999999999997E-5
0.41599999999999998	9.8833999999999996E-5
0.41699999999999998	9.8924000000000004E-5
0.41799999999999998	9.9191999999999995E-5
0.41899999999999998	9.9549999999999994E-5
0.42	9.9908000000000006E-5
0.42099999999999999	1.0018000000000001E-4
0.42199999999999999	1.0053E-4
0.42299999999999999	1.0089E-4
0.42399999999999999	1.0124999999999999E-4
0.42499999999999999	1.0143E-4
0.42599999999999999	1.0187999999999999E-4
0.42699999999999999	1.0213999999999999E-4
0.42799999999999999	1.025E-4
0.42899999999999999	1.0304E-4
0.43	1.0322E-4
0.43099999999999999	1.0349E-4
0.432	1.0375E-4
0.433	1.0411E-4
0.434	1.0446999999999999E-4
0.435	1.0501E-4
0.436	1.0545E-4
0.437	1.0581000000000001E-4
0.438	1.0626E-4
0.439	1.0671E-4
0.44	1.0697E-4
0.441	1.0751000000000001E-4
0.442	1.0796E-4
0.443	1.0832000000000001E-4
0.44400000000000001	1.0885E-4
0.44500000000000001	1.093E-4
0.44600000000000001	1.0966E-4
0.44700000000000001	1.1001E-4
0.44800000000000001	1.1064E-4
0.44900000000000001	1.1109E-4
0.45	1.1162000000000001E-4
0.45100000000000001	1.1207E-4
0.45200000000000001	1.1260999999999999E-4
0.45300000000000001	1.1306000000000001E-4
0.45400000000000001	1.1359E-4
0.45500000000000002	1.1422E-4
0.45600000000000002	1.1476000000000001E-4
0.45700000000000002	1.1529E-4
0.45800000000000002	1.1582999999999999E-4
0.45900000000000002	1.1628E-4
0.46	1.169E-4
0.46100000000000002	1.1752999999999999E-4
0.46200000000000002	1.1806E-4
0.46300000000000002	1.186E-4
0.46400000000000002	1.1923E-4
0.46500000000000002	1.1976000000000001E-4
0.46600000000000003	1.203E-4
0.46700000000000003	1.2093E-4
0.46800000000000003	1.2146000000000001E-4
0.46899999999999997	1.2208999999999999E-4
0.47	1.2271999999999999E-4
0.47099999999999997	1.2343E-4
0.47199999999999998	1.2406E-4
0.47299999999999998	1.2459E-4
0.47399999999999998	1.2522E-4
0.47499999999999998	1.2594E-4
0.47599999999999998	1.2664999999999999E-4
0.47699999999999998	1.2737E-4
0.47799999999999998	1.2789999999999999E-4
0.47899999999999998	1.2862E-4
0.48	1.2933000000000001E-4
0.48099999999999998	1.2987E-4
0.48199999999999998	1.305E-4
0.48299999999999998	1.3129999999999999E-4
0.48399999999999999	1.3192999999999999E-4
0.48499999999999999	1.3255E-4
0.48599999999999999	1.3327E-4
0.48699999999999999	1.3407E-4
0.48799999999999999	1.3469999999999999E-4
0.48899999999999999	1.3542E-4
0.49	1.3604000000000001E-4
0.49099999999999999	1.3667E-4
0.49199999999999999	1.3737999999999999E-4
0.49299999999999999	1.381E-4
0.49399999999999999	1.3863999999999999E-4
0.495	1.3925999999999999E-4
0.496	1.3998E-4
0.497	1.4069000000000001E-4
0.498	1.4132000000000001E-4
0.499	1.4203999999999999E-4
0.5	1.4275E-4
0.501	1.4347000000000001E-4
0.502	1.4417999999999999E-4
0.503	1.4472000000000001E-4
0.504	1.4525000000000001E-4
0.505	1.4596999999999999E-4
0.50600000000000001	1.4668999999999999E-4
0.50700000000000001	1.4757999999999999E-4
0.50800000000000001	1.4812000000000001E-4
0.50900000000000001	1.4873999999999999E-4
0.51	1.4909999999999999E-4
0.51100000000000001	1.4964000000000001E-4
0.51200000000000001	1.5025999999999999E-4
0.51300000000000001	1.5088999999999999E-4
0.51400000000000001	1.5134E-4
0.51500000000000001	1.5186999999999999E-4
0.51600000000000001	1.5241000000000001E-4
0.51700000000000002	1.5295E-4
0.51800000000000002	1.5348E-4
0.51900000000000002	1.5393000000000001E-4
0.52	1.5438E-4
0.52100000000000002	1.5490999999999999E-4
0.52200000000000002	1.5545000000000001E-4
0.52300000000000002	1.5589999999999999E-4
0.52400000000000002	1.5644000000000001E-4
0.52500000000000002	1.5697000000000001E-4
0.52600000000000002	1.5733000000000001E-4
0.52700000000000002	1.5787E-4
0.52800000000000002	1.5822000000000001E-4
0.52900000000000003	1.5849000000000001E-4
0.53	1.5885000000000001E-4
0.53100000000000003	1.593E-4
0.53200000000000003	1.5966E-4
0.53300000000000003	1.6001000000000001E-4
0.53400000000000003	1.6037000000000001E-4
0.53500000000000003	1.6064000000000001E-4
0.53600000000000003	1.6100000000000001E-4
0.53700000000000003	1.6134999999999999E-4
0.53800000000000003	1.6171E-4
0.53900000000000003	1.6197999999999999E-4
0.54	1.6225000000000001E-4
0.54100000000000004	1.6252000000000001E-4
0.54200000000000004	1.627E-4
0.54300000000000004	1.6296E-4
0.54400000000000004	1.6322999999999999E-4
0.54500000000000004	1.6341000000000001E-4
0.54600000000000004	1.6368E-4
0.54700000000000004	1.6395E-4
0.54800000000000004	1.6412999999999999E-4
0.54900000000000004	1.6422E-4
0.55000000000000004	1.6440000000000001E-4
0.55100000000000005	1.6466000000000001E-4
0.55200000000000005	1.6484E-4
0.55300000000000005	1.6501999999999999E-4
0.55400000000000005	1.652E-4
0.55500000000000005	1.6529000000000001E-4
0.55600000000000005	1.6547E-4
0.55700000000000005	1.6556000000000001E-4
0.55800000000000005	1.6556000000000001E-4
0.55900000000000005	1.6564999999999999E-4
0.56000000000000005	1.6592000000000001E-4
0.56100000000000005	1.6592000000000001E-4
0.56200000000000006	1.6600999999999999E-4
0.56299999999999994	1.6618000000000001E-4
0.56399999999999995	1.6618000000000001E-4
0.56499999999999995	1.6618000000000001E-4
0.56599999999999995	1.6636E-4
0.56699999999999995	1.6645000000000001E-4
0.56799999999999995	1.6636E-4
0.56899999999999995	1.6653999999999999E-4
0.56999999999999995	1.6653999999999999E-4
0.57099999999999995	1.6645000000000001E-4
0.57199999999999995	1.6653999999999999E-4
0.57299999999999995	1.6672E-4
0.57399999999999995	1.6681000000000001E-4
0.57499999999999996	1.6689999999999999E-4
0.57599999999999996	1.6689999999999999E-4
0.57699999999999996	1.6681000000000001E-4
0.57799999999999996	1.6689999999999999E-4
0.57899999999999996	1.6699E-4
0.57999999999999996	1.6708000000000001E-4
0.58099999999999996	1.6708000000000001E-4
0.58199999999999996	1.6716999999999999E-4
0.58299999999999996	1.6725999999999999E-4
0.58399999999999996	1.6708000000000001E-4
0.58499999999999996	1.6716999999999999E-4
0.58599999999999997	1.6735E-4
0.58699999999999997	1.6735E-4
0.58799999999999997	1.6752999999999999E-4
0.58899999999999997	1.6771000000000001E-4
0.59	1.6778999999999999E-4
0.59099999999999997	1.6788E-4
0.59199999999999997	1.6797000000000001E-4
0.59299999999999997	1.6797000000000001E-4
0.59399999999999997	1.6797000000000001E-4
0.59499999999999997	1.6814999999999999E-4
0.59599999999999997	1.6824E-4
0.59699999999999998	1.6824E-4
0.59799999999999998	1.6841999999999999E-4
0.59899999999999998	1.6869000000000001E-4
0.6	1.6869000000000001E-4
0.60099999999999998	1.6896000000000001E-4
0.60199999999999998	1.6914E-4
0.60299999999999998	1.6932000000000001E-4
0.60399999999999998	1.694E-4
0.60499999999999998	1.6958000000000001E-4
0.60599999999999998	1.6966999999999999E-4
0.60699999999999998	1.6993999999999999E-4
0.60799999999999998	1.7021000000000001E-4
0.60899999999999999	1.7066E-4
0.61	1.7092999999999999E-4
0.61099999999999999	1.7101E-4
0.61199999999999999	1.7110000000000001E-4
0.61299999999999999	1.7128E-4
0.61399999999999999	1.7145999999999999E-4
0.61499999999999999	1.7173000000000001E-4
0.61599999999999999	1.7200000000000001E-4
0.61699999999999999	1.7217999999999999E-4
0.61799999999999999	1.7244999999999999E-4
0.61899999999999999	1.7270999999999999E-4
0.62	1.7297999999999999E-4
0.621	1.7333999999999999E-4
0.622	1.7352000000000001E-4
0.623	1.7388000000000001E-4
0.624	1.7422999999999999E-4
0.625	1.7450000000000001E-4
0.626	1.7477000000000001E-4
0.627	1.7521999999999999E-4
0.628	1.7558E-4
0.629	1.7602000000000001E-4
0.63	1.7637999999999999E-4

Figura 69 - Voltammogramma ciclico del polimero 3.2.c registrato a una velocità di scansione di 0.05 V/s in soluzione di THF con TBAPF₆ 0.1 M. L'analisi qualitativa delle curve corrente/potenziale rivela la natura dei processi di ossido-riduzione dello scheletro coniugato, evidenziandone il grado di reversibilità. In un sistema elettrochimicamente reversibile, il processo di trasferimento elettronico si manifesta con la comparsa di un picco diretto e di un corrispondente picco di ritorno durante la scansione inversa, caratterizzati da un rapporto tra l'intensità della corrente anodica e catodica (I_pa/I_pc) prossimo all'unità. Nei tracciati registrati per la serie di polimeri in esame, al contrario, si osserva sistematicamente un marcato discostamento da questo comportamento ideale. Dal punto di vista grafico, l'irreversibilità si palesa attraverso lo sviluppo di ampie onde faradiche durante le scansioni di andata, alle quali non fa seguito alcun corrispondente picco di ritorno termodinamicamente simmetrico.

0.05 V/s X	0.05 V/s Y	0.1 V/s X	0.1 V/s Y	0.5 V/s X	0.5 V/s Y	1 V/s X	1 V/s Y
0.63100000000000001	1.7629000000000001E-4	0.63100000000000001	9.6766000000000002E-5	0.627	2.2274000000000001E-5	0.622	1.171E-5
0.63	1.5401999999999999E-4	0.629	7.6464000000000005E-5	0.61699999999999999	1.3196999999999999E-5	0.60199999999999998	5.5430000000000001E-6
0.629	1.3040999999999999E-4	0.627	6.2391999999999995E-5	0.60699999999999998	7.4161E-6	0.58199999999999996	1.6249999999999999E-6
0.628	1.1476000000000001E-4	0.625	5.3220999999999997E-5	0.59699999999999998	3.4987999999999999E-6	0.56200000000000006	-1.0380000000000001E-6
0.627	1.0465E-4	0.623	4.6770000000000001E-5	0.58699999999999997	6.8815999999999999E-7	0.54200000000000004	-2.92E-6
0.626	9.7492999999999996E-5	0.621	4.1962999999999998E-5	0.57699999999999996	-1.4176E-6	0.52200000000000002	-4.2939999999999999E-6
0.625	9.2126000000000005E-5	0.61899999999999999	3.8074000000000002E-5	0.56699999999999995	-3.0547000000000002E-6	0.502	-5.3260000000000003E-6
0.624	8.7993999999999998E-5	0.61699999999999999	3.4848000000000002E-5	0.55700000000000005	-4.3699000000000003E-6	0.48199999999999998	-6.1040000000000003E-6
0.623	8.4336E-5	0.61499999999999999	3.2064999999999999E-5	0.54700000000000004	-5.4504000000000004E-6	0.46200000000000002	-6.7039999999999997E-6
0.622	8.1178000000000001E-5	0.61299999999999999	2.9601999999999999E-5	0.53700000000000003	-6.3497999999999998E-6	0.442	-7.1790000000000002E-6
0.621	7.8522000000000005E-5	0.61099999999999999	2.7416999999999999E-5	0.52700000000000002	-7.1276000000000002E-6	0.42199999999999999	-7.5530000000000004E-6
0.62	7.5999000000000002E-5	0.60899999999999999	2.5250999999999999E-5	0.51700000000000002	-7.7980000000000006E-6	0.40200000000000002	-7.858E-6
0.61899999999999999	7.3566999999999995E-5	0.60699999999999998	2.3391E-5	0.50700000000000001	-8.4061000000000007E-6	0.38200000000000001	-8.0960000000000001E-6
0.61799999999999999	7.1384000000000006E-5	0.60499999999999998	2.1766000000000001E-5	0.497	-8.9407000000000006E-6	0.36199999999999999	-8.2879999999999993E-6
0.61699999999999999	6.9290999999999998E-5	0.60299999999999998	2.0153000000000002E-5	0.48699999999999999	-9.4017000000000001E-6	0.34200000000000003	-8.4449999999999996E-6
0.61599999999999999	6.7279000000000004E-5	0.60099999999999998	1.8695E-5	0.47699999999999998	-9.8145999999999992E-6	0.32200000000000001	-8.5730000000000008E-6
0.61499999999999999	6.5426999999999995E-5	0.59899999999999998	1.7354999999999999E-5	0.46700000000000003	-1.0190999999999999E-5	0.30199999999999999	-8.6829999999999997E-6
0.61399999999999999	6.3646999999999996E-5	0.59699999999999998	1.5994999999999998E-5	0.45700000000000002	-1.0539E-5	0.28199999999999997	-8.7630000000000006E-6
0.61299999999999999	6.1814000000000001E-5	0.59499999999999997	1.4799E-5	0.44700000000000001	-1.0849999999999999E-5	0.26200000000000001	-8.8219999999999996E-6
0.61199999999999999	6.0222E-5	0.59299999999999997	1.3601000000000001E-5	0.437	-1.1121000000000001E-5	0.24199999999999999	-8.8780000000000004E-6
0.61099999999999999	5.8799999999999999E-5	0.59099999999999997	1.2466000000000001E-5	0.42699999999999999	-1.137E-5	0.222	-8.9360000000000005E-6
0.61	5.7225000000000002E-5	0.58899999999999997	1.1372000000000001E-5	0.41699999999999998	-1.1593999999999999E-5	0.20200000000000001	-9.0070000000000003E-6
0.60899999999999999	5.5705000000000003E-5	0.58699999999999997	1.0312000000000001E-5	0.40699999999999997	-1.1789E-5	0.182	-9.081E-6
0.60799999999999998	5.3934000000000002E-5	0.58499999999999996	9.3919999999999992E-6	0.39700000000000002	-1.1980999999999999E-5	0.16200000000000001	-9.1269999999999992E-6
0.60699999999999998	5.2601E-5	0.58299999999999996	8.4970000000000001E-6	0.38700000000000001	-1.2125E-5	0.14199999999999999	-9.0939999999999997E-6
0.60599999999999998	5.1421000000000001E-5	0.58099999999999996	7.6052999999999998E-6	0.377	-1.2261E-5	0.122	-8.9039999999999998E-6
0.60499999999999998	5.0365000000000003E-5	0.57899999999999996	6.7673000000000004E-6	0.36699999999999999	-1.2386E-5	0.10199999999999999	-8.5280000000000003E-6
0.60399999999999998	4.9085999999999997E-5	0.57699999999999996	5.8533999999999997E-6	0.35699999999999998	-1.2496E-5	8.2000000000000003E-2	-8.0209999999999999E-6
0.60299999999999998	4.7843000000000003E-5	0.57499999999999996	5.0849000000000002E-6	0.34699999999999998	-1.2605999999999999E-5	6.2E-2	-7.4909999999999999E-6
0.60199999999999998	4.6733999999999997E-5	0.57299999999999995	4.2753999999999998E-6	0.33700000000000002	-1.2694000000000001E-5	4.2000000000000003E-2	-7.0450000000000003E-6
0.60099999999999998	4.5571000000000001E-5	0.57099999999999995	3.5165000000000001E-6	0.32700000000000001	-1.2779000000000001E-5	2.1999999999999999E-2	-6.7009999999999999E-6
0.6	4.4515999999999999E-5	0.56899999999999995	2.7983E-6	0.317	-1.2852E-5	2E-3	-6.4500000000000001E-6
0.59899999999999998	4.3523000000000003E-5	0.56699999999999995	2.1503E-6	0.307	-1.2923E-5	-1.7999999999999999E-2	-6.2620000000000004E-6
0.59799999999999998	4.2503000000000003E-5	0.56499999999999995	1.3588E-6	0.29699999999999999	-1.3002E-5	-3.7999999999999999E-2	-6.0959999999999997E-6
0.59699999999999998	4.1421000000000002E-5	0.56299999999999994	7.1625999999999998E-7	0.28699999999999998	-1.3047999999999999E-5	-5.8000000000000003E-2	-5.9499999999999998E-6
0.59599999999999997	4.0491000000000002E-5	0.56100000000000005	5.5339999999999998E-8	0.27700000000000002	-1.3087E-5	-7.8E-2	-5.8019999999999997E-6
0.59499999999999997	3.9569E-5	0.55900000000000005	-5.6225E-7	0.26700000000000002	-1.3132000000000001E-5	-9.8000000000000004E-2	-5.6450000000000002E-6
0.59399999999999997	3.8612000000000002E-5	0.55700000000000005	-1.2007E-6	0.25700000000000001	-1.3189E-5	-0.11799999999999999	-5.48E-6
0.59299999999999997	3.7663999999999997E-5	0.55500000000000005	-1.7984E-6	0.247	-1.3230999999999999E-5	-0.13800000000000001	-5.2920000000000003E-6
0.59199999999999997	3.6876999999999999E-5	0.55300000000000005	-2.4378000000000002E-6	0.23699999999999999	-1.3291E-5	-0.158	-5.096E-6
0.59099999999999997	3.5964999999999999E-5	0.55100000000000005	-2.9921000000000001E-6	0.22700000000000001	-1.3353000000000001E-5	-0.17799999999999999	-4.8980000000000004E-6
0.59	3.5034999999999999E-5	0.54900000000000004	-3.5955000000000001E-6	0.217	-1.3421000000000001E-5	-0.19800000000000001	-4.6970000000000001E-6
0.58899999999999997	3.4158000000000001E-5	0.54700000000000004	-4.1362999999999997E-6	0.20699999999999999	-1.3485999999999999E-5	-0.218	-4.5079999999999999E-6
0.58799999999999997	3.3325999999999999E-5	0.54500000000000004	-4.6643999999999998E-6	0.19700000000000001	-1.3565E-5	-0.23799999999999999	-4.3229999999999999E-6
0.58699999999999997	3.2486E-5	0.54300000000000004	-5.2019000000000001E-6	0.187	-1.3616E-5	-0.25800000000000001	-4.1590000000000003E-6
0.58599999999999997	3.1814999999999999E-5	0.54100000000000004	-5.7552999999999998E-6	0.17699999999999999	-1.3642000000000001E-5	-0.27800000000000002	-4.0210000000000001E-6
0.58499999999999996	3.1000999999999997E-5	0.53900000000000003	-6.2833999999999998E-6	0.16700000000000001	-1.361E-5	-0.29799999999999999	-3.9149999999999998E-6
0.58399999999999996	3.0196E-5	0.53700000000000003	-6.8051999999999997E-6	0.157	-1.3528E-5	-0.318	-3.8469999999999998E-6
0.58299999999999996	2.9471E-5	0.53500000000000003	-7.3016999999999999E-6	0.14699999999999999	-1.3363999999999999E-5	-0.33800000000000002	-3.8070000000000001E-6
0.58199999999999996	2.8827E-5	0.53300000000000003	-7.7633999999999992E-6	0.13700000000000001	-1.3115000000000001E-5	-0.35799999999999998	-3.8039999999999999E-6
0.58099999999999996	2.8076E-5	0.53100000000000003	-8.2377000000000008E-6	0.127	-1.2779000000000001E-5	-0.378	-3.8319999999999999E-6
0.57999999999999996	2.7325E-5	0.52900000000000003	-8.7309999999999999E-6	0.11700000000000001	-1.2386E-5	-0.39800000000000002	-3.8850000000000001E-6
0.57899999999999996	2.6743000000000001E-5	0.52700000000000002	-9.2497000000000006E-6	0.107	-1.1963999999999999E-5	-0.41799999999999998	-3.9650000000000002E-6
0.57799999999999996	2.5973999999999999E-5	0.52500000000000002	-9.7177000000000001E-6	9.7000000000000003E-2	-1.1548E-5	-0.438	-4.0559999999999998E-6
0.57699999999999996	2.5284999999999999E-5	0.52300000000000002	-1.0169999999999999E-5	8.6999999999999994E-2	-1.1151999999999999E-5	-0.45800000000000002	-4.1629999999999998E-6
0.57599999999999996	2.4686E-5	0.52100000000000002	-1.0644E-5	7.6999999999999999E-2	-1.0781999999999999E-5	-0.47799999999999998	-4.2830000000000003E-6
0.57499999999999996	2.3980000000000001E-5	0.51900000000000002	-1.1062E-5	6.7000000000000004E-2	-1.046E-5	-0.498	-4.4050000000000002E-6
0.57399999999999995	2.3309E-5	0.51700000000000002	-1.152E-5	5.7000000000000002E-2	-1.0196E-5	-0.51800000000000002	-4.5329999999999996E-6
0.57299999999999995	2.279E-5	0.51500000000000001	-1.1956999999999999E-5	4.7E-2	-9.9843000000000003E-6	-0.53800000000000003	-4.6580000000000001E-6
0.57199999999999995	2.2164E-5	0.51300000000000001	-1.238E-5	3.6999999999999998E-2	-9.8005000000000004E-6	-0.55800000000000005	-4.7829999999999998E-6
0.57099999999999995	2.1413E-5	0.51100000000000001	-1.2858E-5	2.7E-2	-9.6392999999999993E-6	-0.57799999999999996	-4.8969999999999999E-6
0.56999999999999995	2.0876000000000001E-5	0.50900000000000001	-1.3225E-5	1.7000000000000001E-2	-9.5007000000000004E-6	-0.59799999999999998	-5.0250000000000002E-6
0.56899999999999995	2.0285999999999999E-5	0.50700000000000001	-1.3733999999999999E-5	7.0000000000000001E-3	-9.3790999999999997E-6	-0.61799999999999999	-5.147E-6
0.56799999999999995	1.9660000000000002E-5	0.505	-1.4224E-5	-3.0000000000000001E-3	-9.2744000000000005E-6	-0.63800000000000001	-5.2619999999999998E-6
0.56699999999999995	1.9096000000000001E-5	0.503	-1.4524E-5	-1.2999999999999999E-2	-9.1810999999999992E-6	-0.65800000000000003	-5.3689999999999998E-6
0.56599999999999995	1.8524000000000001E-5	0.501	-1.4922999999999999E-5	-2.3E-2	-9.0821000000000007E-6	-0.67800000000000005	-5.4750000000000001E-6
0.56499999999999995	1.7924E-5	0.499	-1.5274E-5	-3.3000000000000002E-2	-8.9802999999999994E-6	-0.69799999999999995	-5.5770000000000001E-6
0.56399999999999995	1.7379000000000001E-5	0.497	-1.5682E-5	-4.2999999999999997E-2	-8.8868999999999996E-6	-0.71799999999999997	-5.6760000000000004E-6
0.56299999999999994	1.6833E-5	0.495	-1.6030000000000001E-5	-5.2999999999999999E-2	-8.7823000000000006E-6	-0.73799999999999999	-5.7710000000000003E-6
0.56200000000000006	1.6198E-5	0.49299999999999999	-1.6399999999999999E-5	-6.3E-2	-8.6833000000000004E-6	-0.75800000000000001	-5.857E-6
0.56100000000000005	1.5644000000000001E-5	0.49099999999999999	-1.6747000000000001E-5	-7.2999999999999995E-2	-8.5758000000000001E-6	-0.77800000000000002	-5.9440000000000002E-6
0.56000000000000005	1.5160999999999999E-5	0.48899999999999999	-1.7113999999999999E-5	-8.3000000000000004E-2	-8.4570000000000005E-6	-0.79800000000000004	-6.0220000000000001E-6
0.55900000000000005	1.4517E-5	0.48699999999999999	-1.751E-5	-9.2999999999999999E-2	-8.3381999999999992E-6	-0.81799999999999995	-6.0970000000000002E-6
0.55800000000000005	1.3953E-5	0.48499999999999999	-1.7847999999999999E-5	-0.10299999999999999	-8.2108999999999996E-6	-0.83799999999999997	-6.1709999999999999E-6
0.55700000000000005	1.3488E-5	0.48299999999999998	-1.8151E-5	-0.113	-8.0978000000000006E-6	-0.85799999999999998	-6.2299999999999996E-6
0.55600000000000005	1.2969000000000001E-5	0.48099999999999998	-1.8536999999999999E-5	-0.123	-7.9450999999999995E-6	-0.878	-6.2859999999999996E-6
0.55500000000000005	1.2343E-5	0.47899999999999998	-1.891E-5	-0.13300000000000001	-7.8007999999999999E-6	-0.89800000000000002	-6.3339999999999998E-6
0.55400000000000005	1.1887E-5	0.47699999999999998	-1.9239E-5	-0.14299999999999999	-7.6593999999999999E-6	-0.91800000000000004	-6.3759999999999996E-6
0.55300000000000005	1.1377E-5	0.47499999999999998	-1.9593E-5	-0.153	-7.5179999999999998E-6	-0.93799999999999994	-6.4169999999999997E-6
0.55200000000000005	1.0823E-5	0.47299999999999998	-1.9902999999999999E-5	-0.16300000000000001	-7.3737000000000002E-6	-0.95799999999999996	-6.4439999999999996E-6
0.55100000000000005	1.0402E-5	0.47099999999999997	-2.0251E-5	-0.17299999999999999	-7.2238000000000002E-6	-0.97799999999999998	-6.4740000000000002E-6
0.55000000000000004	9.9459999999999993E-6	0.46899999999999997	-2.0542000000000001E-5	-0.183	-7.0795999999999999E-6	-0.998	-6.4930000000000003E-6
0.54900000000000004	9.3647000000000003E-6	0.46700000000000003	-2.0826999999999999E-5	-0.193	-6.9380999999999997E-6	-1.018	-6.5069999999999997E-6
0.54800000000000004	8.8199E-6	0.46500000000000002	-2.1149E-5	-0.20300000000000001	-6.7994999999999999E-6	-1.038	-6.5230000000000001E-6
0.54700000000000004	8.4147999999999995E-6	0.46300000000000002	-2.1461999999999999E-5	-0.21299999999999999	-6.6722999999999996E-6	-1.0580000000000001	-6.5270000000000004E-6
0.54600000000000004	7.9147999999999992E-6	0.46100000000000002	-2.1744000000000001E-5	-0.223	-6.5365E-6	-1.0780000000000001	-6.5320000000000003E-6
0.54500000000000004	7.5096000000000001E-6	0.45900000000000002	-2.2065999999999998E-5	-0.23300000000000001	-6.4064000000000002E-6	-1.0980000000000001	-6.528E-6
0.54400000000000004	7.0883000000000004E-6	0.45700000000000002	-2.2323E-5	-0.24299999999999999	-6.2933000000000004E-6	-1.1180000000000001	-6.5270000000000004E-6
0.54300000000000004	6.5587999999999998E-6	0.45500000000000002	-2.2612999999999998E-5	-0.253	-6.1828999999999997E-6	-1.1379999999999999	-6.5309999999999998E-6
0.54200000000000004	5.9784000000000002E-6	0.45300000000000001	-2.2895E-5	-0.26300000000000001	-6.0811000000000001E-6	-1.1579999999999999	-6.5230000000000001E-6
0.54100000000000004	5.5607E-6	0.45100000000000001	-2.3186000000000001E-5	-0.27300000000000002	-5.9962999999999997E-6	-1.1779999999999999	-6.5220000000000004E-6
0.54	5.0374000000000003E-6	0.44900000000000001	-2.3397999999999999E-5	-0.28299999999999997	-5.9170999999999996E-6	-1.198	-6.5200000000000003E-6
0.53900000000000003	4.5401E-6	0.44700000000000001	-2.3669999999999999E-5	-0.29299999999999998	-5.8548000000000003E-6	-1.218	-6.516E-6
0.53800000000000003	4.0579999999999999E-6	0.44500000000000001	-2.3913E-5	-0.30299999999999999	-5.7953999999999996E-6	-1.238	-6.5209999999999999E-6
0.53700000000000003	3.5706000000000002E-6	0.443	-2.4168999999999998E-5	-0.313	-5.7699999999999998E-6	-1.258	-6.5230000000000001E-6
0.53600000000000003	3.0187E-6	0.441	-2.4383999999999999E-5	-0.32300000000000001	-5.7361E-6	-1.278	-6.528E-6
0.53500000000000003	2.7056E-6	0.439	-2.4579999999999998E-5	-0.33300000000000002	-5.7191E-6	-1.298	-6.5440000000000004E-6
0.53400000000000003	2.2888E-6	0.437	-2.4833000000000001E-5	-0.34300000000000003	-5.7134000000000002E-6	-1.3180000000000001	-6.5610000000000004E-6
0.53300000000000003	1.7343000000000001E-6	0.435	-2.5074000000000001E-5	-0.35299999999999998	-5.7246999999999996E-6	-1.3380000000000001	-6.5889999999999999E-6
0.53200000000000003	1.3345000000000001E-6	0.433	-2.5276E-5	-0.36299999999999999	-5.7444999999999998E-6	-1.3580000000000001	-6.6279999999999999E-6
0.53100000000000003	1.0143E-6	0.43099999999999999	-2.5507000000000002E-5	-0.373	-5.7784999999999998E-6	-1.3779999999999999	-6.674E-6
0.53	4.8245000000000004E-7	0.42899999999999999	-2.5636999999999999E-5	-0.38300000000000001	-5.8181000000000003E-6	-1.3979999999999999	-6.7360000000000004E-6
0.52900000000000003	6.1330999999999995E-8	0.42699999999999999	-2.5854999999999999E-5	-0.39300000000000002	-5.8661999999999998E-6	-1.4179999999999999	-6.815E-6
0.52800000000000002	-3.9649999999999998E-7	0.42499999999999999	-2.6067E-5	-0.40300000000000002	-5.9255999999999996E-6	-1.4379999999999999	-6.917E-6
0.52700000000000002	-8.5247999999999997E-7	0.42299999999999999	-2.6247000000000001E-5	-0.41299999999999998	-5.9962999999999997E-6	-1.458	-7.0389999999999999E-6
0.52600000000000002	-1.3139E-6	0.42099999999999999	-2.6471000000000001E-5	-0.42299999999999999	-6.0697999999999999E-6	-1.478	-7.1720000000000001E-6
0.52500000000000002	-1.7593E-6	0.41899999999999998	-2.6614E-5	-0.433	-6.1461999999999997E-6	-1.498	-7.3189999999999997E-6
0.52400000000000002	-2.2262E-6	0.41699999999999998	-2.6769000000000001E-5	-0.443	-6.2281999999999999E-6	-1.518	-7.4619999999999999E-6
0.52300000000000002	-2.6224999999999999E-6	0.41499999999999998	-2.6905000000000001E-5	-0.45300000000000001	-6.3187000000000002E-6	-1.538	-7.5979999999999999E-6
0.52200000000000002	-3.0634000000000002E-6	0.41299999999999998	-2.7104E-5	-0.46300000000000002	-6.4092000000000004E-6	-1.5580000000000001	-7.7170000000000008E-6
0.52100000000000002	-3.4023999999999998E-6	0.41099999999999998	-2.7308999999999999E-5	-0.47299999999999998	-6.5026000000000002E-6	-1.5780000000000001	-7.8120000000000008E-6
0.52	-3.9203000000000004E-6	0.40899999999999997	-2.7452000000000001E-5	-0.48299999999999998	-6.5958999999999998E-6	-1.5980000000000001	-7.9019999999999999E-6
0.51900000000000002	-4.3201000000000004E-6	0.40699999999999997	-2.7552999999999999E-5	-0.49299999999999999	-6.6949000000000001E-6	-1.6180000000000001	-7.9840000000000001E-6
0.51800000000000002	-4.634E-6	0.40500000000000003	-2.7761999999999999E-5	-0.503	-6.7939000000000003E-6	-1.6379999999999999	-8.0700000000000007E-6
0.51700000000000002	-5.1197000000000003E-6	0.40300000000000002	-2.8014999999999999E-5	-0.51300000000000001	-6.8928999999999997E-6	-1.6579999999999999	-8.1750000000000005E-6
0.51600000000000001	-5.6026999999999997E-6	0.40100000000000002	-2.8147E-5	-0.52300000000000002	-7.0032000000000001E-6	-1.6779999999999999	-8.2910000000000007E-6
0.51500000000000001	-5.9676000000000003E-6	0.39900000000000002	-2.8192E-5	-0.53300000000000003	-7.0879999999999997E-6	-1.698	-8.4249999999999998E-6
0.51400000000000001	-6.4246999999999997E-6	0.39700000000000002	-2.8311999999999999E-5	-0.54300000000000004	-7.187E-6	-1.718	-8.5709999999999998E-6
0.51300000000000001	-6.8692000000000002E-6	0.39500000000000002	-2.847E-5	-0.55300000000000005	-7.2832E-6	-1.738	-8.7199999999999995E-6
0.51200000000000001	-7.1894000000000001E-6	0.39300000000000002	-2.8552E-5	-0.56299999999999994	-7.3737000000000002E-6	-1.758	-8.8769999999999999E-6
0.51100000000000001	-7.6035000000000001E-6	0.39100000000000001	-2.8634000000000001E-5	-0.57299999999999995	-7.4444000000000002E-6	-1.778	-9.0229999999999998E-6
0.51	-8.0382000000000004E-6	0.38900000000000001	-2.8742E-5	-0.58299999999999996	-7.5518999999999996E-6	-1.798	-9.1649999999999995E-6
0.50900000000000001	-8.3387000000000003E-6	0.38700000000000001	-2.8867999999999999E-5	-0.59299999999999997	-7.6451999999999992E-6	-1.8180000000000001	-9.2960000000000004E-6
0.50800000000000001	-8.8118999999999994E-6	0.38500000000000001	-2.9033000000000001E-5	-0.60299999999999998	-7.7386000000000008E-6	-1.8380000000000001	-9.4190000000000008E-6
0.50700000000000001	-9.2752000000000006E-6	0.38300000000000001	-2.9166000000000002E-5	-0.61299999999999999	-7.8262999999999999E-6	-1.8580000000000001	-9.5300000000000002E-6
0.50600000000000001	-9.9012999999999995E-6	0.38100000000000001	-2.9280000000000001E-5	-0.623	-7.9253000000000002E-6	-1.8779999999999999	-9.6190000000000006E-6
0.505	-1.0429E-5	0.379	-2.9377999999999999E-5	-0.63300000000000001	-7.9988000000000004E-6	-1.8979999999999999	-9.696E-6
0.504	-1.0688E-5	0.377	-2.9468999999999999E-5	-0.64300000000000002	-8.0779999999999996E-6	-1.9179999999999999	-9.7529999999999996E-6
0.503	-1.1001E-5	0.375	-2.9519999999999999E-5	-0.65300000000000002	-8.1543999999999994E-6	-1.9379999999999999	-9.7990000000000005E-6
0.502	-1.1234E-5	0.373	-2.9680999999999999E-5	-0.66300000000000003	-8.2307000000000007E-6	-1.958	-9.8449999999999998E-6
0.501	-1.1654000000000001E-5	0.371	-2.9808E-5	-0.67300000000000004	-8.3156000000000005E-6	-1.978	-9.8810000000000008E-6
0.5	-1.2111E-5	0.36899999999999999	-2.9899E-5	-0.68300000000000005	-8.3835000000000003E-6	-1.998	-9.9229999999999997E-6
0.499	-1.2415000000000001E-5	0.36699999999999999	-2.9997000000000001E-5	-0.69299999999999995	-8.4541999999999995E-6	-2.0179999999999998	-9.9729999999999992E-6
0.498	-1.2826000000000001E-5	0.36499999999999999	-3.0012999999999999E-5	-0.70299999999999996	-8.5220999999999993E-6	-2.0379999999999998	-1.0030000000000001E-5
0.497	-1.3202E-5	0.36299999999999999	-3.0120999999999998E-5	-0.71299999999999997	-8.5928000000000001E-6	-2.0579999999999998	-1.011E-5
0.496	-1.3577000000000001E-5	0.36099999999999999	-3.0272000000000001E-5	-0.72299999999999998	-8.6719999999999993E-6	-2.0779999999999998	-1.0200000000000001E-5
0.495	-1.3988999999999999E-5	0.35899999999999999	-3.0383E-5	-0.73299999999999998	-8.7314000000000008E-6	-2.0979999999999999	-1.0339999999999999E-5
0.49399999999999999	-1.432E-5	0.35699999999999998	-3.0459000000000001E-5	-0.74299999999999999	-8.7963999999999993E-6	-2.1179999999999999	-1.0530000000000001E-5
0.49299999999999999	-1.4579000000000001E-5	0.35499999999999998	-3.0540999999999998E-5	-0.753	-8.8501000000000002E-6	-2.1379999999999999	-1.079E-5
0.49199999999999999	-1.4963999999999999E-5	0.35299999999999998	-3.0664999999999999E-5	-0.76300000000000001	-8.9067000000000006E-6	-2.1579999999999999	-1.114E-5
0.49099999999999999	-1.5447E-5	0.35099999999999998	-3.0787999999999997E-5	-0.77300000000000002	-8.9717999999999994E-6	-2.16	-8.2230000000000007E-6
0.49	-1.5733E-5	0.34899999999999998	-3.0873000000000001E-5	-0.78300000000000003	-9.0255000000000002E-6	-2.14	-4.3109999999999999E-6
0.48899999999999999	-1.6036999999999999E-5	0.34699999999999998	-3.0920999999999998E-5	-0.79300000000000004	-9.0792999999999996E-6	-2.12	-2.244E-6
0.48799999999999999	-1.6492999999999999E-5	0.34499999999999997	-3.0993E-5	-0.80300000000000005	-9.1245000000000005E-6	-2.1	-8.8370000000000001E-7
0.48699999999999999	-1.6886999999999999E-5	0.34300000000000003	-3.1114000000000001E-5	-0.81299999999999994	-9.1754000000000003E-6	-2.08	7.8899999999999998E-8
0.48599999999999999	-1.7218E-5	0.34100000000000003	-3.1195999999999997E-5	-0.82299999999999995	-9.2291999999999997E-6	-2.06	7.8540000000000003E-7
0.48499999999999999	-1.7638E-5	0.33900000000000002	-3.1223999999999998E-5	-0.83299999999999996	-9.2744000000000005E-6	-2.04	1.3170000000000001E-6
0.48399999999999999	-1.7951000000000001E-5	0.33700000000000002	-3.1272000000000001E-5	-0.84299999999999997	-9.3139999999999993E-6	-2.02	1.719E-6
0.48299999999999998	-1.8363E-5	0.33500000000000002	-3.1378999999999999E-5	-0.85299999999999998	-9.3508000000000003E-6	-2	2.041E-6
0.48199999999999998	-1.8774E-5	0.33300000000000002	-3.1442999999999997E-5	-0.86299999999999999	-9.3847000000000001E-6	-1.98	2.3010000000000001E-6
0.48099999999999998	-1.9131999999999999E-5	0.33100000000000002	-3.1534E-5	-0.873	-9.4243000000000006E-6	-1.96	2.5239999999999999E-6
0.48	-1.9202999999999999E-5	0.32900000000000001	-3.1619999999999999E-5	-0.88300000000000001	-9.4553999999999993E-6	-1.94	2.7180000000000001E-6
0.47899999999999998	-1.9525E-5	0.32700000000000001	-3.1622999999999999E-5	-0.89300000000000002	-9.4864999999999997E-6	-1.92	2.881E-6
0.47799999999999998	-2.0035E-5	0.32500000000000001	-3.1686000000000001E-5	-0.90300000000000002	-9.5148000000000008E-6	-1.9	3.0350000000000002E-6
0.47699999999999998	-2.033E-5	0.32300000000000001	-3.1780999999999999E-5	-0.91300000000000003	-9.5431000000000002E-6	-1.88	3.1690000000000001E-6
0.47599999999999998	-2.0715000000000001E-5	0.32100000000000001	-3.1906999999999998E-5	-0.92300000000000004	-9.5657000000000006E-6	-1.86	3.2990000000000001E-6
0.47499999999999998	-2.1152999999999999E-5	0.31900000000000001	-3.1939E-5	-0.93300000000000005	-9.6025E-6	-1.84	3.4300000000000002E-6
0.47399999999999998	-2.1484E-5	0.317	-3.2002000000000003E-5	-0.94299999999999995	-9.6137999999999993E-6	-1.82	3.5499999999999999E-6
0.47299999999999998	-2.1869E-5	0.315	-3.2033999999999999E-5	-0.95299999999999996	-9.6365E-6	-1.8	3.6739999999999999E-6
0.47199999999999998	-2.2181999999999999E-5	0.313	-3.2097000000000001E-5	-0.96299999999999997	-9.6562999999999993E-6	-1.78	3.8070000000000001E-6
0.47099999999999997	-2.2476999999999998E-5	0.311	-3.2159999999999997E-5	-0.97299999999999998	-9.6732000000000008E-6	-1.76	3.9480000000000001E-6
0.47	-2.2710000000000001E-5	0.309	-3.2286999999999998E-5	-0.98299999999999998	-9.6873999999999998E-6	-1.74	4.1019999999999999E-6
0.46899999999999997	-2.3057999999999998E-5	0.307	-3.2317999999999998E-5	-0.99299999999999999	-9.7015000000000002E-6	-1.72	4.2479999999999998E-6
0.46800000000000003	-2.3416000000000001E-5	0.30499999999999999	-3.235E-5	-1.0029999999999999	-9.7100000000000002E-6	-1.7	4.3850000000000004E-6
0.46700000000000003	-2.3612999999999999E-5	0.30299999999999999	-3.2413000000000003E-5	-1.0129999999999999	-9.7241000000000006E-6	-1.68	4.5079999999999999E-6
0.46600000000000003	-2.3997000000000001E-5	0.30099999999999999	-3.2666000000000002E-5	-1.0229999999999999	-9.7270000000000002E-6	-1.66	4.6099999999999999E-6
0.46500000000000002	-2.4372999999999999E-5	0.29899999999999999	-3.2635000000000002E-5	-1.0329999999999999	-9.7467999999999996E-6	-1.64	4.7049999999999998E-6
0.46400000000000002	-2.4624E-5	0.29699999999999999	-3.2635000000000002E-5	-1.0429999999999999	-9.7467999999999996E-6	-1.62	4.78E-6
0.46300000000000002	-2.4955000000000001E-5	0.29499999999999998	-3.2666000000000002E-5	-1.0529999999999999	-9.7496000000000006E-6	-1.6	4.848E-6
0.46200000000000002	-2.5276999999999999E-5	0.29299999999999998	-3.273E-5	-1.0629999999999999	-9.7551999999999994E-6	-1.58	4.9130000000000002E-6
0.46100000000000002	-2.5491E-5	0.29099999999999998	-3.2761E-5	-1.073	-9.7581000000000006E-6	-1.56	4.9629999999999997E-6
0.46	-2.5876000000000001E-5	0.28899999999999998	-3.2793000000000003E-5	-1.083	-9.7694E-6	-1.54	5.0139999999999998E-6
0.45900000000000002	-2.6251E-5	0.28699999999999998	-3.2824000000000003E-5	-1.093	-9.7694E-6	-1.52	5.057E-6
0.45800000000000002	-2.6475E-5	0.28499999999999998	-3.2888000000000001E-5	-1.103	-9.7721999999999994E-6	-1.5	5.0989999999999998E-6
0.45700000000000002	-2.6733999999999998E-5	0.28299999999999997	-3.2919000000000001E-5	-1.113	-9.7721999999999994E-6	-1.48	5.1390000000000003E-6
0.45600000000000002	-2.7056E-5	0.28100000000000003	-3.2982999999999999E-5	-1.123	-9.7750000000000004E-6	-1.46	5.1839999999999998E-6
0.45500000000000002	-2.7378000000000001E-5	0.27900000000000003	-3.3013999999999999E-5	-1.133	-9.7920000000000004E-6	-1.44	5.2290000000000002E-6
0.45400000000000001	-2.7781E-5	0.27700000000000002	-3.3077000000000002E-5	-1.143	-9.7891999999999994E-6	-1.42	5.2680000000000002E-6
0.45300000000000001	-2.8093999999999999E-5	0.27500000000000002	-3.3108999999999998E-5	-1.153	-9.7891999999999994E-6	-1.4	5.3120000000000001E-6
0.45200000000000001	-2.8263999999999999E-5	0.27300000000000002	-3.3204000000000003E-5	-1.163	-9.7947999999999998E-6	-1.38	5.3499999999999996E-6
0.45100000000000001	-2.8479E-5	0.27100000000000002	-3.3266999999999998E-5	-1.173	-9.8005000000000004E-6	-1.36	5.3920000000000002E-6
0.45	-2.8747000000000001E-5	0.26900000000000002	-3.3330000000000001E-5	-1.1830000000000001	-9.8090000000000004E-6	-1.34	5.4360000000000001E-6
0.44900000000000001	-2.906E-5	0.26700000000000002	-3.3361999999999997E-5	-1.1930000000000001	-9.8202999999999998E-6	-1.32	5.4750000000000001E-6
0.44800000000000001	-2.9257000000000001E-5	0.26500000000000001	-3.3457000000000002E-5	-1.2030000000000001	-9.8230999999999992E-6	-1.3	5.5210000000000002E-6
0.44700000000000001	-2.957E-5	0.26300000000000001	-3.3457000000000002E-5	-1.2130000000000001	-9.8344000000000002E-6	-1.28	5.5620000000000003E-6
0.44600000000000001	-2.9882999999999998E-5	0.26100000000000001	-3.3519999999999998E-5	-1.2230000000000001	-9.8457999999999998E-6	-1.26	5.6019999999999999E-6
0.44500000000000001	-3.0114999999999999E-5	0.25900000000000001	-3.3519999999999998E-5	-1.2330000000000001	-9.8684000000000002E-6	-1.24	5.648E-6
0.44400000000000001	-3.0232000000000001E-5	0.25700000000000001	-3.3646999999999998E-5	-1.2430000000000001	-9.8854000000000003E-6	-1.22	5.6969999999999998E-6
0.443	-3.0463999999999998E-5	0.255	-3.3677999999999998E-5	-1.2529999999999999	-9.9023E-6	-1.2	5.733E-6
0.442	-3.0660999999999997E-5	0.253	-3.3710000000000001E-5	-1.2629999999999999	-9.9165000000000007E-6	-1.18	5.7799999999999997E-6
0.441	-3.0929000000000002E-5	0.251	-3.3772999999999997E-5	-1.2729999999999999	-9.9446999999999998E-6	-1.1599999999999999	5.8220000000000003E-6
0.44	-3.1269000000000002E-5	0.249	-3.3772999999999997E-5	-1.2829999999999999	-9.9786999999999999E-6	-1.1399999999999999	5.8649999999999998E-6
0.439	-3.1466E-5	0.247	-3.3868000000000002E-5	-1.2929999999999999	-1.0015E-5	-1.1200000000000001	5.9089999999999997E-6
0.438	-3.1724999999999999E-5	0.245	-3.3930999999999998E-5	-1.3029999999999999	-1.0052E-5	-1.1000000000000001	5.9490000000000001E-6
0.437	-3.1949000000000002E-5	0.24299999999999999	-3.4026000000000003E-5	-1.3129999999999999	-1.0097E-5	-1.08	5.9939999999999997E-6
0.436	-3.2181000000000002E-5	0.24099999999999999	-3.4088999999999998E-5	-1.323	-1.0146000000000001E-5	-1.06	6.0349999999999998E-6
0.435	-3.2431999999999997E-5	0.23899999999999999	-3.4121000000000001E-5	-1.333	-1.0213E-5	-1.04	6.0789999999999997E-6
0.434	-3.2709000000000001E-5	0.23699999999999999	-3.4183999999999997E-5	-1.343	-1.029E-5	-1.02	6.1319999999999999E-6
0.433	-3.2950999999999997E-5	0.23499999999999999	-3.4183999999999997E-5	-1.353	-1.0355E-5	-1	6.1739999999999997E-6
0.432	-3.3058000000000001E-5	0.23300000000000001	-3.4310999999999997E-5	-1.363	-1.0437E-5	-0.98	6.224E-6
0.43099999999999999	-3.3246E-5	0.23100000000000001	-3.4406000000000002E-5	-1.373	-1.0539E-5	-0.96	6.2720000000000003E-6
0.43	-3.3504999999999999E-5	0.22900000000000001	-3.4437000000000002E-5	-1.383	-1.0643E-5	-0.94	6.3180000000000003E-6
0.42899999999999999	-3.3577000000000001E-5	0.22700000000000001	-3.4468999999999998E-5	-1.393	-1.0764999999999999E-5	-0.92	6.3720000000000001E-6
0.42799999999999999	-3.3773999999999999E-5	0.22500000000000001	-3.4499999999999998E-5	-1.403	-1.0898E-5	-0.9	6.4130000000000003E-6
0.42699999999999999	-3.4112999999999997E-5	0.223	-3.4532000000000001E-5	-1.413	-1.1045E-5	-0.88	6.4509999999999997E-6
0.42599999999999999	-3.4266E-5	0.221	-3.4595000000000003E-5	-1.423	-1.1202999999999999E-5	-0.86	6.4860000000000002E-6
0.42499999999999999	-3.4409000000000002E-5	0.219	-3.4659000000000001E-5	-1.4330000000000001	-1.1365E-5	-0.84	6.516E-6
0.42399999999999999	-3.4740000000000003E-5	0.217	-3.4721999999999997E-5	-1.4430000000000001	-1.1551E-5	-0.82	6.5459999999999997E-6
0.42299999999999999	-3.4847E-5	0.215	-3.4817000000000002E-5	-1.4530000000000001	-1.1718E-5	-0.8	6.5599999999999999E-6
0.42199999999999999	-3.5008000000000001E-5	0.21299999999999999	-3.4848000000000002E-5	-1.4630000000000001	-1.1895999999999999E-5	-0.78	6.5729999999999996E-6
0.42099999999999999	-3.5187E-5	0.21099999999999999	-3.4817000000000002E-5	-1.4730000000000001	-1.2075E-5	-0.76	6.5869999999999998E-6
0.42	-3.5339000000000002E-5	0.20899999999999999	-3.4912E-5	-1.4830000000000001	-1.2238999999999999E-5	-0.74	6.584E-6
0.41899999999999998	-3.5509000000000002E-5	0.20699999999999999	-3.5006000000000003E-5	-1.4930000000000001	-1.2403E-5	-0.72	6.5849999999999996E-6
0.41799999999999998	-3.5750000000000002E-5	0.20499999999999999	-3.5070000000000001E-5	-1.5029999999999999	-1.2547E-5	-0.7	6.5749999999999997E-6
0.41699999999999998	-3.6010000000000003E-5	0.20300000000000001	-3.5070000000000001E-5	-1.5129999999999999	-1.2677000000000001E-5	-0.68	6.5599999999999999E-6
0.41599999999999998	-3.6028000000000001E-5	0.20100000000000001	-3.5132999999999997E-5	-1.5229999999999999	-1.279E-5	-0.66	6.5420000000000002E-6
0.41499999999999998	-3.6295999999999999E-5	0.19900000000000001	-3.5259000000000002E-5	-1.5329999999999999	-1.2886E-5	-0.64	6.5200000000000003E-6
0.41399999999999998	-3.6501999999999997E-5	0.19700000000000001	-3.5290999999999998E-5	-1.5429999999999999	-1.2985E-5	-0.62	6.4949999999999996E-6
0.41299999999999998	-3.6554999999999998E-5	0.19500000000000001	-3.5259000000000002E-5	-1.5529999999999999	-1.3053E-5	-0.6	6.46E-6
0.41199999999999998	-3.6806E-5	0.193	-3.5259000000000002E-5	-1.5629999999999999	-1.3113E-5	-0.57999999999999996	6.421E-6
0.41099999999999998	-3.6984999999999999E-5	0.191	-3.5259000000000002E-5	-1.573	-1.3172E-5	-0.56000000000000005	6.3659999999999997E-6
0.41	-3.7092000000000003E-5	0.189	-3.5165E-5	-1.583	-1.3223E-5	-0.54	6.3210000000000001E-6
0.40899999999999997	-3.7280000000000002E-5	0.187	-3.5165E-5	-1.593	-1.3281999999999999E-5	-0.52	6.268E-6
0.40799999999999997	-3.7539000000000001E-5	0.185	-3.5132999999999997E-5	-1.603	-1.3346999999999999E-5	-0.5	6.2029999999999997E-6
0.40699999999999997	-3.7530000000000002E-5	0.183	-3.5101000000000002E-5	-1.613	-1.3407000000000001E-5	-0.48	6.1249999999999998E-6
0.40600000000000003	-3.7629000000000002E-5	0.18099999999999999	-3.5070000000000001E-5	-1.623	-1.348E-5	-0.46	6.0410000000000003E-6
0.40500000000000003	-3.7790000000000002E-5	0.17899999999999999	-3.4975000000000003E-5	-1.633	-1.3565E-5	-0.44	5.947E-6
0.40400000000000003	-3.8102999999999998E-5	0.17699999999999999	-3.4912E-5	-1.643	-1.3667E-5	-0.42	5.852E-6
0.40300000000000002	-3.8495999999999999E-5	0.17499999999999999	-3.4817000000000002E-5	-1.653	-1.3777E-5	-0.4	5.7529999999999998E-6
0.40200000000000002	-3.8577E-5	0.17299999999999999	-3.4659000000000001E-5	-1.663	-1.3876000000000001E-5	-0.38	5.6520000000000003E-6
0.40100000000000002	-3.8729000000000001E-5	0.17100000000000001	-3.4532000000000001E-5	-1.673	-1.4001E-5	-0.36	5.5659999999999997E-6
0.4	-3.8674999999999998E-5	0.16900000000000001	-3.4437000000000002E-5	-1.6830000000000001	-1.4131000000000001E-5	-0.34	5.4879999999999998E-6
0.39900000000000002	-3.8702000000000003E-5	0.16700000000000001	-3.4374E-5	-1.6930000000000001	-1.4258E-5	-0.32	5.4310000000000002E-6
0.39800000000000002	-3.8908000000000001E-5	0.16500000000000001	-3.4279000000000002E-5	-1.7030000000000001	-1.4391E-5	-0.3	5.4E-6
0.39700000000000002	-3.8943000000000003E-5	0.16300000000000001	-3.4153000000000003E-5	-1.7130000000000001	-1.4515000000000001E-5	-0.28000000000000003	5.3850000000000001E-6
0.39600000000000002	-3.9167E-5	0.161	-3.3930999999999998E-5	-1.7230000000000001	-1.4651000000000001E-5	-0.26	5.4029999999999998E-6
0.39500000000000002	-3.9328E-5	0.159	-3.3804999999999999E-5	-1.7330000000000001	-1.4783999999999999E-5	-0.24	5.4480000000000002E-6
0.39400000000000002	-3.9363999999999998E-5	0.157	-3.3646999999999998E-5	-1.7430000000000001	-1.4926000000000001E-5	-0.22	5.5199999999999997E-6
0.39300000000000002	-3.9524999999999999E-5	0.155	-3.3488999999999997E-5	-1.7529999999999999	-1.507E-5	-0.2	5.6210000000000001E-6
0.39200000000000002	-3.9623000000000003E-5	0.153	-3.3330000000000001E-5	-1.7629999999999999	-1.5194000000000001E-5	-0.18	5.7379999999999999E-6
0.39100000000000001	-3.9694999999999999E-5	0.151	-3.3108999999999998E-5	-1.7729999999999999	-1.5327000000000001E-5	-0.16	5.879E-6
0.39	-3.9721999999999997E-5	0.14899999999999999	-3.2982999999999999E-5	-1.7829999999999999	-1.5449000000000001E-5	-0.14000000000000001	6.0279999999999997E-6
0.38900000000000001	-3.9953999999999997E-5	0.14699999999999999	-3.273E-5	-1.7929999999999999	-1.5576000000000001E-5	-0.12	6.1940000000000003E-6
0.38800000000000001	-4.0096999999999999E-5	0.14499999999999999	-3.2508000000000001E-5	-1.8029999999999999	-1.5678000000000001E-5	-0.1	6.3740000000000003E-6
0.38700000000000001	-4.0123999999999997E-5	0.14299999999999999	-3.2286999999999998E-5	-1.8129999999999999	-1.5801999999999999E-5	-0.08	6.55E-6
0.38600000000000001	-4.0330000000000002E-5	0.14099999999999999	-3.2128999999999997E-5	-1.823	-1.5900999999999999E-5	-0.06	6.737E-6
0.38500000000000001	-4.0543999999999997E-5	0.13900000000000001	-3.1906999999999998E-5	-1.833	-1.5985999999999999E-5	-0.04	6.9260000000000003E-6
0.38400000000000001	-4.0482000000000003E-5	0.13700000000000001	-3.1686000000000001E-5	-1.843	-1.6065E-5	-0.02	7.1210000000000001E-6
0.38300000000000001	-4.0633999999999998E-5	0.13500000000000001	-3.1408000000000002E-5	-1.853	-1.6152999999999999E-5	0	7.3250000000000002E-6
0.38200000000000001	-4.0812999999999997E-5	0.13300000000000001	-3.1233999999999999E-5	-1.863	-1.6203999999999999E-5	0.02	7.5159999999999997E-6
0.38100000000000001	-4.0911000000000002E-5	0.13100000000000001	-3.1003000000000001E-5	-1.873	-1.6246E-5	0.04	7.7039999999999994E-6
0.38	-4.1081000000000002E-5	0.129	-3.0842E-5	-1.883	-1.6291999999999999E-5	0.06	7.8909999999999995E-6
0.379	-4.1170000000000001E-5	0.127	-3.0614000000000002E-5	-1.893	-1.6322999999999999E-5	0.08	8.0770000000000008E-6
0.378	-4.1125999999999999E-5	0.125	-3.0389E-5	-1.903	-1.6354E-5	0.1	8.2849999999999995E-6
0.377	-4.1196999999999999E-5	0.123	-3.0159E-5	-1.913	-1.6379E-5	0.12	8.5180000000000004E-6
0.376	-4.1366999999999999E-5	0.121	-2.9978E-5	-1.923	-1.6405E-5	0.14000000000000001	8.8040000000000007E-6
0.375	-4.1483999999999998E-5	0.11899999999999999	-2.9754E-5	-1.9330000000000001	-1.6436E-5	0.16	9.1609999999999992E-6
0.374	-4.1554999999999998E-5	0.11700000000000001	-2.9612E-5	-1.9430000000000001	-1.6453E-5	0.18	9.5889999999999992E-6
0.373	-4.1680000000000001E-5	0.115	-2.9371000000000001E-5	-1.9530000000000001	-1.6501E-5	0.2	1.006E-5
0.372	-4.1885999999999998E-5	0.113	-2.9181000000000001E-5	-1.9630000000000001	-1.6532E-5	0.22	1.0530000000000001E-5
0.371	-4.1922000000000003E-5	0.111	-2.8963E-5	-1.9730000000000001	-1.6569E-5	0.24	1.093E-5
0.37	-4.2082999999999997E-5	0.109	-2.8748E-5	-1.9830000000000001	-1.6606E-5	0.26	1.1229999999999999E-5
0.36899999999999999	-4.2262000000000003E-5	0.107	-2.8589999999999999E-5	-1.9930000000000001	-1.6659000000000001E-5	0.28000000000000003	1.1440000000000001E-5
0.36799999999999999	-4.2234999999999998E-5	0.105	-2.8422999999999999E-5	-2.0030000000000001	-1.6710000000000001E-5	0.3	1.1579999999999999E-5
0.36699999999999999	-4.2342000000000002E-5	0.10299999999999999	-2.828E-5	-2.0129999999999999	-1.677E-5	0.32	1.168E-5
0.36599999999999999	-4.2475999999999998E-5	0.10100000000000001	-2.8132000000000001E-5	-2.0230000000000001	-1.6843000000000001E-5	0.34	1.1770000000000001E-5
0.36499999999999999	-4.2493999999999997E-5	9.9000000000000005E-2	-2.7966999999999998E-5	-2.0329999999999999	-1.6922000000000002E-5	0.36	1.187E-5
0.36399999999999999	-4.2512000000000002E-5	9.7000000000000003E-2	-2.7898E-5	-2.0430000000000001	-1.7020999999999998E-5	0.38	1.198E-5
0.36299999999999999	-4.278E-5	9.5000000000000001E-2	-2.7742999999999998E-5	-2.0529999999999999	-1.7132000000000001E-5	0.4	1.2089999999999999E-5
0.36199999999999999	-4.2843000000000003E-5	9.2999999999999999E-2	-2.7562000000000001E-5	-2.0630000000000002	-1.7269999999999999E-5	0.42	1.221E-5
0.36099999999999999	-4.2861000000000002E-5	9.0999999999999998E-2	-2.7392000000000001E-5	-2.073	-1.7422999999999999E-5	0.44	1.2320000000000001E-5
0.36	-4.2967999999999999E-5	8.8999999999999996E-2	-2.7274999999999999E-5	-2.0830000000000002	-1.7601E-5	0.46	1.2439999999999999E-5
0.35899999999999999	-4.3075999999999999E-5	8.6999999999999994E-2	-2.7107E-5	-2.093	-1.7810999999999999E-5	0.48	1.258E-5
0.35799999999999998	-4.3173999999999997E-5	8.5000000000000006E-2	-2.6945999999999999E-5	-2.1030000000000002	-1.8051E-5	0.5	1.277E-5
0.35699999999999998	-4.3343999999999997E-5	8.3000000000000004E-2	-2.6803000000000001E-5	-2.113	-1.8325000000000002E-5	0.52	1.3020000000000001E-5
0.35599999999999998	-4.3398E-5	8.1000000000000003E-2	-2.6727999999999999E-5	-2.1230000000000002	-1.8638999999999999E-5	0.54	1.3329999999999999E-5
0.35499999999999998	-4.3389000000000001E-5	7.9000000000000001E-2	-2.6611E-5	-2.133	-1.9001E-5	0.56000000000000005	1.3730000000000001E-5
0.35399999999999998	-4.3504999999999998E-5	7.6999999999999999E-2	-2.6512999999999998E-5	-2.1429999999999998	-1.942E-5	0.57999999999999996	1.4209999999999999E-5
0.35299999999999998	-4.3594000000000003E-5	7.4999999999999997E-2	-2.6418E-5	-2.153	-1.9891999999999999E-5	0.6	1.4739999999999999E-5
0.35199999999999998	-4.3656999999999999E-5	7.2999999999999995E-2	-2.6259999999999999E-5	-2.1629999999999998	-2.0407E-5	0.62	1.5270000000000001E-5
0.35099999999999998	-4.3782000000000002E-5	7.0999999999999994E-2	-2.6146E-5	-2.165	-1.6767000000000001E-5
0.35	-4.3915999999999998E-5	6.9000000000000006E-2	-2.6067E-5	-2.1549999999999998	-1.1099E-5
0.34899999999999998	-4.3934000000000003E-5	6.7000000000000004E-2	-2.5987999999999999E-5	-2.145	-8.1572000000000004E-6
0.34799999999999998	-4.4058999999999999E-5	6.5000000000000002E-2	-2.5933999999999999E-5	-2.1349999999999998	-6.1404999999999999E-6
0.34699999999999998	-4.4085999999999998E-5	6.3E-2	-2.5845000000000001E-5	-2.125	-4.5877000000000001E-6
0.34599999999999997	-4.4229E-5	6.0999999999999999E-2	-2.5754000000000001E-5	-2.1150000000000002	-3.3403999999999998E-6
0.34499999999999997	-4.4336999999999999E-5	5.8999999999999997E-2	-2.569E-5	-2.105	-2.3111000000000002E-6
0.34399999999999997	-4.439E-5	5.7000000000000002E-2	-2.5605E-5	-2.0950000000000002	-1.4609000000000001E-6
0.34300000000000003	-4.4471000000000002E-5	5.5E-2	-2.5503999999999998E-5	-2.085	-7.5122999999999998E-7
0.34200000000000003	-4.4569E-5	5.2999999999999999E-2	-2.5466E-5	-2.0750000000000002	-1.4763999999999999E-7
0.34100000000000003	-4.4595999999999998E-5	5.0999999999999997E-2	-2.5443999999999999E-5	-2.0649999999999999	3.6091000000000002E-7
0.34	-4.4641000000000002E-5	4.9000000000000002E-2	-2.5349000000000001E-5	-2.0550000000000002	8.0978000000000004E-7
0.33900000000000002	-4.4632000000000002E-5	4.7E-2	-2.5273E-5	-2.0449999999999999	1.1862E-6
0.33800000000000002	-4.4739E-5	4.4999999999999998E-2	-2.5244000000000001E-5	-2.0350000000000001	1.5109E-6
0.33700000000000002	-4.4909E-5	4.2999999999999997E-2	-2.5202999999999999E-5	-2.0249999999999999	1.7966000000000001E-6
0.33600000000000002	-4.4909E-5	4.1000000000000002E-2	-2.5137E-5	-2.0150000000000001	2.0540000000000002E-6
0.33500000000000002	-4.4990000000000001E-5	3.9E-2	-2.5038999999999999E-5	-2.0049999999999999	2.2904999999999999E-6
0.33400000000000002	-4.5142000000000002E-5	3.6999999999999998E-2	-2.5007E-5	-1.9950000000000001	2.5036999999999998E-6
0.33300000000000002	-4.5185999999999997E-5	3.5000000000000003E-2	-2.4938000000000001E-5	-1.9850000000000001	2.6917999999999998E-6
0.33200000000000002	-4.5275999999999998E-5	3.3000000000000002E-2	-2.4924999999999999E-5	-1.9750000000000001	2.8679999999999999E-6
0.33100000000000002	-4.5293999999999997E-5	3.1E-2	-2.4865E-5	-1.9650000000000001	3.0321000000000002E-6
0.33	-4.5346999999999998E-5	2.9000000000000001E-2	-2.4794999999999999E-5	-1.9550000000000001	3.1905000000000002E-6
0.32900000000000001	-4.5419E-5	2.7E-2	-2.4786E-5	-1.9450000000000001	3.3403999999999998E-6
0.32800000000000001	-4.5553000000000002E-5	2.5000000000000001E-2	-2.4748000000000001E-5	-1.9350000000000001	3.4676999999999999E-6
0.32700000000000001	-4.5597999999999999E-5	2.3E-2	-2.4666000000000001E-5	-1.925	3.5920999999999999E-6
0.32600000000000001	-4.5516999999999998E-5	2.1000000000000001E-2	-2.4609000000000001E-5	-1.915	3.7137000000000001E-6
0.32500000000000001	-4.5597999999999999E-5	1.9E-2	-2.4573999999999999E-5	-1.905	3.8325000000000002E-6
0.32400000000000001	-4.5741000000000001E-5	1.7000000000000001E-2	-2.4545999999999998E-5	-1.895	3.9512999999999998E-6
0.32300000000000001	-4.5704999999999997E-5	1.4999999999999999E-2	-2.4527000000000001E-5	-1.885	4.0531000000000002E-6
0.32200000000000001	-4.5847999999999999E-5	1.2999999999999999E-2	-2.4491999999999999E-5	-1.875	4.1633999999999998E-6
0.32100000000000001	-4.5973999999999997E-5	1.0999999999999999E-2	-2.4443999999999998E-5	-1.865	4.2652999999999996E-6
0.32	-4.6090000000000001E-5	8.9999999999999993E-3	-2.4437999999999999E-5	-1.855	4.3699000000000003E-6
0.31900000000000001	-4.6116999999999999E-5	7.0000000000000001E-3	-2.4352999999999999E-5	-1.845	4.4886999999999999E-6
0.318	-4.6161000000000001E-5	5.0000000000000001E-3	-2.4312E-5	-1.835	4.5820999999999997E-6
0.317	-4.6161000000000001E-5	3.0000000000000001E-3	-2.4280000000000001E-5	-1.825	4.6867000000000004E-6
0.316	-4.6278E-5	1E-3	-2.4280000000000001E-5	-1.8149999999999999	4.7941999999999998E-6
0.315	-4.6286999999999999E-5	-1E-3	-2.4229000000000001E-5	-1.8049999999999999	4.9045000000000002E-6
0.314	-4.6205999999999998E-5	-3.0000000000000001E-3	-2.4162999999999999E-5	-1.7949999999999999	5.0147999999999998E-6
0.313	-4.6242000000000002E-5	-5.0000000000000001E-3	-2.4239E-5	-1.7849999999999999	5.1448999999999996E-6
0.312	-4.6384999999999997E-5	-7.0000000000000001E-3	-2.4229000000000001E-5	-1.7749999999999999	5.2777999999999997E-6
0.311	-4.6501000000000001E-5	-8.9999999999999993E-3	-2.4125E-5	-1.7649999999999999	5.4107999999999999E-6
0.31	-4.6483000000000002E-5	-1.0999999999999999E-2	-2.4111999999999999E-5	-1.7549999999999999	5.5493999999999998E-6
0.309	-4.6625999999999997E-5	-1.2999999999999999E-2	-2.4029999999999999E-5	-1.7450000000000001	5.6964999999999996E-6
0.308	-4.6743000000000003E-5	-1.4999999999999999E-2	-2.3998999999999998E-5	-1.7350000000000001	5.835E-6
0.307	-4.6697999999999999E-5	-1.7000000000000001E-2	-2.3957000000000001E-5	-1.7250000000000001	5.9622999999999996E-6
0.30599999999999999	-4.6779000000000001E-5	-1.9E-2	-2.3878000000000001E-5	-1.7150000000000001	6.0811000000000001E-6
0.30499999999999999	-4.6913000000000003E-5	-2.1000000000000001E-2	-2.3887999999999999E-5	-1.7050000000000001	6.1913999999999997E-6
0.30399999999999999	-4.6885999999999998E-5	-2.3E-2	-2.3836999999999999E-5	-1.6950000000000001	6.2933000000000004E-6
0.30299999999999999	-4.6931000000000002E-5	-2.5000000000000001E-2	-2.3799E-5	-1.6850000000000001	6.3809000000000002E-6
0.30199999999999999	-4.7037999999999999E-5	-2.7E-2	-2.3782999999999999E-5	-1.675	6.4544999999999998E-6
0.30099999999999999	-4.7475999999999997E-5	-2.9000000000000001E-2	-2.3757999999999999E-5	-1.665	6.5223999999999996E-6
0.3	-4.7539E-5	-3.1E-2	-2.3672999999999998E-5	-1.655	6.5845999999999996E-6
0.29899999999999999	-4.7369E-5	-3.3000000000000002E-2	-2.3621999999999998E-5	-1.645	6.6552999999999996E-6
0.29799999999999999	-4.7234999999999998E-5	-3.5000000000000003E-2	-2.3603000000000001E-5	-1.635	6.7147000000000003E-6
0.29699999999999999	-4.7243999999999997E-5	-3.6999999999999998E-2	-2.3561999999999999E-5	-1.625	6.7486000000000001E-6
0.29599999999999999	-4.7305999999999997E-5	-3.9E-2	-2.3482999999999999E-5	-1.615	6.7966999999999997E-6
0.29499999999999998	-4.7305999999999997E-5	-4.1000000000000002E-2	-2.3414E-5	-1.605	6.8391000000000003E-6
0.29399999999999998	-4.7395999999999998E-5	-4.2999999999999997E-2	-2.3428999999999999E-5	-1.595	6.8786999999999999E-6
0.29299999999999998	-4.7503000000000002E-5	-4.4999999999999998E-2	-2.3334000000000001E-5	-1.585	6.9211999999999999E-6
0.29199999999999998	-4.7475999999999997E-5	-4.7E-2	-2.3306E-5	-1.575	6.9550999999999997E-6
0.29099999999999998	-4.744E-5	-4.9000000000000002E-2	-2.3249000000000001E-5	-1.5649999999999999	6.9975000000000003E-6
0.28999999999999998	-4.7592000000000001E-5	-5.0999999999999997E-2	-2.3221E-5	-1.5549999999999999	7.0342999999999997E-6
0.28899999999999998	-4.7682000000000002E-5	-5.2999999999999999E-2	-2.3167E-5	-1.5449999999999999	7.0795999999999999E-6
0.28799999999999998	-4.7547999999999999E-5	-5.5E-2	-2.3122999999999999E-5	-1.5349999999999999	7.1248E-6
0.28699999999999998	-4.7574999999999998E-5	-5.7000000000000002E-2	-2.3053000000000001E-5	-1.5249999999999999	7.1644000000000004E-6
0.28599999999999998	-4.7664000000000003E-5	-5.8999999999999997E-2	-2.3034E-5	-1.5149999999999999	7.1955E-6
0.28499999999999998	-4.7601E-5	-6.0999999999999999E-2	-2.2960999999999999E-5	-1.5049999999999999	7.2436000000000004E-6
0.28399999999999997	-4.7718E-5	-6.3E-2	-2.2908000000000002E-5	-1.4950000000000001	7.2917E-6
0.28299999999999997	-4.7834000000000003E-5	-6.5000000000000002E-2	-2.2841E-5	-1.4850000000000001	7.3425999999999998E-6
0.28199999999999997	-4.7896999999999999E-5	-6.7000000000000004E-2	-2.2781000000000001E-5	-1.4750000000000001	7.3879E-6
0.28100000000000003	-4.7985999999999998E-5	-6.9000000000000006E-2	-2.2730000000000001E-5	-1.4650000000000001	7.4359000000000002E-6
0.28000000000000003	-4.8111000000000001E-5	-7.0999999999999994E-2	-2.2663999999999998E-5	-1.4550000000000001	7.4839999999999998E-6
0.27900000000000003	-4.812E-5	-7.2999999999999995E-2	-2.2631999999999999E-5	-1.4450000000000001	7.5348999999999996E-6
0.27800000000000002	-4.8058E-5	-7.4999999999999997E-2	-2.2582000000000002E-5	-1.4350000000000001	7.5971999999999999E-6
0.27700000000000002	-4.8075000000000003E-5	-7.6999999999999999E-2	-2.2506000000000001E-5	-1.425	7.6451999999999992E-6
0.27600000000000002	-4.8146999999999998E-5	-7.9000000000000001E-2	-2.2427000000000001E-5	-1.415	7.6932999999999997E-6
0.27500000000000002	-4.8066999999999999E-5	-8.1000000000000003E-2	-2.2373000000000001E-5	-1.405	7.7386000000000008E-6
0.27400000000000002	-4.8219E-5	-8.3000000000000004E-2	-2.2274999999999999E-5	-1.395	7.7895000000000006E-6
0.27300000000000002	-4.829E-5	-8.5000000000000006E-2	-2.2259000000000002E-5	-1.385	7.8375999999999993E-6
0.27200000000000002	-4.8299E-5	-8.6999999999999994E-2	-2.2171000000000002E-5	-1.375	7.8885000000000008E-6
0.27100000000000002	-4.8353000000000003E-5	-8.8999999999999996E-2	-2.213E-5	-1.365	7.9394000000000006E-6
0.27	-4.8451000000000001E-5	-9.0999999999999998E-2	-2.2082E-5	-1.355	7.9874999999999993E-6
0.26900000000000002	-4.8451000000000001E-5	-9.2999999999999999E-2	-2.1990000000000001E-5	-1.345	8.0384000000000008E-6
0.26800000000000002	-4.8557999999999998E-5	-9.5000000000000001E-2	-2.1880000000000001E-5	-1.335	8.0978000000000006E-6
0.26700000000000002	-4.8621000000000001E-5	-9.7000000000000003E-2	-2.1880000000000001E-5	-1.325	8.1317000000000004E-6
0.26600000000000001	-4.8683999999999997E-5	-9.9000000000000005E-2	-2.1823000000000001E-5	-1.3149999999999999	8.1742000000000004E-6
0.26500000000000001	-4.8639E-5	-0.10100000000000001	-2.1741000000000001E-5	-1.3049999999999999	8.2193999999999996E-6
0.26400000000000001	-4.8674999999999997E-5	-0.10299999999999999	-2.1668E-5	-1.2949999999999999	8.2647000000000007E-6
0.26300000000000001	-4.8718999999999999E-5	-0.105	-2.1602000000000001E-5	-1.2849999999999999	8.3156000000000005E-6
0.26200000000000001	-4.8621000000000001E-5	-0.107	-2.1551000000000001E-5	-1.2749999999999999	8.3551999999999992E-6
0.26100000000000001	-4.88E-5	-0.109	-2.1576000000000001E-5	-1.2649999999999999	8.4032999999999997E-6
0.26	-4.8925000000000003E-5	-0.111	-2.1430999999999999E-5	-1.2549999999999999	8.4400000000000005E-6
0.25900000000000001	-4.8853999999999997E-5	-0.113	-2.1364000000000001E-5	-1.2450000000000001	8.4880999999999993E-6
0.25800000000000001	-4.8844999999999997E-5	-0.115	-2.1273000000000001E-5	-1.2350000000000001	8.5390000000000007E-6
0.25700000000000001	-4.9005999999999998E-5	-0.11700000000000001	-2.1234999999999999E-5	-1.2250000000000001	8.5814000000000005E-6
0.25600000000000001	-4.9014999999999997E-5	-0.11899999999999999	-2.1124E-5	-1.2150000000000001	8.6209999999999993E-6
0.255	-4.914E-5	-0.121	-2.101E-5	-1.2050000000000001	8.6549999999999993E-6
0.254	-4.9157999999999999E-5	-0.123	-2.0990999999999999E-5	-1.1950000000000001	8.6974000000000008E-6
0.253	-4.9104000000000003E-5	-0.125	-2.0908999999999999E-5	-1.1850000000000001	8.7398000000000006E-6
0.252	-4.9202000000000001E-5	-0.127	-2.0883999999999999E-5	-1.175	8.7851E-6
0.251	-4.9345999999999998E-5	-0.129	-2.0808000000000001E-5	-1.165	8.8247000000000004E-6
0.25	-4.9193000000000001E-5	-0.13100000000000001	-2.0675000000000001E-5	-1.155	8.8558000000000008E-6
0.249	-4.914E-5	-0.13300000000000001	-2.0642999999999999E-5	-1.145	8.8982000000000006E-6
0.248	-4.9301000000000001E-5	-0.13500000000000001	-2.0530000000000002E-5	-1.135	8.9377999999999994E-6
0.247	-4.9416999999999998E-5	-0.13700000000000001	-2.0460000000000001E-5	-1.125	8.9886999999999992E-6
0.246	-4.939E-5	-0.13900000000000001	-2.0435E-5	-1.115	9.0198999999999998E-6
0.245	-4.9506999999999999E-5	-0.14099999999999999	-2.0384E-5	-1.105	9.0537999999999996E-6
0.24399999999999999	-4.9595999999999997E-5	-0.14299999999999999	-2.0295000000000001E-5	-1.095	9.1046999999999994E-6
0.24299999999999999	-4.9659E-5	-0.14499999999999999	-2.0222999999999999E-5	-1.085	9.1357999999999998E-6
0.24199999999999999	-4.9650000000000001E-5	-0.14699999999999999	-2.0125000000000001E-5	-1.075	9.1810999999999992E-6
0.24099999999999999	-4.9685000000000003E-5	-0.14899999999999999	-2.0061E-5	-1.0649999999999999	9.2235000000000007E-6
0.24	-4.9694000000000002E-5	-0.151	-2.0020000000000001E-5	-1.0549999999999999	9.2630999999999995E-6
0.23899999999999999	-4.9829E-5	-0.153	-1.9947999999999999E-5	-1.0449999999999999	9.3054999999999993E-6
0.23799999999999999	-4.99E-5	-0.155	-1.9850000000000001E-5	-1.0349999999999999	9.3535999999999997E-6
0.23699999999999999	-4.9836999999999997E-5	-0.157	-1.978E-5	-1.0249999999999999	9.4102000000000001E-6
0.23599999999999999	-4.9864000000000002E-5	-0.159	-1.9732999999999999E-5	-1.0149999999999999	9.4440999999999999E-6
0.23499999999999999	-4.9917999999999999E-5	-0.161	-1.9630999999999999E-5	-1.0049999999999999	9.4864999999999997E-6
0.23400000000000001	-4.9963000000000003E-5	-0.16300000000000001	-1.9568E-5	-0.995	9.5346000000000002E-6
0.23300000000000001	-4.9944999999999997E-5	-0.16500000000000001	-1.9502000000000001E-5	-0.98499999999999999	9.5798999999999995E-6
0.23200000000000001	-5.007E-5	-0.16700000000000001	-1.9439000000000001E-5	-0.97499999999999998	9.6336000000000004E-6
0.23100000000000001	-5.0167999999999998E-5	-0.16900000000000001	-1.9363000000000001E-5	-0.96499999999999997	9.6732000000000008E-6
0.23	-5.0195000000000003E-5	-0.17100000000000001	-1.9293E-5	-0.95499999999999996	9.7127999999999996E-6
0.22900000000000001	-5.0284999999999997E-5	-0.17299999999999999	-1.9216999999999999E-5	-0.94499999999999995	9.7524E-6
0.22800000000000001	-5.0294000000000003E-5	-0.17499999999999999	-1.9140999999999999E-5	-0.93500000000000005	9.7976999999999994E-6
0.22700000000000001	-5.0266999999999998E-5	-0.17699999999999999	-1.9080999999999999E-5	-0.92500000000000004	9.8541999999999996E-6
0.22600000000000001	-5.0319999999999999E-5	-0.17899999999999999	-1.9018E-5	-0.91500000000000004	9.8796999999999996E-6
0.22500000000000001	-5.041E-5	-0.18099999999999999	-1.8955000000000001E-5	-0.90500000000000003	9.9135999999999994E-6
0.224	-5.0257999999999999E-5	-0.183	-1.8887999999999999E-5	-0.89500000000000002	9.9446999999999998E-6
0.223	-5.0383000000000002E-5	-0.185	-1.8768000000000001E-5	-0.88500000000000001	9.9759000000000005E-6
0.222	-5.0516999999999998E-5	-0.187	-1.8723999999999999E-5	-0.875	1.0003999999999999E-5
0.221	-5.0498999999999999E-5	-0.189	-1.8657000000000001E-5	-0.86499999999999999	1.0027000000000001E-5
0.22	-5.0498999999999999E-5	-0.191	-1.861E-5	-0.85499999999999998	1.0057999999999999E-5
0.219	-5.0589E-5	-0.193	-1.8525E-5	-0.84499999999999997	1.0071999999999999E-5
0.218	-5.0659999999999999E-5	-0.19500000000000001	-1.8451999999999999E-5	-0.83499999999999996	1.0091999999999999E-5
0.217	-5.075E-5	-0.19700000000000001	-1.8423E-5	-0.82499999999999996	1.0117E-5
0.216	-5.0812000000000001E-5	-0.19900000000000001	-1.8318999999999999E-5	-0.81499999999999995	1.0122999999999999E-5
0.215	-5.0794999999999997E-5	-0.20100000000000001	-1.825E-5	-0.80500000000000005	1.0134E-5
0.214	-5.0695999999999997E-5	-0.20300000000000001	-1.8215000000000001E-5	-0.79500000000000004	1.0137E-5
0.21299999999999999	-5.0794999999999997E-5	-0.20499999999999999	-1.8125999999999999E-5	-0.78500000000000003	1.0142999999999999E-5
0.21199999999999999	-5.0865999999999997E-5	-0.20699999999999999	-1.8071999999999999E-5	-0.77500000000000002	1.0151E-5
0.21099999999999999	-5.0785999999999998E-5	-0.20899999999999999	-1.8E-5	-0.76500000000000001	1.0148E-5
0.21	-5.0856999999999998E-5	-0.21099999999999999	-1.8040999999999999E-5	-0.755	1.0146000000000001E-5
0.20899999999999999	-5.0937999999999999E-5	-0.21299999999999999	-1.7901999999999999E-5	-0.745	1.0137E-5
0.20799999999999999	-5.0856999999999998E-5	-0.215	-1.7832000000000001E-5	-0.73499999999999999	1.0134E-5
0.20699999999999999	-5.092E-5	-0.217	-1.7750000000000001E-5	-0.72499999999999998	1.0129000000000001E-5
0.20599999999999999	-5.1E-5	-0.219	-1.7702000000000001E-5	-0.71499999999999997	1.0125999999999999E-5
0.20499999999999999	-5.0973000000000001E-5	-0.221	-1.7626999999999999E-5	-0.70499999999999996	1.0105999999999999E-5
0.20399999999999999	-5.1E-5	-0.223	-1.7550999999999998E-5	-0.69499999999999995	1.0095000000000001E-5
0.20300000000000001	-5.1116999999999999E-5	-0.22500000000000001	-1.7518999999999999E-5	-0.68500000000000005	1.0078000000000001E-5
0.20200000000000001	-5.1008999999999999E-5	-0.22700000000000001	-1.7433999999999999E-5	-0.67500000000000004	1.0061000000000001E-5
0.20100000000000001	-5.1017999999999998E-5	-0.22900000000000001	-1.7385999999999999E-5	-0.66500000000000004	1.0044000000000001E-5
0.2	-5.1125000000000003E-5	-0.23100000000000001	-1.7331999999999999E-5	-0.65500000000000003	1.0018E-5
0.19900000000000001	-5.134E-5	-0.23300000000000001	-1.7275999999999999E-5	-0.64500000000000002	1.0001E-5
0.19800000000000001	-5.1536999999999998E-5	-0.23499999999999999	-1.7238E-5	-0.63500000000000001	9.9786999999999999E-6
0.19700000000000001	-5.1412000000000002E-5	-0.23699999999999999	-1.7124000000000001E-5	-0.625	9.9531999999999998E-6
0.19600000000000001	-5.1286000000000003E-5	-0.23899999999999999	-1.7098000000000001E-5	-0.61499999999999999	9.9419000000000005E-6
0.19500000000000001	-5.117E-5	-0.24099999999999999	-1.7059999999999999E-5	-0.60499999999999998	9.9023E-6
0.19400000000000001	-5.1107999999999999E-5	-0.24299999999999999	-1.7016000000000001E-5	-0.59499999999999997	9.8711999999999996E-6
0.193	-5.1187999999999998E-5	-0.245	-1.6952999999999998E-5	-0.58499999999999996	9.8372999999999998E-6
0.192	-5.109E-5	-0.247	-1.6898999999999999E-5	-0.57499999999999996	9.7947999999999998E-6
0.191	-5.0973000000000001E-5	-0.249	-1.6826000000000001E-5	-0.56499999999999995	9.7270000000000002E-6
0.19	-5.1026999999999998E-5	-0.251	-1.6798000000000001E-5	-0.55500000000000005	9.7072000000000008E-6
0.189	-5.1017999999999998E-5	-0.253	-1.6741000000000001E-5	-0.54500000000000004	9.6703999999999998E-6
0.188	-5.0982000000000001E-5	-0.255	-1.6728E-5	-0.53500000000000003	9.628E-6
0.187	-5.0964000000000002E-5	-0.25700000000000001	-1.6668E-5	-0.52500000000000002	9.5771000000000002E-6
0.186	-5.0929E-5	-0.25900000000000001	-1.6611000000000001E-5	-0.51500000000000001	9.5318000000000008E-6
0.185	-5.0776999999999999E-5	-0.26100000000000001	-1.6555E-5	-0.505	9.4638999999999993E-6
0.184	-5.0776999999999999E-5	-0.26300000000000001	-1.6523000000000001E-5	-0.495	9.3989000000000008E-6
0.183	-5.0686999999999998E-5	-0.26500000000000001	-1.6484999999999999E-5	-0.48499999999999999	9.3365999999999997E-6
0.182	-5.0705000000000003E-5	-0.26700000000000002	-1.6460000000000002E-5	-0.47499999999999998	9.2688000000000001E-6
0.18099999999999999	-5.0705000000000003E-5	-0.26900000000000002	-1.6399999999999999E-5	-0.46500000000000002	9.1951999999999996E-6
0.18	-5.0695999999999997E-5	-0.27100000000000002	-1.6371E-5	-0.45500000000000002	9.1301999999999994E-6
0.17899999999999999	-5.0633999999999997E-5	-0.27300000000000002	-1.6324000000000002E-5	-0.44500000000000001	9.0510000000000002E-6
0.17799999999999999	-5.0544000000000003E-5	-0.27500000000000002	-1.6273000000000002E-5	-0.435	8.9688999999999998E-6
0.17699999999999999	-5.0481E-5	-0.27700000000000002	-1.626E-5	-0.42499999999999999	8.8982000000000006E-6
0.17599999999999999	-5.0312000000000002E-5	-0.27900000000000003	-1.6212999999999999E-5	-0.41499999999999998	8.8332000000000004E-6
0.17499999999999999	-5.0319999999999999E-5	-0.28100000000000003	-1.6209999999999999E-5	-0.40500000000000003	8.7568000000000006E-6
0.17399999999999999	-5.0257999999999999E-5	-0.28299999999999997	-1.6166000000000001E-5	-0.39500000000000002	8.6804000000000008E-6
0.17299999999999999	-4.9981000000000001E-5	-0.28499999999999998	-1.6101999999999999E-5	-0.38500000000000001	8.6125999999999995E-6
0.17199999999999999	-4.9836999999999997E-5	-0.28699999999999998	-1.6058000000000001E-5	-0.375	8.5446999999999997E-6
0.17100000000000001	-4.9926999999999998E-5	-0.28899999999999998	-1.6055000000000001E-5	-0.36499999999999999	8.4880999999999993E-6
0.17	-4.9882000000000001E-5	-0.29099999999999998	-1.6033E-5	-0.35499999999999998	8.4315000000000005E-6
0.16900000000000001	-4.9659E-5	-0.29299999999999998	-1.6011E-5	-0.34499999999999997	8.3777999999999996E-6
0.16800000000000001	-4.9623000000000002E-5	-0.29499999999999998	-1.6011E-5	-0.33500000000000002	8.3353999999999998E-6
0.16700000000000001	-4.9650000000000001E-5	-0.29699999999999999	-1.5962999999999999E-5	-0.32500000000000001	8.3042999999999994E-6
0.16600000000000001	-4.9471000000000001E-5	-0.29899999999999999	-1.5931999999999999E-5	-0.315	8.2901000000000005E-6
0.16500000000000001	-4.9345999999999998E-5	-0.30099999999999999	-1.59E-5	-0.30499999999999999	8.2816000000000005E-6
0.16400000000000001	-4.9310000000000001E-5	-0.30299999999999999	-1.5889999999999999E-5	-0.29499999999999998	8.2702999999999994E-6
0.16300000000000001	-4.9122000000000002E-5	-0.30499999999999999	-1.5883999999999999E-5	-0.28499999999999998	8.276E-6
0.16200000000000001	-4.8925000000000003E-5	-0.307	-1.5865000000000001E-5	-0.27500000000000002	8.2928999999999998E-6
0.161	-4.8888999999999999E-5	-0.309	-1.5834000000000001E-5	-0.26500000000000001	8.3241000000000005E-6
0.16	-4.8693000000000003E-5	-0.311	-1.5852E-5	-0.255	8.3607999999999996E-6
0.159	-4.8603000000000002E-5	-0.313	-1.5883999999999999E-5	-0.245	8.4089000000000001E-6
0.158	-4.8541000000000002E-5	-0.315	-1.5829999999999999E-5	-0.23499999999999999	8.4682999999999999E-6
0.157	-4.8325999999999998E-5	-0.317	-1.5767E-5	-0.22500000000000001	8.5361999999999997E-6
0.156	-4.8201000000000001E-5	-0.31900000000000001	-1.5801999999999999E-5	-0.215	8.6209999999999993E-6
0.155	-4.8128999999999999E-5	-0.32100000000000001	-1.5780000000000001E-5	-0.20499999999999999	8.7144000000000008E-6
0.154	-4.8049E-5	-0.32300000000000001	-1.5758000000000001E-5	-0.19500000000000001	8.7992000000000004E-6
0.153	-4.7976999999999998E-5	-0.32500000000000001	-1.5747999999999999E-5	-0.185	8.9067000000000006E-6
0.152	-4.7788999999999999E-5	-0.32700000000000001	-1.5747999999999999E-5	-0.17499999999999999	9.0141999999999992E-6
0.151	-4.7565999999999998E-5	-0.32900000000000001	-1.5716999999999999E-5	-0.16500000000000001	9.1330000000000005E-6
0.15	-4.7305999999999997E-5	-0.33100000000000002	-1.5744999999999999E-5	-0.155	9.2518000000000001E-6
0.14899999999999999	-4.7253000000000003E-5	-0.33300000000000002	-1.5750999999999999E-5	-0.14499999999999999	9.3790999999999997E-6
0.14799999999999999	-4.7144999999999997E-5	-0.33500000000000002	-1.5739E-5	-0.13500000000000001	9.5063000000000008E-6
0.14699999999999999	-4.7029E-5	-0.33700000000000002	-1.5722999999999998E-5	-0.125	9.6448999999999998E-6
0.14599999999999999	-4.6832000000000002E-5	-0.33900000000000002	-1.5707000000000001E-5	-0.115	9.7806999999999994E-6
0.14499999999999999	-4.6662000000000001E-5	-0.34100000000000003	-1.5741999999999999E-5	-0.105	9.9334000000000005E-6
0.14399999999999999	-4.651E-5	-0.34300000000000003	-1.5726000000000002E-5	-9.5000000000000001E-2	1.0069E-5
0.14299999999999999	-4.6439E-5	-0.34499999999999997	-1.5726000000000002E-5	-8.5000000000000006E-2	1.0213E-5
0.14199999999999999	-4.6357999999999999E-5	-0.34699999999999998	-1.577E-5	-7.4999999999999997E-2	1.0361E-5
0.14099999999999999	-4.6152000000000001E-5	-0.34899999999999998	-1.5761E-5	-6.5000000000000002E-2	1.0508E-5
0.14000000000000001	-4.5920000000000001E-5	-0.35099999999999998	-1.5722999999999998E-5	-5.5E-2	1.0669000000000001E-5
0.13900000000000001	-4.5794999999999998E-5	-0.35299999999999998	-1.5750999999999999E-5	-4.4999999999999998E-2	1.0824E-5
0.13800000000000001	-4.5695999999999998E-5	-0.35499999999999998	-1.5777000000000002E-5	-3.5000000000000003E-2	1.0986E-5
0.13700000000000001	-4.5544000000000003E-5	-0.35699999999999998	-1.5777000000000002E-5	-2.5000000000000001E-2	1.1151999999999999E-5
0.13600000000000001	-4.5445999999999998E-5	-0.35899999999999999	-1.5804999999999999E-5	-1.4999999999999999E-2	1.1308000000000001E-5
0.13500000000000001	-4.5178E-5	-0.36099999999999999	-1.5824E-5	-5.0000000000000001E-3	1.1477999999999999E-5
0.13400000000000001	-4.4944999999999997E-5	-0.36299999999999999	-1.5846E-5	5.0000000000000001E-3	1.163E-5
0.13300000000000001	-4.4873000000000002E-5	-0.36499999999999999	-1.5852E-5	1.4999999999999999E-2	1.1763000000000001E-5
0.13200000000000001	-4.4756999999999999E-5	-0.36699999999999999	-1.5849E-5	2.5000000000000001E-2	1.1902000000000001E-5
0.13100000000000001	-4.4480000000000001E-5	-0.36899999999999999	-1.5858999999999998E-5	3.5000000000000003E-2	1.2038000000000001E-5
0.13	-4.4407999999999999E-5	-0.371	-1.59E-5	4.4999999999999998E-2	1.2184999999999999E-5
0.129	-4.4354999999999998E-5	-0.373	-1.5913000000000002E-5	5.5E-2	1.2326E-5
0.128	-4.4149E-5	-0.375	-1.5931999999999999E-5	6.5000000000000002E-2	1.2468E-5
0.127	-4.4005999999999998E-5	-0.377	-1.5937999999999999E-5	7.4999999999999997E-2	1.2618E-5
0.126	-4.3835999999999998E-5	-0.379	-1.5970000000000001E-5	8.5000000000000006E-2	1.2779000000000001E-5
0.125	-4.3621000000000001E-5	-0.38100000000000001	-1.5976000000000001E-5	9.5000000000000001E-2	1.2968E-5
0.124	-4.3568E-5	-0.38300000000000001	-1.6011E-5	0.105	1.3178E-5
0.123	-4.3414999999999997E-5	-0.38500000000000001	-1.6055000000000001E-5	0.115	1.3397999999999999E-5
0.122	-4.3075999999999999E-5	-0.38700000000000001	-1.6045E-5	0.125	1.3655999999999999E-5
0.121	-4.2967999999999999E-5	-0.38900000000000001	-1.6052000000000001E-5	0.13500000000000001	1.395E-5
0.12	-4.2905999999999999E-5	-0.39100000000000001	-1.6067999999999999E-5	0.14499999999999999	1.4278E-5
0.11899999999999999	-4.2789E-5	-0.39300000000000002	-1.615E-5	0.155	1.4646E-5
0.11799999999999999	-4.2700000000000001E-5	-0.39500000000000002	-1.6191000000000001E-5	0.16500000000000001	1.5033E-5
0.11700000000000001	-4.2645999999999998E-5	-0.39700000000000002	-1.6194000000000001E-5	0.17499999999999999	1.5438E-5
0.11600000000000001	-4.2466999999999998E-5	-0.39900000000000002	-1.6203999999999999E-5	0.185	1.5851000000000001E-5
0.115	-4.2324000000000003E-5	-0.40100000000000002	-1.6237999999999999E-5	0.19500000000000001	1.6246E-5
0.114	-4.2199E-5	-0.40300000000000002	-1.6254000000000001E-5	0.20499999999999999	1.6631000000000001E-5
0.113	-4.2128000000000001E-5	-0.40500000000000003	-1.6297999999999999E-5	0.215	1.6928000000000001E-5
0.112	-4.1912999999999997E-5	-0.40699999999999997	-1.6327000000000001E-5	0.22500000000000001	1.7180000000000002E-5
0.111	-4.1797E-5	-0.40899999999999997	-1.6376999999999999E-5	0.23499999999999999	1.7377999999999999E-5
0.11	-4.1644999999999999E-5	-0.41099999999999998	-1.6424999999999999E-5	0.245	1.7521999999999999E-5
0.109	-4.1474999999999998E-5	-0.41299999999999998	-1.6444E-5	0.255	1.7626999999999999E-5
0.108	-4.1403000000000003E-5	-0.41499999999999998	-1.6545000000000002E-5	0.26500000000000001	1.7697E-5
0.107	-4.1340000000000001E-5	-0.41699999999999998	-1.6551000000000001E-5	0.27500000000000002	1.774E-5
0.106	-4.1152999999999997E-5	-0.41899999999999998	-1.6551000000000001E-5	0.28499999999999998	1.7791E-5
0.105	-4.1001000000000003E-5	-0.42099999999999999	-1.6592E-5	0.29499999999999998	1.7842E-5
0.104	-4.0902000000000002E-5	-0.42299999999999999	-1.6653000000000001E-5	0.30499999999999999	1.791E-5
0.10299999999999999	-4.0822000000000003E-5	-0.42499999999999999	-1.6653000000000001E-5	0.315	1.7961E-5
0.10199999999999999	-4.0741000000000002E-5	-0.42699999999999999	-1.6702999999999999E-5	0.32500000000000001	1.8034E-5
0.10100000000000001	-4.0670000000000002E-5	-0.42899999999999999	-1.6716000000000001E-5	0.33500000000000002	1.8113000000000001E-5
0.1	-4.0562000000000002E-5	-0.43099999999999999	-1.6753999999999999E-5	0.34499999999999997	1.8195000000000001E-5
9.9000000000000005E-2	-4.0392000000000002E-5	-0.433	-1.6804E-5	0.35499999999999998	1.8308000000000002E-5
9.8000000000000004E-2	-4.0330000000000002E-5	-0.435	-1.6861E-5	0.36499999999999999	1.8422000000000001E-5
9.7000000000000003E-2	-4.0284999999999998E-5	-0.437	-1.6898999999999999E-5	0.375	1.8538000000000001E-5
9.6000000000000002E-2	-4.0419E-5	-0.439	-1.694E-5	0.38500000000000001	1.8651000000000002E-5
9.5000000000000001E-2	-4.0213000000000003E-5	-0.441	-1.6931000000000001E-5	0.39500000000000002	1.8780999999999999E-5
9.4E-2	-4.0079E-5	-0.443	-1.6997E-5	0.40500000000000003	1.8924999999999999E-5
9.2999999999999999E-2	-3.9802000000000003E-5	-0.44500000000000001	-1.7070000000000001E-5	0.41499999999999998	1.9063999999999999E-5
9.1999999999999998E-2	-3.9650000000000002E-5	-0.44700000000000001	-1.7133E-5	0.42499999999999999	1.9213999999999999E-5
9.0999999999999998E-2	-3.9659000000000001E-5	-0.44900000000000001	-1.7139999999999999E-5	0.435	1.9363000000000001E-5
0.09	-3.9551999999999997E-5	-0.45100000000000001	-1.7170999999999999E-5	0.44500000000000001	1.9536000000000001E-5
8.8999999999999996E-2	-3.9533999999999998E-5	-0.45300000000000001	-1.7218999999999999E-5	0.45500000000000002	1.9745000000000002E-5
8.7999999999999995E-2	-3.9434999999999998E-5	-0.45500000000000002	-1.7266E-5	0.46500000000000002	1.9969000000000001E-5
8.6999999999999994E-2	-3.9273999999999997E-5	-0.45700000000000002	-1.7323E-5	0.47499999999999998	2.0225999999999999E-5
8.5999999999999993E-2	-3.9113000000000003E-5	-0.45900000000000002	-1.7385999999999999E-5	0.48499999999999999	2.0523E-5
8.5000000000000006E-2	-3.9113000000000003E-5	-0.46100000000000002	-1.7393000000000001E-5	0.495	2.0857E-5
8.4000000000000005E-2	-3.9094999999999998E-5	-0.46300000000000002	-1.7456E-5	0.505	2.1243999999999999E-5
8.3000000000000004E-2	-3.8890000000000002E-5	-0.46500000000000002	-1.7499999999999998E-5	0.51500000000000001	2.1673999999999999E-5
8.2000000000000003E-2	-3.8862999999999997E-5	-0.46700000000000003	-1.7554000000000002E-5	0.52500000000000002	2.2147E-5
8.1000000000000003E-2	-3.8818E-5	-0.46899999999999997	-1.7611000000000001E-5	0.53500000000000003	2.2663999999999998E-5
0.08	-3.8665999999999999E-5	-0.47099999999999997	-1.7626999999999999E-5	0.54500000000000004	2.3221E-5
7.9000000000000001E-2	-3.8711000000000003E-5	-0.47299999999999998	-1.7686999999999999E-5	0.55500000000000005	2.3810000000000001E-5
7.8E-2	-3.8603000000000003E-5	-0.47499999999999998	-1.7737E-5	0.56499999999999995	2.4392E-5
7.6999999999999999E-2	-3.8460000000000001E-5	-0.47699999999999998	-1.7768999999999999E-5	0.57499999999999996	2.4989000000000001E-5
7.5999999999999998E-2	-3.8451000000000002E-5	-0.47899999999999998	-1.7804000000000001E-5	0.58499999999999996	2.5527000000000001E-5
7.4999999999999997E-2	-3.8460000000000001E-5	-0.48099999999999998	-1.7861000000000001E-5	0.59499999999999997	2.601E-5
7.3999999999999996E-2	-3.8325999999999999E-5	-0.48299999999999998	-1.7907999999999999E-5	0.60499999999999998	2.6415E-5
7.2999999999999995E-2	-3.8254999999999999E-5	-0.48499999999999999	-1.7955E-5	0.61499999999999999	2.6763000000000001E-5
7.1999999999999995E-2	-3.8219000000000001E-5	-0.48699999999999999	-1.8028000000000001E-5	0.625	2.7033999999999999E-5
7.0999999999999994E-2	-3.8111999999999997E-5	-0.48899999999999999	-1.8046999999999998E-5
7.0000000000000007E-2	-3.7941999999999997E-5	-0.49099999999999999	-1.8128999999999999E-5
6.9000000000000006E-2	-3.7941999999999997E-5	-0.49299999999999999	-1.8155000000000002E-5
6.8000000000000005E-2	-3.7932999999999997E-5	-0.495	-1.8179999999999999E-5
6.7000000000000004E-2	-3.7806999999999999E-5	-0.497	-1.8246000000000001E-5
6.6000000000000003E-2	-3.7842999999999997E-5	-0.499	-1.8315999999999999E-5
6.5000000000000002E-2	-3.7842999999999997E-5	-0.501	-1.8340999999999999E-5
6.4000000000000001E-2	-3.7781000000000003E-5	-0.503	-1.842E-5
6.3E-2	-3.7709000000000001E-5	-0.505	-1.8436000000000001E-5
6.2E-2	-3.7636999999999999E-5	-0.50700000000000001	-1.8496E-5
6.0999999999999999E-2	-3.7493999999999997E-5	-0.50900000000000001	-1.8553E-5
0.06	-3.7512000000000003E-5	-0.51100000000000001	-1.8587999999999999E-5
5.8999999999999997E-2	-3.7557E-5	-0.51300000000000001	-1.8632000000000001E-5
5.8000000000000003E-2	-3.7422999999999997E-5	-0.51500000000000001	-1.8680000000000001E-5
5.7000000000000002E-2	-3.7369000000000001E-5	-0.51700000000000002	-1.8805999999999999E-5
5.6000000000000001E-2	-3.7387E-5	-0.51900000000000002	-1.8844000000000001E-5
5.5E-2	-3.7261999999999997E-5	-0.52100000000000002	-1.8844000000000001E-5
5.3999999999999999E-2	-3.7234999999999998E-5	-0.52300000000000002	-1.8904000000000001E-5
5.2999999999999999E-2	-3.7289000000000002E-5	-0.52500000000000002	-1.8958E-5
5.1999999999999998E-2	-3.7323999999999997E-5	-0.52700000000000002	-1.8980000000000001E-5
5.0999999999999997E-2	-3.7119000000000002E-5	-0.52900000000000003	-1.9055999999999998E-5
0.05	-3.7163000000000003E-5	-0.53100000000000003	-1.9069E-5
4.9000000000000002E-2	-3.7225999999999999E-5	-0.53300000000000003	-1.9131999999999999E-5
4.8000000000000001E-2	-3.7047E-5	-0.53500000000000003	-1.9179000000000001E-5
4.7E-2	-3.7047E-5	-0.53700000000000003	-1.9245999999999998E-5
4.5999999999999999E-2	-3.7064999999999998E-5	-0.53900000000000003	-1.9298999999999999E-5
4.4999999999999998E-2	-3.7038E-5	-0.54100000000000004	-1.9312000000000001E-5
4.3999999999999997E-2	-3.6967E-5	-0.54300000000000004	-1.9366000000000001E-5
4.2999999999999997E-2	-3.6976E-5	-0.54500000000000004	-1.9423E-5
4.2000000000000003E-2	-3.6823999999999998E-5	-0.54700000000000004	-1.9483E-5
4.1000000000000002E-2	-3.6832999999999998E-5	-0.54900000000000004	-1.9565E-5
0.04	-3.6859000000000001E-5	-0.55100000000000005	-1.9573999999999999E-5
3.9E-2	-3.6814999999999999E-5	-0.55300000000000005	-1.9616E-5
3.7999999999999999E-2	-3.6797E-5	-0.55500000000000005	-1.9681999999999999E-5
3.6999999999999998E-2	-3.6752000000000003E-5	-0.55700000000000005	-1.9717000000000001E-5
3.5999999999999997E-2	-3.6698E-5	-0.55900000000000005	-1.9777000000000001E-5
3.5000000000000003E-2	-3.6600000000000002E-5	-0.56100000000000005	-1.9834E-5
3.4000000000000002E-2	-3.6662999999999998E-5	-0.56299999999999994	-1.9891E-5
3.3000000000000002E-2	-3.6644999999999999E-5	-0.56499999999999995	-1.9928999999999998E-5
3.2000000000000001E-2	-3.6545999999999999E-5	-0.56699999999999995	-1.9962999999999998E-5
3.1E-2	-3.6519000000000001E-5	-0.56899999999999995	-1.9771000000000001E-5
0.03	-3.6536999999999999E-5	-0.57099999999999995	-1.9925999999999999E-5
2.9000000000000001E-2	-3.6483999999999998E-5	-0.57299999999999995	-2.0046000000000001E-5
2.8000000000000001E-2	-3.6465999999999999E-5	-0.57499999999999996	-2.0125000000000001E-5
2.7E-2	-3.6474999999999999E-5	-0.57699999999999996	-2.0231999999999999E-5
2.5999999999999999E-2	-3.6511000000000003E-5	-0.57899999999999996	-2.0239000000000001E-5
2.5000000000000001E-2	-3.6430000000000002E-5	-0.58099999999999996	-2.0279999999999999E-5
2.4E-2	-3.6465999999999999E-5	-0.58299999999999996	-2.0324000000000001E-5
2.3E-2	-3.6457E-5	-0.58499999999999996	-2.0364999999999999E-5
2.1999999999999999E-2	-3.6350000000000003E-5	-0.58699999999999997	-2.0446999999999999E-5
2.1000000000000001E-2	-3.6313999999999998E-5	-0.58899999999999997	-2.0485000000000001E-5
0.02	-3.6322999999999998E-5	-0.59099999999999997	-2.0542000000000001E-5
1.9E-2	-3.6232999999999997E-5	-0.59299999999999997	-2.0599E-5
1.7999999999999999E-2	-3.6322999999999998E-5	-0.59499999999999997	-2.0590000000000001E-5
1.7000000000000001E-2	-3.6331999999999997E-5	-0.59699999999999998	-2.0647000000000001E-5
1.6E-2	-3.6171000000000003E-5	-0.59899999999999998	-2.071E-5
1.4999999999999999E-2	-3.6214999999999998E-5	-0.60099999999999998	-2.0769999999999999E-5
1.4E-2	-3.6260000000000002E-5	-0.60299999999999998	-2.0832999999999999E-5
1.2999999999999999E-2	-3.6196999999999999E-5	-0.60499999999999998	-2.0852E-5
1.2E-2	-3.6278000000000001E-5	-0.60699999999999998	-2.0871000000000001E-5
1.0999999999999999E-2	-3.6171000000000003E-5	-0.60899999999999999	-2.0937E-5
0.01	-3.6028000000000001E-5	-0.61099999999999999	-2.0985E-5
8.9999999999999993E-3	-3.6117E-5	-0.61299999999999999	-2.1067E-5
8.0000000000000002E-3	-3.6134999999999999E-5	-0.61499999999999999	-2.1092000000000001E-5
7.0000000000000001E-3	-3.6019000000000002E-5	-0.61699999999999999	-2.1115E-5
6.0000000000000001E-3	-3.6001000000000003E-5	-0.61899999999999999	-2.1203E-5
5.0000000000000001E-3	-3.6053999999999997E-5	-0.621	-2.1330000000000001E-5
4.0000000000000001E-3	-3.6081000000000002E-5	-0.623	-2.1282000000000001E-5
3.0000000000000001E-3	-3.6001000000000003E-5	-0.625	-2.1325999999999999E-5
2E-3	-3.6001000000000003E-5	-0.627	-2.1376999999999999E-5
1E-3	-3.6072000000000003E-5	-0.629	-2.1399E-5
0	-3.5982999999999998E-5	-0.63100000000000001	-2.1447E-5
-1E-3	-3.5955999999999999E-5	-0.63300000000000001	-2.1424E-5
-2E-3	-3.6062999999999997E-5	-0.63500000000000001	-2.1506999999999999E-5
-3.0000000000000001E-3	-3.5874999999999998E-5	-0.63700000000000001	-2.1563999999999999E-5
-4.0000000000000001E-3	-3.5867000000000001E-5	-0.63900000000000001	-2.1636000000000001E-5
-5.0000000000000001E-3	-3.5929000000000001E-5	-0.64100000000000001	-2.1654999999999998E-5
-6.0000000000000001E-3	-3.6134999999999999E-5	-0.64300000000000002	-2.1690000000000001E-5
-7.0000000000000001E-3	-3.6134999999999999E-5	-0.64500000000000002	-2.1693000000000001E-5
-8.0000000000000002E-3	-3.5982999999999998E-5	-0.64700000000000002	-2.1763000000000002E-5
-8.9999999999999993E-3	-3.5831000000000003E-5	-0.64900000000000002	-2.1790999999999999E-5
-0.01	-3.5840000000000002E-5	-0.65100000000000002	-2.1835999999999999E-5
-1.0999999999999999E-2	-3.5883999999999997E-5	-0.65300000000000002	-2.1917999999999999E-5
-1.2E-2	-3.5812999999999997E-5	-0.65500000000000003	-2.1905000000000001E-5
-1.2999999999999999E-2	-3.5741000000000002E-5	-0.65700000000000003	-2.1943E-5
-1.4E-2	-3.5706E-5	-0.65900000000000003	-2.1984000000000002E-5
-1.4999999999999999E-2	-3.5750000000000002E-5	-0.66100000000000003	-2.2038000000000001E-5
-1.6E-2	-3.5624999999999999E-5	-0.66300000000000003	-2.2089000000000001E-5
-1.7000000000000001E-2	-3.5661000000000003E-5	-0.66500000000000004	-2.2107E-5
-1.7999999999999999E-2	-3.5670000000000002E-5	-0.66700000000000004	-2.2177000000000001E-5
-1.9E-2	-3.5509000000000002E-5	-0.66900000000000004	-2.2167999999999998E-5
-0.02	-3.5598E-5	-0.67100000000000004	-2.2231000000000001E-5
-2.1000000000000001E-2	-3.5651999999999997E-5	-0.67300000000000004	-2.2252999999999999E-5
-2.1999999999999999E-2	-3.5580000000000002E-5	-0.67500000000000004	-2.2294E-5
-2.3E-2	-3.5509000000000002E-5	-0.67700000000000005	-2.2359999999999999E-5
-2.4E-2	-3.5509000000000002E-5	-0.67900000000000005	-2.2405E-5
-2.5000000000000001E-2	-3.5553000000000003E-5	-0.68100000000000005	-2.2373000000000001E-5
-2.5999999999999999E-2	-3.5509000000000002E-5	-0.68300000000000005	-2.2455000000000001E-5
-2.7E-2	-3.5472999999999997E-5	-0.68500000000000005	-2.2446000000000002E-5
-2.8000000000000001E-2	-3.5472999999999997E-5	-0.68700000000000006	-2.2484E-5
-2.9000000000000001E-2	-3.5311999999999997E-5	-0.68899999999999995	-2.2549999999999999E-5
-0.03	-3.5410000000000001E-5	-0.69099999999999995	-2.2594000000000001E-5
-3.1E-2	-3.5410000000000001E-5	-0.69299999999999995	-2.2594000000000001E-5
-3.2000000000000001E-2	-3.5240000000000001E-5	-0.69499999999999995	-2.2639000000000001E-5
-3.3000000000000002E-2	-3.5284999999999998E-5	-0.69699999999999995	-2.2670000000000001E-5
-3.4000000000000002E-2	-3.5284999999999998E-5	-0.69899999999999995	-2.268E-5
-3.5000000000000003E-2	-3.5187E-5	-0.70099999999999996	-2.2714999999999999E-5
-3.5999999999999997E-2	-3.5196E-5	-0.70299999999999996	-2.2778000000000001E-5
-3.6999999999999998E-2	-3.5187E-5	-0.70499999999999996	-2.2787000000000001E-5
-3.7999999999999999E-2	-3.5142000000000003E-5	-0.70699999999999996	-2.2799999999999999E-5
-3.9E-2	-3.5151000000000003E-5	-0.70899999999999996	-2.2821999999999999E-5
-0.04	-3.5160000000000002E-5	-0.71099999999999997	-2.287E-5
-4.1000000000000002E-2	-3.5079000000000001E-5	-0.71299999999999997	-2.2881999999999999E-5
-4.2000000000000003E-2	-3.5008000000000001E-5	-0.71499999999999997	-2.2955E-5
-4.2999999999999997E-2	-3.5034999999999999E-5	-0.71699999999999997	-2.2963999999999999E-5
-4.3999999999999997E-2	-3.4999000000000002E-5	-0.71899999999999997	-2.3011999999999999E-5
-4.4999999999999998E-2	-3.4882999999999998E-5	-0.72099999999999997	-2.304E-5
-4.5999999999999999E-2	-3.4873999999999998E-5	-0.72299999999999998	-2.3125999999999998E-5
-4.7E-2	-3.4882999999999998E-5	-0.72499999999999998	-2.3110000000000001E-5
-4.8000000000000001E-2	-3.4811000000000003E-5	-0.72699999999999998	-2.3085E-5
-4.9000000000000002E-2	-3.4792999999999997E-5	-0.72899999999999998	-2.3153999999999999E-5
-0.05	-3.4792999999999997E-5	-0.73099999999999998	-2.3183000000000001E-5
-5.0999999999999997E-2	-3.4783999999999998E-5	-0.73299999999999998	-2.3201999999999999E-5
-5.1999999999999998E-2	-3.4740000000000003E-5	-0.73499999999999999	-2.3195000000000001E-5
-5.2999999999999999E-2	-3.4703999999999998E-5	-0.73699999999999999	-2.3227E-5
-5.3999999999999999E-2	-3.4632000000000003E-5	-0.73899999999999999	-2.3264999999999998E-5
-5.5E-2	-3.4595999999999999E-5	-0.74099999999999999	-2.3281E-5
-5.6000000000000001E-2	-3.4613999999999998E-5	-0.74299999999999999	-2.3315E-5
-5.7000000000000002E-2	-3.4570000000000003E-5	-0.745	-2.3325000000000001E-5
-5.8000000000000003E-2	-3.4443999999999998E-5	-0.747	-2.3346999999999999E-5
-5.8999999999999997E-2	-3.4452999999999997E-5	-0.749	-2.3357E-5
-0.06	-3.4381999999999997E-5	-0.751	-2.3371999999999999E-5
-6.0999999999999999E-2	-3.4301000000000002E-5	-0.753	-2.3436000000000001E-5
-6.2E-2	-3.4345999999999999E-5	-0.755	-2.3461000000000001E-5
-6.3E-2	-3.4292000000000003E-5	-0.75700000000000001	-2.3461000000000001E-5
-6.4000000000000001E-2	-3.4239000000000002E-5	-0.75900000000000001	-2.3504999999999999E-5
-6.5000000000000002E-2	-3.4248000000000001E-5	-0.76100000000000001	-2.3467000000000001E-5
-6.6000000000000003E-2	-3.4167E-5	-0.76300000000000001	-2.3536999999999998E-5
-6.7000000000000004E-2	-3.4032999999999998E-5	-0.76500000000000001	-2.3543000000000001E-5
-6.8000000000000005E-2	-3.4060000000000003E-5	-0.76700000000000002	-2.3591000000000002E-5
-6.9000000000000006E-2	-3.4069000000000002E-5	-0.76900000000000002	-2.3572000000000001E-5
-7.0000000000000007E-2	-3.3988000000000001E-5	-0.77100000000000002	-2.3575E-5
-7.0999999999999994E-2	-3.3908000000000001E-5	-0.77300000000000002	-2.3663E-5
-7.1999999999999995E-2	-3.3899000000000002E-5	-0.77500000000000002	-2.3682000000000001E-5
-7.2999999999999995E-2	-3.3890000000000002E-5	-0.77700000000000002	-2.3648000000000001E-5
-7.3999999999999996E-2	-3.3747000000000001E-5	-0.77900000000000003	-2.3682000000000001E-5
-7.4999999999999997E-2	-3.3782999999999998E-5	-0.78100000000000003	-2.3708000000000001E-5
-7.5999999999999998E-2	-3.3773999999999999E-5	-0.78300000000000003	-2.3717E-5
-7.6999999999999999E-2	-3.3701999999999997E-5	-0.78500000000000003	-2.3745999999999999E-5
-7.8E-2	-3.3692999999999997E-5	-0.78700000000000003	-2.3730000000000001E-5
-7.9000000000000001E-2	-3.3657E-5	-0.78900000000000003	-2.3733000000000001E-5
-0.08	-3.3495999999999999E-5	-0.79100000000000004	-2.3757999999999999E-5
-8.1000000000000003E-2	-3.3513999999999998E-5	-0.79300000000000004	-2.3802E-5
-8.2000000000000003E-2	-3.3416E-5	-0.79500000000000004	-2.3793000000000001E-5
-8.3000000000000004E-2	-3.3325999999999999E-5	-0.79700000000000004	-2.3818000000000001E-5
-8.4000000000000005E-2	-3.3317E-5	-0.79900000000000004	-2.385E-5
-8.5000000000000006E-2	-3.3334999999999998E-5	-0.80100000000000005	-2.3836999999999999E-5
-8.5999999999999993E-2	-3.3228000000000001E-5	-0.80300000000000005	-2.3847000000000001E-5
-8.6999999999999994E-2	-3.3237E-5	-0.80500000000000005	-2.3907E-5
-8.7999999999999995E-2	-3.3272999999999998E-5	-0.80700000000000005	-2.3938E-5
-8.8999999999999996E-2	-3.3237E-5	-0.80900000000000005	-2.3918999999999999E-5
-0.09	-3.3164999999999998E-5	-0.81100000000000005	-2.3944999999999999E-5
-9.0999999999999998E-2	-3.3120999999999997E-5	-0.81299999999999994	-2.3954000000000001E-5
-9.1999999999999998E-2	-3.2978000000000002E-5	-0.81499999999999995	-2.3947999999999998E-5
-9.2999999999999999E-2	-3.2833999999999998E-5	-0.81699999999999995	-2.3969999999999999E-5
-9.4E-2	-3.2888000000000001E-5	-0.81899999999999995	-2.3989E-5
-9.5000000000000001E-2	-3.2833999999999998E-5	-0.82099999999999995	-2.4014000000000001E-5
-9.6000000000000002E-2	-3.2727E-5	-0.82299999999999995	-2.4008000000000001E-5
-9.7000000000000003E-2	-3.2771999999999997E-5	-0.82499999999999996	-2.4147000000000001E-5
-9.8000000000000004E-2	-3.2790000000000003E-5	-0.82699999999999996	-2.4080999999999999E-5
-9.9000000000000005E-2	-3.2656E-5	-0.82899999999999996	-2.4074E-5
-0.1	-3.2611000000000003E-5	-0.83099999999999996	-2.4116000000000001E-5
-0.10100000000000001	-3.2656E-5	-0.83299999999999996	-2.4093000000000001E-5
-0.10199999999999999	-3.2539000000000001E-5	-0.83499999999999996	-2.4105999999999999E-5
-0.10299999999999999	-3.2495E-5	-0.83699999999999997	-2.4097E-5
-0.104	-3.2450000000000003E-5	-0.83899999999999997	-2.4102999999999999E-5
-0.105	-3.2325E-5	-0.84099999999999997	-2.4116000000000001E-5
-0.106	-3.2333999999999999E-5	-0.84299999999999997	-2.4150000000000001E-5
-0.107	-3.2298000000000001E-5	-0.84499999999999997	-2.4153000000000001E-5
-0.108	-3.2307000000000001E-5	-0.84699999999999998	-2.4165999999999999E-5
-0.109	-3.2477000000000001E-5	-0.84899999999999998	-2.4131E-5
-0.11	-3.2360000000000002E-5	-0.85099999999999998	-2.4144000000000001E-5
-0.111	-3.2163999999999999E-5	-0.85299999999999998	-2.4187999999999999E-5
-0.112	-3.2002999999999998E-5	-0.85499999999999998	-2.4190999999999999E-5
-0.113	-3.1985E-5	-0.85699999999999998	-2.4223000000000002E-5
-0.114	-3.2020000000000002E-5	-0.85899999999999999	-2.4226000000000001E-5
-0.115	-3.1912999999999998E-5	-0.86099999999999999	-2.4201000000000001E-5
-0.11600000000000001	-3.1832999999999998E-5	-0.86299999999999999	-2.4261E-5
-0.11700000000000001	-3.1832999999999998E-5	-0.86499999999999999	-2.4236E-5
-0.11799999999999999	-3.1742999999999997E-5	-0.86699999999999999	-2.4226000000000001E-5
-0.11899999999999999	-3.1653999999999999E-5	-0.86899999999999999	-2.4241999999999999E-5
-0.12	-3.1644999999999999E-5	-0.871	-2.4283000000000001E-5
-0.121	-3.1538000000000002E-5	-0.873	-2.4286000000000001E-5
-0.122	-3.1483999999999999E-5	-0.875	-2.4292999999999999E-5
-0.123	-3.1492999999999998E-5	-0.877	-2.4315E-5
-0.124	-3.1393999999999998E-5	-0.879	-2.4324E-5
-0.125	-3.1313999999999999E-5	-0.88100000000000001	-2.4298999999999999E-5
-0.126	-3.1304999999999999E-5	-0.88300000000000001	-2.4321E-5
-0.127	-3.1359000000000002E-5	-0.88500000000000001	-2.4337000000000001E-5
-0.128	-3.1161999999999997E-5	-0.88700000000000001	-2.4343000000000001E-5
-0.129	-3.1189000000000002E-5	-0.88900000000000001	-2.4298999999999999E-5
-0.13	-3.1170999999999997E-5	-0.89100000000000001	-2.4372E-5
-0.13100000000000001	-3.0982999999999998E-5	-0.89300000000000002	-2.4365000000000001E-5
-0.13200000000000001	-3.1000999999999997E-5	-0.89500000000000002	-2.4358999999999998E-5
-0.13300000000000001	-3.0938000000000001E-5	-0.89700000000000002	-2.4377999999999999E-5
-0.13400000000000001	-3.0794999999999999E-5	-0.89900000000000002	-2.4386999999999999E-5
-0.13500000000000001	-3.0794999999999999E-5	-0.90100000000000002	-2.4403E-5
-0.13600000000000001	-3.0821999999999997E-5	-0.90300000000000002	-2.4383999999999999E-5
-0.13700000000000001	-3.0768000000000001E-5	-0.90500000000000003	-2.4406E-5
-0.13800000000000001	-3.0624999999999999E-5	-0.90700000000000003	-2.4431999999999999E-5
-0.13900000000000001	-3.0642999999999998E-5	-0.90900000000000003	-2.4437999999999999E-5
-0.14000000000000001	-3.0688000000000002E-5	-0.91100000000000003	-2.4419000000000001E-5
-0.14099999999999999	-3.0518000000000002E-5	-0.91300000000000003	-2.4425000000000001E-5
-0.14199999999999999	-3.0499999999999999E-5	-0.91500000000000004	-2.4394000000000001E-5
-0.14299999999999999	-3.0482000000000001E-5	-0.91700000000000004	-2.4451E-5
-0.14399999999999999	-3.025E-5	-0.91900000000000004	-2.4501000000000001E-5
-0.14499999999999999	-3.0267E-5	-0.92100000000000004	-2.4488999999999999E-5
-0.14599999999999999	-3.0303000000000001E-5	-0.92300000000000004	-2.4498000000000002E-5
-0.14699999999999999	-3.0142E-5	-0.92500000000000004	-2.4467000000000001E-5
-0.14799999999999999	-3.0114999999999999E-5	-0.92700000000000005	-2.4561000000000001E-5
-0.14899999999999999	-3.0105999999999999E-5	-0.92900000000000005	-2.4576999999999999E-5
-0.15	-2.9989999999999999E-5	-0.93100000000000005	-2.4552000000000001E-5
-0.151	-2.9998999999999999E-5	-0.93300000000000005	-2.4561000000000001E-5
-0.152	-2.9998999999999999E-5	-0.93500000000000005	-2.4539E-5
-0.153	-2.9918999999999999E-5	-0.93700000000000006	-2.4498000000000002E-5
-0.154	-2.9882999999999998E-5	-0.93899999999999995	-2.4494999999999998E-5
-0.155	-2.9793000000000001E-5	-0.94099999999999995	-2.4511E-5
-0.156	-2.9722000000000001E-5	-0.94299999999999995	-2.4576999999999999E-5
-0.157	-2.9649999999999999E-5	-0.94499999999999995	-2.4576999999999999E-5
-0.158	-2.9668000000000001E-5	-0.94699999999999995	-2.4573999999999999E-5
-0.159	-2.9632E-5	-0.94899999999999995	-2.4570999999999999E-5
-0.16	-2.9507000000000001E-5	-0.95099999999999996	-2.4576999999999999E-5
-0.161	-2.9436000000000001E-5	-0.95299999999999996	-2.4564999999999999E-5
-0.16200000000000001	-2.9453000000000001E-5	-0.95499999999999996	-2.4567999999999999E-5
-0.16300000000000001	-2.9354999999999999E-5	-0.95699999999999996	-2.4593E-5
-0.16400000000000001	-2.9283999999999999E-5	-0.95899999999999996	-2.4615000000000001E-5
-0.16500000000000001	-2.9257000000000001E-5	-0.96099999999999997	-2.4606000000000001E-5
-0.16600000000000001	-2.9184999999999999E-5	-0.96299999999999997	-2.4593E-5
-0.16700000000000001	-2.9087000000000001E-5	-0.96499999999999997	-2.4612000000000001E-5
-0.16800000000000001	-2.9149000000000002E-5	-0.96699999999999997	-2.4593E-5
-0.16900000000000001	-2.9077999999999998E-5	-0.96899999999999997	-2.4637000000000001E-5
-0.17	-2.8943999999999999E-5	-0.97099999999999997	-2.4644E-5
-0.17100000000000001	-2.8969999999999999E-5	-0.97299999999999998	-2.4640000000000001E-5
-0.17199999999999999	-2.8853999999999999E-5	-0.97499999999999998	-2.4658999999999999E-5
-0.17299999999999999	-2.8792000000000001E-5	-0.97699999999999998	-2.4640000000000001E-5
-0.17399999999999999	-2.8801000000000001E-5	-0.97899999999999998	-2.4723E-5
-0.17499999999999999	-2.8756E-5	-0.98099999999999998	-2.4703999999999999E-5
-0.17599999999999999	-2.8649E-5	-0.98299999999999998	-2.4658999999999999E-5
-0.17699999999999999	-2.8631000000000001E-5	-0.98499999999999999	-2.4685000000000002E-5
-0.17799999999999999	-2.8577000000000001E-5	-0.98699999999999999	-2.4694000000000001E-5
-0.17899999999999999	-2.8523000000000001E-5	-0.98899999999999999	-2.4694000000000001E-5
-0.18	-2.8461000000000001E-5	-0.99099999999999999	-2.4706999999999999E-5
-0.18099999999999999	-2.8388999999999999E-5	-0.99299999999999999	-2.4732E-5
-0.182	-2.8309E-5	-0.995	-2.4703999999999999E-5
-0.183	-2.8291000000000001E-5	-0.997	-2.4737999999999999E-5
-0.184	-2.8326999999999998E-5	-0.999	-2.4763999999999999E-5
-0.185	-2.8209999999999999E-5	-1.0009999999999999	-2.4712999999999999E-5
-0.186	-2.8067000000000001E-5	-1.0029999999999999	-2.4754000000000001E-5
-0.187	-2.8076E-5	-1.0049999999999999	-2.4732E-5
-0.188	-2.8022E-5	-1.0069999999999999	-2.4754000000000001E-5
-0.189	-2.7968999999999999E-5	-1.0089999999999999	-2.478E-5
-0.19	-2.7951000000000001E-5	-1.0109999999999999	-2.4799000000000001E-5
-0.191	-2.7906E-5	-1.0129999999999999	-2.4769999999999998E-5
-0.192	-2.7826000000000001E-5	-1.0149999999999999	-2.4802000000000001E-5
-0.193	-2.7763000000000002E-5	-1.0169999999999999	-2.4802000000000001E-5
-0.19400000000000001	-2.7718000000000001E-5	-1.0189999999999999	-2.478E-5
-0.19500000000000001	-2.7611E-5	-1.0209999999999999	-2.4837E-5
-0.19600000000000001	-2.7611E-5	-1.0229999999999999	-2.4827000000000001E-5
-0.19700000000000001	-2.7602000000000001E-5	-1.0249999999999999	-2.4856000000000001E-5
-0.19800000000000001	-2.7495E-5	-1.0269999999999999	-2.4842999999999999E-5
-0.19900000000000001	-2.7467999999999999E-5	-1.0289999999999999	-2.4924999999999999E-5
-0.2	-2.745E-5	-1.0309999999999999	-2.5004E-5
-0.20100000000000001	-2.7334E-5	-1.0329999999999999	-2.4902999999999999E-5
-0.20200000000000001	-2.7288999999999999E-5	-1.0349999999999999	-2.4884000000000001E-5
-0.20300000000000001	-2.7307000000000001E-5	-1.0369999999999999	-2.4896999999999999E-5
-0.20399999999999999	-2.728E-5	-1.0389999999999999	-2.4919E-5
-0.20499999999999999	-2.7191000000000001E-5	-1.0409999999999999	-2.4922E-5
-0.20599999999999999	-2.72E-5	-1.0429999999999999	-2.4902999999999999E-5
-0.20699999999999999	-2.7101E-5	-1.0449999999999999	-2.4919E-5
-0.20799999999999999	-2.6993999999999999E-5	-1.0469999999999999	-2.4930999999999999E-5
-0.20899999999999999	-2.6967000000000001E-5	-1.0489999999999999	-2.4963000000000001E-5
-0.21	-2.6931E-5	-1.0509999999999999	-2.4998E-5
-0.21099999999999999	-2.7083000000000001E-5	-1.0529999999999999	-2.4973E-5
-0.21199999999999999	-2.7047E-5	-1.0549999999999999	-2.4990999999999998E-5
-0.21299999999999999	-2.6851000000000001E-5	-1.0569999999999999	-2.5014000000000001E-5
-0.214	-2.6707999999999999E-5	-1.0589999999999999	-2.5017000000000001E-5
-0.215	-2.6707999999999999E-5	-1.0609999999999999	-2.5045000000000002E-5
-0.216	-2.6662999999999999E-5	-1.0629999999999999	-2.5045000000000002E-5
-0.217	-2.6591E-5	-1.0649999999999999	-2.5041999999999998E-5
-0.218	-2.6618000000000002E-5	-1.0669999999999999	-2.5063999999999999E-5
-0.219	-2.6573000000000001E-5	-1.069	-2.5066999999999999E-5
-0.22	-2.6448000000000002E-5	-1.071	-2.5074000000000001E-5
-0.221	-2.6403000000000001E-5	-1.073	-2.5083E-5
-0.222	-2.6376999999999998E-5	-1.075	-2.5117999999999999E-5
-0.223	-2.6359E-5	-1.077	-2.5108000000000001E-5
-0.224	-2.6234E-5	-1.079	-2.5162000000000001E-5
-0.22500000000000001	-2.6207000000000002E-5	-1.081	-2.5162000000000001E-5
-0.22600000000000001	-2.6242E-5	-1.083	-2.5177999999999998E-5
-0.22700000000000001	-2.6152999999999998E-5	-1.085	-2.5159000000000001E-5
-0.22800000000000001	-2.6098999999999999E-5	-1.087	-2.5162000000000001E-5
-0.22900000000000001	-2.6046000000000001E-5	-1.089	-2.5216E-5
-0.23	-2.5992000000000001E-5	-1.091	-2.5194E-5
-0.23100000000000001	-2.5973999999999999E-5	-1.093	-2.5238000000000001E-5
-0.23200000000000001	-2.6001000000000001E-5	-1.095	-2.5241000000000001E-5
-0.23300000000000001	-2.5876000000000001E-5	-1.097	-2.5256999999999999E-5
-0.23400000000000001	-2.5822000000000001E-5	-1.099	-2.5262999999999999E-5
-0.23499999999999999	-2.5803999999999999E-5	-1.101	-2.5313999999999999E-5
-0.23599999999999999	-2.5724E-5	-1.103	-2.5307999999999999E-5
-0.23699999999999999	-2.5687999999999999E-5	-1.105	-2.5307999999999999E-5
-0.23799999999999999	-2.5652000000000001E-5	-1.107	-2.5310999999999999E-5
-0.23899999999999999	-2.5581000000000001E-5	-1.109	-2.5361E-5
-0.24	-2.5554E-5	-1.111	-2.5377000000000001E-5
-0.24099999999999999	-2.5536000000000001E-5	-1.113	-2.5392999999999999E-5
-0.24199999999999999	-2.5527000000000001E-5	-1.115	-2.5406E-5
-0.24299999999999999	-2.5491E-5	-1.117	-2.5389999999999999E-5
-0.24399999999999999	-2.5491E-5	-1.119	-2.5415E-5
-0.245	-2.5411000000000001E-5	-1.121	-2.5474999999999999E-5
-0.246	-2.5222999999999999E-5	-1.123	-2.5471999999999999E-5
-0.247	-2.5276999999999999E-5	-1.125	-2.5491E-5
-0.248	-2.525E-5	-1.127	-2.552E-5
-0.249	-2.516E-5	-1.129	-2.5558000000000002E-5
-0.25	-2.5142000000000001E-5	-1.131	-2.5588999999999998E-5
-0.251	-2.5168999999999999E-5	-1.133	-2.5721999999999999E-5
-0.252	-2.5116000000000001E-5	-1.135	-2.5667999999999999E-5
-0.253	-2.5052999999999999E-5	-1.137	-2.5670999999999999E-5
-0.254	-2.5007999999999998E-5	-1.139	-2.5664999999999999E-5
-0.255	-2.5052999999999999E-5	-1.141	-2.5667999999999999E-5
-0.25600000000000001	-2.4981E-5	-1.143	-2.5687E-5
-0.25700000000000001	-2.4955000000000001E-5	-1.145	-2.5697000000000001E-5
-0.25800000000000001	-2.4901000000000001E-5	-1.147	-2.5763E-5
-0.25900000000000001	-2.4794E-5	-1.149	-2.5749999999999999E-5
-0.26	-2.4828999999999999E-5	-1.151	-2.5800999999999999E-5
-0.26100000000000001	-2.4811E-5	-1.153	-2.5826E-5
-0.26200000000000001	-2.4802000000000001E-5	-1.155	-2.5848000000000001E-5
-0.26300000000000001	-2.4703999999999999E-5	-1.157	-2.5854999999999999E-5
-0.26400000000000001	-2.4757999999999999E-5	-1.159	-2.5896000000000001E-5
-0.26500000000000001	-2.4641E-5	-1.161	-2.5905E-5
-0.26600000000000001	-2.4587999999999999E-5	-1.163	-2.5987999999999999E-5
-0.26700000000000002	-2.4606000000000001E-5	-1.165	-2.5999999999999998E-5
-0.26800000000000002	-2.4587999999999999E-5	-1.167	-2.6021999999999999E-5
-0.26900000000000002	-2.4516E-5	-1.169	-2.6063000000000001E-5
-0.27	-2.4525E-5	-1.171	-2.6081999999999999E-5
-0.27100000000000002	-2.4498000000000002E-5	-1.173	-2.6114000000000001E-5
-0.27200000000000002	-2.4454E-5	-1.175	-2.6126999999999999E-5
-0.27300000000000002	-2.4417999999999999E-5	-1.177	-2.6154999999999999E-5
-0.27400000000000002	-2.4355E-5	-1.179	-2.6228E-5
-0.27500000000000002	-2.4284E-5	-1.181	-2.6253000000000001E-5
-0.27600000000000002	-2.4301999999999999E-5	-1.1830000000000001	-2.6293999999999999E-5
-0.27700000000000002	-2.4275000000000001E-5	-1.1850000000000001	-2.6367E-5
-0.27800000000000002	-2.4266000000000001E-5	-1.1870000000000001	-2.6364E-5
-0.27900000000000003	-2.4239E-5	-1.1890000000000001	-2.6410999999999998E-5
-0.28000000000000003	-2.4256999999999998E-5	-1.1910000000000001	-2.6471000000000001E-5
-0.28100000000000003	-2.4167000000000001E-5	-1.1930000000000001	-2.6480999999999999E-5
-0.28199999999999997	-2.4122999999999999E-5	-1.1950000000000001	-2.65E-5
-0.28299999999999997	-2.4193999999999999E-5	-1.1970000000000001	-2.6537999999999999E-5
-0.28399999999999997	-2.4185E-5	-1.1990000000000001	-2.6579000000000001E-5
-0.28499999999999998	-2.4051000000000001E-5	-1.2010000000000001	-2.6652000000000002E-5
-0.28599999999999998	-2.4042000000000001E-5	-1.2030000000000001	-2.6686000000000002E-5
-0.28699999999999998	-2.4032999999999998E-5	-1.2050000000000001	-2.6743000000000001E-5
-0.28799999999999998	-2.3935E-5	-1.2070000000000001	-2.6791000000000001E-5
-0.28899999999999998	-2.3944E-5	-1.2090000000000001	-2.6803000000000001E-5
-0.28999999999999998	-2.3980000000000001E-5	-1.2110000000000001	-2.6894999999999999E-5
-0.29099999999999998	-2.3907999999999999E-5	-1.2130000000000001	-2.6917E-5
-0.29199999999999998	-2.3926000000000001E-5	-1.2150000000000001	-2.6976999999999999E-5
-0.29299999999999998	-2.3935E-5	-1.2170000000000001	-2.7036999999999999E-5
-0.29399999999999998	-2.3853999999999999E-5	-1.2190000000000001	-2.7090999999999999E-5
-0.29499999999999998	-2.3845E-5	-1.2210000000000001	-2.7123000000000001E-5
-0.29599999999999999	-2.3935E-5	-1.2230000000000001	-2.7172999999999999E-5
-0.29699999999999999	-2.3845E-5	-1.2250000000000001	-2.7277999999999999E-5
-0.29799999999999999	-2.3801000000000001E-5	-1.2270000000000001	-2.7322E-5
-0.29899999999999999	-2.3791999999999999E-5	-1.2290000000000001	-2.7351E-5
-0.3	-2.3782999999999999E-5	-1.2310000000000001	-2.7416999999999999E-5
-0.30099999999999999	-2.3711E-5	-1.2330000000000001	-2.7509E-5
-0.30199999999999999	-2.3711E-5	-1.2350000000000001	-2.7657E-5
-0.30299999999999999	-2.3737999999999999E-5	-1.2370000000000001	-2.7682999999999999E-5
-0.30399999999999999	-2.3666999999999999E-5	-1.2390000000000001	-2.7705E-5
-0.30499999999999999	-2.3666999999999999E-5	-1.2410000000000001	-2.7776999999999998E-5
-0.30599999999999999	-2.3657999999999999E-5	-1.2430000000000001	-2.7821999999999999E-5
-0.307	-2.3693000000000002E-5	-1.2450000000000001	-2.7900999999999999E-5
-0.308	-2.3649E-5	-1.2470000000000001	-2.7970000000000002E-5
-0.309	-2.3621999999999998E-5	-1.2490000000000001	-2.8027000000000001E-5
-0.31	-2.3586000000000001E-5	-1.2509999999999999	-2.8132000000000001E-5
-0.311	-2.3631000000000001E-5	-1.2529999999999999	-2.8214000000000001E-5
-0.312	-2.3604E-5	-1.2549999999999999	-2.8317999999999999E-5
-0.313	-2.3711E-5	-1.2569999999999999	-2.8334E-5
-0.314	-2.3728999999999999E-5	-1.2589999999999999	-2.8399999999999999E-5
-0.315	-2.3604E-5	-1.2609999999999999	-2.8479E-5
-0.316	-2.3541E-5	-1.2629999999999999	-2.8595999999999999E-5
-0.317	-2.3461000000000001E-5	-1.2649999999999999	-2.8707000000000001E-5
-0.318	-2.3506000000000002E-5	-1.2669999999999999	-2.8779999999999999E-5
-0.31900000000000001	-2.3558999999999999E-5	-1.2689999999999999	-2.8894000000000002E-5
-0.32	-2.3532000000000001E-5	-1.2709999999999999	-2.8963E-5
-0.32100000000000001	-2.3513999999999999E-5	-1.2729999999999999	-2.9071E-5
-0.32200000000000001	-2.3513999999999999E-5	-1.2749999999999999	-2.9196999999999998E-5
-0.32300000000000001	-2.3434E-5	-1.2769999999999999	-2.9280000000000001E-5
-0.32400000000000001	-2.3442999999999999E-5	-1.2789999999999999	-2.9377999999999999E-5
-0.32500000000000001	-2.3425E-5	-1.2809999999999999	-2.9536E-5
-0.32600000000000001	-2.3407000000000001E-5	-1.2829999999999999	-2.9598999999999999E-5
-0.32700000000000001	-2.338E-5	-1.2849999999999999	-2.9706E-5
-0.32800000000000001	-2.3425E-5	-1.2869999999999999	-2.9816999999999999E-5
-0.32900000000000001	-2.3397999999999999E-5	-1.2889999999999999	-2.9927999999999999E-5
-0.33	-2.3425E-5	-1.2909999999999999	-3.0102000000000001E-5
-0.33100000000000002	-2.3451999999999998E-5	-1.2929999999999999	-3.0209000000000002E-5
-0.33200000000000002	-2.3434E-5	-1.2949999999999999	-3.0329E-5
-0.33300000000000002	-2.3451999999999998E-5	-1.2969999999999999	-3.0443E-5
-0.33400000000000002	-2.3434E-5	-1.2989999999999999	-3.0516000000000001E-5
-0.33500000000000002	-2.3425E-5	-1.3009999999999999	-3.0686999999999999E-5
-0.33600000000000002	-2.338E-5	-1.3029999999999999	-3.0828999999999999E-5
-0.33700000000000002	-2.3388999999999999E-5	-1.3049999999999999	-3.1003000000000001E-5
-0.33800000000000002	-2.3371E-5	-1.3069999999999999	-3.1133000000000002E-5
-0.33900000000000002	-2.3336000000000002E-5	-1.3089999999999999	-3.1239999999999999E-5
-0.34	-2.3407000000000001E-5	-1.3109999999999999	-3.1401E-5
-0.34100000000000003	-2.3451999999999998E-5	-1.3129999999999999	-3.1541000000000002E-5
-0.34200000000000003	-2.3371E-5	-1.3149999999999999	-3.1686000000000001E-5
-0.34300000000000003	-2.3416000000000001E-5	-1.3169999999999999	-3.1875999999999998E-5
-0.34399999999999997	-2.3434E-5	-1.319	-3.2033999999999999E-5
-0.34499999999999997	-2.3353000000000002E-5	-1.321	-3.2159999999999997E-5
-0.34599999999999997	-2.3388999999999999E-5	-1.323	-3.2317999999999998E-5
-0.34699999999999998	-2.338E-5	-1.325	-3.2477000000000001E-5
-0.34799999999999998	-2.3407000000000001E-5	-1.327	-3.2697999999999998E-5
-0.34899999999999998	-2.3416000000000001E-5	-1.329	-3.2888000000000001E-5
-0.35	-2.3407000000000001E-5	-1.331	-3.3046000000000002E-5
-0.35099999999999998	-2.3434E-5	-1.333	-3.3204000000000003E-5
-0.35199999999999998	-2.3371E-5	-1.335	-3.3393999999999999E-5
-0.35299999999999998	-2.3461000000000001E-5	-1.337	-3.3710000000000001E-5
-0.35399999999999998	-2.3451999999999998E-5	-1.339	-3.3868000000000002E-5
-0.35499999999999998	-2.3416000000000001E-5	-1.341	-3.3963E-5
-0.35599999999999998	-2.3451999999999998E-5	-1.343	-3.4183999999999997E-5
-0.35699999999999998	-2.3461000000000001E-5	-1.345	-3.4374E-5
-0.35799999999999998	-2.3425E-5	-1.347	-3.4532000000000001E-5
-0.35899999999999999	-2.3434E-5	-1.349	-3.4752999999999997E-5
-0.36	-2.3513999999999999E-5	-1.351	-3.4943000000000001E-5
-0.36099999999999999	-2.3451999999999998E-5	-1.353	-3.5165E-5
-0.36199999999999999	-2.3461000000000001E-5	-1.355	-3.5386000000000003E-5
-0.36299999999999999	-2.3541E-5	-1.357	-3.5639000000000002E-5
-0.36399999999999999	-2.3513999999999999E-5	-1.359	-3.5797000000000003E-5
-0.36499999999999999	-2.3541E-5	-1.361	-3.6050000000000002E-5
-0.36599999999999999	-2.3595E-5	-1.363	-3.6176000000000001E-5
-0.36699999999999999	-2.3541E-5	-1.365	-3.6397999999999999E-5
-0.36799999999999999	-2.3532000000000001E-5	-1.367	-3.6681999999999999E-5
-0.36899999999999999	-2.3532000000000001E-5	-1.369	-3.6903999999999998E-5
-0.37	-2.3640000000000001E-5	-1.371	-3.7156999999999997E-5
-0.371	-2.3532000000000001E-5	-1.373	-3.7345999999999998E-5
-0.372	-2.3595E-5	-1.375	-3.7567999999999997E-5
-0.373	-2.3657999999999999E-5	-1.377	-3.7758E-5
-0.374	-2.3612999999999999E-5	-1.379	-3.8010999999999999E-5
-0.375	-2.3612999999999999E-5	-1.381	-3.8232000000000003E-5
-0.376	-2.3640000000000001E-5	-1.383	-3.8485000000000002E-5
-0.377	-2.3612999999999999E-5	-1.385	-3.8705999999999998E-5
-0.378	-2.3649E-5	-1.387	-3.8927999999999997E-5
-0.379	-2.3666999999999999E-5	-1.389	-3.9181000000000003E-5
-0.38	-2.3666999999999999E-5	-1.391	-3.9402E-5
-0.38100000000000001	-2.3683999999999999E-5	-1.393	-3.9654999999999999E-5
-0.38200000000000001	-2.3711E-5	-1.395	-3.9876000000000002E-5
-0.38300000000000001	-2.3756000000000001E-5	-1.397	-4.0129000000000002E-5
-0.38400000000000001	-2.3728999999999999E-5	-1.399	-4.0382000000000001E-5
-0.38500000000000001	-2.3853999999999999E-5	-1.401	-4.0571999999999997E-5
-0.38600000000000001	-2.3828E-5	-1.403	-4.0793000000000001E-5
-0.38700000000000001	-2.3791999999999999E-5	-1.405	-4.1014999999999999E-5
-0.38800000000000001	-2.3828E-5	-1.407	-4.1362999999999997E-5
-0.38900000000000001	-2.3853999999999999E-5	-1.409	-4.1520999999999998E-5
-0.39	-2.3765E-5	-1.411	-4.1742000000000001E-5
-0.39100000000000001	-2.3845E-5	-1.413	-4.1962999999999998E-5
-0.39200000000000002	-2.3898999999999999E-5	-1.415	-4.2153000000000001E-5
-0.39300000000000002	-2.3898999999999999E-5	-1.417	-4.2375E-5
-0.39400000000000002	-2.3917000000000002E-5	-1.419	-4.2691000000000002E-5
-0.39500000000000002	-2.3944E-5	-1.421	-4.2849000000000003E-5
-0.39600000000000002	-2.4006E-5	-1.423	-4.3038999999999999E-5
-0.39700000000000002	-2.3989E-5	-1.425	-4.3260000000000003E-5
-0.39800000000000002	-2.4042000000000001E-5	-1.427	-4.3386000000000001E-5
-0.39900000000000002	-2.4015E-5	-1.429	-4.3671000000000003E-5
-0.4	-2.4042000000000001E-5	-1.431	-4.3860999999999999E-5
-0.40100000000000002	-2.4096000000000001E-5	-1.4330000000000001	-4.4051000000000002E-5
-0.40200000000000002	-2.4141000000000001E-5	-1.4350000000000001	-4.4209000000000003E-5
-0.40300000000000002	-2.4068999999999999E-5	-1.4370000000000001	-4.443E-5
-0.40400000000000003	-2.4096000000000001E-5	-1.4390000000000001	-4.4715000000000001E-5
-0.40500000000000003	-2.4150000000000001E-5	-1.4410000000000001	-4.4873000000000002E-5
-0.40600000000000003	-2.4141000000000001E-5	-1.4430000000000001	-4.4968E-5
-0.40699999999999997	-2.423E-5	-1.4450000000000001	-4.5126000000000001E-5
-0.40799999999999997	-2.4266000000000001E-5	-1.4470000000000001	-4.5284000000000002E-5
-0.40899999999999997	-2.4247999999999999E-5	-1.4490000000000001	-4.5442000000000003E-5
-0.41	-2.4256999999999998E-5	-1.4510000000000001	-4.5599999999999997E-5
-0.41099999999999998	-2.4311000000000002E-5	-1.4530000000000001	-4.5726999999999998E-5
-0.41199999999999998	-2.4311000000000002E-5	-1.4550000000000001	-4.5884999999999999E-5
-0.41299999999999998	-2.4284E-5	-1.4570000000000001	-4.6042999999999999E-5
-0.41399999999999998	-2.4372999999999999E-5	-1.4590000000000001	-4.6168999999999998E-5
-0.41499999999999998	-2.4445000000000001E-5	-1.4610000000000001	-4.6264000000000003E-5
-0.41599999999999998	-2.4624E-5	-1.4630000000000001	-4.6421999999999997E-5
-0.41699999999999998	-2.457E-5	-1.4650000000000001	-4.6453999999999999E-5
-0.41799999999999998	-2.4488999999999999E-5	-1.4670000000000001	-4.6548999999999998E-5
-0.41899999999999998	-2.4479999999999999E-5	-1.4690000000000001	-4.6675000000000003E-5
-0.42	-2.4552000000000001E-5	-1.4710000000000001	-4.6801999999999997E-5
-0.42099999999999999	-2.4579E-5	-1.4730000000000001	-4.6864999999999999E-5
-0.42199999999999999	-2.4587999999999999E-5	-1.4750000000000001	-4.6928000000000002E-5
-0.42299999999999999	-2.4579E-5	-1.4770000000000001	-4.7023E-5
-0.42399999999999999	-2.4632999999999999E-5	-1.4790000000000001	-4.7086000000000003E-5
-0.42499999999999999	-2.4641E-5	-1.4810000000000001	-4.7150000000000001E-5
-0.42599999999999999	-2.4668000000000002E-5	-1.4830000000000001	-4.7243999999999997E-5
-0.42699999999999999	-2.4722000000000001E-5	-1.4850000000000001	-4.7275999999999999E-5
-0.42799999999999999	-2.4695E-5	-1.4870000000000001	-4.7308000000000002E-5
-0.42899999999999999	-2.4677000000000001E-5	-1.4890000000000001	-4.7403E-5
-0.43	-2.4766999999999999E-5	-1.4910000000000001	-4.7434E-5
-0.43099999999999999	-2.482E-5	-1.4930000000000001	-4.7466000000000003E-5
-0.432	-2.4837999999999998E-5	-1.4950000000000001	-4.7497000000000003E-5
-0.433	-2.4873999999999999E-5	-1.4970000000000001	-4.7528999999999998E-5
-0.434	-2.491E-5	-1.4990000000000001	-4.7561000000000001E-5
-0.435	-2.4936999999999999E-5	-1.5009999999999999	-4.7561000000000001E-5
-0.436	-2.4981E-5	-1.5029999999999999	-4.7592000000000001E-5
-0.437	-2.5007999999999998E-5	-1.5049999999999999	-4.7623999999999997E-5
-0.438	-2.4963000000000001E-5	-1.5069999999999999	-4.7623999999999997E-5
-0.439	-2.5035E-5	-1.5089999999999999	-4.7655999999999999E-5
-0.44	-2.5089E-5	-1.5109999999999999	-4.7686999999999999E-5
-0.441	-2.5052999999999999E-5	-1.5129999999999999	-4.7686999999999999E-5
-0.442	-2.5026000000000001E-5	-1.5149999999999999	-4.7719000000000002E-5
-0.443	-2.5142000000000001E-5	-1.5169999999999999	-4.7686999999999999E-5
-0.44400000000000001	-2.5168999999999999E-5	-1.5189999999999999	-4.7719000000000002E-5
-0.44500000000000001	-2.5205E-5	-1.5209999999999999	-4.7686999999999999E-5
-0.44600000000000001	-2.5222999999999999E-5	-1.5229999999999999	-4.7750000000000002E-5
-0.44700000000000001	-2.5284999999999999E-5	-1.5249999999999999	-4.7719000000000002E-5
-0.44800000000000001	-2.5321E-5	-1.5269999999999999	-4.7750000000000002E-5
-0.44900000000000001	-2.5347999999999999E-5	-1.5289999999999999	-4.7719000000000002E-5
-0.45	-2.5401999999999998E-5	-1.5309999999999999	-4.7719000000000002E-5
-0.45100000000000001	-2.5375E-5	-1.5329999999999999	-4.7686999999999999E-5
-0.45200000000000001	-2.5454999999999999E-5	-1.5349999999999999	-4.7781999999999998E-5
-0.45300000000000001	-2.5482000000000001E-5	-1.5369999999999999	-4.7750000000000002E-5
-0.45400000000000001	-2.5384E-5	-1.5389999999999999	-4.7719000000000002E-5
-0.45500000000000002	-2.5491E-5	-1.5409999999999999	-4.7781999999999998E-5
-0.45600000000000002	-2.5581000000000001E-5	-1.5429999999999999	-4.7908999999999998E-5
-0.45700000000000002	-2.5571999999999998E-5	-1.5449999999999999	-4.7845E-5
-0.45800000000000002	-2.5571999999999998E-5	-1.5469999999999999	-4.7781999999999998E-5
-0.45900000000000002	-2.5624999999999999E-5	-1.5489999999999999	-4.7781999999999998E-5
-0.46	-2.5678999999999999E-5	-1.5509999999999999	-4.7781999999999998E-5
-0.46100000000000002	-2.5687999999999999E-5	-1.5529999999999999	-4.7814E-5
-0.46200000000000002	-2.5795E-5	-1.5549999999999999	-4.7781999999999998E-5
-0.46300000000000002	-2.5831000000000001E-5	-1.5569999999999999	-4.7814E-5
-0.46400000000000002	-2.5732999999999999E-5	-1.5589999999999999	-4.7814E-5
-0.46500000000000002	-2.5795E-5	-1.5609999999999999	-4.7877000000000003E-5
-0.46600000000000003	-2.5857999999999999E-5	-1.5629999999999999	-4.7877000000000003E-5
-0.46700000000000003	-2.5876000000000001E-5	-1.5649999999999999	-4.7908999999999998E-5
-0.46800000000000003	-2.5956E-5	-1.5669999999999999	-4.7877000000000003E-5
-0.46899999999999997	-2.5982999999999998E-5	-1.569	-4.7908999999999998E-5
-0.47	-2.5947000000000001E-5	-1.571	-4.7939999999999998E-5
-0.47099999999999997	-2.601E-5	-1.573	-4.8003000000000001E-5
-0.47199999999999998	-2.6046000000000001E-5	-1.575	-4.8034999999999997E-5
-0.47299999999999998	-2.6064E-5	-1.577	-4.8034999999999997E-5
-0.47399999999999998	-2.6098999999999999E-5	-1.579	-4.8034999999999997E-5
-0.47499999999999998	-2.6152999999999998E-5	-1.581	-4.8066999999999999E-5
-0.47599999999999998	-2.6251E-5	-1.583	-4.8130000000000002E-5
-0.47699999999999998	-2.6225E-5	-1.585	-4.8256E-5
-0.47799999999999998	-2.6268999999999999E-5	-1.587	-4.8256E-5
-0.47899999999999998	-2.6287000000000001E-5	-1.589	-4.8288000000000003E-5
-0.48	-2.6234E-5	-1.591	-4.8383000000000001E-5
-0.48099999999999998	-2.6332000000000001E-5	-1.593	-4.8414000000000001E-5
-0.48199999999999998	-2.6376999999999998E-5	-1.595	-4.8477999999999999E-5
-0.48299999999999998	-2.6359E-5	-1.597	-4.8541000000000002E-5
-0.48399999999999999	-2.6438999999999999E-5	-1.599	-4.8572999999999997E-5
-0.48499999999999999	-2.652E-5	-1.601	-4.8667E-5
-0.48599999999999999	-2.6511000000000001E-5	-1.603	-4.8730999999999998E-5
-0.48699999999999999	-2.6529E-5	-1.605	-4.8794000000000001E-5
-0.48799999999999999	-2.6627000000000001E-5	-1.607	-4.8826000000000003E-5
-0.48899999999999999	-2.6582000000000001E-5	-1.609	-4.8888999999999999E-5
-0.49	-2.6618000000000002E-5	-1.611	-4.8983999999999997E-5
-0.49099999999999999	-2.6653999999999999E-5	-1.613	-4.9079000000000002E-5
-0.49199999999999999	-2.6699E-5	-1.615	-4.9141999999999998E-5
-0.49299999999999999	-2.6672000000000001E-5	-1.617	-4.9237000000000003E-5
-0.49399999999999999	-2.6788000000000002E-5	-1.619	-4.9299999999999999E-5
-0.495	-2.6788000000000002E-5	-1.621	-4.9394999999999997E-5
-0.496	-2.6788000000000002E-5	-1.623	-4.9490000000000002E-5
-0.497	-2.6869E-5	-1.625	-4.9585E-5
-0.498	-2.6922000000000001E-5	-1.627	-4.9679000000000003E-5
-0.499	-2.6948999999999999E-5	-1.629	-4.9710999999999999E-5
-0.5	-2.7021000000000001E-5	-1.631	-4.9836999999999997E-5
-0.501	-2.7002999999999999E-5	-1.633	-4.9963999999999998E-5
-0.502	-2.6985E-5	-1.635	-5.0027000000000001E-5
-0.503	-2.7039E-5	-1.637	-5.0090000000000003E-5
-0.504	-2.7137000000000001E-5	-1.639	-5.0249E-5
-0.505	-2.7155E-5	-1.641	-5.0343000000000002E-5
-0.50600000000000001	-2.7056E-5	-1.643	-5.0501999999999999E-5
-0.50700000000000001	-2.7191000000000001E-5	-1.645	-5.0627999999999997E-5
-0.50800000000000001	-2.7325E-5	-1.647	-5.0723000000000002E-5
-0.50900000000000001	-2.7243999999999999E-5	-1.649	-5.0818E-5
-0.51	-2.7217E-5	-1.651	-5.0881000000000003E-5
-0.51100000000000001	-2.7316000000000001E-5	-1.653	-5.1007999999999997E-5
-0.51200000000000001	-2.7361000000000001E-5	-1.655	-5.1102E-5
-0.51300000000000001	-2.7432000000000001E-5	-1.657	-5.1229E-5
-0.51400000000000001	-2.7413999999999999E-5	-1.659	-5.1323999999999999E-5
-0.51500000000000001	-2.7432000000000001E-5	-1.661	-5.1387000000000001E-5
-0.51600000000000001	-2.7538999999999998E-5	-1.663	-5.1514000000000002E-5
-0.51700000000000002	-2.7512999999999999E-5	-1.665	-5.1672000000000003E-5
-0.51800000000000002	-2.7744999999999999E-5	-1.667	-5.1765999999999999E-5
-0.51900000000000002	-2.7798999999999999E-5	-1.669	-5.1798000000000001E-5
-0.52	-2.7744999999999999E-5	-1.671	-5.1956000000000002E-5
-0.52100000000000002	-2.7674E-5	-1.673	-5.2018999999999998E-5
-0.52200000000000002	-2.7656000000000001E-5	-1.675	-5.2209000000000001E-5
-0.52300000000000002	-2.7753999999999999E-5	-1.677	-5.2271999999999997E-5
-0.52400000000000002	-2.7763000000000002E-5	-1.679	-5.2367000000000002E-5
-0.52500000000000002	-2.7861E-5	-1.681	-5.2494000000000003E-5
-0.52600000000000002	-2.7826000000000001E-5	-1.6830000000000001	-5.2589000000000001E-5
-0.52700000000000002	-2.7897000000000001E-5	-1.6850000000000001	-5.2747000000000002E-5
-0.52800000000000002	-2.7869999999999999E-5	-1.6870000000000001	-5.2873E-5
-0.52900000000000003	-2.7942000000000001E-5	-1.6890000000000001	-5.3000000000000001E-5
-0.53	-2.7932999999999998E-5	-1.6910000000000001	-5.3031000000000001E-5
-0.53100000000000003	-2.7951000000000001E-5	-1.6930000000000001	-5.3189999999999997E-5
-0.53200000000000003	-2.8013000000000001E-5	-1.6950000000000001	-5.3316000000000002E-5
-0.53300000000000003	-2.8121000000000001E-5	-1.6970000000000001	-5.3442000000000001E-5
-0.53400000000000003	-2.8076E-5	-1.6990000000000001	-5.3536999999999999E-5
-0.53500000000000003	-2.8093999999999999E-5	-1.7010000000000001	-5.3631999999999997E-5
-0.53600000000000003	-2.8183000000000001E-5	-1.7030000000000001	-5.3789999999999998E-5
-0.53700000000000003	-2.8255E-5	-1.7050000000000001	-5.3885000000000003E-5
-0.53800000000000003	-2.8201E-5	-1.7070000000000001	-5.3980000000000002E-5
-0.53900000000000003	-2.8246E-5	-1.7090000000000001	-5.4107000000000002E-5
-0.54	-2.8282000000000001E-5	-1.7110000000000001	-5.4233000000000001E-5
-0.54100000000000004	-2.83E-5	-1.7130000000000001	-5.4360000000000001E-5
-0.54200000000000004	-2.8416E-5	-1.7150000000000001	-5.4486E-5
-0.54300000000000004	-2.8407000000000001E-5	-1.7170000000000001	-5.4580999999999998E-5
-0.54400000000000004	-2.8291000000000001E-5	-1.7190000000000001	-5.4771000000000001E-5
-0.54500000000000004	-2.847E-5	-1.7210000000000001	-5.4802000000000001E-5
-0.54600000000000004	-2.8504999999999999E-5	-1.7230000000000001	-5.4960000000000002E-5
-0.54700000000000004	-2.8504999999999999E-5	-1.7250000000000001	-5.5055000000000001E-5
-0.54800000000000004	-2.8577000000000001E-5	-1.7270000000000001	-5.5244999999999997E-5
-0.54900000000000004	-2.8603999999999999E-5	-1.7290000000000001	-5.5371000000000002E-5
-0.55000000000000004	-2.8595E-5	-1.7310000000000001	-5.5498000000000003E-5
-0.55100000000000005	-2.8649E-5	-1.7330000000000001	-5.5655999999999997E-5
-0.55200000000000005	-2.8719999999999999E-5	-1.7350000000000001	-5.5719E-5
-0.55300000000000005	-2.8693000000000001E-5	-1.7370000000000001	-5.5877000000000001E-5
-0.55400000000000005	-2.8674999999999999E-5	-1.7390000000000001	-5.6004000000000001E-5
-0.55500000000000005	-2.8747000000000001E-5	-1.7410000000000001	-5.6162000000000002E-5
-0.55600000000000005	-2.8818000000000001E-5	-1.7430000000000001	-5.6320000000000003E-5
-0.55700000000000005	-2.8801000000000001E-5	-1.7450000000000001	-5.6446999999999997E-5
-0.55800000000000005	-2.8872000000000001E-5	-1.7470000000000001	-5.6731000000000003E-5
-0.55900000000000005	-2.8926000000000001E-5	-1.7490000000000001	-5.6762999999999998E-5
-0.56000000000000005	-2.8917000000000001E-5	-1.7509999999999999	-5.6857999999999997E-5
-0.56100000000000005	-2.8952999999999999E-5	-1.7529999999999999	-5.6984000000000002E-5
-0.56200000000000006	-2.8997E-5	-1.7549999999999999	-5.7173999999999998E-5
-0.56299999999999994	-2.9006E-5	-1.7569999999999999	-5.7299999999999997E-5
-0.56399999999999995	-2.9087000000000001E-5	-1.7589999999999999	-5.7395000000000002E-5
-0.56499999999999995	-2.9105E-5	-1.7609999999999999	-5.7553000000000003E-5
-0.56599999999999995	-2.9068999999999999E-5	-1.7629999999999999	-5.7648000000000001E-5
-0.56699999999999995	-2.9149000000000002E-5	-1.7649999999999999	-5.7806000000000002E-5
-0.56799999999999995	-2.9184999999999999E-5	-1.7669999999999999	-5.7933000000000003E-5
-0.56899999999999995	-2.8844999999999999E-5	-1.7689999999999999	-5.8028000000000001E-5
-0.56999999999999995	-2.8702000000000001E-5	-1.7709999999999999	-5.8153999999999999E-5
-0.57099999999999995	-2.9096000000000001E-5	-1.7729999999999999	-5.8281E-5
-0.57199999999999995	-2.9257000000000001E-5	-1.7749999999999999	-5.8439000000000001E-5
-0.57299999999999995	-2.9319000000000002E-5	-1.7769999999999999	-5.8597000000000002E-5
-0.57399999999999995	-2.9328000000000001E-5	-1.7789999999999999	-5.8692E-5
-0.57499999999999996	-2.9382000000000001E-5	-1.7809999999999999	-5.8786999999999998E-5
-0.57599999999999996	-2.9382000000000001E-5	-1.7829999999999999	-5.8913000000000003E-5
-0.57699999999999996	-2.9453000000000001E-5	-1.7849999999999999	-5.9039999999999997E-5
-0.57799999999999996	-2.9516E-5	-1.7869999999999999	-5.9103E-5
-0.57899999999999996	-2.9462E-5	-1.7889999999999999	-5.9135000000000002E-5
-0.57999999999999996	-2.9516E-5	-1.7909999999999999	-5.9324000000000003E-5
-0.58099999999999996	-2.9552000000000001E-5	-1.7929999999999999	-5.9388000000000001E-5
-0.58199999999999996	-2.9543000000000002E-5	-1.7949999999999999	-5.9481999999999997E-5
-0.58299999999999996	-2.9606000000000001E-5	-1.7969999999999999	-5.9514E-5
-0.58399999999999996	-2.9649999999999999E-5	-1.7989999999999999	-5.9546000000000002E-5
-0.58499999999999996	-2.9668000000000001E-5	-1.8009999999999999	-5.9672000000000001E-5
-0.58599999999999997	-2.9658999999999998E-5	-1.8029999999999999	-5.9766999999999999E-5
-0.58699999999999997	-2.9731E-5	-1.8049999999999999	-5.9861999999999997E-5
-0.58799999999999997	-2.9774999999999999E-5	-1.8069999999999999	-5.9925E-5
-0.58899999999999997	-2.9784000000000001E-5	-1.8089999999999999	-5.9988000000000002E-5
-0.59	-2.9828999999999999E-5	-1.8109999999999999	-6.0019999999999998E-5
-0.59099999999999997	-2.9865E-5	-1.8129999999999999	-6.0052E-5
-0.59199999999999997	-2.9865E-5	-1.8149999999999999	-6.0146999999999999E-5
-0.59299999999999997	-2.9963000000000001E-5	-1.8169999999999999	-6.0177999999999999E-5
-0.59399999999999997	-2.9981E-5	-1.819	-6.0241000000000001E-5
-0.59499999999999997	-2.9828999999999999E-5	-1.821	-6.0241000000000001E-5
-0.59599999999999997	-3.0008000000000001E-5	-1.823	-6.0272999999999997E-5
-0.59699999999999998	-3.0088999999999999E-5	-1.825	-6.0272999999999997E-5
-0.59799999999999998	-3.008E-5	-1.827	-6.0304999999999999E-5
-0.59899999999999998	-3.0114999999999999E-5	-1.829	-6.0368000000000002E-5
-0.6	-3.0142E-5	-1.831	-6.0399999999999998E-5
-0.60099999999999998	-3.0159999999999999E-5	-1.833	-6.0368000000000002E-5
-0.60199999999999998	-3.0205E-5	-1.835	-6.0430999999999998E-5
-0.60299999999999998	-3.0222999999999998E-5	-1.837	-6.0368000000000002E-5
-0.60399999999999998	-3.0213999999999999E-5	-1.839	-6.0399999999999998E-5
-0.60499999999999998	-3.025E-5	-1.841	-6.0430999999999998E-5
-0.60599999999999998	-3.0329999999999999E-5	-1.843	-6.0430999999999998E-5
-0.60699999999999998	-3.0312E-5	-1.845	-6.0526000000000003E-5
-0.60799999999999998	-3.0258000000000001E-5	-1.847	-6.0430999999999998E-5
-0.60899999999999999	-3.0392999999999999E-5	-1.849	-6.0588999999999999E-5
-0.61	-3.0446E-5	-1.851	-6.0526000000000003E-5
-0.61099999999999999	-3.0402000000000001E-5	-1.853	-6.0463E-5
-0.61199999999999999	-3.0473000000000001E-5	-1.855	-6.0526000000000003E-5
-0.61299999999999999	-3.0527000000000001E-5	-1.857	-6.0494000000000001E-5
-0.61399999999999999	-3.0527000000000001E-5	-1.859	-6.0526000000000003E-5
-0.61499999999999999	-3.0598000000000001E-5	-1.861	-6.0463E-5
-0.61599999999999999	-3.0633999999999998E-5	-1.863	-6.0463E-5
-0.61699999999999999	-3.0580000000000002E-5	-1.865	-6.0399999999999998E-5
-0.61799999999999999	-3.0580000000000002E-5	-1.867	-6.0463E-5
-0.61899999999999999	-3.0679000000000002E-5	-1.869	-6.0494000000000001E-5
-0.62	-3.0741000000000003E-5	-1.871	-6.0430999999999998E-5
-0.621	-3.0929000000000002E-5	-1.873	-6.0463E-5
-0.622	-3.0821999999999997E-5	-1.875	-6.0368000000000002E-5
-0.623	-3.0849000000000002E-5	-1.877	-6.0399999999999998E-5
-0.624	-3.0777E-5	-1.879	-6.0399999999999998E-5
-0.625	-3.0840000000000003E-5	-1.881	-6.0463E-5
-0.626	-3.0876000000000001E-5	-1.883	-6.0399999999999998E-5
-0.627	-3.0830999999999997E-5	-1.885	-6.0430999999999998E-5
-0.628	-3.0920000000000002E-5	-1.887	-6.0430999999999998E-5
-0.629	-3.1010000000000003E-5	-1.889	-6.0494000000000001E-5
-0.63	-3.0991999999999997E-5	-1.891	-6.0463E-5
-0.63100000000000001	-3.1000999999999997E-5	-1.893	-6.0494000000000001E-5
-0.63200000000000001	-3.0991999999999997E-5	-1.895	-6.0526000000000003E-5
-0.63300000000000001	-3.0982999999999998E-5	-1.897	-6.0463E-5
-0.63400000000000001	-3.0973999999999999E-5	-1.899	-6.0557999999999999E-5
-0.63500000000000001	-3.1134999999999999E-5	-1.901	-6.0557999999999999E-5
-0.63600000000000001	-3.1126E-5	-1.903	-6.0557999999999999E-5
-0.63700000000000001	-3.1126E-5	-1.905	-6.0588999999999999E-5
-0.63800000000000001	-3.1170999999999997E-5	-1.907	-6.0621000000000001E-5
-0.63900000000000001	-3.1223999999999998E-5	-1.909	-6.0652000000000001E-5
-0.64	-3.1170999999999997E-5	-1.911	-6.0621000000000001E-5
-0.64100000000000001	-3.1223999999999998E-5	-1.913	-6.0652000000000001E-5
-0.64200000000000002	-3.1313999999999999E-5	-1.915	-6.0683999999999997E-5
-0.64300000000000002	-3.1304999999999999E-5	-1.917	-6.0715999999999999E-5
-0.64400000000000002	-3.1350000000000003E-5	-1.919	-6.0747E-5
-0.64500000000000002	-3.1448000000000001E-5	-1.921	-6.0779000000000002E-5
-0.64600000000000002	-3.1313999999999999E-5	-1.923	-6.0747E-5
-0.64700000000000002	-3.1331999999999997E-5	-1.925	-6.0810999999999998E-5
-0.64800000000000002	-3.1359000000000002E-5	-1.927	-6.0841999999999998E-5
-0.64900000000000002	-3.1430000000000002E-5	-1.929	-6.0874E-5
-0.65	-3.1448000000000001E-5	-1.931	-6.0937000000000003E-5
-0.65100000000000002	-3.1545999999999999E-5	-1.9330000000000001	-6.0968999999999999E-5
-0.65200000000000002	-3.1572999999999997E-5	-1.9350000000000001	-6.1032000000000001E-5
-0.65300000000000002	-3.1538000000000002E-5	-1.9370000000000001	-6.1063999999999997E-5
-0.65400000000000003	-3.1572999999999997E-5	-1.9390000000000001	-6.1094999999999997E-5
-0.65500000000000003	-3.1636E-5	-1.9410000000000001	-6.1158E-5
-0.65600000000000003	-3.1563999999999998E-5	-1.9430000000000001	-6.1190000000000002E-5
-0.65700000000000003	-3.1662999999999998E-5	-1.9450000000000001	-6.1284999999999993E-5
-0.65800000000000003	-3.1715999999999999E-5	-1.9470000000000001	-6.1316999999999996E-5
-0.65900000000000003	-3.1609000000000002E-5	-1.9490000000000001	-6.1379999999999998E-5
-0.66	-3.1733999999999998E-5	-1.9510000000000001	-6.1538000000000006E-5
-0.66100000000000003	-3.1823999999999999E-5	-1.9530000000000001	-6.1569999999999995E-5
-0.66200000000000003	-3.1770000000000002E-5	-1.9550000000000001	-6.1569999999999995E-5
-0.66300000000000003	-3.1770000000000002E-5	-1.9570000000000001	-6.1663999999999998E-5
-0.66400000000000003	-3.1823999999999999E-5	-1.9590000000000001	-6.1728000000000003E-5
-0.66500000000000004	-3.1850999999999997E-5	-1.9610000000000001	-6.1728000000000003E-5
-0.66600000000000004	-3.1894999999999999E-5	-1.9630000000000001	-6.1759000000000003E-5
-0.66700000000000004	-3.1940000000000003E-5	-1.9650000000000001	-6.1853999999999994E-5
-0.66800000000000004	-3.1940000000000003E-5	-1.9670000000000001	-6.1948999999999999E-5
-0.66900000000000004	-3.1903999999999998E-5	-1.9690000000000001	-6.2044000000000004E-5
-0.67	-3.2020000000000002E-5	-1.9710000000000001	-6.2106999999999993E-5
-0.67100000000000004	-3.2029000000000001E-5	-1.9730000000000001	-6.2234000000000001E-5
-0.67200000000000004	-3.1976E-5	-1.9750000000000001	-6.2297000000000003E-5
-0.67300000000000004	-3.2029000000000001E-5	-1.9770000000000001	-6.2297000000000003E-5
-0.67400000000000004	-3.2064999999999999E-5	-1.9790000000000001	-6.2454999999999997E-5
-0.67500000000000004	-3.2055999999999999E-5	-1.9810000000000001	-6.2550000000000003E-5
-0.67600000000000005	-3.2101000000000003E-5	-1.9830000000000001	-6.2675999999999994E-5
-0.67700000000000005	-3.2172999999999998E-5	-1.9850000000000001	-6.2739999999999999E-5
-0.67800000000000005	-3.2128000000000001E-5	-1.9870000000000001	-6.2834000000000002E-5
-0.67900000000000005	-3.2234999999999999E-5	-1.9890000000000001	-6.2928999999999993E-5
-0.68	-3.2190000000000002E-5	-1.9910000000000001	-6.3056000000000001E-5
-0.68100000000000005	-3.2172999999999998E-5	-1.9930000000000001	-6.3151000000000006E-5
-0.68200000000000005	-3.2234999999999999E-5	-1.9950000000000001	-6.3245999999999997E-5
-0.68300000000000005	-3.2316E-5	-1.9970000000000001	-6.334E-5
-0.68400000000000005	-3.2378000000000001E-5	-1.9990000000000001	-6.3466999999999994E-5
-0.68500000000000005	-3.2261999999999997E-5	-2.0009999999999999	-6.3625000000000002E-5
-0.68600000000000005	-3.2333999999999999E-5	-2.0030000000000001	-6.3751999999999995E-5
-0.68700000000000006	-3.2333999999999999E-5	-2.0049999999999999	-6.3910000000000003E-5
-0.68799999999999994	-3.2325E-5	-2.0070000000000001	-6.4004000000000006E-5
-0.68899999999999995	-3.2422999999999998E-5	-2.0089999999999999	-6.4131E-5
-0.69	-3.2477000000000001E-5	-2.0110000000000001	-6.4257000000000005E-5
-0.69099999999999995	-3.2441000000000003E-5	-2.0129999999999999	-6.4416000000000001E-5
-0.69199999999999995	-3.2468000000000002E-5	-2.0150000000000001	-6.4542000000000006E-5
-0.69299999999999995	-3.2583999999999998E-5	-2.0169999999999999	-6.4732000000000003E-5
-0.69399999999999995	-3.2512000000000003E-5	-2.0190000000000001	-6.4857999999999995E-5
-0.69499999999999995	-3.2530000000000002E-5	-2.0209999999999999	-6.5048000000000005E-5
-0.69599999999999995	-3.2583999999999998E-5	-2.0230000000000001	-6.5174999999999999E-5
-0.69699999999999995	-3.2539000000000001E-5	-2.0249999999999999	-6.5364000000000006E-5
-0.69799999999999995	-3.2530000000000002E-5	-2.0270000000000001	-6.5586000000000005E-5
-0.69899999999999995	-3.2691000000000003E-5	-2.0289999999999999	-6.5711999999999997E-5
-0.7	-3.2682000000000003E-5	-2.0310000000000001	-6.5870000000000005E-5
-0.70099999999999996	-3.2638000000000002E-5	-2.0329999999999999	-6.6092000000000004E-5
-0.70199999999999996	-3.2663999999999998E-5	-2.0350000000000001	-6.6217999999999995E-5
-0.70299999999999996	-3.2753999999999998E-5	-2.0369999999999999	-6.6439000000000005E-5
-0.70399999999999996	-3.2753999999999998E-5	-2.0390000000000001	-6.6661000000000004E-5
-0.70499999999999996	-3.2736E-5	-2.0409999999999999	-6.6851000000000001E-5
-0.70599999999999996	-3.2852000000000003E-5	-2.0430000000000001	-6.7071999999999998E-5
-0.70699999999999996	-3.2833999999999998E-5	-2.0449999999999999	-6.7261999999999994E-5
-0.70799999999999996	-3.2817000000000001E-5	-2.0470000000000002	-6.7483000000000004E-5
-0.70899999999999996	-3.2879000000000001E-5	-2.0489999999999999	-6.7704000000000001E-5
-0.71	-3.2824999999999998E-5	-2.0510000000000002	-6.7957E-5
-0.71099999999999997	-3.2799000000000002E-5	-2.0529999999999999	-6.8274000000000004E-5
-0.71199999999999997	-3.2879000000000001E-5	-2.0550000000000002	-6.8590000000000006E-5
-0.71299999999999997	-3.2906E-5	-2.0569999999999999	-6.8684999999999997E-5
-0.71399999999999997	-3.2923999999999999E-5	-2.0590000000000002	-6.8937999999999996E-5
-0.71499999999999997	-3.2978000000000002E-5	-2.0609999999999999	-6.9190999999999995E-5
-0.71599999999999997	-3.3049000000000002E-5	-2.0630000000000002	-6.9412000000000006E-5
-0.71699999999999997	-3.3040000000000002E-5	-2.0649999999999999	-6.9696999999999994E-5
-0.71799999999999997	-3.3031000000000003E-5	-2.0670000000000002	-6.9950000000000006E-5
-0.71899999999999997	-3.3058000000000001E-5	-2.069	-7.0234000000000006E-5
-0.72	-3.3102999999999998E-5	-2.0710000000000002	-7.0518999999999993E-5
-0.72099999999999997	-3.3111999999999997E-5	-2.073	-7.0866999999999998E-5
-0.72199999999999998	-3.3147E-5	-2.0750000000000002	-7.1150999999999997E-5
-0.72299999999999998	-3.3317E-5	-2.077	-7.1435999999999998E-5
-0.72399999999999998	-3.3343999999999998E-5	-2.0790000000000002	-7.1784000000000003E-5
-0.72499999999999998	-3.3300000000000003E-5	-2.081	-7.2068000000000002E-5
-0.72599999999999998	-3.3246E-5	-2.0830000000000002	-7.2353000000000003E-5
-0.72699999999999998	-3.3317E-5	-2.085	-7.2731999999999994E-5
-0.72799999999999998	-3.3308E-5	-2.0870000000000002	-7.3112000000000001E-5
-0.72899999999999998	-3.3325999999999999E-5	-2.089	-7.3460000000000005E-5
-0.73	-3.3325999999999999E-5	-2.0910000000000002	-7.3870999999999998E-5
-0.73099999999999998	-3.3352999999999997E-5	-2.093	-7.4187E-5
-0.73199999999999998	-3.3343999999999998E-5	-2.0950000000000002	-7.4598000000000006E-5
-0.73299999999999998	-3.3352999999999997E-5	-2.097	-7.5072000000000002E-5
-0.73399999999999999	-3.3361999999999997E-5	-2.0990000000000002	-7.5420000000000006E-5
-0.73499999999999999	-3.3407E-5	-2.101	-7.5831E-5
-0.73599999999999999	-3.3281999999999997E-5	-2.1030000000000002	-7.6305999999999998E-5
-0.73699999999999999	-3.3416E-5	-2.105	-7.6748000000000004E-5
-0.73799999999999999	-3.3451999999999998E-5	-2.1070000000000002	-7.7191E-5
-0.73899999999999999	-3.3407E-5	-2.109	-7.7665999999999998E-5
-0.74	-3.3504999999999999E-5	-2.1110000000000002	-7.8171999999999996E-5
-0.74099999999999999	-3.3612999999999998E-5	-2.113	-7.8677000000000006E-5
-0.74199999999999999	-3.3522999999999997E-5	-2.1150000000000002	-7.9183000000000004E-5
-0.74299999999999999	-3.3568000000000001E-5	-2.117	-7.9658000000000002E-5
-0.74399999999999999	-3.3522999999999997E-5	-2.1190000000000002	-8.0259000000000005E-5
-0.745	-3.3586E-5	-2.121	-8.0796000000000004E-5
-0.746	-3.3612999999999998E-5	-2.1230000000000002	-8.1365000000000004E-5
-0.747	-3.3683999999999998E-5	-2.125	-8.1903000000000005E-5
-0.748	-3.3630000000000002E-5	-2.1269999999999998	-8.2534999999999995E-5
-0.749	-3.3531999999999997E-5	-2.129	-8.3072999999999996E-5
-0.75	-3.3612999999999998E-5	-2.1309999999999998	-8.3673999999999999E-5
-0.751	-3.3674999999999999E-5	-2.133	-8.4275000000000002E-5
-0.752	-3.3701999999999997E-5	-2.1349999999999998	-8.4907000000000005E-5
-0.753	-3.3729000000000002E-5	-2.137	-8.5507999999999995E-5
-0.754	-3.3756E-5	-2.1389999999999998	-8.6172000000000001E-5
-0.755	-3.3764999999999999E-5	-2.141	-8.6773000000000004E-5
-0.75600000000000001	-3.3747000000000001E-5	-2.1429999999999998	-8.7342000000000005E-5
-0.75700000000000001	-3.3800000000000002E-5	-2.145	-8.8005999999999997E-5
-0.75800000000000001	-3.3844999999999999E-5	-2.1469999999999998	-8.8670000000000003E-5
-0.75900000000000001	-3.3844999999999999E-5	-2.149	-8.9271000000000006E-5
-0.76	-3.3961000000000002E-5	-2.1509999999999998	-8.9903999999999998E-5
-0.76100000000000001	-3.3890000000000002E-5	-2.153	-9.0472999999999999E-5
-0.76200000000000001	-3.3862999999999997E-5	-2.1549999999999998	-9.1199999999999994E-5
-0.76300000000000001	-3.3917000000000001E-5	-2.157	-9.1896000000000002E-5
-0.76400000000000001	-3.3899000000000002E-5	-2.1589999999999998	-9.2369999999999998E-5
-0.76500000000000001	-3.3862999999999997E-5	-2.161	-9.3003000000000004E-5
-0.76600000000000001	-3.3979000000000001E-5	-2.1629999999999998	-9.3603000000000005E-5
-0.76700000000000002	-3.4014999999999999E-5	-2.165	-9.4172999999999994E-5
-0.76800000000000002	-3.4005999999999999E-5	-2.1669999999999998	-9.4710000000000006E-5
-0.76900000000000002	-3.4096E-5	-2.169	-8.9586999999999995E-5
-0.77	-3.4041999999999997E-5	-2.1669999999999998	-7.6401000000000003E-5
-0.77100000000000002	-3.4060000000000003E-5	-2.165	-6.9633000000000002E-5
-0.77200000000000002	-3.4041999999999997E-5	-2.1629999999999998	-6.5427999999999998E-5
-0.77300000000000002	-3.4060000000000003E-5	-2.161	-6.2076000000000007E-5
-0.77400000000000002	-3.4122000000000003E-5	-2.1589999999999998	-5.9261000000000001E-5
-0.77500000000000002	-3.4239000000000002E-5	-2.157	-5.6668E-5
-0.77600000000000002	-3.4239000000000002E-5	-2.1549999999999998	-5.4296000000000003E-5
-0.77700000000000002	-3.4140000000000002E-5	-2.153	-5.2240999999999997E-5
-0.77800000000000002	-3.4087000000000001E-5	-2.1509999999999998	-5.0216999999999997E-5
-0.77900000000000003	-3.4221000000000003E-5	-2.149	-4.8319999999999998E-5
-0.78	-3.4221000000000003E-5	-2.1469999999999998	-4.6548999999999998E-5
-0.78100000000000003	-3.4221000000000003E-5	-2.145	-4.4873000000000002E-5
-0.78200000000000003	-3.4282999999999997E-5	-2.1429999999999998	-4.3322999999999998E-5
-0.78300000000000003	-3.4266E-5	-2.141	-4.1804999999999997E-5
-0.78400000000000003	-3.4221000000000003E-5	-2.1389999999999998	-4.0318999999999998E-5
-0.78500000000000003	-3.4301000000000002E-5	-2.137	-3.8958999999999997E-5
-0.78600000000000003	-3.4310000000000002E-5	-2.1349999999999998	-3.7663000000000002E-5
-0.78700000000000003	-3.4230000000000003E-5	-2.133	-3.6397999999999999E-5
-0.78800000000000003	-3.4230000000000003E-5	-2.1309999999999998	-3.5165E-5
-0.78900000000000003	-3.4363999999999998E-5	-2.129	-3.4026000000000003E-5
-0.79	-3.4354999999999999E-5	-2.1269999999999998	-3.2919000000000001E-5
-0.79100000000000004	-3.4363999999999998E-5	-2.125	-3.1875999999999998E-5
-0.79200000000000004	-3.4443999999999998E-5	-2.1230000000000002	-3.0825999999999999E-5
-0.79300000000000004	-3.4427000000000001E-5	-2.121	-2.9887E-5
-0.79400000000000004	-3.4400000000000003E-5	-2.1190000000000002	-2.8943999999999999E-5
-0.79500000000000004	-3.4427000000000001E-5	-2.117	-2.8053000000000001E-5
-0.79600000000000004	-3.4434999999999998E-5	-2.1150000000000002	-2.7166999999999999E-5
-0.79700000000000004	-3.4524999999999999E-5	-2.113	-2.6367E-5
-0.79800000000000004	-3.4489000000000001E-5	-2.1110000000000002	-2.5525999999999999E-5
-0.79900000000000004	-3.4507E-5	-2.109	-2.4783E-5
-0.8	-3.4391000000000003E-5	-2.1070000000000002	-2.4020999999999999E-5
-0.80100000000000005	-3.4471000000000003E-5	-2.105	-2.3346999999999999E-5
-0.80200000000000005	-3.4551999999999997E-5	-2.1030000000000002	-2.2642000000000001E-5
-0.80300000000000005	-3.4489000000000001E-5	-2.101	-2.2008999999999999E-5
-0.80400000000000005	-3.4570000000000003E-5	-2.0990000000000002	-2.1342E-5
-0.80500000000000005	-3.4570000000000003E-5	-2.097	-2.0769999999999999E-5
-0.80600000000000005	-3.4586999999999999E-5	-2.0950000000000002	-2.0177999999999999E-5
-0.80700000000000005	-3.4677E-5	-2.093	-1.9624999999999999E-5
-0.80800000000000005	-3.4668000000000001E-5	-2.0910000000000002	-1.9097E-5
-0.80900000000000005	-3.4604999999999998E-5	-2.089	-1.8593999999999998E-5
-0.81	-3.4604999999999998E-5	-2.0870000000000002	-1.8050000000000002E-5
-0.81100000000000005	-3.4694999999999999E-5	-2.085	-1.7560000000000001E-5
-0.81200000000000006	-3.4694999999999999E-5	-2.0830000000000002	-1.7139999999999999E-5
-0.81299999999999994	-3.4659000000000001E-5	-2.081	-1.6648999999999999E-5
-0.81399999999999995	-3.4730999999999997E-5	-2.0790000000000002	-1.626E-5
-0.81499999999999995	-3.4756999999999999E-5	-2.077	-1.5824E-5
-0.81599999999999995	-3.4740000000000003E-5	-2.0750000000000002	-1.5441E-5
-0.81699999999999995	-3.4756999999999999E-5	-2.073	-1.4980000000000001E-5
-0.81799999999999995	-3.4792999999999997E-5	-2.0710000000000002	-1.466E-5
-0.81899999999999995	-3.4802000000000003E-5	-2.069	-1.4265E-5
-0.82	-3.4730999999999997E-5	-2.0670000000000002	-1.3913999999999999E-5
-0.82099999999999995	-3.4847E-5	-2.0649999999999999	-1.3569E-5
-0.82199999999999995	-3.4802000000000003E-5	-2.0630000000000002	-1.3247E-5
-0.82299999999999995	-3.4811000000000003E-5	-2.0609999999999999	-1.2874000000000001E-5
-0.82399999999999995	-3.4847E-5	-2.0590000000000002	-1.2554E-5
-0.82499999999999996	-3.4953999999999998E-5	-2.0569999999999999	-1.2301E-5
-0.82599999999999996	-3.5070000000000001E-5	-2.0550000000000002	-1.1946999999999999E-5
-0.82699999999999996	-3.5008000000000001E-5	-2.0529999999999999	-1.1583000000000001E-5
-0.82799999999999996	-3.4962999999999997E-5	-2.0510000000000002	-1.1365E-5
-0.82899999999999996	-3.4900999999999997E-5	-2.0489999999999999	-1.1114999999999999E-5
-0.83	-3.4918E-5	-2.0470000000000002	-1.0885E-5
-0.83099999999999996	-3.4944999999999998E-5	-2.0449999999999999	-1.0613E-5
-0.83199999999999996	-3.4990000000000002E-5	-2.0430000000000001	-1.0302999999999999E-5
-0.83299999999999996	-3.4962999999999997E-5	-2.0409999999999999	-1.0151E-5
-0.83399999999999996	-3.4972000000000003E-5	-2.0390000000000001	-9.8694999999999993E-6
-0.83499999999999996	-3.5017E-5	-2.0369999999999999	-9.6576000000000005E-6
-0.83599999999999997	-3.4972000000000003E-5	-2.0350000000000001	-9.4457E-6
-0.83699999999999997	-3.5017E-5	-2.0329999999999999	-9.1642999999999997E-6
-0.83799999999999997	-3.4935999999999999E-5	-2.0310000000000001	-9.0282999999999996E-6
-0.83899999999999997	-3.5008000000000001E-5	-2.0289999999999999	-8.7531999999999995E-6
-0.84	-3.5097E-5	-2.0270000000000001	-8.5698000000000005E-6
-0.84099999999999997	-3.5061999999999997E-5	-2.0249999999999999	-8.3958000000000002E-6
-0.84199999999999997	-3.4990000000000002E-5	-2.0230000000000001	-8.1618000000000004E-6
-0.84299999999999997	-3.5017E-5	-2.0209999999999999	-7.9626000000000006E-6
-0.84399999999999997	-3.5088E-5	-2.0190000000000001	-7.7759999999999997E-6
-0.84499999999999997	-3.5097E-5	-2.0169999999999999	-7.6052999999999998E-6
-0.84599999999999997	-3.5123999999999998E-5	-2.0150000000000001	-7.4471999999999996E-6
-0.84699999999999998	-3.5132999999999997E-5	-2.0129999999999999	-7.2510999999999999E-6
-0.84799999999999998	-3.5114999999999998E-5	-2.0110000000000001	-7.0423999999999997E-6
-0.84899999999999998	-3.5187E-5	-2.0089999999999999	-6.9444E-6
-0.85	-3.5196E-5	-2.0070000000000001	-6.7325000000000003E-6
-0.85099999999999998	-3.5026E-5	-2.0049999999999999	-6.5363999999999998E-6
-0.85199999999999998	-3.5079000000000001E-5	-2.0030000000000001	-6.3656999999999999E-6
-0.85299999999999998	-3.5196E-5	-2.0009999999999999	-6.1981E-6
-0.85399999999999998	-3.5178000000000001E-5	-1.9990000000000001	-6.1094999999999997E-6
-0.85499999999999998	-3.5187E-5	-1.9970000000000001	-5.9008000000000003E-6
-0.85599999999999998	-3.5204999999999999E-5	-1.9950000000000001	-5.7521999999999997E-6
-0.85699999999999998	-3.5196E-5	-1.9930000000000001	-5.6667999999999997E-6
-0.85799999999999998	-3.5249000000000001E-5	-1.9910000000000001	-5.5055000000000001E-6
-0.85899999999999999	-3.5222999999999998E-5	-1.9890000000000001	-5.4106999999999997E-6
-0.86	-3.5267E-5	-1.9870000000000001	-5.2367000000000002E-6
-0.86099999999999999	-3.5231000000000002E-5	-1.9850000000000001	-5.0564999999999998E-6
-0.86199999999999999	-3.5330000000000002E-5	-1.9830000000000001	-4.9173000000000003E-6
-0.86299999999999999	-3.5302999999999997E-5	-1.9810000000000001	-4.7940000000000002E-6
-0.86399999999999999	-3.5178000000000001E-5	-1.9790000000000001	-4.6897000000000002E-6
-0.86499999999999999	-3.5249000000000001E-5	-1.9770000000000001	-4.5853E-6
-0.86599999999999999	-3.5284999999999998E-5	-1.9750000000000001	-4.4209000000000003E-6
-0.86699999999999999	-3.5284999999999998E-5	-1.9730000000000001	-4.3323E-6
-0.86799999999999999	-3.5366E-5	-1.9710000000000001	-4.1710000000000004E-6
-0.86899999999999999	-3.5401000000000002E-5	-1.9690000000000001	-4.0446000000000002E-6
-0.87	-3.5321000000000003E-5	-1.9670000000000001	-3.9496999999999996E-6
-0.871	-3.5348000000000001E-5	-1.9650000000000001	-3.7946999999999999E-6
-0.872	-3.5374999999999999E-5	-1.9630000000000001	-3.6998999999999999E-6
-0.873	-3.5348000000000001E-5	-1.9610000000000001	-3.6144999999999999E-6
-0.874	-3.5321000000000003E-5	-1.9590000000000001	-3.4912000000000001E-6
-0.875	-3.5383999999999999E-5	-1.9570000000000001	-3.3361999999999999E-6
-0.876	-3.5383999999999999E-5	-1.9550000000000001	-3.2698E-6
-0.877	-3.5419000000000001E-5	-1.9530000000000001	-3.1281000000000002E-6
-0.878	-3.5419000000000001E-5	-1.9510000000000001	-2.9063999999999998E-6
-0.879	-3.5401000000000002E-5	-1.9490000000000001	-2.8698E-6
-0.88	-3.5383999999999999E-5	-1.9470000000000001	-2.8327999999999998E-6
-0.88100000000000001	-3.5428E-5	-1.9450000000000001	-2.7103999999999999E-6
-0.88200000000000001	-3.5500000000000002E-5	-1.9430000000000001	-2.6209000000000002E-6
-0.88300000000000001	-3.5472999999999997E-5	-1.9410000000000001	-2.5345999999999998E-6
-0.88400000000000001	-3.5437E-5	-1.9390000000000001	-2.4331E-6
-0.88500000000000001	-3.5481999999999997E-5	-1.9370000000000001	-2.2933000000000001E-6
-0.88600000000000001	-3.5481999999999997E-5	-1.9350000000000001	-2.2666999999999998E-6
-0.88700000000000001	-3.5491000000000003E-5	-1.9330000000000001	-2.1096000000000001E-6
-0.88800000000000001	-3.5500000000000002E-5	-1.931	-2.0011000000000002E-6
-0.88900000000000001	-3.5410000000000001E-5	-1.929	-1.9251999999999998E-6
-0.89	-3.5428E-5	-1.927	-1.8604E-6
-0.89100000000000001	-3.5481999999999997E-5	-1.925	-1.7794000000000001E-6
-0.89200000000000002	-3.5536E-5	-1.923	-1.6751000000000001E-6
-0.89300000000000002	-3.5463999999999998E-5	-1.921	-1.59E-6
-0.89400000000000002	-3.5500000000000002E-5	-1.919	-1.4939E-6
-0.89500000000000002	-3.5527000000000001E-5	-1.917	-1.361E-6
-0.89600000000000002	-3.5509000000000002E-5	-1.915	-1.2858E-6
-0.89700000000000002	-3.5553000000000003E-5	-1.913	-1.2281999999999999E-6
-0.89800000000000002	-3.5553000000000003E-5	-1.911	-1.1305E-6
-0.89900000000000002	-3.5509000000000002E-5	-1.909	-1.0476999999999999E-6
-0.9	-3.5598E-5	-1.907	-9.5089999999999997E-7
-0.90100000000000002	-3.5553000000000003E-5	-1.905	-8.5445000000000003E-7
-0.90200000000000002	-3.5500000000000002E-5	-1.903	-7.7443999999999999E-7
-0.90300000000000002	-3.5491000000000003E-5	-1.901	-6.9632999999999999E-7
-0.90400000000000003	-3.5562000000000003E-5	-1.899	-5.9134999999999996E-7
-0.90500000000000003	-3.5589000000000001E-5	-1.897	-5.5940999999999995E-7
-0.90600000000000003	-3.5607E-5	-1.895	-4.3132999999999999E-7
-0.90700000000000003	-3.5615999999999999E-5	-1.893	-3.5291E-7
-0.90800000000000003	-3.5679000000000002E-5	-1.891	-2.7332000000000001E-7
-0.90900000000000003	-3.5661000000000003E-5	-1.889	-1.5653000000000001E-7
-0.91	-3.5642999999999997E-5	-1.887	-1.5963000000000001E-7
-0.91100000000000003	-3.5642999999999997E-5	-1.885	-6.7893999999999999E-8
-0.91200000000000003	-3.5624999999999999E-5	-1.883	2.7552999999999999E-8
-0.91300000000000003	-3.5679000000000002E-5	-1.881	1.6035999999999999E-7
-0.91400000000000003	-3.5741000000000002E-5	-1.879	2.515E-7
-0.91500000000000004	-3.5553000000000003E-5	-1.877	2.5829000000000002E-7
-0.91600000000000004	-3.5598E-5	-1.875	3.5165E-7
-0.91700000000000004	-3.5688000000000001E-5	-1.873	4.6138000000000002E-7
-0.91800000000000004	-3.5688000000000001E-5	-1.871	5.1544999999999997E-7
-0.91900000000000004	-3.5651999999999997E-5	-1.869	6.0874000000000004E-7
-0.92	-3.5759000000000001E-5	-1.867	7.2004999999999999E-7
-0.92100000000000004	-3.5713999999999997E-5	-1.865	7.7191000000000003E-7
-0.92200000000000004	-3.5713999999999997E-5	-1.863	8.6077E-7
-0.92300000000000004	-3.5697000000000001E-5	-1.861	8.7753000000000005E-7
-0.92400000000000004	-3.5768E-5	-1.859	1.0056E-6
-0.92500000000000004	-3.5759000000000001E-5	-1.857	1.0925999999999999E-6
-0.92600000000000005	-3.5713999999999997E-5	-1.855	1.1908999999999999E-6
-0.92700000000000005	-3.5777E-5	-1.853	1.2469000000000001E-6
-0.92800000000000005	-3.5982999999999998E-5	-1.851	1.3458999999999999E-6
-0.92900000000000005	-3.5955999999999999E-5	-1.849	1.5565E-6
-0.93	-3.5867000000000001E-5	-1.847	1.5935000000000001E-6
-0.93100000000000005	-3.5803999999999998E-5	-1.845	1.6102000000000001E-6
-0.93200000000000005	-3.5794999999999999E-5	-1.843	1.6921000000000001E-6
-0.93300000000000005	-3.5849000000000002E-5	-1.841	1.7885999999999999E-6
-0.93400000000000005	-3.5840000000000002E-5	-1.839	1.8079000000000001E-6
-0.93500000000000005	-3.5867000000000001E-5	-1.837	1.9570999999999999E-6
-0.93600000000000005	-3.5867000000000001E-5	-1.835	2.0358999999999999E-6
-0.93700000000000006	-3.5821999999999997E-5	-1.833	2.1038999999999999E-6
-0.93799999999999994	-3.5777E-5	-1.831	2.1967999999999999E-6
-0.93899999999999995	-3.5785999999999999E-5	-1.829	2.3141999999999998E-6
-0.94	-3.5849000000000002E-5	-1.827	2.4165999999999999E-6
-0.94099999999999995	-3.5803999999999998E-5	-1.825	2.4435E-6
-0.94199999999999995	-3.5902000000000003E-5	-1.823	2.5415000000000001E-6
-0.94299999999999995	-3.5883999999999997E-5	-1.821	2.6743E-6
-0.94399999999999995	-3.5741000000000002E-5	-1.819	2.7711E-6
-0.94499999999999995	-3.5812999999999997E-5	-1.8169999999999999	2.8745000000000002E-6
-0.94599999999999995	-3.5911000000000002E-5	-1.8149999999999999	2.9724999999999999E-6
-0.94699999999999995	-3.5858000000000001E-5	-1.8129999999999999	3.0968000000000001E-6
-0.94799999999999995	-3.5883999999999997E-5	-1.8109999999999999	3.1480000000000002E-6
-0.94899999999999995	-3.5938E-5	-1.8089999999999999	3.2760999999999999E-6
-0.95	-3.5902000000000003E-5	-1.8069999999999999	3.3836000000000001E-6
-0.95099999999999996	-3.5867000000000001E-5	-1.8049999999999999	3.5196000000000001E-6
-0.95199999999999996	-3.5892999999999997E-5	-1.8029999999999999	3.6239999999999999E-6
-0.95299999999999996	-3.5902000000000003E-5	-1.8009999999999999	3.7662999999999998E-6
-0.95399999999999996	-3.5858000000000001E-5	-1.7989999999999999	3.8264000000000003E-6
-0.95499999999999996	-3.5911000000000002E-5	-1.7969999999999999	3.8232000000000001E-6
-0.95599999999999996	-3.5955999999999999E-5	-1.7949999999999999	4.0129000000000002E-6
-0.95699999999999996	-3.5883999999999997E-5	-1.7929999999999999	4.1679000000000004E-6
-0.95799999999999996	-3.5911000000000002E-5	-1.7909999999999999	4.3323E-6
-0.95899999999999996	-3.5973999999999998E-5	-1.7889999999999999	4.4144999999999998E-6
-0.96	-3.5973999999999998E-5	-1.7869999999999999	4.5347E-6
-0.96099999999999997	-3.5982999999999998E-5	-1.7849999999999999	4.7180999999999998E-6
-0.96199999999999997	-3.6044999999999998E-5	-1.7829999999999999	4.7972000000000004E-6
-0.96299999999999997	-3.5938E-5	-1.7809999999999999	4.9585E-6
-0.96399999999999997	-3.5947E-5	-1.7789999999999999	5.0849000000000002E-6
-0.96499999999999997	-3.5964999999999999E-5	-1.7769999999999999	5.2082999999999998E-6
-0.96599999999999997	-3.5955999999999999E-5	-1.7749999999999999	5.3506000000000001E-6
-0.96699999999999997	-3.5911000000000002E-5	-1.7729999999999999	5.4518E-6
-0.96799999999999997	-3.5973999999999998E-5	-1.7709999999999999	5.6067E-6
-0.96899999999999997	-3.5964999999999999E-5	-1.7689999999999999	5.7490000000000004E-6
-0.97	-3.6001000000000003E-5	-1.7669999999999999	5.8881999999999998E-6
-0.97099999999999997	-3.6125999999999999E-5	-1.7649999999999999	5.9988000000000001E-6
-0.97199999999999998	-3.6134999999999999E-5	-1.7629999999999999	6.1475E-6
-0.97299999999999998	-3.5973999999999998E-5	-1.7609999999999999	6.3056000000000002E-6
-0.97399999999999998	-3.6081000000000002E-5	-1.7589999999999999	6.4478999999999997E-6
-0.97499999999999998	-3.6152999999999998E-5	-1.7569999999999999	6.5459000000000003E-6
-0.97599999999999998	-3.6035999999999999E-5	-1.7549999999999999	6.6439E-6
-0.97699999999999998	-3.6072000000000003E-5	-1.7529999999999999	6.8368000000000003E-6
-0.97799999999999998	-3.6143999999999998E-5	-1.7509999999999999	6.9949999999999999E-6
-0.97899999999999998	-3.6180000000000003E-5	-1.7490000000000001	7.0898000000000003E-6
-0.98	-3.6125999999999999E-5	-1.7470000000000001	7.3174999999999998E-6
-0.98099999999999998	-3.6099000000000001E-5	-1.7450000000000001	7.4219E-6
-0.98199999999999998	-3.6090000000000002E-5	-1.7430000000000001	7.4692999999999998E-6
-0.98299999999999998	-3.6099000000000001E-5	-1.7410000000000001	7.6210999999999998E-6
-0.98399999999999999	-3.6196999999999999E-5	-1.7390000000000001	7.7254000000000006E-6
-0.98499999999999999	-3.6205999999999999E-5	-1.7370000000000001	7.8107999999999998E-6
-0.98599999999999999	-3.6196999999999999E-5	-1.7350000000000001	7.9278000000000006E-6
-0.98699999999999999	-3.6125999999999999E-5	-1.7330000000000001	8.0068999999999995E-6
-0.98799999999999999	-3.6143999999999998E-5	-1.7310000000000001	8.1207E-6
-0.98899999999999999	-3.6081000000000002E-5	-1.7290000000000001	8.2440999999999996E-6
-0.99	-3.6180000000000003E-5	-1.7270000000000001	8.3579000000000001E-6
-0.99099999999999999	-3.6214999999999998E-5	-1.7250000000000001	8.4463999999999993E-6
-0.99199999999999999	-3.6053999999999997E-5	-1.7230000000000001	8.5413000000000007E-6
-0.99299999999999999	-3.6161999999999997E-5	-1.7210000000000001	8.5886999999999996E-6
-0.99399999999999999	-3.6269000000000001E-5	-1.7190000000000001	8.6867999999999996E-6
-0.995	-3.6161999999999997E-5	-1.7170000000000001	8.7405000000000004E-6
-0.996	-3.6205999999999999E-5	-1.7150000000000001	8.8195999999999994E-6
-0.997	-3.6223999999999997E-5	-1.7130000000000001	8.9302999999999999E-6
-0.998	-3.6189000000000002E-5	-1.7110000000000001	8.9650999999999999E-6
-0.999	-3.6232999999999997E-5	-1.7090000000000001	8.9966999999999998E-6
-1	-3.6242000000000003E-5	-1.7070000000000001	9.0757000000000002E-6
-1.0009999999999999	-3.6196999999999999E-5	-1.7050000000000001	9.1262999999999993E-6
-1.002	-3.6260000000000002E-5	-1.7030000000000001	9.2149000000000005E-6
-1.0029999999999999	-3.6287E-5	-1.7010000000000001	9.2402000000000001E-6
-1.004	-3.6242000000000003E-5	-1.6990000000000001	9.2938999999999992E-6
-1.0049999999999999	-3.6180000000000003E-5	-1.6970000000000001	9.3349999999999996E-6
-1.006	-3.6269000000000001E-5	-1.6950000000000001	9.3888000000000006E-6
-1.0069999999999999	-3.6304999999999999E-5	-1.6930000000000001	9.4298999999999993E-6
-1.008	-3.6242000000000003E-5	-1.6910000000000001	9.4772999999999999E-6
-1.0089999999999999	-3.6251000000000002E-5	-1.6890000000000001	9.4868000000000004E-6
-1.01	-3.6304999999999999E-5	-1.6870000000000001	9.5596000000000008E-6
-1.0109999999999999	-3.6304999999999999E-5	-1.6850000000000001	9.5501000000000003E-6
-1.012	-3.6350000000000003E-5	-1.6830000000000001	9.5912000000000006E-6
-1.0129999999999999	-3.6421000000000002E-5	-1.681	9.6448999999999998E-6
-1.014	-3.6313999999999998E-5	-1.679	9.6385999999999995E-6
-1.0149999999999999	-3.6313999999999998E-5	-1.677	9.7272000000000007E-6
-1.016	-3.6412000000000003E-5	-1.675	9.7620000000000007E-6
-1.0169999999999999	-3.6322999999999998E-5	-1.673	9.7777999999999998E-6
-1.018	-3.6322999999999998E-5	-1.671	9.8284000000000006E-6
-1.0189999999999999	-3.6384999999999998E-5	-1.669	9.8061999999999994E-6
-1.02	-3.6393999999999997E-5	-1.667	9.9011000000000008E-6
-1.0209999999999999	-3.6393999999999997E-5	-1.665	9.9549000000000002E-6
-1.022	-3.6412000000000003E-5	-1.663	9.9612000000000004E-6
-1.0229999999999999	-3.6448000000000001E-5	-1.661	9.9896E-6
-1.024	-3.6448000000000001E-5	-1.659	1.0043E-5
-1.0249999999999999	-3.6474999999999999E-5	-1.657	1.0043E-5
-1.026	-3.6421000000000002E-5	-1.655	1.0145E-5
-1.0269999999999999	-3.6384999999999998E-5	-1.653	1.0173000000000001E-5
-1.028	-3.6430000000000002E-5	-1.651	1.0236E-5
-1.0289999999999999	-3.6448000000000001E-5	-1.649	1.0251999999999999E-5
-1.03	-3.6698E-5	-1.647	1.0274E-5
-1.0309999999999999	-3.6724999999999998E-5	-1.645	1.0353000000000001E-5
-1.032	-3.6644999999999999E-5	-1.643	1.0438999999999999E-5
-1.0329999999999999	-3.6563999999999998E-5	-1.641	1.0400999999999999E-5
-1.034	-3.6501999999999997E-5	-1.639	1.0451E-5
-1.0349999999999999	-3.6536999999999999E-5	-1.637	1.0508E-5
-1.036	-3.6536999999999999E-5	-1.635	1.0499000000000001E-5
-1.0369999999999999	-3.6519000000000001E-5	-1.633	1.0581000000000001E-5
-1.038	-3.6572999999999997E-5	-1.631	1.0565E-5
-1.0389999999999999	-3.6582000000000003E-5	-1.629	1.0647E-5
-1.04	-3.6511000000000003E-5	-1.627	1.0665999999999999E-5
-1.0409999999999999	-3.6591000000000003E-5	-1.625	1.0739E-5
-1.042	-3.6733999999999998E-5	-1.623	1.0783E-5
-1.0429999999999999	-3.6545999999999999E-5	-1.621	1.0796E-5
-1.044	-3.6591000000000003E-5	-1.619	1.0798999999999999E-5
-1.0449999999999999	-3.6653999999999998E-5	-1.617	1.0893999999999999E-5
-1.046	-3.6644999999999999E-5	-1.615	1.0937999999999999E-5
-1.0469999999999999	-3.6591000000000003E-5	-1.613	1.1002000000000001E-5
-1.048	-3.6644999999999999E-5	-1.611	1.1017E-5
-1.0489999999999999	-3.6671999999999997E-5	-1.609	1.1036000000000001E-5
-1.05	-3.6698E-5	-1.607	1.1093E-5
-1.0509999999999999	-3.6680000000000001E-5	-1.605	1.1106E-5
-1.052	-3.6698E-5	-1.603	1.1178999999999999E-5
-1.0529999999999999	-3.6636E-5	-1.601	1.1207E-5
-1.054	-3.6733999999999998E-5	-1.599	1.1245E-5
-1.0549999999999999	-3.6779000000000001E-5	-1.597	1.1353E-5
-1.056	-3.6671999999999997E-5	-1.595	1.1358999999999999E-5
-1.0569999999999999	-3.6733999999999998E-5	-1.593	1.1447000000000001E-5
-1.0580000000000001	-3.6752000000000003E-5	-1.591	1.146E-5
-1.0589999999999999	-3.6698E-5	-1.589	1.1463E-5
-1.06	-3.6742999999999997E-5	-1.587	1.1498000000000001E-5
-1.0609999999999999	-3.6876999999999999E-5	-1.585	1.1576999999999999E-5
-1.0620000000000001	-3.6850000000000001E-5	-1.583	1.1612E-5
-1.0629999999999999	-3.6806E-5	-1.581	1.1634000000000001E-5
-1.0640000000000001	-3.6797E-5	-1.579	1.1674999999999999E-5
-1.0649999999999999	-3.6850000000000001E-5	-1.577	1.1738E-5
-1.0660000000000001	-3.6806E-5	-1.575	1.1836E-5
-1.0669999999999999	-3.6922000000000003E-5	-1.573	1.183E-5
-1.0680000000000001	-3.6832999999999998E-5	-1.571	1.1849E-5
-1.069	-3.6797E-5	-1.569	1.1871E-5
-1.07	-3.6912999999999997E-5	-1.5669999999999999	1.1919000000000001E-5
-1.071	-3.6958000000000001E-5	-1.5649999999999999	1.202E-5
-1.0720000000000001	-3.6931000000000003E-5	-1.5629999999999999	1.2055000000000001E-5
-1.073	-3.6949000000000001E-5	-1.5609999999999999	1.2086000000000001E-5
-1.0740000000000001	-3.6967E-5	-1.5589999999999999	1.2140000000000001E-5
-1.075	-3.6958000000000001E-5	-1.5569999999999999	1.2149E-5
-1.0760000000000001	-3.6993999999999999E-5	-1.5549999999999999	1.2191000000000001E-5
-1.077	-3.7055999999999999E-5	-1.5529999999999999	1.2238E-5
-1.0780000000000001	-3.6967E-5	-1.5509999999999999	1.2311E-5
-1.079	-3.7011000000000002E-5	-1.5489999999999999	1.2354999999999999E-5
-1.08	-3.7055999999999999E-5	-1.5469999999999999	1.2444E-5
-1.081	-3.7101000000000003E-5	-1.5449999999999999	1.2437E-5
-1.0820000000000001	-3.7064999999999998E-5	-1.5429999999999999	1.2510000000000001E-5
-1.083	-3.7029000000000001E-5	-1.5409999999999999	1.2639999999999999E-5
-1.0840000000000001	-3.7082999999999997E-5	-1.5389999999999999	1.2632999999999999E-5
-1.085	-3.7101000000000003E-5	-1.5369999999999999	1.269E-5
-1.0860000000000001	-3.7137E-5	-1.5349999999999999	1.269E-5
-1.087	-3.7146E-5	-1.5329999999999999	1.2763E-5
-1.0880000000000001	-3.7128000000000001E-5	-1.5309999999999999	1.2772000000000001E-5
-1.089	-3.7208E-5	-1.5289999999999999	1.2829E-5
-1.0900000000000001	-3.7217E-5	-1.5269999999999999	1.2908000000000001E-5
-1.091	-3.7217E-5	-1.5249999999999999	1.2931E-5
-1.0920000000000001	-3.7280000000000002E-5	-1.5229999999999999	1.2999999999999999E-5
-1.093	-3.7234999999999998E-5	-1.5209999999999999	1.307E-5
-1.0940000000000001	-3.7154999999999999E-5	-1.5189999999999999	1.3098000000000001E-5
-1.095	-3.7199000000000001E-5	-1.5169999999999999	1.3101E-5
-1.0960000000000001	-3.7333000000000003E-5	-1.5149999999999999	1.3161E-5
-1.097	-3.7298000000000001E-5	-1.5129999999999999	1.3263E-5
-1.0980000000000001	-3.7307E-5	-1.5109999999999999	1.332E-5
-1.099	-3.7342000000000003E-5	-1.5089999999999999	1.3407999999999999E-5
-1.1000000000000001	-3.7271000000000003E-5	-1.5069999999999999	1.3402E-5
-1.101	-3.7369000000000001E-5	-1.5049999999999999	1.3492999999999999E-5
-1.1020000000000001	-3.7404999999999998E-5	-1.5029999999999999	1.3506000000000001E-5
-1.103	-3.7450000000000002E-5	-1.5009999999999999	1.3563E-5
-1.1040000000000001	-3.7387E-5	-1.4990000000000001	1.3614E-5
-1.105	-3.7378E-5	-1.4970000000000001	1.3699E-5
-1.1060000000000001	-3.7431999999999997E-5	-1.4950000000000001	1.3828999999999999E-5
-1.107	-3.7342000000000003E-5	-1.4930000000000001	1.3822000000000001E-5
-1.1080000000000001	-3.7475999999999998E-5	-1.4910000000000001	1.3901E-5
-1.109	-3.7512000000000003E-5	-1.4890000000000001	1.3954999999999999E-5
-1.1100000000000001	-3.7431999999999997E-5	-1.4870000000000001	1.4015E-5
-1.111	-3.7484999999999998E-5	-1.4850000000000001	1.4059E-5
-1.1120000000000001	-3.7557E-5	-1.4830000000000001	1.4141999999999999E-5
-1.113	-3.7601999999999997E-5	-1.4810000000000001	1.4188999999999999E-5
-1.1140000000000001	-3.7601999999999997E-5	-1.4790000000000001	1.4275E-5
-1.115	-3.7629000000000002E-5	-1.4770000000000001	1.43E-5
-1.1160000000000001	-3.7557E-5	-1.4750000000000001	1.4363E-5
-1.117	-3.7548E-5	-1.4730000000000001	1.4442E-5
-1.1180000000000001	-3.7663999999999997E-5	-1.4710000000000001	1.4528E-5
-1.119	-3.7691000000000002E-5	-1.4690000000000001	1.4591E-5
-1.1200000000000001	-3.7629000000000002E-5	-1.4670000000000001	1.4651000000000001E-5
-1.121	-3.7636999999999999E-5	-1.4650000000000001	1.4676E-5
-1.1220000000000001	-3.7744999999999999E-5	-1.4630000000000001	1.4773999999999999E-5
-1.123	-3.7735999999999999E-5	-1.4610000000000001	1.4841000000000001E-5
-1.1240000000000001	-3.7798E-5	-1.4590000000000001	1.4871999999999999E-5
-1.125	-3.7790000000000002E-5	-1.4570000000000001	1.5014000000000001E-5
-1.1259999999999999	-3.7815999999999998E-5	-1.4550000000000001	1.5081E-5
-1.127	-3.7879000000000001E-5	-1.4530000000000001	1.5131E-5
-1.1279999999999999	-3.7951000000000003E-5	-1.4510000000000001	1.5192E-5
-1.129	-3.7923999999999998E-5	-1.4490000000000001	1.5299E-5
-1.1299999999999999	-3.7941999999999997E-5	-1.4470000000000001	1.5375000000000001E-5
-1.131	-3.7897E-5	-1.4450000000000001	1.5415999999999999E-5
-1.1319999999999999	-3.8003999999999997E-5	-1.4430000000000001	1.5492E-5
-1.133	-3.8281000000000002E-5	-1.4410000000000001	1.5571000000000001E-5
-1.1339999999999999	-3.8111999999999997E-5	-1.4390000000000001	1.5758000000000001E-5
-1.135	-3.8102999999999998E-5	-1.4370000000000001	1.577E-5
-1.1359999999999999	-3.8003999999999997E-5	-1.4350000000000001	1.5818E-5
-1.137	-3.8022000000000003E-5	-1.4330000000000001	1.5865000000000001E-5
-1.1379999999999999	-3.8146999999999999E-5	-1.431	1.5951E-5
-1.139	-3.8138E-5	-1.429	1.6016999999999999E-5
-1.1399999999999999	-3.8129E-5	-1.427	1.6070999999999999E-5
-1.141	-3.8146999999999999E-5	-1.425	1.615E-5
-1.1419999999999999	-3.8173999999999997E-5	-1.423	1.6248000000000001E-5
-1.143	-3.8210000000000002E-5	-1.421	1.6308E-5
-1.1439999999999999	-3.8325999999999999E-5	-1.419	1.6405999999999998E-5
-1.145	-3.8263999999999998E-5	-1.417	1.6460000000000002E-5
-1.1459999999999999	-3.8146999999999999E-5	-1.415	1.6535999999999999E-5
-1.147	-3.8308E-5	-1.413	1.6592E-5
-1.1479999999999999	-3.8316999999999999E-5	-1.411	1.6629999999999998E-5
-1.149	-3.8299E-5	-1.409	1.677E-5
-1.1499999999999999	-3.8380000000000002E-5	-1.407	1.6855E-5
-1.151	-3.8433999999999998E-5	-1.405	1.6895999999999999E-5
-1.1519999999999999	-3.8433999999999998E-5	-1.403	1.6985000000000001E-5
-1.153	-3.8478E-5	-1.401	1.7031999999999999E-5
-1.1539999999999999	-3.8550000000000002E-5	-1.399	1.7091999999999998E-5
-1.155	-3.8559000000000001E-5	-1.397	1.7193E-5
-1.1559999999999999	-3.8532000000000003E-5	-1.395	1.7294000000000001E-5
-1.157	-3.8559000000000001E-5	-1.393	1.7388999999999999E-5
-1.1579999999999999	-3.8541000000000003E-5	-1.391	1.7418000000000002E-5
-1.159	-3.8577E-5	-1.389	1.7516E-5
-1.1599999999999999	-3.8630000000000001E-5	-1.387	1.7529000000000001E-5
-1.161	-3.8683999999999998E-5	-1.385	1.7668000000000001E-5
-1.1619999999999999	-3.8738000000000001E-5	-1.383	1.7702000000000001E-5
-1.163	-3.8791000000000002E-5	-1.381	1.7788E-5
-1.1639999999999999	-3.8756E-5	-1.379	1.7847999999999999E-5
-1.165	-3.8763999999999997E-5	-1.377	1.7910999999999998E-5
-1.1659999999999999	-3.8853999999999998E-5	-1.375	1.8006E-5
-1.167	-3.8917E-5	-1.373	1.8068999999999999E-5
-1.1679999999999999	-3.8924999999999997E-5	-1.371	1.8136000000000001E-5
-1.169	-3.8996999999999999E-5	-1.369	1.8215000000000001E-5
-1.17	-3.8943000000000003E-5	-1.367	1.8278E-5
-1.171	-3.8961000000000002E-5	-1.365	1.8357000000000001E-5
-1.1719999999999999	-3.8970000000000001E-5	-1.363	1.8389E-5
-1.173	-3.9078000000000001E-5	-1.361	1.8487000000000001E-5
-1.1739999999999999	-3.9094999999999998E-5	-1.359	1.8527999999999999E-5
-1.175	-3.9131000000000002E-5	-1.357	1.8623000000000001E-5
-1.1759999999999999	-3.9212000000000003E-5	-1.355	1.8705000000000001E-5
-1.177	-3.9212000000000003E-5	-1.353	1.8759000000000001E-5
-1.1779999999999999	-3.9239000000000002E-5	-1.351	1.8853000000000001E-5
-1.179	-3.9292000000000003E-5	-1.349	1.8847000000000001E-5
-1.18	-3.9381999999999997E-5	-1.347	1.8958E-5
-1.181	-3.9363999999999998E-5	-1.345	1.9015E-5
-1.1819999999999999	-3.9381999999999997E-5	-1.343	1.9077999999999999E-5
-1.1830000000000001	-3.9443999999999997E-5	-1.341	1.9125000000000001E-5
-1.1839999999999999	-3.9507E-5	-1.339	1.9219999999999999E-5
-1.1850000000000001	-3.9613999999999997E-5	-1.337	1.9412999999999999E-5
-1.1859999999999999	-3.9677E-5	-1.335	1.9445000000000001E-5
-1.1870000000000001	-3.9586999999999999E-5	-1.333	1.9397000000000001E-5
-1.1879999999999999	-3.9641000000000002E-5	-1.331	1.9470000000000002E-5
-1.1890000000000001	-3.9659000000000001E-5	-1.329	1.9548999999999999E-5
-1.19	-3.9739E-5	-1.327	1.9581000000000001E-5
-1.1910000000000001	-3.9774999999999998E-5	-1.325	1.9599999999999999E-5
-1.1919999999999999	-3.9739E-5	-1.323	1.9663000000000001E-5
-1.1930000000000001	-3.9765999999999998E-5	-1.321	1.9758E-5
-1.194	-3.9855999999999999E-5	-1.319	1.9837E-5
-1.1950000000000001	-3.9972000000000003E-5	-1.3169999999999999	1.9910000000000001E-5
-1.196	-3.9953999999999997E-5	-1.3149999999999999	1.9947999999999999E-5
-1.1970000000000001	-3.9926999999999999E-5	-1.3129999999999999	1.9998000000000001E-5
-1.198	-4.0017E-5	-1.3109999999999999	2.0007999999999999E-5
-1.1990000000000001	-4.0114999999999998E-5	-1.3089999999999999	2.0080000000000001E-5
-1.2	-4.0061000000000002E-5	-1.3069999999999999	2.0153000000000002E-5
-1.2010000000000001	-4.0187E-5	-1.3049999999999999	2.0210000000000001E-5
-1.202	-4.0231000000000002E-5	-1.3029999999999999	2.0267000000000001E-5
-1.2030000000000001	-4.0240000000000001E-5	-1.3009999999999999	2.0288999999999998E-5
-1.204	-4.0373999999999997E-5	-1.2989999999999999	2.033E-5
-1.2050000000000001	-4.0373999999999997E-5	-1.2969999999999999	2.0421999999999999E-5
-1.206	-4.0330000000000002E-5	-1.2949999999999999	2.0449999999999999E-5
-1.2070000000000001	-4.0428E-5	-1.2929999999999999	2.0530000000000002E-5
-1.208	-4.0615999999999999E-5	-1.2909999999999999	2.0582999999999999E-5
-1.2090000000000001	-4.0615999999999999E-5	-1.2889999999999999	2.0639999999999999E-5
-1.21	-4.0543999999999997E-5	-1.2869999999999999	2.0707E-5
-1.2110000000000001	-4.0633999999999998E-5	-1.2849999999999999	2.0729000000000001E-5
-1.212	-4.0615999999999999E-5	-1.2829999999999999	2.0767E-5
-1.2130000000000001	-4.0661000000000003E-5	-1.2809999999999999	2.0849E-5
-1.214	-4.0750000000000001E-5	-1.2789999999999999	2.0890000000000002E-5
-1.2150000000000001	-4.0883999999999997E-5	-1.2769999999999999	2.0917999999999999E-5
-1.216	-4.0929000000000001E-5	-1.2749999999999999	2.0975000000000002E-5
-1.2170000000000001	-4.0982999999999997E-5	-1.2729999999999999	2.1013E-5
-1.218	-4.1063000000000003E-5	-1.2709999999999999	2.1047999999999999E-5
-1.2190000000000001	-4.1026999999999999E-5	-1.2689999999999999	2.1080000000000001E-5
-1.22	-4.1152999999999997E-5	-1.2669999999999999	2.1146E-5
-1.2210000000000001	-4.1143999999999998E-5	-1.2649999999999999	2.1219000000000001E-5
-1.222	-4.1179E-5	-1.2629999999999999	2.1237999999999999E-5
-1.2230000000000001	-4.1242000000000003E-5	-1.2609999999999999	2.1279000000000001E-5
-1.224	-4.1340000000000001E-5	-1.2589999999999999	2.1294999999999999E-5
-1.2250000000000001	-4.1393999999999997E-5	-1.2569999999999999	2.1352000000000002E-5
-1.226	-4.1492000000000002E-5	-1.2549999999999999	2.1430999999999999E-5
-1.2270000000000001	-4.1554999999999998E-5	-1.2529999999999999	2.1458999999999999E-5
-1.228	-4.1653000000000003E-5	-1.2509999999999999	2.1515999999999999E-5
-1.2290000000000001	-4.1689E-5	-1.2490000000000001	2.1532E-5
-1.23	-4.1779000000000001E-5	-1.2470000000000001	2.1551000000000001E-5
-1.2310000000000001	-4.1814000000000003E-5	-1.2450000000000001	2.1608E-5
-1.232	-4.1779000000000001E-5	-1.2430000000000001	2.1673999999999999E-5
-1.2330000000000001	-4.1814000000000003E-5	-1.2410000000000001	2.1733999999999999E-5
-1.234	-4.1993000000000003E-5	-1.2390000000000001	2.1747E-5
-1.2350000000000001	-4.2314999999999997E-5	-1.2370000000000001	2.1787999999999999E-5
-1.236	-4.2333000000000003E-5	-1.2350000000000001	2.1911000000000001E-5
-1.2370000000000001	-4.2262000000000003E-5	-1.2330000000000001	2.1987000000000001E-5
-1.238	-4.2216999999999999E-5	-1.2310000000000001	2.1920999999999999E-5
-1.2390000000000001	-4.2289000000000001E-5	-1.2290000000000001	2.2013000000000001E-5
-1.24	-4.2386999999999999E-5	-1.2270000000000001	2.2035000000000002E-5
-1.2410000000000001	-4.2475999999999998E-5	-1.2250000000000001	2.2035000000000002E-5
-1.242	-4.2574999999999998E-5	-1.2230000000000001	2.2062999999999999E-5
-1.2430000000000001	-4.2718E-5	-1.2210000000000001	2.2065999999999998E-5
-1.244	-4.2726999999999999E-5	-1.2190000000000001	2.2135999999999999E-5
-1.2450000000000001	-4.2735999999999999E-5	-1.2170000000000001	2.2212E-5
-1.246	-4.2789E-5	-1.2150000000000001	2.2212E-5
-1.2470000000000001	-4.2896999999999999E-5	-1.2130000000000001	2.2255999999999998E-5
-1.248	-4.2870000000000001E-5	-1.2110000000000001	2.2319000000000001E-5
-1.2490000000000001	-4.3058E-5	-1.2090000000000001	2.2303999999999999E-5
-1.25	-4.3219000000000001E-5	-1.2070000000000001	2.2348E-5
-1.2509999999999999	-4.3173999999999997E-5	-1.2050000000000001	2.2364000000000001E-5
-1.252	-4.3281000000000001E-5	-1.2030000000000001	2.2467999999999999E-5
-1.2529999999999999	-4.3380000000000001E-5	-1.2010000000000001	2.2473999999999999E-5
-1.254	-4.3486999999999999E-5	-1.1990000000000001	2.2500000000000001E-5
-1.2549999999999999	-4.3603000000000002E-5	-1.1970000000000001	2.2531000000000002E-5
-1.256	-4.3594000000000003E-5	-1.1950000000000001	2.2569E-5
-1.2569999999999999	-4.3630000000000001E-5	-1.1930000000000001	2.2603999999999999E-5
-1.258	-4.3736999999999998E-5	-1.1910000000000001	2.2631999999999999E-5
-1.2589999999999999	-4.3897999999999999E-5	-1.1890000000000001	2.2674E-5
-1.26	-4.3943000000000003E-5	-1.1870000000000001	2.2708E-5
-1.2609999999999999	-4.3897999999999999E-5	-1.1850000000000001	2.2756E-5
-1.262	-4.4104000000000003E-5	-1.1830000000000001	2.281E-5
-1.2629999999999999	-4.4255999999999998E-5	-1.181	2.2838000000000001E-5
-1.264	-4.4264999999999997E-5	-1.179	2.2821999999999999E-5
-1.2649999999999999	-4.4416999999999998E-5	-1.177	2.2844E-5
-1.266	-4.4577999999999999E-5	-1.175	2.2929999999999999E-5
-1.2669999999999999	-4.4613999999999997E-5	-1.173	2.2960999999999999E-5
-1.268	-4.4685999999999999E-5	-1.171	2.2968000000000001E-5
-1.2689999999999999	-4.4838E-5	-1.169	2.3011999999999999E-5
-1.27	-4.4864000000000003E-5	-1.167	2.3020999999999999E-5
-1.2709999999999999	-4.4935999999999998E-5	-1.165	2.3065999999999999E-5
-1.272	-4.5034000000000003E-5	-1.163	2.3104000000000001E-5
-1.2729999999999999	-4.5151000000000002E-5	-1.161	2.3119E-5
-1.274	-4.5169000000000001E-5	-1.159	2.3183000000000001E-5
-1.2749999999999999	-4.5436999999999999E-5	-1.157	2.3192000000000001E-5
-1.276	-4.5534999999999997E-5	-1.155	2.3221E-5
-1.2769999999999999	-4.5534999999999997E-5	-1.153	2.3264999999999998E-5
-1.278	-4.5723000000000003E-5	-1.151	2.3289999999999999E-5
-1.2789999999999999	-4.5838999999999999E-5	-1.149	2.3325000000000001E-5
-1.28	-4.5964999999999998E-5	-1.147	2.3346999999999999E-5
-1.2809999999999999	-4.6090000000000001E-5	-1.145	2.3334000000000001E-5
-1.282	-4.6187999999999999E-5	-1.143	2.3404000000000002E-5
-1.2829999999999999	-4.6286999999999999E-5	-1.141	2.3451E-5
-1.284	-4.6421000000000002E-5	-1.139	2.3493E-5
-1.2849999999999999	-4.6519E-5	-1.137	2.3536999999999998E-5
-1.286	-4.6609E-5	-1.135	2.3518000000000001E-5
-1.2869999999999999	-4.6689E-5	-1.133	2.3638E-5
-1.288	-4.685E-5	-1.131	2.3733000000000001E-5
-1.2889999999999999	-4.7011000000000001E-5	-1.129	2.3679000000000001E-5
-1.29	-4.7181000000000001E-5	-1.127	2.3700999999999999E-5
-1.2909999999999999	-4.7296999999999998E-5	-1.125	2.3714E-5
-1.292	-4.7377999999999999E-5	-1.123	2.3765E-5
-1.2929999999999999	-4.7503000000000002E-5	-1.121	2.3757999999999999E-5
-1.294	-4.7627999999999999E-5	-1.119	2.3796000000000001E-5
-1.2949999999999999	-4.778E-5	-1.117	2.3881999999999999E-5
-1.296	-4.7896999999999999E-5	-1.115	2.3872000000000001E-5
-1.2969999999999999	-4.8040000000000001E-5	-1.113	2.3915999999999999E-5
-1.298	-4.8192000000000002E-5	-1.111	2.3932000000000001E-5
-1.2989999999999999	-4.8254000000000003E-5	-1.109	2.3957000000000001E-5
-1.3	-4.8451000000000001E-5	-1.107	2.4002000000000002E-5
-1.3009999999999999	-4.8585000000000003E-5	-1.105	2.4023999999999999E-5
-1.302	-4.8603000000000002E-5	-1.103	2.4062000000000001E-5
-1.3029999999999999	-4.8736999999999998E-5	-1.101	2.4128E-5
-1.304	-4.8934000000000003E-5	-1.099	2.4159999999999999E-5
-1.3049999999999999	-4.9131000000000001E-5	-1.097	2.4182E-5
-1.306	-4.9319E-5	-1.095	2.4229000000000001E-5
-1.3069999999999999	-4.9506999999999999E-5	-1.093	2.4219999999999999E-5
-1.3080000000000001	-4.9577999999999999E-5	-1.091	2.427E-5
-1.3089999999999999	-4.9703000000000002E-5	-1.089	2.4337000000000001E-5
-1.31	-4.9873000000000002E-5	-1.087	2.4369E-5
-1.3109999999999999	-4.9981000000000001E-5	-1.085	2.4375E-5
-1.3120000000000001	-5.0096999999999998E-5	-1.083	2.4403E-5
-1.3129999999999999	-5.0355999999999997E-5	-1.081	2.4437999999999999E-5
-1.3140000000000001	-5.0535000000000003E-5	-1.079	2.4498000000000002E-5
-1.3149999999999999	-5.0606999999999998E-5	-1.077	2.4501000000000001E-5
-1.3160000000000001	-5.0741000000000001E-5	-1.075	2.4567999999999999E-5
-1.3169999999999999	-5.1035999999999997E-5	-1.073	2.4618E-5
-1.3180000000000001	-5.1242000000000002E-5	-1.071	2.4606000000000001E-5
-1.319	-5.1421000000000001E-5	-1.069	2.4658999999999999E-5
-1.32	-5.1554999999999997E-5	-1.0669999999999999	2.4697000000000001E-5
-1.321	-5.1653000000000002E-5	-1.0649999999999999	2.4754000000000001E-5
-1.3220000000000001	-5.1805000000000003E-5	-1.0629999999999999	2.4760999999999999E-5
-1.323	-5.202E-5	-1.0609999999999999	2.4820999999999998E-5
-1.3240000000000001	-5.2243000000000001E-5	-1.0589999999999999	2.4862E-5
-1.325	-5.2351000000000001E-5	-1.0569999999999999	2.4881000000000001E-5
-1.3260000000000001	-5.2512000000000001E-5	-1.0549999999999999	2.4871E-5
-1.327	-5.2691000000000001E-5	-1.0529999999999999	2.4953999999999999E-5
-1.3280000000000001	-5.2886999999999997E-5	-1.0509999999999999	2.4975999999999999E-5
-1.329	-5.3084000000000002E-5	-1.0489999999999999	2.5038999999999999E-5
-1.33	-5.3281E-5	-1.0469999999999999	2.5020000000000001E-5
-1.331	-5.346E-5	-1.0449999999999999	2.5071000000000001E-5
-1.3320000000000001	-5.3621E-5	-1.0429999999999999	2.5117999999999999E-5
-1.333	-5.3835999999999998E-5	-1.0409999999999999	2.5168999999999999E-5
-1.3340000000000001	-5.4058999999999999E-5	-1.0389999999999999	2.5196999999999999E-5
-1.335	-5.4193000000000001E-5	-1.0369999999999999	2.5248E-5
-1.3360000000000001	-5.4453000000000002E-5	-1.0349999999999999	2.5292000000000001E-5
-1.337	-5.4775000000000003E-5	-1.0329999999999999	2.5335999999999999E-5
-1.3380000000000001	-5.5034000000000002E-5	-1.0309999999999999	2.5377000000000001E-5
-1.339	-5.5043000000000001E-5	-1.0289999999999999	2.5482000000000001E-5
-1.34	-5.5266999999999998E-5	-1.0269999999999999	2.5494E-5
-1.341	-5.5401E-5	-1.0249999999999999	2.5459000000000001E-5
-1.3420000000000001	-5.5642E-5	-1.0229999999999999	2.5503999999999998E-5
-1.343	-5.5865999999999997E-5	-1.0209999999999999	2.5542E-5
-1.3440000000000001	-5.6081000000000001E-5	-1.0189999999999999	2.5551E-5
-1.345	-5.6196999999999997E-5	-1.0169999999999999	2.5595000000000001E-5
-1.3460000000000001	-5.6375999999999997E-5	-1.0149999999999999	2.5646000000000001E-5
-1.347	-5.6518999999999999E-5	-1.0129999999999999	2.5670999999999999E-5
-1.3480000000000001	-5.6742E-5	-1.0109999999999999	2.5757000000000001E-5
-1.349	-5.7028999999999999E-5	-1.0089999999999999	2.5766E-5
-1.35	-5.7207999999999998E-5	-1.0069999999999999	2.5766E-5
-1.351	-5.7404000000000001E-5	-1.0049999999999999	2.5814000000000001E-5
-1.3520000000000001	-5.7627999999999998E-5	-1.0029999999999999	2.5817E-5
-1.353	-5.7797999999999998E-5	-1.0009999999999999	2.582E-5
-1.3540000000000001	-5.7958999999999999E-5	-0.999	2.5874E-5
-1.355	-5.8272E-5	-0.997	2.5953E-5
-1.3560000000000001	-5.8513E-5	-0.995	2.5945999999999999E-5
-1.357	-5.8700999999999999E-5	-0.99299999999999999	2.6013E-5
-1.3580000000000001	-5.8925000000000002E-5	-0.99099999999999999	2.6021999999999999E-5
-1.359	-5.9131E-5	-0.98899999999999999	2.6067E-5
-1.36	-5.9246999999999997E-5	-0.98699999999999999	2.6092E-5
-1.361	-5.9462000000000001E-5	-0.98499999999999999	2.6114000000000001E-5
-1.3620000000000001	-5.9738999999999998E-5	-0.98299999999999998	2.6183999999999999E-5
-1.363	-5.9855000000000002E-5	-0.98099999999999998	2.6186999999999998E-5
-1.3640000000000001	-6.0096999999999997E-5	-0.97899999999999998	2.6259999999999999E-5
-1.365	-6.0365000000000002E-5	-0.97699999999999998	2.6313E-5
-1.3660000000000001	-6.0535000000000002E-5	-0.97499999999999998	2.6293999999999999E-5
-1.367	-6.0776000000000002E-5	-0.97299999999999998	2.6313E-5
-1.3680000000000001	-6.0982E-5	-0.97099999999999997	2.6361000000000001E-5
-1.369	-6.1231999999999999E-5	-0.96899999999999997	2.6401999999999999E-5
-1.37	-6.1402000000000006E-5	-0.96699999999999997	2.6395999999999999E-5
-1.371	-6.1599000000000004E-5	-0.96499999999999997	2.6395999999999999E-5
-1.3720000000000001	-6.1884999999999994E-5	-0.96299999999999997	2.6452E-5
-1.373	-6.2028999999999999E-5	-0.96099999999999997	2.65E-5
-1.3740000000000001	-6.2252E-5	-0.95899999999999996	2.6512999999999998E-5
-1.375	-6.2476000000000003E-5	-0.95699999999999996	2.6534999999999999E-5
-1.3759999999999999	-6.2582999999999994E-5	-0.95499999999999996	2.6550000000000002E-5
-1.377	-6.2932E-5	-0.95299999999999996	2.6519000000000001E-5
-1.3779999999999999	-6.3200000000000005E-5	-0.95099999999999996	2.6601000000000002E-5
-1.379	-6.3307999999999998E-5	-0.94899999999999995	2.6679999999999999E-5
-1.38	-6.3513E-5	-0.94699999999999995	2.669E-5
-1.381	-6.3719000000000004E-5	-0.94499999999999995	2.6730999999999999E-5
-1.3819999999999999	-6.3952E-5	-0.94299999999999995	2.6775E-5
-1.383	-6.4220000000000005E-5	-0.94099999999999995	2.6800000000000001E-5
-1.3839999999999999	-6.4308999999999997E-5	-0.93899999999999995	2.6784E-5
-1.385	-6.4533E-5	-0.93700000000000006	2.6800000000000001E-5
-1.3859999999999999	-6.4774E-5	-0.93500000000000005	2.6840999999999999E-5
-1.387	-6.5052E-5	-0.93300000000000005	2.6869999999999999E-5
-1.3879999999999999	-6.5149999999999998E-5	-0.93100000000000005	2.6857000000000001E-5
-1.389	-6.5328999999999997E-5	-0.92900000000000005	2.6911E-5
-1.39	-6.5517000000000003E-5	-0.92700000000000005	2.705E-5
-1.391	-6.5748999999999997E-5	-0.92500000000000004	2.7019E-5
-1.3919999999999999	-6.5937000000000002E-5	-0.92300000000000004	2.6993000000000001E-5
-1.393	-6.6161000000000006E-5	-0.92100000000000004	2.7008999999999998E-5
-1.3939999999999999	-6.6392999999999999E-5	-0.91900000000000004	2.7012000000000002E-5
-1.395	-6.6571999999999999E-5	-0.91700000000000004	2.6993000000000001E-5
-1.3959999999999999	-6.6832E-5	-0.91500000000000004	2.7053E-5
-1.397	-6.7002000000000007E-5	-0.91300000000000003	2.7078999999999999E-5
-1.3979999999999999	-6.7126999999999996E-5	-0.91100000000000003	2.7056E-5
-1.399	-6.7269999999999998E-5	-0.90900000000000003	2.7132E-5
-1.4	-6.7538000000000003E-5	-0.90700000000000003	2.7129000000000001E-5
-1.401	-6.7753E-5	-0.90500000000000003	2.7148000000000002E-5
-1.4019999999999999	-6.7931999999999999E-5	-0.90300000000000002	2.7172999999999999E-5
-1.403	-6.8120000000000005E-5	-0.90100000000000002	2.7135999999999999E-5
-1.4039999999999999	-6.8369999999999998E-5	-0.89900000000000002	2.7177000000000001E-5
-1.405	-6.8477000000000002E-5	-0.89700000000000002	2.7183E-5
-1.4059999999999999	-6.8646999999999995E-5	-0.89500000000000002	2.7237E-5
-1.407	-6.8898000000000003E-5	-0.89300000000000002	2.7234E-5
-1.4079999999999999	-6.8978000000000003E-5	-0.89100000000000001	2.7246E-5
-1.409	-6.9202000000000006E-5	-0.88900000000000001	2.7248999999999999E-5
-1.41	-6.9363000000000007E-5	-0.88700000000000001	2.7322E-5
-1.411	-6.9497000000000002E-5	-0.88500000000000001	2.73E-5
-1.4119999999999999	-6.9684999999999994E-5	-0.88300000000000001	2.7359999999999999E-5
-1.413	-6.9890999999999999E-5	-0.88100000000000001	2.7382E-5
-1.4139999999999999	-7.0034000000000001E-5	-0.879	2.7347000000000001E-5
-1.415	-7.0185999999999995E-5	-0.877	2.7385E-5
-1.4159999999999999	-7.0390999999999997E-5	-0.875	2.7395000000000001E-5
-1.417	-7.0551999999999998E-5	-0.873	2.7370000000000001E-5
-1.4179999999999999	-7.0730999999999998E-5	-0.871	2.7426000000000001E-5
-1.419	-7.0945999999999995E-5	-0.86899999999999999	2.7470999999999998E-5
-1.42	-7.1035E-5	-0.86699999999999999	2.7441999999999999E-5
-1.421	-7.1241000000000005E-5	-0.86499999999999999	2.7426000000000001E-5
-1.4219999999999999	-7.1365999999999994E-5	-0.86299999999999999	2.7382E-5
-1.423	-7.1526999999999995E-5	-0.86099999999999999	2.7444999999999999E-5
-1.4239999999999999	-7.1662000000000006E-5	-0.85899999999999999	2.7433E-5
-1.425	-7.1876000000000001E-5	-0.85699999999999998	2.7474000000000002E-5
-1.4259999999999999	-7.1957000000000002E-5	-0.85499999999999998	2.7504999999999998E-5
-1.427	-7.1975000000000001E-5	-0.85299999999999998	2.7483000000000001E-5
-1.4279999999999999	-7.2162000000000005E-5	-0.85099999999999998	2.7474000000000002E-5
-1.429	-7.2349999999999997E-5	-0.84899999999999998	2.7498999999999999E-5
-1.43	-7.2484000000000006E-5	-0.84699999999999998	2.7483000000000001E-5
-1.431	-7.2653999999999999E-5	-0.84499999999999997	2.7504999999999998E-5
-1.4319999999999999	-7.2805999999999994E-5	-0.84299999999999997	2.7552999999999999E-5
-1.4330000000000001	-7.2966999999999994E-5	-0.84099999999999997	2.7483000000000001E-5
-1.4339999999999999	-7.3102000000000006E-5	-0.83899999999999997	2.7504999999999998E-5
-1.4350000000000001	-7.3263000000000007E-5	-0.83699999999999997	2.7518E-5
-1.4359999999999999	-7.3288999999999996E-5	-0.83499999999999996	2.7613000000000001E-5
-1.4370000000000001	-7.3316000000000001E-5	-0.83299999999999996	2.7648E-5
-1.4379999999999999	-7.3584999999999994E-5	-0.83099999999999996	2.7645E-5
-1.4390000000000001	-7.3737000000000002E-5	-0.82899999999999996	2.7574999999999999E-5
-1.44	-7.3960000000000003E-5	-0.82699999999999996	2.7610000000000002E-5
-1.4410000000000001	-7.4041000000000005E-5	-0.82499999999999996	2.7736E-5
-1.4419999999999999	-7.4111999999999998E-5	-0.82299999999999995	2.7739E-5
-1.4430000000000001	-7.4139000000000003E-5	-0.82099999999999995	2.7676000000000001E-5
-1.444	-7.4210999999999998E-5	-0.81899999999999995	2.7664000000000001E-5
-1.4450000000000001	-7.4326999999999995E-5	-0.81699999999999995	2.7664000000000001E-5
-1.446	-7.4443000000000005E-5	-0.81499999999999995	2.7657E-5
-1.4470000000000001	-7.4585999999999994E-5	-0.81299999999999994	2.7645E-5
-1.448	-7.4612999999999999E-5	-0.81100000000000005	2.7616000000000001E-5
-1.4490000000000001	-7.4532999999999999E-5	-0.80900000000000005	2.7637999999999999E-5
-1.45	-7.4773999999999999E-5	-0.80700000000000005	2.7637999999999999E-5
-1.4510000000000001	-7.4881000000000004E-5	-0.80500000000000005	2.7670000000000001E-5
-1.452	-7.4970999999999998E-5	-0.80300000000000005	2.7682999999999999E-5
-1.4530000000000001	-7.4998000000000003E-5	-0.80100000000000005	2.7657E-5
-1.454	-7.5086999999999994E-5	-0.79900000000000004	2.7585000000000001E-5
-1.4550000000000001	-7.5185999999999995E-5	-0.79700000000000004	2.7628999999999999E-5
-1.456	-7.5247999999999995E-5	-0.79500000000000004	2.7628999999999999E-5
-1.4570000000000001	-7.5292999999999999E-5	-0.79300000000000004	2.7670000000000001E-5
-1.458	-7.5364000000000006E-5	-0.79100000000000004	2.7688999999999999E-5
-1.4590000000000001	-7.5390999999999997E-5	-0.78900000000000003	2.7676000000000001E-5
-1.46	-7.5561000000000004E-5	-0.78700000000000003	2.7645E-5
-1.4610000000000001	-7.5632999999999999E-5	-0.78500000000000003	2.7670000000000001E-5
-1.462	-7.5668999999999997E-5	-0.78300000000000003	2.7654E-5
-1.4630000000000001	-7.5766999999999995E-5	-0.78100000000000003	2.7670000000000001E-5
-1.464	-7.5740000000000003E-5	-0.77900000000000003	2.7667000000000001E-5
-1.4650000000000001	-7.5740000000000003E-5	-0.77700000000000002	2.7651E-5
-1.466	-7.5829999999999997E-5	-0.77500000000000002	2.7673000000000001E-5
-1.4670000000000001	-7.5901000000000004E-5	-0.77300000000000002	2.7682999999999999E-5
-1.468	-7.5919000000000003E-5	-0.77100000000000002	2.7702E-5
-1.4690000000000001	-7.5982000000000005E-5	-0.76900000000000002	2.7736E-5
-1.47	-7.6052999999999998E-5	-0.76700000000000002	2.7685999999999999E-5
-1.4710000000000001	-7.6098000000000002E-5	-0.76500000000000001	2.7651E-5
-1.472	-7.6080000000000003E-5	-0.76300000000000001	2.7708E-5
-1.4730000000000001	-7.6143000000000006E-5	-0.76100000000000001	2.7640999999999998E-5
-1.474	-7.6249999999999997E-5	-0.75900000000000001	2.7688999999999999E-5
-1.4750000000000001	-7.6205000000000006E-5	-0.75700000000000001	2.7682999999999999E-5
-1.476	-7.6223000000000005E-5	-0.755	2.7682999999999999E-5
-1.4770000000000001	-7.6304000000000007E-5	-0.753	2.7695000000000002E-5
-1.478	-7.6329999999999996E-5	-0.751	2.7659999999999999E-5
-1.4790000000000001	-7.6321000000000003E-5	-0.749	2.7648E-5
-1.48	-7.6329999999999996E-5	-0.747	2.7628999999999999E-5
-1.4810000000000001	-7.6375E-5	-0.745	2.7664000000000001E-5
-1.482	-7.6420000000000004E-5	-0.74299999999999999	2.7657E-5
-1.4830000000000001	-7.6508999999999995E-5	-0.74099999999999999	2.7628999999999999E-5
-1.484	-7.6490999999999997E-5	-0.73899999999999999	2.7631999999999999E-5
-1.4850000000000001	-7.6536E-5	-0.73699999999999999	2.7645E-5
-1.486	-7.6490999999999997E-5	-0.73499999999999999	2.76E-5
-1.4870000000000001	-7.6536E-5	-0.73299999999999998	2.7594E-5
-1.488	-7.6490999999999997E-5	-0.73099999999999998	2.7610000000000002E-5
-1.4890000000000001	-7.6581000000000004E-5	-0.72899999999999998	2.7654E-5
-1.49	-7.6617000000000002E-5	-0.72699999999999998	2.7637999999999999E-5
-1.4910000000000001	-7.6607999999999996E-5	-0.72499999999999998	2.7594E-5
-1.492	-7.6617000000000002E-5	-0.72299999999999998	2.7673000000000001E-5
-1.4930000000000001	-7.6669999999999996E-5	-0.72099999999999997	2.7702E-5
-1.494	-7.6625999999999994E-5	-0.71899999999999997	2.76E-5
-1.4950000000000001	-7.6599000000000003E-5	-0.71699999999999997	2.7585000000000001E-5
-1.496	-7.6715E-5	-0.71499999999999997	2.76E-5
-1.4970000000000001	-7.6715E-5	-0.71299999999999997	2.7572E-5
-1.498	-7.6697000000000001E-5	-0.71099999999999997	2.7580999999999999E-5
-1.4990000000000001	-7.6643000000000005E-5	-0.70899999999999996	2.7501999999999999E-5
-1.5	-7.6705999999999994E-5	-0.70699999999999996	2.7552999999999999E-5
-1.5009999999999999	-7.6661000000000003E-5	-0.70499999999999996	2.7549999999999999E-5
-1.502	-7.6705999999999994E-5	-0.70299999999999996	2.7518E-5
-1.5029999999999999	-7.6760000000000004E-5	-0.70099999999999996	2.7523999999999999E-5
-1.504	-7.6661000000000003E-5	-0.69899999999999995	2.7495999999999999E-5
-1.5049999999999999	-7.6679000000000002E-5	-0.69699999999999995	2.7477000000000001E-5
-1.506	-7.6724000000000006E-5	-0.69499999999999995	2.7495999999999999E-5
-1.5069999999999999	-7.6643000000000005E-5	-0.69299999999999995	2.7474000000000002E-5
-1.508	-7.6705999999999994E-5	-0.69099999999999995	2.7449000000000001E-5
-1.5089999999999999	-7.6742000000000005E-5	-0.68899999999999995	2.7483000000000001E-5
-1.51	-7.6812999999999998E-5	-0.68700000000000006	2.7455000000000001E-5
-1.5109999999999999	-7.6858000000000002E-5	-0.68500000000000005	2.7438999999999999E-5
-1.512	-7.6830999999999997E-5	-0.68300000000000005	2.7413999999999999E-5
-1.5129999999999999	-7.6760000000000004E-5	-0.68100000000000005	2.7395000000000001E-5
-1.514	-7.6715E-5	-0.67900000000000005	2.7441999999999999E-5
-1.5149999999999999	-7.6804000000000005E-5	-0.67700000000000005	2.7433E-5
-1.516	-7.6732999999999999E-5	-0.67500000000000004	2.7398000000000001E-5
-1.5169999999999999	-7.6715E-5	-0.67300000000000004	2.7373E-5
-1.518	-7.6732999999999999E-5	-0.67100000000000004	2.7376E-5
-1.5189999999999999	-7.6876000000000001E-5	-0.66900000000000004	2.7376E-5
-1.52	-7.6768999999999996E-5	-0.66700000000000004	2.7322E-5
-1.5209999999999999	-7.6742000000000005E-5	-0.66500000000000004	2.7373E-5
-1.522	-7.6750999999999998E-5	-0.66300000000000003	2.7328E-5
-1.5229999999999999	-7.6742000000000005E-5	-0.66100000000000003	2.7302999999999999E-5
-1.524	-7.6812999999999998E-5	-0.65900000000000003	2.7305999999999999E-5
-1.5249999999999999	-7.6840000000000003E-5	-0.65700000000000003	2.7280999999999999E-5
-1.526	-7.6778000000000002E-5	-0.65500000000000003	2.7253000000000001E-5
-1.5269999999999999	-7.6804000000000005E-5	-0.65300000000000002	2.7246E-5
-1.528	-7.6893999999999999E-5	-0.65100000000000002	2.724E-5
-1.5289999999999999	-7.6866999999999994E-5	-0.64900000000000002	2.7243E-5
-1.53	-7.6732999999999999E-5	-0.64700000000000002	2.724E-5
-1.5309999999999999	-7.6822000000000004E-5	-0.64500000000000002	2.7180000000000001E-5
-1.532	-7.6866999999999994E-5	-0.64300000000000002	2.7169999999999999E-5
-1.5329999999999999	-7.6812999999999998E-5	-0.64100000000000001	2.7166999999999999E-5
-1.534	-7.6858000000000002E-5	-0.63900000000000001	2.7158E-5
-1.5349999999999999	-7.6893999999999999E-5	-0.63700000000000001	2.7180000000000001E-5
-1.536	-7.6929999999999997E-5	-0.63500000000000001	2.7144999999999998E-5
-1.5369999999999999	-7.6921000000000004E-5	-0.63300000000000001	2.7104E-5
-1.538	-7.6911999999999998E-5	-0.63100000000000001	2.7075000000000001E-5
-1.5389999999999999	-7.6957000000000002E-5	-0.629	2.7069000000000001E-5
-1.54	-7.6929999999999997E-5	-0.627	2.7098E-5
-1.5409999999999999	-7.7045999999999994E-5	-0.625	2.7081999999999999E-5
-1.542	-7.7224999999999993E-5	-0.623	2.7044000000000001E-5
-1.5429999999999999	-7.7206999999999994E-5	-0.621	2.7090999999999999E-5
-1.544	-7.7162000000000004E-5	-0.61899999999999999	2.7107E-5
-1.5449999999999999	-7.7045999999999994E-5	-0.61699999999999999	2.7015000000000001E-5
-1.546	-7.7055E-5	-0.61499999999999999	2.6996E-5
-1.5469999999999999	-7.7126000000000007E-5	-0.61299999999999999	2.6962E-5
-1.548	-7.7134999999999999E-5	-0.61099999999999999	2.6939000000000001E-5
-1.5489999999999999	-7.7134999999999999E-5	-0.60899999999999999	2.6917E-5
-1.55	-7.7216000000000001E-5	-0.60699999999999998	2.6923999999999998E-5
-1.5509999999999999	-7.7233999999999999E-5	-0.60499999999999998	2.6866999999999999E-5
-1.552	-7.7243000000000006E-5	-0.60299999999999998	2.6891999999999999E-5
-1.5529999999999999	-7.7233999999999999E-5	-0.60099999999999998	2.6876000000000002E-5
-1.554	-7.7188999999999996E-5	-0.59899999999999998	2.6857000000000001E-5
-1.5549999999999999	-7.7162000000000004E-5	-0.59699999999999998	2.6806999999999999E-5
-1.556	-7.7296E-5	-0.59499999999999997	2.6755999999999999E-5
-1.5569999999999999	-7.7349999999999996E-5	-0.59299999999999997	2.6769000000000001E-5
-1.5580000000000001	-7.7331999999999998E-5	-0.59099999999999997	2.6712000000000001E-5
-1.5589999999999999	-7.7341000000000004E-5	-0.58899999999999997	2.6727999999999999E-5
-1.56	-7.7447999999999994E-5	-0.58699999999999997	2.6712000000000001E-5
-1.5609999999999999	-7.7502000000000004E-5	-0.58499999999999996	2.6699E-5
-1.5620000000000001	-7.7484000000000006E-5	-0.58299999999999996	2.6645E-5
-1.5629999999999999	-7.7538000000000002E-5	-0.58099999999999996	2.6582000000000001E-5
-1.5640000000000001	-7.7608999999999995E-5	-0.57899999999999996	2.6604000000000001E-5
-1.5649999999999999	-7.7591999999999998E-5	-0.57699999999999996	2.6588E-5
-1.5660000000000001	-7.7707999999999995E-5	-0.57499999999999996	2.6565999999999999E-5
-1.5669999999999999	-7.7681000000000004E-5	-0.57299999999999995	2.6543999999999999E-5
-1.5680000000000001	-7.7583000000000006E-5	-0.57099999999999995	2.6512999999999998E-5
-1.569	-7.7707999999999995E-5	-0.56899999999999995	2.6228E-5
-1.57	-7.7797000000000001E-5	-0.56699999999999995	2.6304000000000001E-5
-1.571	-7.7815E-5	-0.56499999999999995	2.6367E-5
-1.5720000000000001	-7.7904999999999994E-5	-0.56299999999999994	2.6392000000000001E-5
-1.573	-7.7985000000000006E-5	-0.56100000000000005	2.6335000000000001E-5
-1.5740000000000001	-7.8003000000000005E-5	-0.55900000000000005	2.6319999999999999E-5
-1.575	-7.8057000000000002E-5	-0.55700000000000005	2.6310000000000001E-5
-1.5760000000000001	-7.8137000000000001E-5	-0.55500000000000005	2.6291E-5
-1.577	-7.8137000000000001E-5	-0.55300000000000005	2.6222000000000001E-5
-1.5780000000000001	-7.8236000000000001E-5	-0.55100000000000005	2.6205999999999999E-5
-1.579	-7.8361000000000004E-5	-0.54900000000000004	2.6231E-5
-1.58	-7.8361000000000004E-5	-0.54700000000000004	2.6177E-5
-1.581	-7.8333999999999999E-5	-0.54500000000000004	2.6139000000000002E-5
-1.5820000000000001	-7.8423000000000005E-5	-0.54300000000000004	2.6067E-5
-1.583	-7.8558000000000002E-5	-0.54100000000000004	2.6060000000000001E-5
-1.5840000000000001	-7.8610999999999997E-5	-0.53900000000000003	2.6038E-5
-1.585	-7.8646999999999994E-5	-0.53700000000000003	2.6007E-5
-1.5860000000000001	-7.8753999999999998E-5	-0.53500000000000003	2.5987999999999999E-5
-1.587	-7.8789999999999996E-5	-0.53300000000000003	2.5931E-5
-1.5880000000000001	-7.8942000000000004E-5	-0.53100000000000003	2.5902E-5
-1.589	-7.9048999999999995E-5	-0.52900000000000003	2.5845000000000001E-5
-1.59	-7.9013999999999999E-5	-0.52700000000000002	2.5823E-5
-1.591	-7.9041000000000004E-5	-0.52500000000000002	2.5814000000000001E-5
-1.5920000000000001	-7.9121000000000004E-5	-0.52300000000000002	2.5782000000000002E-5
-1.593	-7.9318000000000002E-5	-0.52100000000000002	2.5746999999999999E-5
-1.5940000000000001	-7.9461000000000004E-5	-0.51900000000000002	2.5741E-5
-1.595	-7.9469999999999996E-5	-0.51700000000000002	2.5792E-5
-1.5960000000000001	-7.9541000000000003E-5	-0.51500000000000001	2.5652000000000001E-5
-1.597	-7.9594999999999999E-5	-0.51300000000000001	2.5610999999999999E-5
-1.5980000000000001	-7.9710999999999996E-5	-0.51100000000000001	2.5605E-5
-1.599	-7.9819000000000003E-5	-0.50900000000000001	2.5551E-5
-1.6	-7.9837000000000001E-5	-0.50700000000000001	2.5497E-5
-1.601	-7.9899000000000002E-5	-0.505	2.5418E-5
-1.6020000000000001	-8.0123000000000005E-5	-0.503	2.5386999999999999E-5
-1.603	-8.0141000000000004E-5	-0.501	2.5374000000000001E-5
-1.6040000000000001	-8.0185000000000006E-5	-0.499	2.5361E-5
-1.605	-8.0247999999999995E-5	-0.497	2.5310999999999999E-5
-1.6060000000000001	-8.0320000000000003E-5	-0.495	2.5262999999999999E-5
-1.607	-8.0489999999999997E-5	-0.49299999999999999	2.5210000000000001E-5
-1.6080000000000001	-8.0632999999999999E-5	-0.49099999999999999	2.5134E-5
-1.609	-8.0649999999999995E-5	-0.48899999999999999	2.5143E-5
-1.61	-8.0712999999999998E-5	-0.48699999999999999	2.5114999999999999E-5
-1.611	-8.0909999999999996E-5	-0.48499999999999999	2.5045000000000002E-5
-1.6120000000000001	-8.0981000000000003E-5	-0.48299999999999998	2.5014000000000001E-5
-1.613	-8.1080000000000003E-5	-0.48099999999999998	2.4987999999999999E-5
-1.6140000000000001	-8.1205000000000006E-5	-0.47899999999999998	2.4924999999999999E-5
-1.615	-8.1366000000000007E-5	-0.47699999999999998	2.4893E-5
-1.6160000000000001	-8.1366000000000007E-5	-0.47499999999999998	2.4862E-5
-1.617	-8.1526999999999994E-5	-0.47299999999999998	2.4848999999999999E-5
-1.6180000000000001	-8.1651999999999997E-5	-0.47099999999999997	2.4788999999999999E-5
-1.619	-8.1633999999999998E-5	-0.46899999999999997	2.4766999999999999E-5
-1.62	-8.1786000000000006E-5	-0.46700000000000003	2.4715999999999998E-5
-1.621	-8.2001000000000003E-5	-0.46500000000000002	2.4666000000000001E-5
-1.6220000000000001	-8.2027999999999995E-5	-0.46300000000000002	2.4584E-5
-1.623	-8.2188999999999995E-5	-0.46100000000000002	2.4593E-5
-1.6240000000000001	-8.2323000000000004E-5	-0.45900000000000002	2.4549000000000002E-5
-1.625	-8.2377000000000001E-5	-0.45700000000000002	2.4498000000000002E-5
-1.6259999999999999	-8.2457E-5	-0.45500000000000002	2.4467000000000001E-5
-1.627	-8.2653999999999998E-5	-0.45300000000000001	2.4377999999999999E-5
-1.6279999999999999	-8.2779000000000001E-5	-0.45100000000000001	2.4352999999999999E-5
-1.629	-8.2896000000000001E-5	-0.44900000000000001	2.4331000000000001E-5
-1.63	-8.2966999999999994E-5	-0.44700000000000001	2.4298999999999999E-5
-1.631	-8.3109999999999995E-5	-0.44500000000000001	2.4267E-5
-1.6319999999999999	-8.3127999999999994E-5	-0.443	2.4219999999999999E-5
-1.633	-8.3200000000000003E-5	-0.441	2.4111999999999999E-5
-1.6339999999999999	-8.3361000000000004E-5	-0.439	2.4111999999999999E-5
-1.635	-8.3467999999999994E-5	-0.437	2.41E-5
-1.6359999999999999	-8.3665000000000006E-5	-0.435	2.4062000000000001E-5
-1.637	-8.3817000000000001E-5	-0.433	2.4020999999999999E-5
-1.6379999999999999	-8.3950999999999996E-5	-0.43099999999999999	2.3969999999999999E-5
-1.639	-8.4067000000000007E-5	-0.42899999999999999	2.3929000000000001E-5
-1.64	-8.4175E-5	-0.42699999999999999	2.3896999999999998E-5
-1.641	-8.4201000000000002E-5	-0.42499999999999999	2.3839999999999999E-5
-1.6419999999999999	-8.4380000000000002E-5	-0.42299999999999999	2.3815000000000002E-5
-1.643	-8.4586000000000006E-5	-0.42099999999999999	2.3774E-5
-1.6439999999999999	-8.4783000000000005E-5	-0.41899999999999998	2.3748999999999999E-5
-1.645	-8.5050999999999996E-5	-0.41699999999999998	2.3714E-5
-1.6459999999999999	-8.5050999999999996E-5	-0.41499999999999998	2.3757999999999999E-5
-1.647	-8.5096E-5	-0.41299999999999998	2.3697999999999999E-5
-1.6479999999999999	-8.5167000000000006E-5	-0.41099999999999998	2.3603000000000001E-5
-1.649	-8.5354999999999998E-5	-0.40899999999999997	2.3572000000000001E-5
-1.65	-8.5498E-5	-0.40699999999999997	2.3572000000000001E-5
-1.651	-8.5551999999999997E-5	-0.40500000000000003	2.3496E-5
-1.6519999999999999	-8.5659000000000001E-5	-0.40300000000000002	2.3425999999999999E-5
-1.653	-8.5847000000000007E-5	-0.40100000000000002	2.3419999999999999E-5
-1.6539999999999999	-8.5953999999999997E-5	-0.39900000000000002	2.3368999999999999E-5
-1.655	-8.6034999999999999E-5	-0.39700000000000002	2.3366E-5
-1.6559999999999999	-8.6223000000000004E-5	-0.39500000000000002	2.3334000000000001E-5
-1.657	-8.6374999999999999E-5	-0.39300000000000002	2.3268000000000002E-5
-1.6579999999999999	-8.6402000000000004E-5	-0.39100000000000001	2.3274000000000001E-5
-1.659	-8.6625000000000005E-5	-0.38900000000000001	2.3189000000000001E-5
-1.66	-8.6776999999999999E-5	-0.38700000000000001	2.3173E-5
-1.661	-8.6786000000000006E-5	-0.38500000000000001	2.3164E-5
-1.6619999999999999	-8.6876E-5	-0.38300000000000001	2.3110000000000001E-5
-1.663	-8.7126000000000006E-5	-0.38100000000000001	2.3088E-5
-1.6639999999999999	-8.7216E-5	-0.379	2.3081000000000001E-5
-1.665	-8.7295999999999999E-5	-0.377	2.3020999999999999E-5
-1.6659999999999999	-8.7546999999999994E-5	-0.375	2.3020999999999999E-5
-1.667	-8.7600000000000002E-5	-0.373	2.2957999999999999E-5
-1.6679999999999999	-8.7725000000000005E-5	-0.371	2.2957999999999999E-5
-1.669	-8.7850999999999996E-5	-0.36899999999999999	2.2963999999999999E-5
-1.67	-8.7850999999999996E-5	-0.36699999999999999	2.2895E-5
-1.671	-8.8038E-5	-0.36499999999999999	2.2911000000000001E-5
-1.6719999999999999	-8.8226000000000005E-5	-0.36299999999999999	2.2911000000000001E-5
-1.673	-8.8333999999999998E-5	-0.36099999999999999	2.2860000000000001E-5
-1.6739999999999999	-8.8441000000000002E-5	-0.35899999999999999	2.2844E-5
-1.675	-8.8566000000000006E-5	-0.35699999999999998	2.2816E-5
-1.6759999999999999	-8.8727000000000006E-5	-0.35499999999999998	2.2796999999999999E-5
-1.677	-8.8789999999999995E-5	-0.35299999999999998	2.2793999999999999E-5
-1.6779999999999999	-8.8996E-5	-0.35099999999999998	2.2742999999999999E-5
-1.679	-8.9165000000000004E-5	-0.34899999999999998	2.2699000000000001E-5
-1.68	-8.9165000000000004E-5	-0.34699999999999998	2.2717999999999998E-5
-1.681	-8.9362000000000003E-5	-0.34499999999999997	2.2696000000000001E-5
-1.6819999999999999	-8.9443000000000004E-5	-0.34300000000000003	2.2711E-5
-1.6830000000000001	-8.9531999999999996E-5	-0.34100000000000003	2.2696000000000001E-5
-1.6839999999999999	-8.9710999999999995E-5	-0.33900000000000002	2.2651E-5
-1.6850000000000001	-8.9979E-5	-0.33700000000000002	2.2642000000000001E-5
-1.6859999999999999	-8.9979E-5	-0.33500000000000002	2.2631999999999999E-5
-1.6870000000000001	-9.0068999999999994E-5	-0.33300000000000002	2.2639000000000001E-5
-1.6879999999999999	-9.0336999999999999E-5	-0.33100000000000002	2.2631999999999999E-5
-1.6890000000000001	-9.0426999999999993E-5	-0.32900000000000001	2.2623E-5
-1.69	-9.0515999999999999E-5	-0.32700000000000001	2.2629E-5
-1.6910000000000001	-9.0694999999999998E-5	-0.32500000000000001	2.2600999999999999E-5
-1.6919999999999999	-9.0784000000000004E-5	-0.32300000000000001	2.2597999999999999E-5
-1.6930000000000001	-9.0963000000000003E-5	-0.32100000000000001	2.2600999999999999E-5
-1.694	-9.1052999999999997E-5	-0.31900000000000001	2.2609999999999999E-5
-1.6950000000000001	-9.1231999999999997E-5	-0.317	2.2612999999999998E-5
-1.696	-9.1231999999999997E-5	-0.315	2.2629E-5
-1.6970000000000001	-9.1500000000000001E-5	-0.313	2.2693000000000001E-5
-1.698	-9.1588999999999993E-5	-0.311	2.2645000000000001E-5
-1.6990000000000001	-9.1679000000000001E-5	-0.309	2.2612999999999998E-5
-1.7	-9.1947000000000006E-5	-0.307	2.2631999999999999E-5
-1.7010000000000001	-9.2126000000000005E-5	-0.30499999999999999	2.2631999999999999E-5
-1.702	-9.2214999999999997E-5	-0.30299999999999999	2.2645000000000001E-5
-1.7030000000000001	-9.2305000000000005E-5	-0.30099999999999999	2.2623E-5
-1.704	-9.2484000000000004E-5	-0.29899999999999999	2.2636000000000001E-5
-1.7050000000000001	-9.2572999999999996E-5	-0.29699999999999999	2.2663999999999998E-5
-1.706	-9.2663000000000004E-5	-0.29499999999999998	2.2670000000000001E-5
-1.7070000000000001	-9.2842000000000003E-5	-0.29299999999999998	2.268E-5
-1.708	-9.3109999999999995E-5	-0.29099999999999998	2.2714999999999999E-5
-1.7090000000000001	-9.302E-5	-0.28899999999999998	2.2724000000000001E-5
-1.71	-9.3199E-5	-0.28699999999999998	2.2727000000000001E-5
-1.7110000000000001	-9.3377999999999999E-5	-0.28499999999999998	2.2748999999999999E-5
-1.712	-9.3467999999999993E-5	-0.28299999999999997	2.2765E-5
-1.7130000000000001	-9.3735999999999998E-5	-0.28100000000000003	2.2796999999999999E-5
-1.714	-9.3914999999999998E-5	-0.27900000000000003	2.281E-5
-1.7150000000000001	-9.3914999999999998E-5	-0.27700000000000002	2.2799999999999999E-5
-1.716	-9.4093999999999997E-5	-0.27500000000000002	2.2853999999999998E-5
-1.7170000000000001	-9.4272999999999997E-5	-0.27300000000000002	2.2917000000000001E-5
-1.718	-9.4362000000000002E-5	-0.27100000000000002	2.2884999999999999E-5
-1.7190000000000001	-9.4451999999999996E-5	-0.26900000000000002	2.2920000000000001E-5
-1.72	-9.4720000000000001E-5	-0.26700000000000002	2.2968000000000001E-5
-1.7210000000000001	-9.4809000000000007E-5	-0.26500000000000001	2.2986999999999999E-5
-1.722	-9.4899000000000001E-5	-0.26300000000000001	2.3017999999999999E-5
-1.7230000000000001	-9.4988000000000006E-5	-0.26100000000000001	2.3065999999999999E-5
-1.724	-9.5167000000000005E-5	-0.25900000000000001	2.3078000000000002E-5
-1.7250000000000001	-9.5346000000000005E-5	-0.25700000000000001	2.3138000000000001E-5
-1.726	-9.5525000000000004E-5	-0.255	2.3167E-5
-1.7270000000000001	-9.5704000000000004E-5	-0.253	2.3183000000000001E-5
-1.728	-9.5792999999999996E-5	-0.251	2.3235999999999999E-5
-1.7290000000000001	-9.6061000000000001E-5	-0.249	2.3232999999999999E-5
-1.73	-9.6150999999999995E-5	-0.247	2.3334000000000001E-5
-1.7310000000000001	-9.6329999999999994E-5	-0.245	2.336E-5
-1.732	-9.6419E-5	-0.24299999999999999	2.3407000000000001E-5
-1.7330000000000001	-9.6688000000000007E-5	-0.24099999999999999	2.3436000000000001E-5
-1.734	-9.6688000000000007E-5	-0.23899999999999999	2.3448E-5
-1.7350000000000001	-9.6776999999999999E-5	-0.23699999999999999	2.3533999999999999E-5
-1.736	-9.7045000000000003E-5	-0.23499999999999999	2.3533999999999999E-5
-1.7370000000000001	-9.7134999999999997E-5	-0.23300000000000001	2.3606000000000001E-5
-1.738	-9.7313999999999997E-5	-0.23100000000000001	2.3676000000000002E-5
-1.7390000000000001	-9.7492999999999996E-5	-0.22900000000000001	2.3697999999999999E-5
-1.74	-9.7670999999999994E-5	-0.22700000000000001	2.3777E-5
-1.7410000000000001	-9.7761000000000001E-5	-0.22500000000000001	2.3818000000000001E-5
-1.742	-9.8029000000000006E-5	-0.223	2.3839999999999999E-5
-1.7430000000000001	-9.8208000000000006E-5	-0.221	2.3887999999999999E-5
-1.744	-9.8208000000000006E-5	-0.219	2.3972999999999999E-5
-1.7450000000000001	-9.8387000000000005E-5	-0.217	2.4020999999999999E-5
-1.746	-9.8566000000000005E-5	-0.215	2.4087000000000002E-5
-1.7470000000000001	-9.9012999999999995E-5	-0.21299999999999999	2.4147000000000001E-5
-1.748	-9.9103000000000003E-5	-0.21099999999999999	2.4280000000000001E-5
-1.7490000000000001	-9.9191999999999995E-5	-0.20899999999999999	2.4307999999999998E-5
-1.75	-9.9281E-5	-0.20699999999999999	2.4331000000000001E-5
-1.7509999999999999	-9.9370999999999994E-5	-0.20499999999999999	2.4352999999999999E-5
-1.752	-9.9549999999999994E-5	-0.20300000000000001	2.4451E-5
-1.7529999999999999	-9.9638999999999999E-5	-0.20100000000000001	2.4498000000000002E-5
-1.754	-9.9817999999999999E-5	-0.19900000000000001	2.4570999999999999E-5
-1.7549999999999999	-9.9996999999999998E-5	-0.19700000000000001	2.4584E-5
-1.756	-1.0018000000000001E-4	-0.19500000000000001	2.4652999999999999E-5
-1.7569999999999999	-1.0027E-4	-0.193	2.4745000000000001E-5
-1.758	-1.0043999999999999E-4	-0.191	2.4824000000000002E-5
-1.7589999999999999	-1.0062E-4	-0.189	2.4868E-5
-1.76	-1.0062E-4	-0.187	2.4966000000000001E-5
-1.7609999999999999	-1.0089E-4	-0.185	2.5017000000000001E-5
-1.762	-1.0107000000000001E-4	-0.183	2.5089999999999999E-5
-1.7629999999999999	-1.0116E-4	-0.18099999999999999	2.5099000000000001E-5
-1.764	-1.0134E-4	-0.17899999999999999	2.5225E-5
-1.7649999999999999	-1.0152E-4	-0.17699999999999999	2.5304999999999999E-5
-1.766	-1.0161E-4	-0.17499999999999999	2.5358E-5
-1.7669999999999999	-1.0179E-4	-0.17299999999999999	2.5428000000000001E-5
-1.768	-1.0187999999999999E-4	-0.17100000000000001	2.5456000000000002E-5
-1.7689999999999999	-1.0196000000000001E-4	-0.16900000000000001	2.5542E-5
-1.77	-1.0205E-4	-0.16700000000000001	2.5633E-5
-1.7709999999999999	-1.0223E-4	-0.16500000000000001	2.5709000000000001E-5
-1.772	-1.0241E-4	-0.16300000000000001	2.5797999999999999E-5
-1.7729999999999999	-1.0241E-4	-0.161	2.5854999999999999E-5
-1.774	-1.0268E-4	-0.159	2.5953E-5
-1.7749999999999999	-1.0276999999999999E-4	-0.157	2.6018999999999999E-5
-1.776	-1.0276999999999999E-4	-0.155	2.6081999999999999E-5
-1.7769999999999999	-1.0304E-4	-0.153	2.6177E-5
-1.778	-1.0313E-4	-0.151	2.6244000000000001E-5
-1.7789999999999999	-1.0322E-4	-0.14899999999999999	2.6291E-5
-1.78	-1.0340000000000001E-4	-0.14699999999999999	2.6361000000000001E-5
-1.7809999999999999	-1.0357E-4	-0.14499999999999999	2.6461999999999998E-5
-1.782	-1.0349E-4	-0.14299999999999999	2.6534999999999999E-5
-1.7829999999999999	-1.0365999999999999E-4	-0.14099999999999999	2.6622999999999999E-5
-1.784	-1.0384E-4	-0.13900000000000001	2.6715000000000001E-5
-1.7849999999999999	-1.0384E-4	-0.13700000000000001	2.6769000000000001E-5
-1.786	-1.0384E-4	-0.13500000000000001	2.6883E-5
-1.7869999999999999	-1.0402E-4	-0.13300000000000001	2.6936000000000001E-5
-1.788	-1.0402E-4	-0.13100000000000001	2.7012000000000002E-5
-1.7889999999999999	-1.042E-4	-0.129	2.7081999999999999E-5
-1.79	-1.0429000000000001E-4	-0.127	2.7192E-5
-1.7909999999999999	-1.0438E-4	-0.125	2.7256000000000001E-5
-1.792	-1.0438E-4	-0.123	2.7359999999999999E-5
-1.7929999999999999	-1.0456E-4	-0.121	2.7410999999999999E-5
-1.794	-1.0465E-4	-0.11899999999999999	2.7501999999999999E-5
-1.7949999999999999	-1.0465E-4	-0.11700000000000001	2.7577999999999999E-5
-1.796	-1.0474E-4	-0.115	2.7708E-5
-1.7969999999999999	-1.0474E-4	-0.113	2.7806000000000001E-5
-1.798	-1.0446999999999999E-4	-0.111	2.7863000000000001E-5
-1.7989999999999999	-1.0446999999999999E-4	-0.109	2.8027000000000001E-5
-1.8	-1.0483E-4	-0.107	2.8127999999999999E-5
-1.8009999999999999	-1.0501E-4	-0.105	2.8160000000000001E-5
-1.802	-1.0501E-4	-0.10299999999999999	2.8255E-5
-1.8029999999999999	-1.0510000000000001E-4	-0.10100000000000001	2.8347000000000002E-5
-1.804	-1.0510000000000001E-4	-9.9000000000000005E-2	2.8407000000000001E-5
-1.8049999999999999	-1.0518000000000001E-4	-9.7000000000000003E-2	2.8521E-5
-1.806	-1.0535999999999999E-4	-9.5000000000000001E-2	2.8578E-5
-1.8069999999999999	-1.0535999999999999E-4	-9.2999999999999999E-2	2.8668999999999999E-5
-1.8080000000000001	-1.0518000000000001E-4	-9.0999999999999998E-2	2.8802E-5
-1.8089999999999999	-1.0535999999999999E-4	-8.8999999999999996E-2	2.8864999999999999E-5
-1.81	-1.0527E-4	-8.6999999999999994E-2	2.8963E-5
-1.8109999999999999	-1.0518000000000001E-4	-8.5000000000000006E-2	2.9068E-5
-1.8120000000000001	-1.0527E-4	-8.3000000000000004E-2	2.9147000000000001E-5
-1.8129999999999999	-1.0535999999999999E-4	-8.1000000000000003E-2	2.9241999999999999E-5
-1.8140000000000001	-1.0535999999999999E-4	-7.9000000000000001E-2	2.9332999999999999E-5
-1.8149999999999999	-1.0535999999999999E-4	-7.6999999999999999E-2	2.9456999999999999E-5
-1.8160000000000001	-1.0535999999999999E-4	-7.4999999999999997E-2	2.957E-5
-1.8169999999999999	-1.0545E-4	-7.2999999999999995E-2	2.9662000000000002E-5
-1.8180000000000001	-1.0545E-4	-7.0999999999999994E-2	2.9722000000000001E-5
-1.819	-1.0545E-4	-6.9000000000000006E-2	2.9767000000000001E-5
-1.82	-1.0545E-4	-6.7000000000000004E-2	2.9887E-5
-1.821	-1.0535999999999999E-4	-6.5000000000000002E-2	3.0073000000000002E-5
-1.8220000000000001	-1.0545E-4	-6.3E-2	3.0209000000000002E-5
-1.823	-1.0545E-4	-6.0999999999999999E-2	3.0263000000000001E-5
-1.8240000000000001	-1.0535999999999999E-4	-5.8999999999999997E-2	3.0363999999999999E-5
-1.825	-1.0545E-4	-5.7000000000000002E-2	3.0494E-5
-1.8260000000000001	-1.0554E-4	-5.5E-2	3.0598000000000001E-5
-1.827	-1.0545E-4	-5.2999999999999999E-2	3.0712E-5
-1.8280000000000001	-1.0545E-4	-5.0999999999999997E-2	3.082E-5
-1.829	-1.0545E-4	-4.9000000000000002E-2	3.0905000000000003E-5
-1.83	-1.0535999999999999E-4	-4.7E-2	3.0984E-5
-1.831	-1.0535999999999999E-4	-4.4999999999999998E-2	3.1075999999999999E-5
-1.8320000000000001	-1.0545E-4	-4.2999999999999997E-2	3.1220999999999998E-5
-1.833	-1.0545E-4	-4.1000000000000002E-2	3.1284000000000001E-5
-1.8340000000000001	-1.0527E-4	-3.9E-2	3.1405000000000002E-5
-1.835	-1.0535999999999999E-4	-3.6999999999999998E-2	3.1489999999999998E-5
-1.8360000000000001	-1.0545E-4	-3.5000000000000003E-2	3.1594000000000003E-5
-1.837	-1.0535999999999999E-4	-3.3000000000000002E-2	3.1686000000000001E-5
-1.8380000000000001	-1.0535999999999999E-4	-3.1E-2	3.1748999999999997E-5
-1.839	-1.0527E-4	-2.9000000000000001E-2	3.1844000000000002E-5
-1.84	-1.0527E-4	-2.7E-2	3.1906999999999998E-5
-1.841	-1.0527E-4	-2.5000000000000001E-2	3.1971000000000003E-5
-1.8420000000000001	-1.0518000000000001E-4	-2.3E-2	3.2002000000000003E-5
-1.843	-1.0518000000000001E-4	-2.1000000000000001E-2	3.2159999999999997E-5
-1.8440000000000001	-1.0527E-4	-1.9E-2	3.2317999999999998E-5
-1.845	-1.0518000000000001E-4	-1.7000000000000001E-2	3.2382000000000003E-5
-1.8460000000000001	-1.0510000000000001E-4	-1.4999999999999999E-2	3.2444999999999999E-5
-1.847	-1.0518000000000001E-4	-1.2999999999999999E-2	3.2539999999999997E-5
-1.8480000000000001	-1.0518000000000001E-4	-1.0999999999999999E-2	3.2602999999999999E-5
-1.849	-1.0535999999999999E-4	-8.9999999999999993E-3	3.2666000000000002E-5
-1.85	-1.0535999999999999E-4	-7.0000000000000001E-3	3.2793000000000003E-5
-1.851	-1.0527E-4	-5.0000000000000001E-3	3.2982999999999999E-5
-1.8520000000000001	-1.0518000000000001E-4	-3.0000000000000001E-3	3.3013999999999999E-5
-1.853	-1.0501E-4	-1E-3	3.3046000000000002E-5
-1.8540000000000001	-1.0510000000000001E-4	1E-3	3.3077000000000002E-5
-1.855	-1.0510000000000001E-4	3.0000000000000001E-3	3.3172E-5
-1.8560000000000001	-1.0501E-4	5.0000000000000001E-3	3.3235999999999998E-5
-1.857	-1.0501E-4	7.0000000000000001E-3	3.3266999999999998E-5
-1.8580000000000001	-1.0501E-4	8.9999999999999993E-3	3.3330000000000001E-5
-1.859	-1.0492000000000001E-4	1.0999999999999999E-2	3.3393999999999999E-5
-1.86	-1.0492000000000001E-4	1.2999999999999999E-2	3.3488999999999997E-5
-1.861	-1.0501E-4	1.4999999999999999E-2	3.3583E-5
-1.8620000000000001	-1.0483E-4	1.7000000000000001E-2	3.3646999999999998E-5
-1.863	-1.0483E-4	1.9E-2	3.3677999999999998E-5
-1.8640000000000001	-1.0501E-4	2.1000000000000001E-2	3.3742000000000003E-5
-1.865	-1.0501E-4	2.3E-2	3.3804999999999999E-5
-1.8660000000000001	-1.0483E-4	2.5000000000000001E-2	3.3868000000000002E-5
-1.867	-1.0483E-4	2.7E-2	3.3930999999999998E-5
-1.8680000000000001	-1.0492000000000001E-4	2.9000000000000001E-2	3.4026000000000003E-5
-1.869	-1.0492000000000001E-4	3.1E-2	3.4121000000000001E-5
-1.87	-1.0492000000000001E-4	3.3000000000000002E-2	3.4153000000000003E-5
-1.871	-1.0483E-4	3.5000000000000003E-2	3.4215999999999999E-5
-1.8720000000000001	-1.0465E-4	3.6999999999999998E-2	3.4279000000000002E-5
-1.873	-1.0474E-4	3.9E-2	3.4406000000000002E-5
-1.8740000000000001	-1.0483E-4	4.1000000000000002E-2	3.4468999999999998E-5
-1.875	-1.0474E-4	4.2999999999999997E-2	3.4499999999999998E-5
-1.8759999999999999	-1.0465E-4	4.4999999999999998E-2	3.4626999999999999E-5
-1.877	-1.0474E-4	4.7E-2	3.4721999999999997E-5
-1.8779999999999999	-1.0474E-4	4.9000000000000002E-2	3.4752999999999997E-5
-1.879	-1.0465E-4	5.0999999999999997E-2	3.4848000000000002E-5
-1.88	-1.0474E-4	5.2999999999999999E-2	3.4975000000000003E-5
-1.881	-1.0474E-4	5.5E-2	3.5037999999999999E-5
-1.8819999999999999	-1.0474E-4	5.7000000000000002E-2	3.5132999999999997E-5
-1.883	-1.0474E-4	5.8999999999999997E-2	3.5165E-5
-1.8839999999999999	-1.0465E-4	6.0999999999999999E-2	3.5259000000000002E-5
-1.885	-1.0465E-4	6.3E-2	3.5354000000000001E-5
-1.8859999999999999	-1.0474E-4	6.5000000000000002E-2	3.5448999999999999E-5
-1.887	-1.0474E-4	6.7000000000000004E-2	3.5576E-5
-1.8879999999999999	-1.0465E-4	6.9000000000000006E-2	3.5639000000000002E-5
-1.889	-1.0465E-4	7.0999999999999994E-2	3.5701999999999998E-5
-1.89	-1.0474E-4	7.2999999999999995E-2	3.5859999999999999E-5
-1.891	-1.0465E-4	7.4999999999999997E-2	3.5892000000000001E-5
-1.8919999999999999	-1.0474E-4	7.6999999999999999E-2	3.5859999999999999E-5
-1.893	-1.0474E-4	7.9000000000000001E-2	3.6145E-5
-1.8939999999999999	-1.0474E-4	8.1000000000000003E-2	3.6334999999999997E-5
-1.895	-1.0474E-4	8.3000000000000004E-2	3.6429E-5
-1.8959999999999999	-1.0474E-4	8.5000000000000006E-2	3.6492999999999998E-5
-1.897	-1.0474E-4	8.6999999999999994E-2	3.6619000000000003E-5
-1.8979999999999999	-1.0474E-4	8.8999999999999996E-2	3.6745999999999997E-5
-1.899	-1.0483E-4	9.0999999999999998E-2	3.6872000000000002E-5
-1.9	-1.0474E-4	9.2999999999999999E-2	3.7030000000000003E-5
-1.901	-1.0474E-4	9.5000000000000001E-2	3.7187999999999997E-5
-1.9019999999999999	-1.0474E-4	9.7000000000000003E-2	3.7441000000000003E-5
-1.903	-1.0483E-4	9.9000000000000005E-2	3.7536000000000001E-5
-1.9039999999999999	-1.0474E-4	0.10100000000000001	3.7630999999999999E-5
-1.905	-1.0483E-4	0.10299999999999999	3.7789E-5
-1.9059999999999999	-1.0483E-4	0.105	3.7947000000000001E-5
-1.907	-1.0492000000000001E-4	0.107	3.8074000000000002E-5
-1.9079999999999999	-1.0492000000000001E-4	0.109	3.8232000000000003E-5
-1.909	-1.0492000000000001E-4	0.111	3.8452999999999999E-5
-1.91	-1.0492000000000001E-4	0.113	3.8643000000000003E-5
-1.911	-1.0483E-4	0.115	3.8770000000000003E-5
-1.9119999999999999	-1.0492000000000001E-4	0.11700000000000001	3.8958999999999997E-5
-1.913	-1.0501E-4	0.11899999999999999	3.9149000000000001E-5
-1.9139999999999999	-1.0492000000000001E-4	0.121	3.9369999999999997E-5
-1.915	-1.0492000000000001E-4	0.123	3.9527999999999998E-5
-1.9159999999999999	-1.0501E-4	0.125	3.9780999999999997E-5
-1.917	-1.0510000000000001E-4	0.127	3.9971000000000001E-5
-1.9179999999999999	-1.0518000000000001E-4	0.129	4.0160999999999997E-5
-1.919	-1.0518000000000001E-4	0.13100000000000001	4.0414000000000003E-5
-1.92	-1.0501E-4	0.13300000000000001	4.0667000000000002E-5
-1.921	-1.0510000000000001E-4	0.13500000000000001	4.0856999999999999E-5
-1.9219999999999999	-1.0527E-4	0.13700000000000001	4.1109999999999998E-5
-1.923	-1.0518000000000001E-4	0.13900000000000001	4.1362999999999997E-5
-1.9239999999999999	-1.0518000000000001E-4	0.14099999999999999	4.1647000000000003E-5
-1.925	-1.0518000000000001E-4	0.14299999999999999	4.1900000000000002E-5
-1.9259999999999999	-1.0527E-4	0.14499999999999999	4.2089999999999999E-5
-1.927	-1.0518000000000001E-4	0.14699999999999999	4.2375E-5
-1.9279999999999999	-1.0535999999999999E-4	0.14899999999999999	4.2595999999999997E-5
-1.929	-1.0535999999999999E-4	0.151	4.2817E-5
-1.93	-1.0535999999999999E-4	0.153	4.3038999999999999E-5
-1.931	-1.0554E-4	0.155	4.3260000000000003E-5
-1.9319999999999999	-1.0554E-4	0.157	4.3544999999999997E-5
-1.9330000000000001	-1.0554E-4	0.159	4.3829000000000003E-5
-1.9339999999999999	-1.0554E-4	0.161	4.4019E-5
-1.9350000000000001	-1.0563E-4	0.16300000000000001	4.4366999999999997E-5
-1.9359999999999999	-1.0554E-4	0.16500000000000001	4.4682999999999999E-5
-1.9370000000000001	-1.0572E-4	0.16700000000000001	4.4999000000000001E-5
-1.9379999999999999	-1.0581000000000001E-4	0.16900000000000001	4.5252E-5
-1.9390000000000001	-1.0563E-4	0.17100000000000001	4.5504999999999999E-5
-1.94	-1.0572E-4	0.17299999999999999	4.5726999999999998E-5
-1.9410000000000001	-1.059E-4	0.17499999999999999	4.5948000000000001E-5
-1.9419999999999999	-1.059E-4	0.17699999999999999	4.6137999999999998E-5
-1.9430000000000001	-1.0599000000000001E-4	0.17899999999999999	4.6359000000000001E-5
-1.944	-1.0599000000000001E-4	0.18099999999999999	4.6612E-5
-1.9450000000000001	-1.0599000000000001E-4	0.183	4.6832999999999997E-5
-1.946	-1.0608E-4	0.185	4.7023E-5
-1.9470000000000001	-1.0616999999999999E-4	0.187	4.7212999999999997E-5
-1.948	-1.0635E-4	0.189	4.7370999999999998E-5
-1.9490000000000001	-1.0626E-4	0.191	4.7561000000000001E-5
-1.95	-1.0626E-4	0.193	4.7719000000000002E-5
-1.9510000000000001	-1.0635E-4	0.19500000000000001	4.7908999999999998E-5
-1.952	-1.0662000000000001E-4	0.19700000000000001	4.8003000000000001E-5
-1.9530000000000001	-1.0662000000000001E-4	0.19900000000000001	4.8256E-5
-1.954	-1.0671E-4	0.20100000000000001	4.8446000000000003E-5
-1.9550000000000001	-1.0653E-4	0.20300000000000001	4.8477999999999999E-5
-1.956	-1.0662000000000001E-4	0.20499999999999999	4.8572999999999997E-5
-1.9570000000000001	-1.0671E-4	0.20699999999999999	4.8636E-5
-1.958	-1.0671E-4	0.20899999999999999	4.8730999999999998E-5
-1.9590000000000001	-1.0688000000000001E-4	0.21099999999999999	4.8826000000000003E-5
-1.96	-1.0697E-4	0.21299999999999999	4.8826000000000003E-5
-1.9610000000000001	-1.0697E-4	0.215	4.8919999999999999E-5
-1.962	-1.0697E-4	0.217	4.8983999999999997E-5
-1.9630000000000001	-1.0705999999999999E-4	0.219	4.8983999999999997E-5
-1.964	-1.0724E-4	0.221	4.8952000000000002E-5
-1.9650000000000001	-1.0705999999999999E-4	0.223	4.9079000000000002E-5
-1.966	-1.0724E-4	0.22500000000000001	4.9141999999999998E-5
-1.9670000000000001	-1.0742E-4	0.22700000000000001	4.9268000000000003E-5
-1.968	-1.0742E-4	0.22900000000000001	4.9332000000000001E-5
-1.9690000000000001	-1.0751000000000001E-4	0.23100000000000001	4.9332000000000001E-5
-1.97	-1.0768999999999999E-4	0.23300000000000001	4.9394999999999997E-5
-1.9710000000000001	-1.0768999999999999E-4	0.23499999999999999	4.9425999999999997E-5
-1.972	-1.0768999999999999E-4	0.23699999999999999	4.9458E-5
-1.9730000000000001	-1.0778E-4	0.23899999999999999	4.9490000000000002E-5
-1.974	-1.0796E-4	0.24099999999999999	4.9490000000000002E-5
-1.9750000000000001	-1.0805E-4	0.24299999999999999	4.9552999999999998E-5
-1.976	-1.0814E-4	0.245	4.9616000000000001E-5
-1.9770000000000001	-1.0823E-4	0.247	4.9679000000000003E-5
-1.978	-1.0823E-4	0.249	4.9679000000000003E-5
-1.9790000000000001	-1.0832000000000001E-4	0.251	4.9679000000000003E-5
-1.98	-1.0840000000000001E-4	0.253	4.9774000000000002E-5
-1.9810000000000001	-1.0840000000000001E-4	0.255	4.9774000000000002E-5
-1.982	-1.0857999999999999E-4	0.25700000000000001	4.9805999999999997E-5
-1.9830000000000001	-1.0867E-4	0.25900000000000001	4.9836999999999997E-5
-1.984	-1.0876E-4	0.26100000000000001	4.9836999999999997E-5
-1.9850000000000001	-1.0885E-4	0.26300000000000001	4.9869E-5
-1.986	-1.0894E-4	0.26500000000000001	4.9869E-5
-1.9870000000000001	-1.0903E-4	0.26700000000000002	4.9774000000000002E-5
-1.988	-1.0921000000000001E-4	0.26900000000000002	4.9774000000000002E-5
-1.9890000000000001	-1.093E-4	0.27100000000000002	4.9901000000000002E-5
-1.99	-1.0938999999999999E-4	0.27300000000000002	4.9996E-5
-1.9910000000000001	-1.0948E-4	0.27500000000000002	5.0121999999999999E-5
-1.992	-1.0957E-4	0.27700000000000002	5.0185000000000001E-5
-1.9930000000000001	-1.0975E-4	0.27900000000000003	5.0185000000000001E-5
-1.994	-1.0975E-4	0.28100000000000003	5.0343000000000002E-5
-1.9950000000000001	-1.0993E-4	0.28299999999999997	5.0470000000000003E-5
-1.996	-1.1010000000000001E-4	0.28499999999999998	5.0565000000000001E-5
-1.9970000000000001	-1.1010000000000001E-4	0.28699999999999998	5.0627999999999997E-5
-1.998	-1.1027999999999999E-4	0.28899999999999998	5.0596000000000001E-5
-1.9990000000000001	-1.1027999999999999E-4	0.29099999999999998	5.0659999999999999E-5
-2	-1.1037E-4	0.29299999999999998	5.0691E-5
-2.0009999999999999	-1.1055E-4	0.29499999999999998	5.0785999999999998E-5
-2.0019999999999998	-1.1073000000000001E-4	0.29699999999999999	5.0943999999999999E-5
-2.0030000000000001	-1.1090999999999999E-4	0.29899999999999999	5.0943999999999999E-5
-2.004	-1.1109E-4	0.30099999999999999	5.1134000000000002E-5
-2.0049999999999999	-1.1109E-4	0.30299999999999999	5.1323999999999999E-5
-2.0059999999999998	-1.1118E-4	0.30499999999999999	5.1418999999999997E-5
-2.0070000000000001	-1.1127E-4	0.307	5.1481999999999999E-5
-2.008	-1.1145E-4	0.309	5.1514000000000002E-5
-2.0089999999999999	-1.1162000000000001E-4	0.311	5.1576999999999998E-5
-2.0099999999999998	-1.1171E-4	0.313	5.1703000000000003E-5
-2.0110000000000001	-1.1179999999999999E-4	0.315	5.1734999999999998E-5
-2.012	-1.1198E-4	0.317	5.1860999999999997E-5
-2.0129999999999999	-1.1207E-4	0.31900000000000001	5.1956000000000002E-5
-2.0139999999999998	-1.1225E-4	0.32100000000000001	5.2051E-5
-2.0150000000000001	-1.1234E-4	0.32300000000000001	5.2178000000000001E-5
-2.016	-1.1243000000000001E-4	0.32500000000000001	5.2303999999999999E-5
-2.0169999999999999	-1.1260999999999999E-4	0.32700000000000001	5.2367000000000002E-5
-2.0179999999999998	-1.1297E-4	0.32900000000000001	5.2494000000000003E-5
-2.0190000000000001	-1.1297E-4	0.33100000000000002	5.2620000000000001E-5
-2.02	-1.1315E-4	0.33300000000000002	5.2778000000000002E-5
-2.0209999999999999	-1.1332000000000001E-4	0.33500000000000002	5.2905000000000003E-5
-2.0219999999999998	-1.1349999999999999E-4	0.33700000000000002	5.3063000000000003E-5
-2.0230000000000001	-1.1368E-4	0.33900000000000002	5.3253E-5
-2.024	-1.1377E-4	0.34100000000000003	5.3347999999999998E-5
-2.0249999999999999	-1.1386E-4	0.34300000000000003	5.3505999999999999E-5
-2.0259999999999998	-1.1404E-4	0.34499999999999997	5.3695E-5
-2.0270000000000001	-1.1430999999999999E-4	0.34699999999999998	5.3822000000000001E-5
-2.028	-1.144E-4	0.34899999999999998	5.3980000000000002E-5
-2.0289999999999999	-1.1449E-4	0.35099999999999998	5.4107000000000002E-5
-2.0299999999999998	-1.1476000000000001E-4	0.35299999999999998	5.4265000000000003E-5
-2.0310000000000001	-1.1493E-4	0.35499999999999998	5.4453999999999997E-5
-2.032	-1.1502000000000001E-4	0.35699999999999998	5.4613E-5
-2.0329999999999999	-1.1519999999999999E-4	0.35899999999999999	5.4738999999999999E-5
-2.0339999999999998	-1.1547E-4	0.36099999999999999	5.4960000000000002E-5
-2.0350000000000001	-1.1565000000000001E-4	0.36299999999999999	5.5118000000000003E-5
-2.036	-1.1582999999999999E-4	0.36499999999999999	5.5276999999999999E-5
-2.0369999999999999	-1.1601E-4	0.36699999999999999	5.5402999999999998E-5
-2.0379999999999998	-1.161E-4	0.36899999999999999	5.5655999999999997E-5
-2.0390000000000001	-1.1628E-4	0.371	5.5813999999999998E-5
-2.04	-1.1663E-4	0.373	5.5971999999999999E-5
-2.0409999999999999	-1.1671999999999999E-4	0.375	5.6162000000000002E-5
-2.0419999999999998	-1.1681E-4	0.377	5.6382999999999999E-5
-2.0430000000000001	-1.1717E-4	0.379	5.6573000000000002E-5
-2.044	-1.1735000000000001E-4	0.38100000000000001	5.6795000000000001E-5
-2.0449999999999999	-1.1752999999999999E-4	0.38300000000000001	5.6953000000000002E-5
-2.0459999999999998	-1.178E-4	0.38500000000000001	5.7173999999999998E-5
-2.0470000000000002	-1.1797E-4	0.38700000000000001	5.7364000000000002E-5
-2.048	-1.1815E-4	0.38900000000000001	5.7522000000000003E-5
-2.0489999999999999	-1.1833E-4	0.39100000000000001	5.7679999999999997E-5
-2.0499999999999998	-1.1851E-4	0.39300000000000002	5.7933000000000003E-5
-2.0510000000000002	-1.1869E-4	0.39500000000000002	5.8122999999999999E-5
-2.052	-1.1896E-4	0.39700000000000002	5.8375999999999998E-5
-2.0529999999999999	-1.1923E-4	0.39900000000000002	5.8597000000000002E-5
-2.0539999999999998	-1.1967E-4	0.40100000000000002	5.8786999999999998E-5
-2.0550000000000002	-1.1993999999999999E-4	0.40300000000000002	5.9103E-5
-2.056	-1.2003E-4	0.40500000000000003	5.9450999999999997E-5
-2.0569999999999999	-1.2012E-4	0.40699999999999997	5.9546000000000002E-5
-2.0579999999999998	-1.203E-4	0.40899999999999997	5.9799000000000001E-5
-2.0590000000000002	-1.2066E-4	0.41099999999999998	6.0019999999999998E-5
-2.06	-1.2084E-4	0.41299999999999998	6.0304999999999999E-5
-2.0609999999999999	-1.2102E-4	0.41499999999999998	6.0494000000000001E-5
-2.0619999999999998	-1.2137E-4	0.41699999999999998	6.0715999999999999E-5
-2.0630000000000002	-1.2155E-4	0.41899999999999998	6.0968999999999999E-5
-2.0640000000000001	-1.2173E-4	0.42099999999999999	6.1253000000000005E-5
-2.0649999999999999	-1.22E-4	0.42299999999999999	6.1538000000000006E-5
-2.0659999999999998	-1.2235999999999999E-4	0.42499999999999999	6.1885999999999997E-5
-2.0670000000000002	-1.2244999999999999E-4	0.42699999999999999	6.2169999999999996E-5
-2.0680000000000001	-1.228E-4	0.42899999999999999	6.2487E-5
-2.069	-1.2307E-4	0.43099999999999999	6.2803000000000002E-5
-2.0699999999999998	-1.2333999999999999E-4	0.433	6.3119000000000003E-5
-2.0710000000000002	-1.2360999999999999E-4	0.435	6.3529999999999997E-5
-2.0720000000000001	-1.2388000000000001E-4	0.437	6.3878000000000001E-5
-2.073	-1.2415000000000001E-4	0.439	6.4163000000000002E-5
-2.0739999999999998	-1.2449999999999999E-4	0.441	6.4447000000000001E-5
-2.0750000000000002	-1.2468000000000001E-4	0.443	6.4763000000000003E-5
-2.0760000000000001	-1.2495E-4	0.44500000000000001	6.5079999999999994E-5
-2.077	-1.2531E-4	0.44700000000000001	6.5807000000000002E-5
-2.0779999999999998	-1.2567000000000001E-4	0.44900000000000001	6.6280999999999998E-5
-2.0790000000000002	-1.2594E-4	0.45100000000000001	6.6661000000000004E-5
-2.08	-1.2611E-4	0.45300000000000001	6.7104E-5
-2.081	-1.2656000000000001E-4	0.45500000000000002	6.7608999999999996E-5
-2.0819999999999999	-1.2692000000000001E-4	0.45700000000000002	6.8052000000000005E-5
-2.0830000000000002	-1.271E-4	0.45900000000000002	6.8558000000000003E-5
-2.0840000000000001	-1.2746E-4	0.46100000000000002	6.9000999999999999E-5
-2.085	-1.2789999999999999E-4	0.46300000000000002	6.9506999999999997E-5
-2.0859999999999999	-1.2816999999999999E-4	0.46500000000000002	6.9981000000000006E-5
-2.0870000000000002	-1.2852999999999999E-4	0.46700000000000003	7.0518999999999993E-5
-2.0880000000000001	-1.2898E-4	0.46899999999999997	7.1056000000000005E-5
-2.089	-1.2933000000000001E-4	0.47099999999999997	7.1562000000000004E-5
-2.09	-1.2951E-4	0.47299999999999998	7.2100000000000004E-5
-2.0910000000000002	-1.2996000000000001E-4	0.47499999999999998	7.2700999999999994E-5
-2.0920000000000001	-1.3040999999999999E-4	0.47699999999999998	7.3332999999999997E-5
-2.093	-1.3067999999999999E-4	0.47899999999999998	7.3934000000000001E-5
-2.0939999999999999	-1.3112E-4	0.48099999999999998	7.4503000000000001E-5
-2.0950000000000002	-1.3156999999999999E-4	0.48299999999999998	7.5135999999999993E-5
-2.0960000000000001	-1.3192999999999999E-4	0.48499999999999999	7.5799999999999999E-5
-2.097	-1.3229E-4	0.48699999999999999	7.6336999999999998E-5
-2.0979999999999999	-1.3273000000000001E-4	0.48899999999999999	7.7001000000000004E-5
-2.0990000000000002	-1.3300000000000001E-4	0.49099999999999999	7.7539000000000004E-5
-2.1	-1.3354E-4	0.49299999999999999	7.8139999999999994E-5
-2.101	-1.3407E-4	0.495	7.8614000000000003E-5
-2.1019999999999999	-1.3443E-4	0.497	7.9562999999999997E-5
-2.1030000000000002	-1.3488000000000001E-4	0.499	8.0352999999999995E-5
-2.1040000000000001	-1.3542E-4	0.501	8.0986E-5
-2.105	-1.3577000000000001E-4	0.503	8.1650000000000006E-5
-2.1059999999999999	-1.3640000000000001E-4	0.505	8.2346000000000001E-5
-2.1070000000000002	-1.3684999999999999E-4	0.50700000000000001	8.3135999999999998E-5
-2.1080000000000001	-1.3711999999999999E-4	0.50900000000000001	8.3737000000000001E-5
-2.109	-1.3756E-4	0.51100000000000001	8.4369999999999994E-5
-2.11	-1.381E-4	0.51300000000000001	8.4969999999999995E-5
-2.1110000000000002	-1.3863999999999999E-4	0.51500000000000001	8.5634E-5
-2.1120000000000001	-1.3899E-4	0.51700000000000002	8.6235000000000004E-5
-2.113	-1.3944000000000001E-4	0.51900000000000002	8.6805000000000007E-5
-2.1139999999999999	-1.3998E-4	0.52100000000000002	8.7436999999999996E-5
-2.1150000000000002	-1.4043000000000001E-4	0.52300000000000002	8.8069E-5
-2.1160000000000001	-1.4096000000000001E-4	0.52500000000000002	8.8670000000000003E-5
-2.117	-1.415E-4	0.52700000000000002	8.9271000000000006E-5
-2.1179999999999999	-1.4186E-4	0.52900000000000003	8.9745000000000002E-5
-2.1190000000000002	-1.4239E-4	0.53100000000000003	9.0315000000000005E-5
-2.12	-1.4292999999999999E-4	0.53300000000000003	9.0884000000000006E-5
-2.121	-1.4347000000000001E-4	0.53500000000000003	9.1358000000000002E-5
-2.1219999999999999	-1.44E-4	0.53700000000000003	9.1864E-5
-2.1230000000000002	-1.4454E-4	0.53900000000000003	9.2338999999999998E-5
-2.1240000000000001	-1.4507999999999999E-4	0.54100000000000004	9.2812999999999994E-5
-2.125	-1.4561000000000001E-4	0.54300000000000004	9.3256000000000003E-5
-2.1259999999999999	-1.4596999999999999E-4	0.54500000000000004	9.3572000000000005E-5
-2.1269999999999998	-1.4651000000000001E-4	0.54700000000000004	9.3919999999999995E-5
-2.1280000000000001	-1.4704E-4	0.54900000000000004	9.4331000000000002E-5
-2.129	-1.4757999999999999E-4	0.55100000000000005	9.4710000000000006E-5
-2.13	-1.4812000000000001E-4	0.55300000000000005	9.5057999999999997E-5
-2.1309999999999998	-1.4846999999999999E-4	0.55500000000000005	9.5373999999999999E-5
-2.1320000000000001	-1.4901000000000001E-4	0.55700000000000005	9.5691000000000003E-5
-2.133	-1.4955E-4	0.55900000000000005	9.5911999999999999E-5
-2.1339999999999999	-1.5008E-4	0.56100000000000005	9.6164999999999998E-5
-2.1349999999999998	-1.5061999999999999E-4	0.56299999999999994	9.6354999999999995E-5
-2.1360000000000001	-1.5116000000000001E-4	0.56499999999999995	9.6576000000000005E-5
-2.137	-1.5160999999999999E-4	0.56699999999999995	9.6733999999999999E-5
-2.1379999999999999	-1.5213999999999999E-4	0.56899999999999995	9.7019000000000001E-5
-2.1389999999999998	-1.5268000000000001E-4	0.57099999999999995	9.7145000000000006E-5
-2.14	-1.5312999999999999E-4	0.57299999999999995	9.7303E-5
-2.141	-1.5357000000000001E-4	0.57499999999999996	9.7398000000000005E-5
-2.1419999999999999	-1.5411E-4	0.57699999999999996	9.7492999999999996E-5
-2.1429999999999998	-1.5464999999999999E-4	0.57899999999999996	9.7620000000000004E-5
-2.1440000000000001	-1.55E-4	0.58099999999999996	9.7745999999999996E-5
-2.145	-1.5563E-4	0.58299999999999996	9.7872000000000001E-5
-2.1459999999999999	-1.5599E-4	0.58499999999999996	9.7998999999999995E-5
-2.1469999999999998	-1.5652E-4	0.58699999999999997	9.8061999999999997E-5
-2.1480000000000001	-1.5697000000000001E-4	0.58899999999999997	9.8251999999999994E-5
-2.149	-1.5741999999999999E-4	0.59099999999999997	9.8283999999999996E-5
-2.15	-1.5796000000000001E-4	0.59299999999999997	9.8377999999999999E-5
-2.1509999999999998	-1.5849000000000001E-4	0.59499999999999997	9.8505000000000006E-5
-2.1520000000000001	-1.5893999999999999E-4	0.59699999999999998	9.8663E-5
-2.153	-1.593E-4	0.59899999999999998	9.8789999999999994E-5
-2.1539999999999999	-1.5974000000000001E-4	0.60099999999999998	9.8948000000000002E-5
-2.1549999999999998	-1.6028E-4	0.60299999999999998	9.9136999999999996E-5
-2.1560000000000001	-1.6072999999999999E-4	0.60499999999999998	9.9264000000000004E-5
-2.157	-1.6134999999999999E-4	0.60699999999999998	9.9454E-5
-2.1579999999999999	-1.618E-4	0.60899999999999999	9.9738E-5
-2.1589999999999998	-1.6225000000000001E-4	0.61099999999999999	9.9833000000000005E-5
-2.16	-1.6260999999999999E-4	0.61299999999999999	1.0009E-4
-2.161	-1.6296E-4	0.61499999999999999	1.0034E-4
-2.1619999999999999	-1.6349999999999999E-4	0.61699999999999999	1.0066E-4
-2.1629999999999998	-1.6385999999999999E-4	0.61899999999999999	1.0088E-4
-2.1640000000000001	-1.6431E-4	0.621	1.0116E-4
-2.165	-1.6484E-4	0.623	1.0151E-4
-2.1659999999999999	-1.6511E-4	0.625	1.0189E-4
-2.1669999999999998	-1.6564999999999999E-4	0.627	1.0226999999999999E-4
-2.1680000000000001	-1.661E-4	0.629	1.0262E-4
-2.169	-1.6412999999999999E-4
-2.1680000000000001	-1.4846999999999999E-4
-2.1669999999999998	-1.3585999999999999E-4
-2.1659999999999999	-1.2951E-4
-2.165	-1.2540000000000001E-4
-2.1640000000000001	-1.2218E-4
-2.1629999999999998	-1.1932E-4
-2.1619999999999999	-1.1663E-4
-2.161	-1.1430999999999999E-4
-2.16	-1.1198E-4
-2.1589999999999998	-1.0993E-4
-2.1579999999999999	-1.0787E-4
-2.157	-1.059E-4
-2.1560000000000001	-1.0393E-4
-2.1549999999999998	-1.0213999999999999E-4
-2.1539999999999999	-1.0053E-4
-2.153	-9.8924000000000004E-5
-2.1520000000000001	-9.7224000000000003E-5
-2.1509999999999998	-9.5704000000000004E-5
-2.15	-9.4272999999999997E-5
-2.149	-9.2842000000000003E-5
-2.1480000000000001	-9.1321000000000002E-5
-2.1469999999999998	-8.9889999999999995E-5
-2.1459999999999999	-8.8646999999999993E-5
-2.145	-8.7331999999999997E-5
-2.1440000000000001	-8.6142000000000003E-5
-2.1429999999999998	-8.4899000000000001E-5
-2.1419999999999999	-8.3700000000000002E-5
-2.141	-8.2367999999999995E-5
-2.14	-8.1321000000000003E-5
-2.1389999999999998	-8.0265999999999993E-5
-2.1379999999999999	-7.8986999999999994E-5
-2.137	-7.7886999999999995E-5
-2.1360000000000001	-7.6903000000000006E-5
-2.1349999999999998	-7.5865000000000006E-5
-2.1339999999999999	-7.4845999999999995E-5
-2.133	-7.4014E-5
-2.1320000000000001	-7.2948999999999996E-5
-2.1309999999999998	-7.1975000000000001E-5
-2.13	-7.1052999999999999E-5
-2.129	-7.0086999999999995E-5
-2.1280000000000001	-6.9175000000000001E-5
-2.1269999999999998	-6.8351999999999999E-5
-2.1259999999999999	-6.7502000000000005E-5
-2.125	-6.6581000000000005E-5
-2.1240000000000001	-6.5758000000000003E-5
-2.1230000000000002	-6.4998000000000003E-5
-2.1219999999999999	-6.4228999999999998E-5
-2.121	-6.3441999999999993E-5
-2.12	-6.2707999999999997E-5
-2.1190000000000002	-6.1859000000000005E-5
-2.1179999999999999	-6.1142999999999994E-5
-2.117	-6.0553000000000001E-5
-2.1160000000000001	-5.9738999999999998E-5
-2.1150000000000002	-5.8996000000000002E-5
-2.1139999999999999	-5.8433000000000001E-5
-2.113	-5.7753000000000001E-5
-2.1120000000000001	-5.7090999999999999E-5
-2.1110000000000002	-5.6403000000000002E-5
-2.11	-5.5758999999999999E-5
-2.109	-5.5124000000000003E-5
-2.1080000000000001	-5.4506000000000003E-5
-2.1070000000000002	-5.3934000000000002E-5
-2.1059999999999999	-5.3263000000000001E-5
-2.105	-5.2744000000000002E-5
-2.1040000000000001	-5.2225999999999998E-5
-2.1030000000000002	-5.1688999999999999E-5
-2.1019999999999999	-5.1125000000000003E-5
-2.101	-5.0686999999999998E-5
-2.1	-4.9963000000000003E-5
-2.0990000000000002	-4.9425999999999997E-5
-2.0979999999999999	-4.8987999999999999E-5
-2.097	-4.8513999999999997E-5
-2.0960000000000001	-4.8031000000000001E-5
-2.0950000000000002	-4.7547999999999999E-5
-2.0939999999999999	-4.7055999999999998E-5
-2.093	-4.6554999999999997E-5
-2.0920000000000001	-4.6187999999999999E-5
-2.0910000000000002	-4.5759E-5
-2.09	-4.5151000000000002E-5
-2.089	-4.4829000000000001E-5
-2.0880000000000001	-4.4462000000000002E-5
-2.0870000000000002	-4.3952000000000002E-5
-2.0859999999999999	-4.3594000000000003E-5
-2.085	-4.3254000000000003E-5
-2.0840000000000001	-4.2753999999999998E-5
-2.0830000000000002	-4.2369E-5
-2.0819999999999999	-4.2128000000000001E-5
-2.081	-4.1582000000000003E-5
-2.08	-4.1295999999999999E-5
-2.0790000000000002	-4.0964999999999998E-5
-2.0779999999999998	-4.0589000000000001E-5
-2.077	-4.0187E-5
-2.0760000000000001	-3.9811000000000002E-5
-2.0750000000000002	-3.9551999999999997E-5
-2.0739999999999998	-3.9193999999999998E-5
-2.073	-3.8890000000000002E-5
-2.0720000000000001	-3.8504999999999998E-5
-2.0710000000000002	-3.8182999999999997E-5
-2.0699999999999998	-3.7914999999999999E-5
-2.069	-3.7700000000000002E-5
-2.0680000000000001	-3.7316E-5
-2.0670000000000002	-3.7038E-5
-2.0659999999999998	-3.6779000000000001E-5
-2.0649999999999999	-3.6457E-5
-2.0640000000000001	-3.6180000000000003E-5
-2.0630000000000002	-3.5867000000000001E-5
-2.0619999999999998	-3.5562000000000003E-5
-2.0609999999999999	-3.5348000000000001E-5
-2.06	-3.5097E-5
-2.0590000000000002	-3.4873999999999998E-5
-2.0579999999999998	-3.4427000000000001E-5
-2.0569999999999999	-3.4175999999999999E-5
-2.056	-3.3997E-5
-2.0550000000000002	-3.3738000000000001E-5
-2.0539999999999998	-3.3451999999999998E-5
-2.0529999999999999	-3.3067E-5
-2.052	-3.2978000000000002E-5
-2.0510000000000002	-3.2762999999999998E-5
-2.0499999999999998	-3.2583999999999998E-5
-2.0489999999999999	-3.2342000000000003E-5
-2.048	-3.2082999999999998E-5
-2.0470000000000002	-3.1931000000000003E-5
-2.0459999999999998	-3.1779000000000002E-5
-2.0449999999999999	-3.1483999999999999E-5
-2.044	-3.1313999999999999E-5
-2.0430000000000001	-3.1028000000000002E-5
-2.0419999999999998	-3.0723999999999999E-5
-2.0409999999999999	-3.0607E-5
-2.04	-3.0589000000000001E-5
-2.0390000000000001	-3.0294000000000002E-5
-2.0379999999999998	-2.9954000000000002E-5
-2.0369999999999999	-2.9819999999999999E-5
-2.036	-2.9658999999999998E-5
-2.0350000000000001	-2.9417999999999999E-5
-2.0339999999999998	-2.923E-5
-2.0329999999999999	-2.9113999999999999E-5
-2.032	-2.8853999999999999E-5
-2.0310000000000001	-2.8765E-5
-2.0299999999999998	-2.8586E-5
-2.0289999999999999	-2.83E-5
-2.028	-2.8255E-5
-2.0270000000000001	-2.813E-5
-2.0259999999999998	-2.7817000000000002E-5
-2.0249999999999999	-2.7699999999999999E-5
-2.024	-2.7486000000000001E-5
-2.0230000000000001	-2.7334E-5
-2.0219999999999998	-2.7146000000000001E-5
-2.0209999999999999	-2.6957999999999998E-5
-2.02	-2.6894999999999999E-5
-2.0190000000000001	-2.6733999999999998E-5
-2.0179999999999998	-2.6582000000000001E-5
-2.0169999999999999	-2.6367999999999999E-5
-2.016	-2.618E-5
-2.0150000000000001	-2.6089999999999999E-5
-2.0139999999999998	-2.5938000000000001E-5
-2.0129999999999999	-2.5803999999999999E-5
-2.012	-2.5741999999999998E-5
-2.0110000000000001	-2.5429E-5
-2.0099999999999998	-2.5276999999999999E-5
-2.0089999999999999	-2.5196000000000001E-5
-2.008	-2.5052999999999999E-5
-2.0070000000000001	-2.4865E-5
-2.0059999999999998	-2.4757999999999999E-5
-2.0049999999999999	-2.4785000000000001E-5
-2.004	-2.4488999999999999E-5
-2.0030000000000001	-2.4292999999999999E-5
-2.0019999999999998	-2.4114E-5
-2.0009999999999999	-2.3926000000000001E-5
-2	-2.3881000000000001E-5
-1.9990000000000001	-2.3853999999999999E-5
-1.998	-2.3640000000000001E-5
-1.9970000000000001	-2.3567999999999999E-5
-1.996	-2.3506000000000002E-5
-1.9950000000000001	-2.3309E-5
-1.994	-2.3237000000000001E-5
-1.9930000000000001	-2.3048999999999999E-5
-1.992	-2.2923999999999999E-5
-1.9910000000000001	-2.2781000000000001E-5
-1.99	-2.2753999999999999E-5
-1.9890000000000001	-2.2717999999999998E-5
-1.988	-2.2413999999999999E-5
-1.9870000000000001	-2.2289E-5
-1.986	-2.2271000000000001E-5
-1.9850000000000001	-2.2155E-5
-1.984	-2.1985E-5
-1.9830000000000001	-2.1869E-5
-1.982	-2.1806000000000001E-5
-1.9810000000000001	-2.16E-5
-1.98	-2.1583E-5
-1.9790000000000001	-2.1484E-5
-1.978	-2.1404E-5
-1.9770000000000001	-2.1296000000000001E-5
-1.976	-2.1243E-5
-1.9750000000000001	-2.1216000000000002E-5
-1.974	-2.0982999999999999E-5
-1.9730000000000001	-2.084E-5
-1.972	-2.0696999999999999E-5
-1.9710000000000001	-2.0571999999999999E-5
-1.97	-2.0545000000000001E-5
-1.9690000000000001	-2.0463999999999999E-5
-1.968	-2.0321000000000001E-5
-1.9670000000000001	-2.0259E-5
-1.966	-2.0106999999999999E-5
-1.9650000000000001	-1.9964000000000001E-5
-1.964	-1.9919E-5
-1.9630000000000001	-1.9910000000000001E-5
-1.962	-1.9820999999999999E-5
-1.9610000000000001	-1.9624E-5
-1.96	-1.9624E-5
-1.9590000000000001	-1.9490000000000001E-5
-1.958	-1.9275000000000001E-5
-1.9570000000000001	-1.9275000000000001E-5
-1.956	-1.9185E-5
-1.9550000000000001	-1.9114E-5
-1.954	-1.9051000000000001E-5
-1.9530000000000001	-1.8828E-5
-1.952	-1.8819000000000001E-5
-1.9510000000000001	-1.8496999999999999E-5
-1.95	-1.8425000000000001E-5
-1.9490000000000001	-1.8479E-5
-1.948	-1.8442999999999999E-5
-1.9470000000000001	-1.8372E-5
-1.946	-1.8272999999999999E-5
-1.9450000000000001	-1.8121000000000001E-5
-1.944	-1.8121000000000001E-5
-1.9430000000000001	-1.8023E-5
-1.9419999999999999	-1.7906000000000001E-5
-1.9410000000000001	-1.7853E-5
-1.94	-1.7808E-5
-1.9390000000000001	-1.7700999999999999E-5
-1.9379999999999999	-1.7700999999999999E-5
-1.9370000000000001	-1.7620000000000001E-5
-1.9359999999999999	-1.7495000000000001E-5
-1.9350000000000001	-1.7405999999999999E-5
-1.9339999999999999	-1.7271000000000001E-5
-1.9330000000000001	-1.7155000000000001E-5
-1.9319999999999999	-1.7227E-5
-1.931	-1.7146000000000002E-5
-1.93	-1.6994E-5
-1.929	-1.6957999999999999E-5
-1.9279999999999999	-1.6886999999999999E-5
-1.927	-1.6699000000000001E-5
-1.9259999999999999	-1.6690000000000001E-5
-1.925	-1.6735000000000002E-5
-1.9239999999999999	-1.6555999999999999E-5
-1.923	-1.6413E-5
-1.9219999999999999	-1.6385999999999999E-5
-1.921	-1.6376999999999999E-5
-1.92	-1.6234000000000001E-5
-1.919	-1.6180000000000001E-5
-1.9179999999999999	-1.5982999999999999E-5
-1.917	-1.5982999999999999E-5
-1.9159999999999999	-1.5974E-5
-1.915	-1.5875999999999998E-5
-1.9139999999999999	-1.5795999999999999E-5
-1.913	-1.5750999999999999E-5
-1.9119999999999999	-1.5715000000000001E-5
-1.911	-1.5644000000000001E-5
-1.91	-1.5536000000000002E-5
-1.909	-1.5517999999999999E-5
-1.9079999999999999	-1.5322E-5
-1.907	-1.5259000000000001E-5
-1.9059999999999999	-1.5169E-5
-1.905	-1.5152E-5
-1.9039999999999999	-1.5125E-5
-1.903	-1.5098E-5
-1.9019999999999999	-1.4973E-5
-1.901	-1.483E-5
-1.9	-1.483E-5
-1.899	-1.4739999999999999E-5
-1.8979999999999999	-1.4588E-5
-1.897	-1.4569999999999999E-5
-1.8959999999999999	-1.4623999999999999E-5
-1.895	-1.4481000000000001E-5
-1.8939999999999999	-1.4382000000000001E-5
-1.893	-1.4338000000000001E-5
-1.8919999999999999	-1.4266E-5
-1.891	-1.4212E-5
-1.89	-1.4204E-5
-1.889	-1.4042999999999999E-5
-1.8879999999999999	-1.3944000000000001E-5
-1.887	-1.3998E-5
-1.8859999999999999	-1.3882E-5
-1.885	-1.381E-5
-1.8839999999999999	-1.3828E-5
-1.883	-1.3738E-5
-1.8819999999999999	-1.3551E-5
-1.881	-1.3524E-5
-1.88	-1.347E-5
-1.879	-1.3399E-5
-1.8779999999999999	-1.3345E-5
-1.877	-1.3318E-5
-1.8759999999999999	-1.3166000000000001E-5
-1.875	-1.3077E-5
-1.8740000000000001	-1.3157E-5
-1.873	-1.3013999999999999E-5
-1.8720000000000001	-1.296E-5
-1.871	-1.2996000000000001E-5
-1.87	-1.2862E-5
-1.869	-1.2692E-5
-1.8680000000000001	-1.2692E-5
-1.867	-1.2629000000000001E-5
-1.8660000000000001	-1.2558000000000001E-5
-1.865	-1.2513E-5
-1.8640000000000001	-1.2459E-5
-1.863	-1.237E-5
-1.8620000000000001	-1.2218000000000001E-5
-1.861	-1.2298E-5
-1.86	-1.2235999999999999E-5
-1.859	-1.2065999999999999E-5
-1.8580000000000001	-1.2065999999999999E-5
-1.857	-1.1967000000000001E-5
-1.8560000000000001	-1.1815E-5
-1.855	-1.1753000000000001E-5
-1.8540000000000001	-1.169E-5
-1.853	-1.1644999999999999E-5
-1.8520000000000001	-1.1708E-5
-1.851	-1.1556000000000001E-5
-1.85	-1.1440000000000001E-5
-1.849	-1.1270000000000001E-5
-1.8480000000000001	-1.1063999999999999E-5
-1.847	-1.1090999999999999E-5
-1.8460000000000001	-1.1090999999999999E-5
-1.845	-1.1117999999999999E-5
-1.8440000000000001	-1.1037E-5
-1.843	-1.093E-5
-1.8420000000000001	-1.0920999999999999E-5
-1.841	-1.0742E-5
-1.84	-1.0696999999999999E-5
-1.839	-1.0715E-5
-1.8380000000000001	-1.059E-5
-1.837	-1.0429E-5
-1.8360000000000001	-1.0429E-5
-1.835	-1.0429E-5
-1.8340000000000001	-1.0322E-5
-1.833	-1.025E-5
-1.8320000000000001	-1.0142999999999999E-5
-1.831	-9.9638999999999996E-6
-1.83	-9.9371000000000001E-6
-1.829	-9.9729000000000007E-6
-1.8280000000000001	-9.8386999999999995E-6
-1.827	-9.6508999999999994E-6
-1.8260000000000001	-9.6687999999999997E-6
-1.825	-9.4540999999999998E-6
-1.8240000000000001	-9.4182999999999993E-6
-1.823	-9.5256000000000008E-6
-1.8220000000000001	-9.4361999999999995E-6
-1.821	-9.2930999999999992E-6
-1.82	-9.1768E-6
-1.819	-9.0605000000000007E-6
-1.8180000000000001	-8.9325999999999998E-6
-1.8169999999999999	-8.8888000000000003E-6
-1.8160000000000001	-8.7699000000000005E-6
-1.8149999999999999	-8.6956000000000002E-6
-1.8140000000000001	-8.6016999999999993E-6
-1.8129999999999999	-8.5292999999999998E-6
-1.8120000000000001	-8.4058000000000001E-6
-1.8109999999999999	-8.3073999999999994E-6
-1.81	-8.3173000000000008E-6
-1.8089999999999999	-8.1223000000000001E-6
-1.8080000000000001	-8.0337000000000007E-6
-1.8069999999999999	-8.0122999999999995E-6
-1.806	-7.8468000000000008E-6
-1.8049999999999999	-7.7770000000000002E-6
-1.804	-7.6437999999999996E-6
-1.8029999999999999	-7.5596999999999998E-6
-1.802	-7.4703000000000003E-6
-1.8009999999999999	-7.3950999999999997E-6
-1.8	-7.2841999999999996E-6
-1.7989999999999999	-7.1975000000000001E-6
-1.798	-7.1268000000000001E-6
-1.7969999999999999	-7.3763E-6
-1.796	-7.0025000000000003E-6
-1.7949999999999999	-6.6545000000000004E-6
-1.794	-6.6903000000000001E-6
-1.7929999999999999	-6.5687000000000003E-6
-1.792	-6.3691999999999999E-6
-1.7909999999999999	-6.2592000000000001E-6
-1.79	-6.2029000000000004E-6
-1.7889999999999999	-6.1160999999999998E-6
-1.788	-5.9479000000000003E-6
-1.7869999999999999	-5.9255999999999996E-6
-1.786	-5.7761999999999999E-6
-1.7849999999999999	-5.6376E-6
-1.784	-5.5373999999999997E-6
-1.7829999999999999	-5.3334999999999998E-6
-1.782	-5.2403999999999998E-6
-1.7809999999999999	-5.2457999999999998E-6
-1.78	-4.9908999999999999E-6
-1.7789999999999999	-4.9049999999999996E-6
-1.778	-4.8639000000000001E-6
-1.7769999999999999	-4.7762000000000001E-6
-1.776	-4.5338999999999999E-6
-1.7749999999999999	-4.3514000000000004E-6
-1.774	-4.2726999999999998E-6
-1.7729999999999999	-4.1376E-6
-1.772	-4.1296000000000002E-6
-1.7709999999999999	-4.0133000000000002E-6
-1.77	-3.8120000000000001E-6
-1.7689999999999999	-3.7181E-6
-1.768	-3.5839999999999999E-6
-1.7669999999999999	-3.4282999999999999E-6
-1.766	-3.2924E-6
-1.7649999999999999	-3.2548000000000002E-6
-1.764	-3.0732999999999999E-6
-1.7629999999999999	-2.9220999999999999E-6
-1.762	-2.8540999999999999E-6
-1.7609999999999999	-2.7307E-6
-1.76	-2.5857999999999999E-6
-1.7589999999999999	-2.4820000000000001E-6
-1.758	-2.3522999999999999E-6
-1.7569999999999999	-2.2039000000000002E-6
-1.756	-2.0947E-6
-1.7549999999999999	-2.0420000000000001E-6
-1.754	-1.9007000000000001E-6
-1.7529999999999999	-1.7871E-6
-1.752	-1.6224999999999999E-6
-1.7509999999999999	-1.4981999999999999E-6
-1.75	-1.432E-6
-1.7490000000000001	-1.3881999999999999E-6
-1.748	-1.1413E-6
-1.7470000000000001	-9.3735999999999997E-7
-1.746	-6.4023000000000001E-7
-1.7450000000000001	-7.7385999999999997E-7
-1.744	-6.9961999999999996E-7
-1.7430000000000001	-6.2010999999999996E-7
-1.742	-5.1269000000000002E-7
-1.7410000000000001	-3.3621999999999998E-7
-1.74	-2.4354999999999998E-7
-1.7390000000000001	-2.1645000000000001E-7
-1.738	-1.2039000000000001E-7
-1.7370000000000001	-1.5554000000000002E-8
-1.736	3.6868000000000003E-8
-1.7350000000000001	1.1466999999999999E-7
-1.734	1.7924000000000001E-7
-1.7330000000000001	2.4740000000000001E-7
-1.732	4.0643000000000002E-7
-1.7310000000000001	5.8897999999999997E-7
-1.73	5.7762000000000001E-7
-1.7290000000000001	7.5417999999999999E-7
-1.728	8.3101000000000003E-7
-1.7270000000000001	8.4236999999999999E-7
-1.726	8.8520999999999997E-7
-1.7250000000000001	9.7581999999999996E-7
-1.724	1.0152E-6
-1.7230000000000001	1.1233999999999999E-6
-1.722	1.2683E-6
-1.7210000000000001	1.2843999999999999E-6
-1.72	1.2683E-6
-1.7190000000000001	1.3792000000000001E-6
-1.718	1.4337999999999999E-6
-1.7170000000000001	1.4642000000000001E-6
-1.716	1.5796000000000001E-6
-1.7150000000000001	1.6564999999999999E-6
-1.714	1.6484E-6
-1.7130000000000001	1.7334E-6
-1.712	1.7397E-6
-1.7110000000000001	1.7504E-6
-1.71	1.8568E-6
-1.7090000000000001	1.9748999999999999E-6
-1.708	1.8694000000000001E-6
-1.7070000000000001	1.9551999999999999E-6
-1.706	2.0795000000000002E-6
-1.7050000000000001	2.1511E-6
-1.704	2.1735E-6
-1.7030000000000001	2.1905E-6
-1.702	2.3559000000000002E-6
-1.7010000000000001	2.3532000000000002E-6
-1.7	2.3192000000000002E-6
-1.6990000000000001	2.3327000000000001E-6
-1.698	2.3711E-6
-1.6970000000000001	2.4721999999999998E-6
-1.696	2.5053E-6
-1.6950000000000001	2.4623999999999999E-6
-1.694	2.6116999999999999E-6
-1.6930000000000001	2.7288999999999998E-6
-1.6919999999999999	2.5517999999999999E-6
-1.6910000000000001	2.7199999999999998E-6
-1.69	2.7638000000000001E-6
-1.6890000000000001	2.8845000000000001E-6
-1.6879999999999999	2.9023999999999999E-6
-1.6870000000000001	2.8227999999999999E-6
-1.6859999999999999	2.9337E-6
-1.6850000000000001	2.9758E-6
-1.6839999999999999	3.0097000000000002E-6
-1.6830000000000001	3.0974000000000002E-6
-1.6819999999999999	3.0527E-6
-1.681	3.0831000000000002E-6
-1.68	3.1493000000000001E-6
-1.679	3.1377E-6
-1.6779999999999999	3.2225999999999999E-6
-1.677	3.3291E-6
-1.6759999999999999	3.2834000000000002E-6
-1.675	3.4203000000000001E-6
-1.6739999999999999	3.5105999999999999E-6
-1.673	3.4945000000000002E-6
-1.6719999999999999	3.4686000000000001E-6
-1.671	3.5553000000000001E-6
-1.67	3.5329999999999999E-6
-1.669	3.4479999999999999E-6
-1.6679999999999999	3.6117000000000001E-6
-1.667	3.7181E-6
-1.6659999999999999	3.7467999999999999E-6
-1.665	3.7915E-6
-1.6639999999999999	3.8647999999999998E-6
-1.663	3.8738000000000001E-6
-1.6619999999999999	3.9373000000000004E-6
-1.661	3.9936000000000002E-6
-1.66	3.9488999999999996E-6
-1.659	4.0338999999999996E-6
-1.6579999999999999	4.1269000000000002E-6
-1.657	4.1331000000000003E-6
-1.6559999999999999	4.1743E-6
-1.655	4.2216999999999997E-6
-1.6539999999999999	4.2780000000000004E-6
-1.653	4.2672999999999998E-6
-1.6519999999999999	4.2432000000000003E-6
-1.651	4.4577999999999999E-6
-1.65	4.4550999999999999E-6
-1.649	4.5016999999999996E-6
-1.6479999999999999	4.5839000000000003E-6
-1.647	4.5347E-6
-1.6459999999999999	4.6268999999999997E-6
-1.645	4.8067000000000001E-6
-1.6439999999999999	4.9319000000000002E-6
-1.643	4.9659000000000002E-6
-1.6419999999999999	4.8996999999999999E-6
-1.641	4.8942999999999999E-6
-1.64	4.9292000000000002E-6
-1.639	4.9945000000000002E-6
-1.6379999999999999	5.0678E-6
-1.637	5.0956E-6
-1.6359999999999999	5.1259999999999997E-6
-1.635	5.2090999999999998E-6
-1.6339999999999999	5.1474E-6
-1.633	5.2341999999999998E-6
-1.6319999999999999	5.2565000000000004E-6
-1.631	5.1868E-6
-1.63	5.3147000000000001E-6
-1.629	5.3746000000000002E-6
-1.6279999999999999	5.3736999999999999E-6
-1.627	5.5276000000000002E-6
-1.6259999999999999	5.5338000000000003E-6
-1.625	5.5651000000000003E-6
-1.6240000000000001	5.6455999999999998E-6
-1.623	5.7046999999999998E-6
-1.6220000000000001	5.7664000000000004E-6
-1.621	5.7332999999999998E-6
-1.62	5.8128999999999999E-6
-1.619	5.8602999999999996E-6
-1.6180000000000001	5.8004000000000004E-6
-1.617	5.9380999999999999E-6
-1.6160000000000001	5.9264999999999999E-6
-1.615	5.9676000000000003E-6
-1.6140000000000001	6.0374E-6
-1.613	6.1689000000000003E-6
-1.6120000000000001	6.1850000000000001E-6
-1.611	6.1983999999999998E-6
-1.61	6.2698999999999999E-6
-1.609	6.3388000000000002E-6
-1.6080000000000001	6.3307999999999996E-6
-1.607	6.3388000000000002E-6
-1.6060000000000001	6.3782000000000002E-6
-1.605	6.3593999999999996E-6
-1.6040000000000001	6.5463000000000003E-6
-1.603	6.6008999999999998E-6
-1.6020000000000001	6.6510000000000004E-6
-1.601	6.7090999999999999E-6
-1.6	6.7734999999999996E-6
-1.599	6.6857999999999996E-6
-1.5980000000000001	6.7556000000000002E-6
-1.597	6.8522000000000002E-6
-1.5960000000000001	6.8933999999999999E-6
-1.595	6.9032000000000002E-6
-1.5940000000000001	7.0311000000000003E-6
-1.593	7.0874000000000001E-6
-1.5920000000000001	7.0874000000000001E-6
-1.591	7.0955000000000001E-6
-1.59	7.1778000000000001E-6
-1.589	7.0848000000000003E-6
-1.5880000000000001	7.2707999999999999E-6
-1.587	7.3424000000000002E-6
-1.5860000000000001	7.2931999999999999E-6
-1.585	7.4004999999999997E-6
-1.5840000000000001	7.4041E-6
-1.583	7.4273E-6
-1.5820000000000001	7.5293000000000001E-6
-1.581	7.6017000000000004E-6
-1.58	7.5426999999999998E-6
-1.579	7.5820999999999998E-6
-1.5780000000000001	7.6822000000000007E-6
-1.577	7.7493000000000005E-6
-1.5760000000000001	7.6992000000000008E-6
-1.575	7.8136999999999994E-6
-1.5740000000000001	7.9765000000000006E-6
-1.573	7.9801E-6
-1.5720000000000001	7.9640000000000003E-6
-1.571	8.0159000000000006E-6
-1.57	8.0606000000000004E-6
-1.569	8.1071000000000007E-6
-1.5680000000000001	8.1509000000000002E-6
-1.5669999999999999	8.0873999999999999E-6
-1.5660000000000001	8.1464000000000005E-6
-1.5649999999999999	8.2878000000000005E-6
-1.5640000000000001	8.2277999999999994E-6
-1.5629999999999999	8.3413999999999995E-6
-1.5620000000000001	8.4084999999999992E-6
-1.5609999999999999	8.4988000000000007E-6
-1.56	8.4835999999999995E-6
-1.5589999999999999	8.6186999999999993E-6
-1.5580000000000001	8.6410999999999993E-6
-1.5569999999999999	8.6098000000000001E-6
-1.556	8.7198000000000008E-6
-1.5549999999999999	8.6920000000000008E-6
-1.554	8.6786000000000002E-6
-1.5529999999999999	8.8101000000000006E-6
-1.552	8.9316999999999995E-6
-1.5509999999999999	8.8744999999999995E-6
-1.55	8.8933E-6
-1.5489999999999999	9.0157999999999993E-6
-1.548	9.0962999999999996E-6
-1.5469999999999999	9.1768E-6
-1.546	9.1768E-6
-1.5449999999999999	9.2214999999999997E-6
-1.544	9.2483999999999994E-6
-1.5429999999999999	9.2573000000000003E-6
-1.542	9.4452000000000006E-6
-1.5409999999999999	9.6865999999999997E-6
-1.54	9.5078000000000007E-6
-1.5389999999999999	9.6060999999999994E-6
-1.538	9.5256000000000008E-6
-1.5369999999999999	9.6060999999999994E-6
-1.536	9.7403000000000006E-6
-1.5349999999999999	9.6865999999999997E-6
-1.534	9.8029000000000006E-6
-1.5329999999999999	9.7760999999999995E-6
-1.532	9.8476000000000004E-6
-1.5309999999999999	9.9638999999999996E-6
-1.53	1.0009E-5
-1.5289999999999999	9.9997000000000002E-6
-1.528	9.9638999999999996E-6
-1.5269999999999999	1.0018E-5
-1.526	1.0142999999999999E-5
-1.5249999999999999	1.0223E-5
-1.524	1.0356999999999999E-5
-1.5229999999999999	1.0331E-5
-1.522	1.0383999999999999E-5
-1.5209999999999999	1.0429E-5
-1.52	1.0526999999999999E-5
-1.5189999999999999	1.0545E-5
-1.518	1.0563E-5
-1.5169999999999999	1.0679000000000001E-5
-1.516	1.0617E-5
-1.5149999999999999	1.0635000000000001E-5
-1.514	1.0778000000000001E-5
-1.5129999999999999	1.0858E-5
-1.512	1.0920999999999999E-5
-1.5109999999999999	1.0975000000000001E-5
-1.51	1.101E-5
-1.5089999999999999	1.1109E-5
-1.508	1.1198E-5
-1.5069999999999999	1.1297E-5
-1.506	1.1279E-5
-1.5049999999999999	1.1358999999999999E-5
-1.504	1.1430999999999999E-5
-1.5029999999999999	1.1297E-5
-1.502	1.1449E-5
-1.5009999999999999	1.1636E-5
-1.5	1.1663E-5
-1.4990000000000001	1.1671999999999999E-5
-1.498	1.1815E-5
-1.4970000000000001	1.1815E-5
-1.496	1.1797000000000001E-5
-1.4950000000000001	1.1932E-5
-1.494	1.2065999999999999E-5
-1.4930000000000001	1.2092999999999999E-5
-1.492	1.2173E-5
-1.4910000000000001	1.2262999999999999E-5
-1.49	1.2235999999999999E-5
-1.4890000000000001	1.2352E-5
-1.488	1.2379E-5
-1.4870000000000001	1.2405999999999999E-5
-1.486	1.2486E-5
-1.4850000000000001	1.2646999999999999E-5
-1.484	1.2719E-5
-1.4830000000000001	1.2763E-5
-1.482	1.2826000000000001E-5
-1.4810000000000001	1.2826000000000001E-5
-1.48	1.2916E-5
-1.4790000000000001	1.3040999999999999E-5
-1.478	1.3112000000000001E-5
-1.4770000000000001	1.3094E-5
-1.476	1.3229E-5
-1.4750000000000001	1.3363000000000001E-5
-1.474	1.3416E-5
-1.4730000000000001	1.3461E-5
-1.472	1.3594999999999999E-5
-1.4710000000000001	1.3621999999999999E-5
-1.47	1.3675999999999999E-5
-1.4690000000000001	1.3774000000000001E-5
-1.468	1.3774000000000001E-5
-1.4670000000000001	1.3890000000000001E-5
-1.466	1.4025E-5
-1.4650000000000001	1.4078E-5
-1.464	1.4015999999999999E-5
-1.4630000000000001	1.4168000000000001E-5
-1.462	1.4239E-5
-1.4610000000000001	1.4275E-5
-1.46	1.4355999999999999E-5
-1.4590000000000001	1.4534E-5
-1.458	1.4615E-5
-1.4570000000000001	1.4749000000000001E-5
-1.456	1.4820999999999999E-5
-1.4550000000000001	1.4803E-5
-1.454	1.4919000000000001E-5
-1.4530000000000001	1.508E-5
-1.452	1.5071E-5
-1.4510000000000001	1.5143000000000001E-5
-1.45	1.5322E-5
-1.4490000000000001	1.5285999999999999E-5
-1.448	1.5330000000000001E-5
-1.4470000000000001	1.5491000000000001E-5
-1.446	1.5617E-5
-1.4450000000000001	1.5625999999999999E-5
-1.444	1.5787E-5
-1.4430000000000001	1.5866999999999999E-5
-1.4419999999999999	1.5885000000000001E-5
-1.4410000000000001	1.5974E-5
-1.44	1.6082E-5
-1.4390000000000001	1.6341000000000002E-5
-1.4379999999999999	1.6422E-5
-1.4370000000000001	1.6314E-5
-1.4359999999999999	1.6252E-5
-1.4350000000000001	1.6636000000000001E-5
-1.4339999999999999	1.6592E-5
-1.4330000000000001	1.6636000000000001E-5
-1.4319999999999999	1.6878E-5
-1.431	1.6895999999999999E-5
-1.43	1.6957999999999999E-5
-1.429	1.7030000000000001E-5
-1.4279999999999999	1.7127999999999999E-5
-1.427	1.7306999999999999E-5
-1.4259999999999999	1.7306999999999999E-5
-1.425	1.7360999999999999E-5
-1.4239999999999999	1.7521999999999999E-5
-1.423	1.7513E-5
-1.4219999999999999	1.7674000000000001E-5
-1.421	1.7736000000000001E-5
-1.42	1.7825999999999998E-5
-1.419	1.7986999999999999E-5
-1.4179999999999999	1.8067000000000002E-5
-1.417	1.8121000000000001E-5
-1.4159999999999999	1.8202E-5
-1.415	1.8309E-5
-1.4139999999999999	1.8345000000000001E-5
-1.413	1.8363E-5
-1.4119999999999999	1.8515000000000001E-5
-1.411	1.8694000000000001E-5
-1.41	1.8729E-5
-1.409	1.8746999999999999E-5
-1.4079999999999999	1.8961999999999999E-5
-1.407	1.8980000000000001E-5
-1.4059999999999999	1.9051000000000001E-5
-1.405	1.9202999999999999E-5
-1.4039999999999999	1.9284E-5
-1.403	1.9436000000000002E-5
-1.4019999999999999	1.9454E-5
-1.401	1.9525E-5
-1.4	1.9596999999999999E-5
-1.399	1.9749E-5
-1.3979999999999999	1.9820999999999999E-5
-1.397	1.9775999999999998E-5
-1.3959999999999999	1.9973E-5
-1.395	2.0125000000000001E-5
-1.3939999999999999	2.0143E-5
-1.393	2.0205000000000001E-5
-1.3919999999999999	2.0366000000000001E-5
-1.391	2.0392999999999999E-5
-1.39	2.0536000000000001E-5
-1.389	2.0616999999999999E-5
-1.3879999999999999	2.0642999999999999E-5
-1.387	2.0750999999999998E-5
-1.3859999999999999	2.0930000000000001E-5
-1.385	2.0903E-5
-1.3839999999999999	2.1036999999999999E-5
-1.383	2.1225000000000001E-5
-1.3819999999999999	2.1268999999999999E-5
-1.381	2.1277999999999999E-5
-1.38	2.1466000000000001E-5
-1.379	2.1492999999999999E-5
-1.3779999999999999	2.1447999999999999E-5
-1.377	2.1654E-5
-1.3759999999999999	2.1851000000000001E-5
-1.375	2.1841999999999999E-5
-1.3740000000000001	2.1895999999999998E-5
-1.373	2.1957999999999999E-5
-1.3720000000000001	2.2082999999999998E-5
-1.371	2.2235E-5
-1.37	2.228E-5
-1.369	2.2361000000000002E-5
-1.3680000000000001	2.2405E-5
-1.367	2.2540000000000001E-5
-1.3660000000000001	2.2691999999999999E-5
-1.365	2.2682999999999999E-5
-1.3640000000000001	2.2710000000000001E-5
-1.363	2.2923999999999999E-5
-1.3620000000000001	2.2835000000000001E-5
-1.361	2.3023E-5
-1.36	2.3156999999999999E-5
-1.359	2.3112000000000002E-5
-1.3580000000000001	2.3281999999999998E-5
-1.357	2.3336000000000002E-5
-1.3560000000000001	2.3371E-5
-1.355	2.3541E-5
-1.3540000000000001	2.3693000000000002E-5
-1.353	2.3728999999999999E-5
-1.3520000000000001	2.3737999999999999E-5
-1.351	2.3791999999999999E-5
-1.35	2.3935E-5
-1.349	2.3935E-5
-1.3480000000000001	2.4087000000000002E-5
-1.347	2.4256999999999998E-5
-1.3460000000000001	2.4202999999999998E-5
-1.345	2.4284E-5
-1.3440000000000001	2.4426999999999998E-5
-1.343	2.4462999999999999E-5
-1.3420000000000001	2.4542999999999999E-5
-1.341	2.4686E-5
-1.34	2.4722000000000001E-5
-1.339	2.4749E-5
-1.3380000000000001	2.4811E-5
-1.337	2.5089E-5
-1.3360000000000001	2.5267999999999999E-5
-1.335	2.5142000000000001E-5
-1.3340000000000001	2.5196000000000001E-5
-1.333	2.5241000000000001E-5
-1.3320000000000001	2.5321E-5
-1.331	2.5437999999999999E-5
-1.33	2.5473000000000002E-5
-1.329	2.5536000000000001E-5
-1.3280000000000001	2.5633999999999999E-5
-1.327	2.5661E-5
-1.3260000000000001	2.5760000000000001E-5
-1.325	2.5768000000000001E-5
-1.3240000000000001	2.5867000000000002E-5
-1.323	2.5867000000000002E-5
-1.3220000000000001	2.6018999999999999E-5
-1.321	2.6081E-5
-1.32	2.6117000000000001E-5
-1.319	2.6216000000000001E-5
-1.3180000000000001	2.6341000000000001E-5
-1.3169999999999999	2.6359E-5
-1.3160000000000001	2.6429999999999999E-5
-1.3149999999999999	2.6511000000000001E-5
-1.3140000000000001	2.6511000000000001E-5
-1.3129999999999999	2.6618000000000002E-5
-1.3120000000000001	2.6707999999999999E-5
-1.3109999999999999	2.6672000000000001E-5
-1.31	2.6769999999999999E-5
-1.3089999999999999	2.6894999999999999E-5
-1.3080000000000001	2.6842000000000002E-5
-1.3069999999999999	2.6985E-5
-1.306	2.7137000000000001E-5
-1.3049999999999999	2.7146000000000001E-5
-1.304	2.7172999999999999E-5
-1.3029999999999999	2.7208000000000001E-5
-1.302	2.7316000000000001E-5
-1.3009999999999999	2.7342999999999999E-5
-1.3	2.7486000000000001E-5
-1.2989999999999999	2.7486000000000001E-5
-1.298	2.7432000000000001E-5
-1.2969999999999999	2.7593000000000002E-5
-1.296	2.7674E-5
-1.2949999999999999	2.7699999999999999E-5
-1.294	2.7727000000000001E-5
-1.2929999999999999	2.7852E-5
-1.292	2.7888000000000001E-5
-1.2909999999999999	2.7968999999999999E-5
-1.29	2.8005E-5
-1.2889999999999999	2.8058000000000001E-5
-1.288	2.8005E-5
-1.2869999999999999	2.8112000000000001E-5
-1.286	2.8263999999999999E-5
-1.2849999999999999	2.8272999999999998E-5
-1.284	2.8326999999999998E-5
-1.2829999999999999	2.8379999999999999E-5
-1.282	2.8371E-5
-1.2809999999999999	2.8407000000000001E-5
-1.28	2.8532000000000001E-5
-1.2789999999999999	2.8558999999999999E-5
-1.278	2.8622000000000001E-5
-1.2769999999999999	2.8631000000000001E-5
-1.276	2.8702000000000001E-5
-1.2749999999999999	2.8711E-5
-1.274	2.8792000000000001E-5
-1.2729999999999999	2.8818000000000001E-5
-1.272	2.8827E-5
-1.2709999999999999	2.8898999999999999E-5
-1.27	2.9006E-5
-1.2689999999999999	2.8962000000000002E-5
-1.268	2.9033000000000001E-5
-1.2669999999999999	2.9184999999999999E-5
-1.266	2.9203000000000001E-5
-1.2649999999999999	2.9328000000000001E-5
-1.264	2.9292E-5
-1.2629999999999999	2.9300999999999999E-5
-1.262	2.9319000000000002E-5
-1.2609999999999999	2.9337000000000001E-5
-1.26	2.9363999999999999E-5
-1.2589999999999999	2.9436000000000001E-5
-1.258	2.9587999999999999E-5
-1.2569999999999999	2.9606000000000001E-5
-1.256	2.957E-5
-1.2549999999999999	2.9686E-5
-1.254	2.9767000000000001E-5
-1.2529999999999999	2.9802E-5
-1.252	2.9802E-5
-1.2509999999999999	2.9901000000000001E-5
-1.25	2.9918999999999999E-5
-1.2490000000000001	2.9944999999999999E-5
-1.248	2.9989999999999999E-5
-1.2470000000000001	2.9963000000000001E-5
-1.246	3.0088999999999999E-5
-1.2450000000000001	3.0105999999999999E-5
-1.244	3.0052999999999998E-5
-1.2430000000000001	3.0178000000000001E-5
-1.242	3.0222999999999998E-5
-1.2410000000000001	3.0267E-5
-1.24	3.0329999999999999E-5
-1.2390000000000001	3.0312E-5
-1.238	3.0366E-5
-1.2370000000000001	3.0411000000000001E-5
-1.236	3.0518000000000002E-5
-1.2350000000000001	3.0589000000000001E-5
-1.234	3.0803999999999998E-5
-1.2330000000000001	3.0741000000000003E-5
-1.232	3.0741000000000003E-5
-1.2310000000000001	3.0670000000000003E-5
-1.23	3.0794999999999999E-5
-1.2290000000000001	3.0812999999999998E-5
-1.228	3.0840000000000003E-5
-1.2270000000000001	3.0803999999999998E-5
-1.226	3.0867000000000001E-5
-1.2250000000000001	3.0902000000000003E-5
-1.224	3.0902000000000003E-5
-1.2230000000000001	3.0902000000000003E-5
-1.222	3.0982999999999998E-5
-1.2210000000000001	3.0885E-5
-1.22	3.1108000000000001E-5
-1.2190000000000001	3.1099000000000002E-5
-1.218	3.1090000000000002E-5
-1.2170000000000001	3.1152999999999998E-5
-1.216	3.1241999999999997E-5
-1.2150000000000001	3.1260000000000002E-5
-1.214	3.1278000000000001E-5
-1.2130000000000001	3.1296E-5
-1.212	3.1350000000000003E-5
-1.2110000000000001	3.1287E-5
-1.21	3.1439000000000002E-5
-1.2090000000000001	3.1368000000000002E-5
-1.208	3.1402999999999997E-5
-1.2070000000000001	3.1492999999999998E-5
-1.206	3.1529000000000003E-5
-1.2050000000000001	3.1474999999999999E-5
-1.204	3.1563999999999998E-5
-1.2030000000000001	3.1698E-5
-1.202	3.1671999999999998E-5
-1.2010000000000001	3.1724999999999999E-5
-1.2	3.1698E-5
-1.1990000000000001	3.1690000000000003E-5
-1.198	3.1733999999999998E-5
-1.1970000000000001	3.1903999999999998E-5
-1.196	3.1832999999999998E-5
-1.1950000000000001	3.1788000000000001E-5
-1.194	3.1859000000000001E-5
-1.1930000000000001	3.1931000000000003E-5
-1.1919999999999999	3.1931000000000003E-5
-1.1910000000000001	3.1940000000000003E-5
-1.19	3.2064999999999999E-5
-1.1890000000000001	3.2064999999999999E-5
-1.1879999999999999	3.2064999999999999E-5
-1.1870000000000001	3.2146E-5
-1.1859999999999999	3.2110000000000003E-5
-1.1850000000000001	3.2190000000000002E-5
-1.1839999999999999	3.2234999999999999E-5
-1.1830000000000001	3.2298000000000001E-5
-1.1819999999999999	3.2271000000000003E-5
-1.181	3.2378000000000001E-5
-1.18	3.2289000000000002E-5
-1.179	3.2342000000000003E-5
-1.1779999999999999	3.2325E-5
-1.177	3.2404999999999999E-5
-1.1759999999999999	3.2459000000000002E-5
-1.175	3.2413999999999998E-5
-1.1739999999999999	3.2548000000000001E-5
-1.173	3.2486E-5
-1.1719999999999999	3.2530000000000002E-5
-1.171	3.2601999999999997E-5
-1.17	3.2548000000000001E-5
-1.169	3.2566E-5
-1.1679999999999999	3.2672999999999997E-5
-1.167	3.2638000000000002E-5
-1.1659999999999999	3.2700000000000002E-5
-1.165	3.2744999999999999E-5
-1.1639999999999999	3.2808000000000002E-5
-1.163	3.2780999999999997E-5
-1.1619999999999999	3.2799000000000002E-5
-1.161	3.2771999999999997E-5
-1.1599999999999999	3.2833999999999998E-5
-1.159	3.2950999999999997E-5
-1.1579999999999999	3.2914999999999999E-5
-1.157	3.2799000000000002E-5
-1.1559999999999999	3.2870000000000002E-5
-1.155	3.2941999999999997E-5
-1.1539999999999999	3.3012999999999997E-5
-1.153	3.3003999999999998E-5
-1.1519999999999999	3.3093999999999999E-5
-1.151	3.3093999999999999E-5
-1.1499999999999999	3.3201000000000003E-5
-1.149	3.3219000000000002E-5
-1.1479999999999999	3.3164999999999998E-5
-1.147	3.3147E-5
-1.1459999999999999	3.3210000000000002E-5
-1.145	3.3272999999999998E-5
-1.1439999999999999	3.3228000000000001E-5
-1.143	3.3343999999999998E-5
-1.1419999999999999	3.3317E-5
-1.141	3.3290999999999997E-5
-1.1399999999999999	3.3398000000000001E-5
-1.139	3.3371000000000003E-5
-1.1379999999999999	3.3352999999999997E-5
-1.137	3.3522999999999997E-5
-1.1359999999999999	3.3568000000000001E-5
-1.135	3.3504999999999999E-5
-1.1339999999999999	3.3541000000000003E-5
-1.133	3.3603999999999999E-5
-1.1319999999999999	3.3756E-5
-1.131	3.3835999999999999E-5
-1.1299999999999999	3.3747000000000001E-5
-1.129	3.3764999999999999E-5
-1.1279999999999999	3.3665999999999999E-5
-1.127	3.3756E-5
-1.1259999999999999	3.3756E-5
-1.125	3.3791000000000002E-5
-1.1240000000000001	3.3871999999999997E-5
-1.123	3.3899000000000002E-5
-1.1220000000000001	3.3827E-5
-1.121	3.3890000000000002E-5
-1.1200000000000001	3.3871999999999997E-5
-1.119	3.3853999999999998E-5
-1.1180000000000001	3.3926E-5
-1.117	3.3979000000000001E-5
-1.1160000000000001	3.3908000000000001E-5
-1.115	3.3988000000000001E-5
-1.1140000000000001	3.4096E-5
-1.113	3.4158000000000001E-5
-1.1120000000000001	3.4096E-5
-1.111	3.4149000000000001E-5
-1.1100000000000001	3.4248000000000001E-5
-1.109	3.4149000000000001E-5
-1.1080000000000001	3.4230000000000003E-5
-1.107	3.4282999999999997E-5
-1.1060000000000001	3.4193999999999998E-5
-1.105	3.4292000000000003E-5
-1.1040000000000001	3.4292000000000003E-5
-1.103	3.4310000000000002E-5
-1.1020000000000001	3.4372999999999998E-5
-1.101	3.4434999999999998E-5
-1.1000000000000001	3.4434999999999998E-5
-1.099	3.4418000000000001E-5
-1.0980000000000001	3.4434999999999998E-5
-1.097	3.4498000000000001E-5
-1.0960000000000001	3.4524999999999999E-5
-1.095	3.4551999999999997E-5
-1.0940000000000001	3.4659000000000001E-5
-1.093	3.4570000000000003E-5
-1.0920000000000001	3.4622999999999997E-5
-1.091	3.4668000000000001E-5
-1.0900000000000001	3.4632000000000003E-5
-1.089	3.4740000000000003E-5
-1.0880000000000001	3.4783999999999998E-5
-1.087	3.4712999999999998E-5
-1.0860000000000001	3.4730999999999997E-5
-1.085	3.4909000000000001E-5
-1.0840000000000001	3.4882999999999998E-5
-1.083	3.4856E-5
-1.0820000000000001	3.4981000000000003E-5
-1.081	3.4909000000000001E-5
-1.08	3.4891999999999997E-5
-1.079	3.5017E-5
-1.0780000000000001	3.5052999999999998E-5
-1.077	3.4999000000000002E-5
-1.0760000000000001	3.5105999999999999E-5
-1.075	3.5169000000000002E-5
-1.0740000000000001	3.5187E-5
-1.073	3.5222999999999998E-5
-1.0720000000000001	3.5293999999999998E-5
-1.071	3.5249000000000001E-5
-1.07	3.5249000000000001E-5
-1.069	3.5275999999999999E-5
-1.0680000000000001	3.5222999999999998E-5
-1.0669999999999999	3.5222999999999998E-5
-1.0660000000000001	3.5330000000000002E-5
-1.0649999999999999	3.5330000000000002E-5
-1.0640000000000001	3.5366E-5
-1.0629999999999999	3.5500000000000002E-5
-1.0620000000000001	3.5598E-5
-1.0609999999999999	3.5527000000000001E-5
-1.06	3.5527000000000001E-5
-1.0589999999999999	3.5580000000000002E-5
-1.0580000000000001	3.5553000000000003E-5
-1.0569999999999999	3.5651999999999997E-5
-1.056	3.5670000000000002E-5
-1.0549999999999999	3.5536E-5
-1.054	3.5633999999999998E-5
-1.0529999999999999	3.5732000000000003E-5
-1.052	3.5697000000000001E-5
-1.0509999999999999	3.5750000000000002E-5
-1.05	3.5831000000000003E-5
-1.0489999999999999	3.5849000000000002E-5
-1.048	3.5920000000000002E-5
-1.0469999999999999	3.5911000000000002E-5
-1.046	3.5831000000000003E-5
-1.0449999999999999	3.5867000000000001E-5
-1.044	3.6028000000000001E-5
-1.0429999999999999	3.6099000000000001E-5
-1.042	3.5964999999999999E-5
-1.0409999999999999	3.6010000000000003E-5
-1.04	3.6108000000000001E-5
-1.0389999999999999	3.6044999999999998E-5
-1.038	3.6062999999999997E-5
-1.0369999999999999	3.6196999999999999E-5
-1.036	3.6171000000000003E-5
-1.0349999999999999	3.6196999999999999E-5
-1.034	3.6313999999999998E-5
-1.0329999999999999	3.6260000000000002E-5
-1.032	3.6251000000000002E-5
-1.0309999999999999	3.6375999999999999E-5
-1.03	3.6457E-5
-1.0289999999999999	3.6689000000000001E-5
-1.028	3.6528E-5
-1.0269999999999999	3.6483999999999998E-5
-1.026	3.6536999999999999E-5
-1.0249999999999999	3.6536999999999999E-5
-1.024	3.6600000000000002E-5
-1.0229999999999999	3.6554999999999998E-5
-1.022	3.6600000000000002E-5
-1.0209999999999999	3.6636E-5
-1.02	3.6618000000000001E-5
-1.0189999999999999	3.6618000000000001E-5
-1.018	3.6742999999999997E-5
-1.0169999999999999	3.6706999999999999E-5
-1.016	3.6680000000000001E-5
-1.0149999999999999	3.6761000000000003E-5
-1.014	3.6724999999999998E-5
-1.0129999999999999	3.6788000000000001E-5
-1.012	3.6885999999999999E-5
-1.0109999999999999	3.6868E-5
-1.01	3.6885999999999999E-5
-1.0089999999999999	3.6949000000000001E-5
-1.008	3.6949000000000001E-5
-1.0069999999999999	3.6912999999999997E-5
-1.006	3.6993999999999999E-5
-1.0049999999999999	3.7038E-5
-1.004	3.6984999999999999E-5
-1.0029999999999999	3.6993999999999999E-5
-1.002	3.7055999999999999E-5
-1.0009999999999999	3.7092000000000003E-5
-1	3.7128000000000001E-5
-0.999	3.7154999999999999E-5
-0.998	3.7199000000000001E-5
-0.997	3.7208E-5
-0.996	3.7307E-5
-0.995	3.7298000000000001E-5
-0.99399999999999999	3.7271000000000003E-5
-0.99299999999999999	3.7351000000000002E-5
-0.99199999999999999	3.7387E-5
-0.99099999999999999	3.7271000000000003E-5
-0.99	3.7307E-5
-0.98899999999999999	3.7413999999999998E-5
-0.98799999999999999	3.7360000000000001E-5
-0.98699999999999999	3.7369000000000001E-5
-0.98599999999999999	3.7459000000000002E-5
-0.98499999999999999	3.7503000000000003E-5
-0.98399999999999999	3.7548E-5
-0.98299999999999998	3.7601999999999997E-5
-0.98199999999999998	3.7565999999999999E-5
-0.98099999999999998	3.7539000000000001E-5
-0.98	3.7654999999999998E-5
-0.97899999999999998	3.7735999999999999E-5
-0.97799999999999998	3.7682000000000003E-5
-0.97699999999999998	3.7727E-5
-0.97599999999999998	3.7753999999999998E-5
-0.97499999999999998	3.7620000000000002E-5
-0.97399999999999998	3.7700000000000002E-5
-0.97299999999999998	3.7709000000000001E-5
-0.97199999999999998	3.7790000000000002E-5
-0.97099999999999997	3.7861000000000002E-5
-0.97	3.7905999999999999E-5
-0.96899999999999997	3.7861000000000002E-5
-0.96799999999999997	3.7914999999999999E-5
-0.96699999999999997	3.7932999999999997E-5
-0.96599999999999997	3.7932999999999997E-5
-0.96499999999999997	3.7806999999999999E-5
-0.96399999999999997	3.7888E-5
-0.96299999999999997	3.7959E-5
-0.96199999999999997	3.8003999999999997E-5
-0.96099999999999997	3.7994999999999998E-5
-0.96	3.8012999999999997E-5
-0.95899999999999996	3.8022000000000003E-5
-0.95799999999999996	3.8102999999999998E-5
-0.95699999999999996	3.8102999999999998E-5
-0.95599999999999996	3.8102999999999998E-5
-0.95499999999999996	3.8192000000000003E-5
-0.95399999999999996	3.8219000000000001E-5
-0.95299999999999996	3.8182999999999997E-5
-0.95199999999999996	3.8084999999999999E-5
-0.95099999999999996	3.8164999999999998E-5
-0.95	3.8228000000000001E-5
-0.94899999999999995	3.8192000000000003E-5
-0.94799999999999995	3.8254999999999999E-5
-0.94699999999999995	3.8316999999999999E-5
-0.94599999999999995	3.8245999999999999E-5
-0.94499999999999995	3.8334999999999998E-5
-0.94399999999999995	3.8398000000000001E-5
-0.94299999999999995	3.8228000000000001E-5
-0.94199999999999995	3.8343999999999997E-5
-0.94099999999999995	3.8415999999999999E-5
-0.94	3.8371000000000002E-5
-0.93899999999999995	3.8343999999999997E-5
-0.93799999999999994	3.8433999999999998E-5
-0.93700000000000006	3.8398000000000001E-5
-0.93600000000000005	3.8433999999999998E-5
-0.93500000000000005	3.8469E-5
-0.93400000000000005	3.8504999999999998E-5
-0.93300000000000005	3.8522999999999997E-5
-0.93200000000000005	3.8495999999999999E-5
-0.93100000000000005	3.8513999999999998E-5
-0.93	3.8577E-5
-0.92900000000000005	3.8594999999999999E-5
-0.92800000000000005	3.8603000000000003E-5
-0.92700000000000005	3.8872000000000003E-5
-0.92600000000000005	3.8835999999999999E-5
-0.92500000000000004	3.8747E-5
-0.92400000000000004	3.8683999999999998E-5
-0.92300000000000004	3.8674999999999998E-5
-0.92200000000000004	3.8747E-5
-0.92100000000000004	3.8747E-5
-0.92	3.8692999999999997E-5
-0.91900000000000004	3.8756E-5
-0.91800000000000004	3.8835999999999999E-5
-0.91700000000000004	3.8738000000000001E-5
-0.91600000000000004	3.8800000000000001E-5
-0.91500000000000004	3.8818E-5
-0.91400000000000003	3.8683999999999998E-5
-0.91300000000000003	3.8763999999999997E-5
-0.91200000000000003	3.8844999999999998E-5
-0.91100000000000003	3.8747E-5
-0.91	3.8800000000000001E-5
-0.90900000000000003	3.8908000000000001E-5
-0.90800000000000003	3.8943000000000003E-5
-0.90700000000000003	3.8924999999999997E-5
-0.90600000000000003	3.8908000000000001E-5
-0.90500000000000003	3.8924999999999997E-5
-0.90400000000000003	3.8872000000000003E-5
-0.90300000000000002	3.8872000000000003E-5
-0.90200000000000002	3.8979000000000001E-5
-0.90100000000000002	3.8872000000000003E-5
-0.9	3.8961000000000002E-5
-0.89900000000000002	3.9042000000000003E-5
-0.89800000000000002	3.8881000000000003E-5
-0.89700000000000002	3.8933999999999997E-5
-0.89600000000000002	3.9069000000000002E-5
-0.89500000000000002	3.9005999999999999E-5
-0.89400000000000002	3.9078000000000001E-5
-0.89300000000000002	3.9023999999999998E-5
-0.89200000000000002	3.9032999999999997E-5
-0.89100000000000001	3.9051000000000003E-5
-0.89	3.9103999999999997E-5
-0.88900000000000001	3.9032999999999997E-5
-0.88800000000000001	3.8952000000000002E-5
-0.88700000000000001	3.9051000000000003E-5
-0.88600000000000001	3.9122000000000003E-5
-0.88500000000000001	3.9140000000000001E-5
-0.88400000000000001	3.9167E-5
-0.88300000000000001	3.9122000000000003E-5
-0.88200000000000001	3.9113000000000003E-5
-0.88100000000000001	3.9140000000000001E-5
-0.88	3.9212000000000003E-5
-0.879	3.9175999999999999E-5
-0.878	3.9202999999999997E-5
-0.877	3.9167E-5
-0.876	3.9158E-5
-0.875	3.9184999999999998E-5
-0.874	3.9140000000000001E-5
-0.873	3.9202999999999997E-5
-0.872	3.9255999999999998E-5
-0.871	3.9328E-5
-0.87	3.9264999999999998E-5
-0.86899999999999999	3.9239000000000002E-5
-0.86799999999999999	3.9301000000000002E-5
-0.86699999999999999	3.9337E-5
-0.86599999999999999	3.9301000000000002E-5
-0.86499999999999999	3.9239000000000002E-5
-0.86399999999999999	3.9273999999999997E-5
-0.86299999999999999	3.9255999999999998E-5
-0.86199999999999999	3.9273999999999997E-5
-0.86099999999999999	3.9283000000000003E-5
-0.86	3.9255999999999998E-5
-0.85899999999999999	3.9345999999999999E-5
-0.85799999999999998	3.9363999999999998E-5
-0.85699999999999998	3.9363999999999998E-5
-0.85599999999999998	3.9319000000000001E-5
-0.85499999999999998	3.9363999999999998E-5
-0.85399999999999998	3.9345999999999999E-5
-0.85299999999999998	3.9255999999999998E-5
-0.85199999999999998	3.9292000000000003E-5
-0.85099999999999998	3.9319000000000001E-5
-0.85	3.9246999999999999E-5
-0.84899999999999998	3.9283000000000003E-5
-0.84799999999999998	3.9328E-5
-0.84699999999999998	3.9310000000000001E-5
-0.84599999999999997	3.9381999999999997E-5
-0.84499999999999997	3.9425999999999998E-5
-0.84399999999999997	3.9443999999999997E-5
-0.84299999999999997	3.9391000000000003E-5
-0.84199999999999997	3.9337E-5
-0.84099999999999997	3.9337E-5
-0.84	3.9434999999999998E-5
-0.83899999999999997	3.9471000000000002E-5
-0.83799999999999997	3.9391000000000003E-5
-0.83699999999999997	3.9301000000000002E-5
-0.83599999999999997	3.9372999999999997E-5
-0.83499999999999996	3.9425999999999998E-5
-0.83399999999999996	3.9363999999999998E-5
-0.83299999999999996	3.9372999999999997E-5
-0.83199999999999996	3.9443999999999997E-5
-0.83099999999999996	3.9416999999999999E-5
-0.83	3.9416999999999999E-5
-0.82899999999999996	3.9434999999999998E-5
-0.82799999999999996	3.9434999999999998E-5
-0.82699999999999996	3.9400000000000002E-5
-0.82599999999999996	3.9434999999999998E-5
-0.82499999999999996	3.9542999999999997E-5
-0.82399999999999995	3.9703999999999998E-5
-0.82299999999999995	3.9578E-5
-0.82199999999999995	3.9524999999999999E-5
-0.82099999999999995	3.9425999999999998E-5
-0.82	3.9443999999999997E-5
-0.81899999999999995	3.9507E-5
-0.81799999999999995	3.9489000000000001E-5
-0.81699999999999995	3.9515999999999999E-5
-0.81599999999999995	3.9507E-5
-0.81499999999999995	3.9391000000000003E-5
-0.81399999999999995	3.9507E-5
-0.81299999999999994	3.9507E-5
-0.81200000000000006	3.9416999999999999E-5
-0.81100000000000005	3.9489000000000001E-5
-0.81	3.9489000000000001E-5
-0.80900000000000005	3.9471000000000002E-5
-0.80800000000000005	3.9434999999999998E-5
-0.80700000000000005	3.9480000000000001E-5
-0.80600000000000005	3.9425999999999998E-5
-0.80500000000000005	3.9443999999999997E-5
-0.80400000000000005	3.9489000000000001E-5
-0.80300000000000005	3.9498E-5
-0.80200000000000005	3.9416999999999999E-5
-0.80100000000000005	3.9480000000000001E-5
-0.8	3.9507E-5
-0.79900000000000004	3.9407999999999999E-5
-0.79800000000000004	3.9372999999999997E-5
-0.79700000000000004	3.9381999999999997E-5
-0.79600000000000004	3.9425999999999998E-5
-0.79500000000000004	3.9416999999999999E-5
-0.79400000000000004	3.9515999999999999E-5
-0.79300000000000004	3.9542999999999997E-5
-0.79200000000000004	3.9400000000000002E-5
-0.79100000000000004	3.9507E-5
-0.79	3.9480000000000001E-5
-0.78900000000000003	3.9400000000000002E-5
-0.78800000000000003	3.9425999999999998E-5
-0.78700000000000003	3.9400000000000002E-5
-0.78600000000000003	3.9363999999999998E-5
-0.78500000000000003	3.9453000000000003E-5
-0.78400000000000003	3.9471000000000002E-5
-0.78300000000000003	3.9434999999999998E-5
-0.78200000000000003	3.9453000000000003E-5
-0.78100000000000003	3.9425999999999998E-5
-0.78	3.9453000000000003E-5
-0.77900000000000003	3.9489000000000001E-5
-0.77800000000000002	3.9471000000000002E-5
-0.77700000000000002	3.9462000000000003E-5
-0.77600000000000002	3.9372999999999997E-5
-0.77500000000000002	3.9416999999999999E-5
-0.77400000000000002	3.9462000000000003E-5
-0.77300000000000002	3.9471000000000002E-5
-0.77200000000000002	3.9434999999999998E-5
-0.77100000000000002	3.9453000000000003E-5
-0.77	3.9372999999999997E-5
-0.76900000000000002	3.9345999999999999E-5
-0.76800000000000002	3.9462000000000003E-5
-0.76700000000000002	3.9381999999999997E-5
-0.76600000000000001	3.9372999999999997E-5
-0.76500000000000001	3.9434999999999998E-5
-0.76400000000000001	3.9443999999999997E-5
-0.76300000000000001	3.9391000000000003E-5
-0.76200000000000001	3.9345999999999999E-5
-0.76100000000000001	3.9337E-5
-0.76	3.9292000000000003E-5
-0.75900000000000001	3.9425999999999998E-5
-0.75800000000000001	3.9391000000000003E-5
-0.75700000000000001	3.9337E-5
-0.75600000000000001	3.9319000000000001E-5
-0.755	3.9425999999999998E-5
-0.754	3.9400000000000002E-5
-0.753	3.9345999999999999E-5
-0.752	3.9381999999999997E-5
-0.751	3.9337E-5
-0.75	3.9310000000000001E-5
-0.749	3.9354999999999998E-5
-0.748	3.9239000000000002E-5
-0.747	3.9255999999999998E-5
-0.746	3.9292000000000003E-5
-0.745	3.9319000000000001E-5
-0.74399999999999999	3.9255999999999998E-5
-0.74299999999999999	3.9310000000000001E-5
-0.74199999999999999	3.9264999999999998E-5
-0.74099999999999999	3.9283000000000003E-5
-0.74	3.9337E-5
-0.73899999999999999	3.9328E-5
-0.73799999999999999	3.9230000000000002E-5
-0.73699999999999999	3.9283000000000003E-5
-0.73599999999999999	3.9301000000000002E-5
-0.73499999999999999	3.9122000000000003E-5
-0.73399999999999999	3.9193999999999998E-5
-0.73299999999999998	3.9246999999999999E-5
-0.73199999999999998	3.9264999999999998E-5
-0.73099999999999998	3.9202999999999997E-5
-0.73	3.9264999999999998E-5
-0.72899999999999998	3.9255999999999998E-5
-0.72799999999999998	3.9255999999999998E-5
-0.72699999999999998	3.9255999999999998E-5
-0.72599999999999998	3.9131000000000002E-5
-0.72499999999999998	3.9140000000000001E-5
-0.72399999999999998	3.9212000000000003E-5
-0.72299999999999998	3.9184999999999998E-5
-0.72199999999999998	3.9416999999999999E-5
-0.72099999999999997	3.9292000000000003E-5
-0.72	3.9230000000000002E-5
-0.71899999999999997	3.9175999999999999E-5
-0.71799999999999997	3.9230000000000002E-5
-0.71699999999999997	3.9221000000000003E-5
-0.71599999999999997	3.9175999999999999E-5
-0.71499999999999997	3.9140000000000001E-5
-0.71399999999999997	3.9167E-5
-0.71299999999999997	3.9140000000000001E-5
-0.71199999999999997	3.9060000000000002E-5
-0.71099999999999997	3.9131000000000002E-5
-0.71	3.9131000000000002E-5
-0.70899999999999996	3.8996999999999999E-5
-0.70799999999999996	3.9069000000000002E-5
-0.70699999999999996	3.9113000000000003E-5
-0.70599999999999996	3.9032999999999997E-5
-0.70499999999999996	3.9149000000000001E-5
-0.70399999999999996	3.9122000000000003E-5
-0.70299999999999996	3.9051000000000003E-5
-0.70199999999999996	3.9051000000000003E-5
-0.70099999999999996	3.9032999999999997E-5
-0.7	3.9051000000000003E-5
-0.69899999999999995	3.9032999999999997E-5
-0.69799999999999995	3.9005999999999999E-5
-0.69699999999999995	3.8943000000000003E-5
-0.69599999999999995	3.8899000000000001E-5
-0.69499999999999995	3.8961000000000002E-5
-0.69399999999999995	3.8924999999999997E-5
-0.69299999999999995	3.8890000000000002E-5
-0.69199999999999995	3.8899000000000001E-5
-0.69099999999999995	3.8943000000000003E-5
-0.69	3.8943000000000003E-5
-0.68899999999999995	3.8970000000000001E-5
-0.68799999999999994	3.8933999999999997E-5
-0.68700000000000006	3.8917E-5
-0.68600000000000005	3.8924999999999997E-5
-0.68500000000000005	3.8908000000000001E-5
-0.68400000000000005	3.8800000000000001E-5
-0.68300000000000005	3.8738000000000001E-5
-0.68200000000000005	3.8826999999999999E-5
-0.68100000000000005	3.8782000000000002E-5
-0.68	3.8756E-5
-0.67900000000000005	3.8908000000000001E-5
-0.67800000000000005	3.8899000000000001E-5
-0.67700000000000005	3.8809000000000001E-5
-0.67600000000000005	3.8826999999999999E-5
-0.67500000000000004	3.8835999999999999E-5
-0.67400000000000004	3.8747E-5
-0.67300000000000004	3.8738000000000001E-5
-0.67200000000000004	3.8738000000000001E-5
-0.67100000000000004	3.8738000000000001E-5
-0.67	3.8756E-5
-0.66900000000000004	3.8756E-5
-0.66800000000000004	3.8711000000000003E-5
-0.66700000000000004	3.8692999999999997E-5
-0.66600000000000004	3.8674999999999998E-5
-0.66500000000000004	3.8702000000000003E-5
-0.66400000000000003	3.8711000000000003E-5
-0.66300000000000003	3.8674999999999998E-5
-0.66200000000000003	3.8665999999999999E-5
-0.66100000000000003	3.8594999999999999E-5
-0.66	3.8594999999999999E-5
-0.65900000000000003	3.8612000000000002E-5
-0.65800000000000003	3.8550000000000002E-5
-0.65700000000000003	3.8594999999999999E-5
-0.65600000000000003	3.8603000000000003E-5
-0.65500000000000003	3.8541000000000003E-5
-0.65400000000000003	3.8559000000000001E-5
-0.65300000000000002	3.8513999999999998E-5
-0.65200000000000002	3.8577E-5
-0.65100000000000002	3.8532000000000003E-5
-0.65	3.8478E-5
-0.64900000000000002	3.8495999999999999E-5
-0.64800000000000002	3.8478E-5
-0.64700000000000002	3.8460000000000001E-5
-0.64600000000000002	3.8415999999999999E-5
-0.64500000000000002	3.8325999999999999E-5
-0.64400000000000002	3.8424999999999999E-5
-0.64300000000000002	3.8495999999999999E-5
-0.64200000000000002	3.8325999999999999E-5
-0.64100000000000001	3.8424999999999999E-5
-0.64	3.8398000000000001E-5
-0.63900000000000001	3.8281000000000002E-5
-0.63800000000000001	3.8352999999999997E-5
-0.63700000000000001	3.8352999999999997E-5
-0.63600000000000001	3.8299E-5
-0.63500000000000001	3.8389000000000001E-5
-0.63400000000000001	3.8352999999999997E-5
-0.63300000000000001	3.8254999999999999E-5
-0.63200000000000001	3.8129E-5
-0.63100000000000001	3.8219000000000001E-5
-0.63	3.8272999999999998E-5
-0.629	3.8237E-5
-0.628	3.8245999999999999E-5
-0.627	3.8245999999999999E-5
-0.626	3.8146999999999999E-5
-0.625	3.8182999999999997E-5
-0.624	3.8210000000000002E-5
-0.623	3.8129E-5
-0.622	3.8120000000000001E-5
-0.621	3.8138E-5
-0.62	3.8308E-5
-0.61899999999999999	3.8325999999999999E-5
-0.61799999999999999	3.8164999999999998E-5
-0.61699999999999999	3.8146999999999999E-5
-0.61599999999999999	3.8067E-5
-0.61499999999999999	3.8058000000000001E-5
-0.61399999999999999	3.8003999999999997E-5
-0.61299999999999999	3.7951000000000003E-5
-0.61199999999999999	3.7985999999999998E-5
-0.61099999999999999	3.8003999999999997E-5
-0.61	3.7959E-5
-0.60899999999999999	3.7976999999999999E-5
-0.60799999999999998	3.7941999999999997E-5
-0.60699999999999998	3.7879000000000001E-5
-0.60599999999999998	3.7852000000000003E-5
-0.60499999999999998	3.7888E-5
-0.60399999999999998	3.7806999999999999E-5
-0.60299999999999998	3.7888E-5
-0.60199999999999998	3.7870000000000002E-5
-0.60099999999999998	3.7781000000000003E-5
-0.6	3.7833999999999997E-5
-0.59899999999999998	3.7815999999999998E-5
-0.59799999999999998	3.7824999999999998E-5
-0.59699999999999998	3.7663999999999997E-5
-0.59599999999999997	3.7654999999999998E-5
-0.59499999999999997	3.7735999999999999E-5
-0.59399999999999997	3.7645999999999998E-5
-0.59299999999999997	3.7682000000000003E-5
-0.59199999999999997	3.7645999999999998E-5
-0.59099999999999997	3.7565999999999999E-5
-0.59	3.7629000000000002E-5
-0.58899999999999997	3.7645999999999998E-5
-0.58799999999999997	3.7601999999999997E-5
-0.58699999999999997	3.7636999999999999E-5
-0.58599999999999997	3.7611000000000003E-5
-0.58499999999999996	3.7530000000000002E-5
-0.58399999999999996	3.7459000000000002E-5
-0.58299999999999996	3.7493999999999997E-5
-0.58199999999999996	3.7503000000000003E-5
-0.58099999999999996	3.7395999999999999E-5
-0.57999999999999996	3.7404999999999998E-5
-0.57899999999999996	3.7413999999999998E-5
-0.57799999999999996	3.7360000000000001E-5
-0.57699999999999996	3.7413999999999998E-5
-0.57599999999999996	3.7404999999999998E-5
-0.57499999999999996	3.7351000000000002E-5
-0.57399999999999995	3.7298000000000001E-5
-0.57299999999999995	3.7378E-5
-0.57199999999999995	3.7307E-5
-0.57099999999999995	3.7243999999999998E-5
-0.56999999999999995	3.7307E-5
-0.56899999999999995	3.6912999999999997E-5
-0.56799999999999995	3.6572999999999997E-5
-0.56699999999999995	3.6912999999999997E-5
-0.56599999999999995	3.7038E-5
-0.56499999999999995	3.7038E-5
-0.56399999999999995	3.7055999999999999E-5
-0.56299999999999994	3.7073999999999998E-5
-0.56200000000000006	3.7029000000000001E-5
-0.56100000000000005	3.7055999999999999E-5
-0.56000000000000005	3.7073999999999998E-5
-0.55900000000000005	3.6912999999999997E-5
-0.55800000000000005	3.6967E-5
-0.55700000000000005	3.7011000000000002E-5
-0.55600000000000005	3.6894999999999998E-5
-0.55500000000000005	3.6859000000000001E-5
-0.55400000000000005	3.6894999999999998E-5
-0.55300000000000005	3.6868E-5
-0.55200000000000005	3.6832999999999998E-5
-0.55100000000000005	3.6806E-5
-0.55000000000000004	3.6770000000000002E-5
-0.54900000000000004	3.6761000000000003E-5
-0.54800000000000004	3.6841000000000002E-5
-0.54700000000000004	3.6823999999999998E-5
-0.54600000000000004	3.6689000000000001E-5
-0.54500000000000004	3.6671999999999997E-5
-0.54400000000000004	3.6706999999999999E-5
-0.54300000000000004	3.6572999999999997E-5
-0.54200000000000004	3.6519000000000001E-5
-0.54100000000000004	3.6582000000000003E-5
-0.54	3.6582000000000003E-5
-0.53900000000000003	3.6545999999999999E-5
-0.53800000000000003	3.6572999999999997E-5
-0.53700000000000003	3.6511000000000003E-5
-0.53600000000000003	3.6430000000000002E-5
-0.53500000000000003	3.6511000000000003E-5
-0.53400000000000003	3.6536999999999999E-5
-0.53300000000000003	3.6402999999999997E-5
-0.53200000000000003	3.6366999999999999E-5
-0.53100000000000003	3.6350000000000003E-5
-0.53	3.6223999999999997E-5
-0.52900000000000003	3.6313999999999998E-5
-0.52800000000000002	3.6322999999999998E-5
-0.52700000000000002	3.6223999999999997E-5
-0.52600000000000002	3.6242000000000003E-5
-0.52500000000000002	3.6278000000000001E-5
-0.52400000000000002	3.6214999999999998E-5
-0.52300000000000002	3.6189000000000002E-5
-0.52200000000000002	3.6117E-5
-0.52100000000000002	3.6062999999999997E-5
-0.52	3.6062999999999997E-5
-0.51900000000000002	3.6090000000000002E-5
-0.51800000000000002	3.6171000000000003E-5
-0.51700000000000002	3.6223999999999997E-5
-0.51600000000000001	3.6108000000000001E-5
-0.51500000000000001	3.6019000000000002E-5
-0.51400000000000001	3.5920000000000002E-5
-0.51300000000000001	3.5964999999999999E-5
-0.51200000000000001	3.5920000000000002E-5
-0.51100000000000001	3.5883999999999997E-5
-0.51	3.5867000000000001E-5
-0.50900000000000001	3.5867000000000001E-5
-0.50800000000000001	3.5768E-5
-0.50700000000000001	3.5713999999999997E-5
-0.50600000000000001	3.5777E-5
-0.505	3.5697000000000001E-5
-0.504	3.5615999999999999E-5
-0.503	3.5633999999999998E-5
-0.502	3.5642999999999997E-5
-0.501	3.5544999999999999E-5
-0.5	3.5509000000000002E-5
-0.499	3.5562000000000003E-5
-0.498	3.5509000000000002E-5
-0.497	3.5454999999999999E-5
-0.496	3.5454999999999999E-5
-0.495	3.5392000000000003E-5
-0.49399999999999999	3.5410000000000001E-5
-0.49299999999999999	3.5419000000000001E-5
-0.49199999999999999	3.5311999999999997E-5
-0.49099999999999999	3.5258E-5
-0.49	3.5357E-5
-0.48899999999999999	3.5258E-5
-0.48799999999999999	3.5240000000000001E-5
-0.48699999999999999	3.5204999999999999E-5
-0.48599999999999999	3.5132999999999997E-5
-0.48499999999999999	3.5123999999999998E-5
-0.48399999999999999	3.5169000000000002E-5
-0.48299999999999998	3.5114999999999998E-5
-0.48199999999999998	3.5026E-5
-0.48099999999999998	3.5052999999999998E-5
-0.48	3.4999000000000002E-5
-0.47899999999999998	3.4953999999999998E-5
-0.47799999999999998	3.4918E-5
-0.47699999999999998	3.4909000000000001E-5
-0.47599999999999998	3.4909000000000001E-5
-0.47499999999999998	3.4829000000000001E-5
-0.47399999999999998	3.4829000000000001E-5
-0.47299999999999998	3.4829000000000001E-5
-0.47199999999999998	3.4802000000000003E-5
-0.47099999999999997	3.4774999999999998E-5
-0.47	3.4765999999999999E-5
-0.46899999999999997	3.4703999999999998E-5
-0.46800000000000003	3.4668000000000001E-5
-0.46700000000000003	3.4622999999999997E-5
-0.46600000000000003	3.4650000000000002E-5
-0.46500000000000002	3.4686E-5
-0.46400000000000002	3.4613999999999998E-5
-0.46300000000000002	3.4462000000000003E-5
-0.46200000000000002	3.4489000000000001E-5
-0.46100000000000002	3.4507E-5
-0.46	3.4471000000000003E-5
-0.45900000000000002	3.4452999999999997E-5
-0.45800000000000002	3.4443999999999998E-5
-0.45700000000000002	3.4409000000000002E-5
-0.45600000000000002	3.4337E-5
-0.45500000000000002	3.4372999999999998E-5
-0.45400000000000001	3.4310000000000002E-5
-0.45300000000000001	3.4175999999999999E-5
-0.45200000000000001	3.4202999999999998E-5
-0.45100000000000001	3.4273999999999997E-5
-0.45	3.4202999999999998E-5
-0.44900000000000001	3.4131000000000002E-5
-0.44800000000000001	3.4158000000000001E-5
-0.44700000000000001	3.4112999999999997E-5
-0.44600000000000001	3.4158000000000001E-5
-0.44500000000000001	3.4069000000000002E-5
-0.44400000000000001	3.3988000000000001E-5
-0.443	3.3961000000000002E-5
-0.442	3.3988000000000001E-5
-0.441	3.3899000000000002E-5
-0.44	3.3844999999999999E-5
-0.439	3.3871999999999997E-5
-0.438	3.3809000000000001E-5
-0.437	3.3827E-5
-0.436	3.3818E-5
-0.435	3.3844999999999999E-5
-0.434	3.3756E-5
-0.433	3.3756E-5
-0.432	3.3773999999999999E-5
-0.43099999999999999	3.3683999999999998E-5
-0.43	3.3701999999999997E-5
-0.42899999999999999	3.3639000000000001E-5
-0.42799999999999999	3.3577000000000001E-5
-0.42699999999999999	3.3568000000000001E-5
-0.42599999999999999	3.3586E-5
-0.42499999999999999	3.3513999999999998E-5
-0.42399999999999999	3.3469000000000001E-5
-0.42299999999999999	3.3541000000000003E-5
-0.42199999999999999	3.3495999999999999E-5
-0.42099999999999999	3.3451999999999998E-5
-0.42	3.3495999999999999E-5
-0.41899999999999998	3.3442999999999998E-5
-0.41799999999999998	3.3308E-5
-0.41699999999999998	3.3389000000000002E-5
-0.41599999999999998	3.3352999999999997E-5
-0.41499999999999998	3.3460999999999997E-5
-0.41399999999999998	3.3416E-5
-0.41299999999999998	3.3290999999999997E-5
-0.41199999999999998	3.3237E-5
-0.41099999999999998	3.3254999999999999E-5
-0.41	3.3237E-5
-0.40899999999999997	3.3210000000000002E-5
-0.40799999999999997	3.3182999999999997E-5
-0.40699999999999997	3.3173999999999998E-5
-0.40600000000000003	3.3120999999999997E-5
-0.40500000000000003	3.3076E-5
-0.40400000000000003	3.3076E-5
-0.40300000000000002	3.3084999999999999E-5
-0.40200000000000002	3.2985999999999999E-5
-0.40100000000000002	3.3022000000000003E-5
-0.4	3.3012999999999997E-5
-0.39900000000000002	3.2879000000000001E-5
-0.39800000000000002	3.2906E-5
-0.39700000000000002	3.2978000000000002E-5
-0.39600000000000002	3.2932999999999998E-5
-0.39500000000000002	3.2906E-5
-0.39400000000000002	3.2888000000000001E-5
-0.39300000000000002	3.2824999999999998E-5
-0.39200000000000002	3.2808000000000002E-5
-0.39100000000000001	3.2852000000000003E-5
-0.39	3.2808000000000002E-5
-0.38900000000000001	3.2647000000000001E-5
-0.38800000000000001	3.2691000000000003E-5
-0.38700000000000001	3.2744999999999999E-5
-0.38600000000000001	3.2672999999999997E-5
-0.38500000000000001	3.2647000000000001E-5
-0.38400000000000001	3.2663999999999998E-5
-0.38300000000000001	3.2691000000000003E-5
-0.38200000000000001	3.2709000000000001E-5
-0.38100000000000001	3.2672999999999997E-5
-0.38	3.2592999999999998E-5
-0.379	3.2530000000000002E-5
-0.378	3.2592999999999998E-5
-0.377	3.2539000000000001E-5
-0.376	3.2512000000000003E-5
-0.375	3.2512000000000003E-5
-0.374	3.2566E-5
-0.373	3.2468000000000002E-5
-0.372	3.2450000000000003E-5
-0.371	3.2502999999999997E-5
-0.37	3.2477000000000001E-5
-0.36899999999999999	3.2486E-5
-0.36799999999999999	3.2441000000000003E-5
-0.36699999999999999	3.2396E-5
-0.36599999999999999	3.2369000000000001E-5
-0.36499999999999999	3.2404999999999999E-5
-0.36399999999999999	3.2459000000000002E-5
-0.36299999999999999	3.2486E-5
-0.36199999999999999	3.2441000000000003E-5
-0.36099999999999999	3.2369000000000001E-5
-0.36	3.2342000000000003E-5
-0.35899999999999999	3.2316E-5
-0.35799999999999998	3.2333999999999999E-5
-0.35699999999999998	3.2316E-5
-0.35599999999999998	3.2360000000000002E-5
-0.35499999999999998	3.2333999999999999E-5
-0.35399999999999998	3.2225999999999999E-5
-0.35299999999999998	3.2325E-5
-0.35199999999999998	3.2325E-5
-0.35099999999999998	3.2199000000000001E-5
-0.35	3.2252999999999998E-5
-0.34899999999999998	3.2307000000000001E-5
-0.34799999999999998	3.2208000000000001E-5
-0.34699999999999998	3.2243999999999998E-5
-0.34599999999999997	3.2280000000000003E-5
-0.34499999999999997	3.2280000000000003E-5
-0.34399999999999997	3.2243999999999998E-5
-0.34300000000000003	3.2181000000000002E-5
-0.34200000000000003	3.2217E-5
-0.34100000000000003	3.2217E-5
-0.34	3.2271000000000003E-5
-0.33900000000000002	3.2243999999999998E-5
-0.33800000000000002	3.2128000000000001E-5
-0.33700000000000002	3.2190000000000002E-5
-0.33600000000000002	3.2217E-5
-0.33500000000000002	3.2146E-5
-0.33400000000000002	3.2163999999999999E-5
-0.33300000000000002	3.2217E-5
-0.33200000000000002	3.2217E-5
-0.33100000000000002	3.2261999999999997E-5
-0.33	3.2234999999999999E-5
-0.32900000000000001	3.2199000000000001E-5
-0.32800000000000001	3.2190000000000002E-5
-0.32700000000000001	3.2234999999999999E-5
-0.32600000000000001	3.2190000000000002E-5
-0.32500000000000001	3.2172999999999998E-5
-0.32400000000000001	3.2199000000000001E-5
-0.32300000000000001	3.2225999999999999E-5
-0.32200000000000001	3.2208000000000001E-5
-0.32100000000000001	3.2225999999999999E-5
-0.32	3.2289000000000002E-5
-0.31900000000000001	3.2261999999999997E-5
-0.318	3.2208000000000001E-5
-0.317	3.2307000000000001E-5
-0.316	3.2271000000000003E-5
-0.315	3.2243999999999998E-5
-0.314	3.2289000000000002E-5
-0.313	3.2387E-5
-0.312	3.2495E-5
-0.311	3.2378000000000001E-5
-0.31	3.2413999999999998E-5
-0.309	3.2378000000000001E-5
-0.308	3.2396E-5
-0.307	3.2378000000000001E-5
-0.30599999999999999	3.2360000000000002E-5
-0.30499999999999999	3.2404999999999999E-5
-0.30399999999999999	3.2459000000000002E-5
-0.30299999999999999	3.2378000000000001E-5
-0.30199999999999999	3.2396E-5
-0.30099999999999999	3.2404999999999999E-5
-0.3	3.2404999999999999E-5
-0.29899999999999999	3.2378000000000001E-5
-0.29799999999999999	3.2495E-5
-0.29699999999999999	3.2486E-5
-0.29599999999999999	3.2468000000000002E-5
-0.29499999999999998	3.2539000000000001E-5
-0.29399999999999998	3.2566E-5
-0.29299999999999998	3.2574999999999999E-5
-0.29199999999999998	3.2574999999999999E-5
-0.29099999999999998	3.2611000000000003E-5
-0.28999999999999998	3.2592999999999998E-5
-0.28899999999999998	3.2647000000000001E-5
-0.28799999999999998	3.2691000000000003E-5
-0.28699999999999998	3.2592999999999998E-5
-0.28599999999999998	3.2656E-5
-0.28499999999999998	3.2682000000000003E-5
-0.28399999999999997	3.2691000000000003E-5
-0.28299999999999997	3.2753999999999998E-5
-0.28199999999999997	3.2799000000000002E-5
-0.28100000000000003	3.2771999999999997E-5
-0.28000000000000003	3.2842999999999997E-5
-0.27900000000000003	3.2842999999999997E-5
-0.27800000000000002	3.2852000000000003E-5
-0.27700000000000002	3.2817000000000001E-5
-0.27600000000000002	3.2629000000000002E-5
-0.27500000000000002	3.2477000000000001E-5
-0.27400000000000002	3.3031000000000003E-5
-0.27300000000000002	3.2897E-5
-0.27200000000000002	3.2870000000000002E-5
-0.27100000000000002	3.2994999999999998E-5
-0.27	3.2932999999999998E-5
-0.26900000000000002	3.3254999999999999E-5
-0.26800000000000002	3.3272999999999998E-5
-0.26700000000000002	3.3451999999999998E-5
-0.26600000000000001	3.3352999999999997E-5
-0.26500000000000001	3.3139000000000002E-5
-0.26400000000000001	3.3139000000000002E-5
-0.26300000000000001	3.3343999999999998E-5
-0.26200000000000001	3.3371000000000003E-5
-0.26100000000000001	3.3371000000000003E-5
-0.26	3.3416E-5
-0.25900000000000001	3.3433999999999999E-5
-0.25800000000000001	3.3352999999999997E-5
-0.25700000000000001	3.3495999999999999E-5
-0.25600000000000001	3.3531999999999997E-5
-0.255	3.3504999999999999E-5
-0.254	3.2941999999999997E-5
-0.253	3.3380000000000002E-5
-0.252	3.3908000000000001E-5
-0.251	3.3943999999999999E-5
-0.25	3.3853999999999998E-5
-0.249	3.3747000000000001E-5
-0.248	3.3738000000000001E-5
-0.247	3.3756E-5
-0.246	3.3862999999999997E-5
-0.245	3.3862999999999997E-5
-0.24399999999999999	3.3881000000000003E-5
-0.24299999999999999	3.3961000000000002E-5
-0.24199999999999999	3.3935E-5
-0.24099999999999999	3.4078000000000001E-5
-0.24	3.4112999999999997E-5
-0.23899999999999999	3.4105E-5
-0.23799999999999999	3.4158000000000001E-5
-0.23699999999999999	3.4221000000000003E-5
-0.23599999999999999	3.4158000000000001E-5
-0.23499999999999999	3.4230000000000003E-5
-0.23400000000000001	3.4319000000000001E-5
-0.23300000000000001	3.4400000000000003E-5
-0.23200000000000001	3.4345999999999999E-5
-0.23100000000000001	3.4391000000000003E-5
-0.23	3.4462000000000003E-5
-0.22900000000000001	3.4551999999999997E-5
-0.22800000000000001	3.4579000000000002E-5
-0.22700000000000001	3.4595999999999999E-5
-0.22600000000000001	3.4622999999999997E-5
-0.22500000000000001	3.4668000000000001E-5
-0.224	3.4756999999999999E-5
-0.223	3.4730999999999997E-5
-0.222	3.4792999999999997E-5
-0.221	3.4847E-5
-0.22	3.4882999999999998E-5
-0.219	3.4972000000000003E-5
-0.218	3.4999000000000002E-5
-0.217	3.5105999999999999E-5
-0.216	3.5114999999999998E-5
-0.215	3.5160000000000002E-5
-0.214	3.5222999999999998E-5
-0.21299999999999999	3.5213999999999999E-5
-0.21199999999999999	3.5267E-5
-0.21099999999999999	3.5437E-5
-0.21	3.5651999999999997E-5
-0.20899999999999999	3.5607E-5
-0.20799999999999999	3.5562000000000003E-5
-0.20699999999999999	3.5527000000000001E-5
-0.20599999999999999	3.5598E-5
-0.20499999999999999	3.5670000000000002E-5
-0.20399999999999999	3.5697000000000001E-5
-0.20300000000000001	3.5741000000000002E-5
-0.20200000000000001	3.5840000000000002E-5
-0.20100000000000001	3.5892999999999997E-5
-0.2	3.5849000000000002E-5
-0.19900000000000001	3.5964999999999999E-5
-0.19800000000000001	3.5982999999999998E-5
-0.19700000000000001	3.6010000000000003E-5
-0.19600000000000001	3.6117E-5
-0.19500000000000001	3.6189000000000002E-5
-0.19400000000000001	3.6180000000000003E-5
-0.193	3.6260000000000002E-5
-0.192	3.6341000000000003E-5
-0.191	3.6341000000000003E-5
-0.19	3.6402999999999997E-5
-0.189	3.6572999999999997E-5
-0.188	3.6511000000000003E-5
-0.187	3.6536999999999999E-5
-0.186	3.6689000000000001E-5
-0.185	3.6689000000000001E-5
-0.184	3.6698E-5
-0.183	3.6761000000000003E-5
-0.182	3.6868E-5
-0.18099999999999999	3.6868E-5
-0.18	3.6984999999999999E-5
-0.17899999999999999	3.7073999999999998E-5
-0.17799999999999999	3.7092000000000003E-5
-0.17699999999999999	3.7119000000000002E-5
-0.17599999999999999	3.7234999999999998E-5
-0.17499999999999999	3.7163000000000003E-5
-0.17399999999999999	3.7280000000000002E-5
-0.17299999999999999	3.7360000000000001E-5
-0.17199999999999999	3.7395999999999999E-5
-0.17100000000000001	3.7459000000000002E-5
-0.17	3.7539000000000001E-5
-0.16900000000000001	3.7583999999999998E-5
-0.16800000000000001	3.7645999999999998E-5
-0.16700000000000001	3.7762999999999997E-5
-0.16600000000000001	3.7852000000000003E-5
-0.16500000000000001	3.7861000000000002E-5
-0.16400000000000001	3.7932999999999997E-5
-0.16300000000000001	3.7968E-5
-0.16200000000000001	3.7985999999999998E-5
-0.161	3.8084999999999999E-5
-0.16	3.8120000000000001E-5
-0.159	3.8146999999999999E-5
-0.158	3.8237E-5
-0.157	3.8334999999999998E-5
-0.156	3.8371000000000002E-5
-0.155	3.8433999999999998E-5
-0.154	3.8541000000000003E-5
-0.153	3.8612000000000002E-5
-0.152	3.8648E-5
-0.151	3.8729000000000001E-5
-0.15	3.8747E-5
-0.14899999999999999	3.8782000000000002E-5
-0.14799999999999999	3.8862999999999997E-5
-0.14699999999999999	3.8970000000000001E-5
-0.14599999999999999	3.8899000000000001E-5
-0.14499999999999999	3.9023999999999998E-5
-0.14399999999999999	3.9158E-5
-0.14299999999999999	3.9167E-5
-0.14199999999999999	3.9230000000000002E-5
-0.14099999999999999	3.9363999999999998E-5
-0.14000000000000001	3.9372999999999997E-5
-0.13900000000000001	3.9453000000000003E-5
-0.13800000000000001	3.9551999999999997E-5
-0.13700000000000001	3.9561000000000003E-5
-0.13600000000000001	3.9613999999999997E-5
-0.13500000000000001	3.9641000000000002E-5
-0.13400000000000001	3.9765999999999998E-5
-0.13300000000000001	3.9694999999999999E-5
-0.13200000000000001	3.9838E-5
-0.13100000000000001	3.9891000000000001E-5
-0.13	3.9972000000000003E-5
-0.129	4.0105999999999999E-5
-0.128	4.0178000000000001E-5
-0.127	4.0213000000000003E-5
-0.126	4.0321000000000002E-5
-0.125	4.0348000000000001E-5
-0.124	4.0419E-5
-0.123	4.0553000000000003E-5
-0.122	4.0642999999999997E-5
-0.121	4.0606999999999999E-5
-0.12	4.0615999999999999E-5
-0.11899999999999999	4.0768E-5
-0.11799999999999999	4.0902000000000002E-5
-0.11700000000000001	4.0902000000000002E-5
-0.11600000000000001	4.0964999999999998E-5
-0.115	4.1099000000000001E-5
-0.114	4.1134999999999998E-5
-0.113	4.1233000000000003E-5
-0.112	4.1295999999999999E-5
-0.111	4.1278E-5
-0.11	4.1375999999999998E-5
-0.109	4.1457E-5
-0.108	4.1770000000000002E-5
-0.107	4.1885999999999998E-5
-0.106	4.1832000000000002E-5
-0.105	4.1859E-5
-0.104	4.1832000000000002E-5
-0.10299999999999999	4.1931000000000002E-5
-0.10199999999999999	4.2029E-5
-0.10100000000000001	4.2110000000000002E-5
-0.1	4.2172000000000002E-5
-9.9000000000000005E-2	4.2271000000000002E-5
-9.8000000000000004E-2	4.2333000000000003E-5
-9.7000000000000003E-2	4.2422999999999997E-5
-9.6000000000000002E-2	4.2475999999999998E-5
-9.5000000000000001E-2	4.2441000000000002E-5
-9.4E-2	4.2556999999999999E-5
-9.2999999999999999E-2	4.2753999999999998E-5
-9.1999999999999998E-2	4.2772000000000003E-5
-9.0999999999999998E-2	4.2815999999999998E-5
-0.09	4.2959E-5
-8.8999999999999996E-2	4.3102000000000002E-5
-8.7999999999999995E-2	4.3102000000000002E-5
-8.6999999999999994E-2	4.3192000000000003E-5
-8.5999999999999993E-2	4.3299E-5
-8.5000000000000006E-2	4.3334999999999998E-5
-8.4000000000000005E-2	4.3389000000000001E-5
-8.3000000000000004E-2	4.3504999999999998E-5
-8.2000000000000003E-2	4.3541000000000002E-5
-8.1000000000000003E-2	4.3594000000000003E-5
-0.08	4.3745999999999998E-5
-7.9000000000000001E-2	4.3809E-5
-7.8E-2	4.3934000000000003E-5
-7.6999999999999999E-2	4.4051000000000002E-5
-7.5999999999999998E-2	4.4067999999999999E-5
-7.4999999999999997E-2	4.4113000000000003E-5
-7.3999999999999996E-2	4.4319E-5
-7.2999999999999995E-2	4.4407999999999999E-5
-7.1999999999999995E-2	4.4416999999999998E-5
-7.0999999999999994E-2	4.4498E-5
-7.0000000000000007E-2	4.4586999999999998E-5
-6.9000000000000006E-2	4.4569E-5
-6.8000000000000005E-2	4.473E-5
-6.7000000000000004E-2	4.4829000000000001E-5
-6.6000000000000003E-2	4.4829000000000001E-5
-6.5000000000000002E-2	4.4981000000000002E-5
-6.4000000000000001E-2	4.5114999999999997E-5
-6.3E-2	4.5231000000000001E-5
-6.2E-2	4.5266999999999999E-5
-6.0999999999999999E-2	4.5364999999999997E-5
-0.06	4.5410000000000001E-5
-5.8999999999999997E-2	4.5482000000000003E-5
-5.8000000000000003E-2	4.5597999999999999E-5
-5.7000000000000002E-2	4.5652000000000003E-5
-5.6000000000000001E-2	4.5723000000000003E-5
-5.5E-2	4.5856999999999998E-5
-5.3999999999999999E-2	4.5946999999999999E-5
-5.2999999999999999E-2	4.5964999999999998E-5
-5.1999999999999998E-2	4.6063000000000003E-5
-5.0999999999999997E-2	4.617E-5
-0.05	4.6205999999999998E-5
-4.9000000000000002E-2	4.6286999999999999E-5
-4.8000000000000001E-2	4.6421000000000002E-5
-4.7E-2	4.6439E-5
-4.5999999999999999E-2	4.6591000000000002E-5
-4.4999999999999998E-2	4.668E-5
-4.3999999999999997E-2	4.668E-5
-4.2999999999999997E-2	4.6671000000000001E-5
-4.2000000000000003E-2	4.6805000000000003E-5
-4.1000000000000002E-2	4.6876999999999999E-5
-0.04	4.7002000000000002E-5
-3.9E-2	4.7092000000000002E-5
-3.7999999999999999E-2	4.7190000000000001E-5
-3.6999999999999998E-2	4.7207999999999999E-5
-3.5999999999999997E-2	4.7278999999999999E-5
-3.5000000000000003E-2	4.7423000000000003E-5
-3.4000000000000002E-2	4.7395999999999998E-5
-3.3000000000000002E-2	4.7503000000000002E-5
-3.2000000000000001E-2	4.7627999999999999E-5
-3.1E-2	4.7601E-5
-0.03	4.7682000000000002E-5
-2.9000000000000001E-2	4.7788999999999999E-5
-2.8000000000000001E-2	4.7852000000000002E-5
-2.7E-2	4.7896999999999999E-5
-2.5999999999999999E-2	4.7914000000000002E-5
-2.5000000000000001E-2	4.8075000000000003E-5
-2.4E-2	4.8128999999999999E-5
-2.3E-2	4.8192000000000002E-5
-2.1999999999999999E-2	4.8299E-5
-2.1000000000000001E-2	4.8307999999999999E-5
-0.02	4.8415000000000003E-5
-1.9E-2	4.8477999999999999E-5
-1.7999999999999999E-2	4.8405999999999997E-5
-1.7000000000000001E-2	4.8504999999999997E-5
-1.6E-2	4.8612000000000001E-5
-1.4999999999999999E-2	4.8647999999999999E-5
-1.4E-2	4.8727999999999998E-5
-1.2999999999999999E-2	4.8863000000000003E-5
-1.2E-2	4.8888999999999999E-5
-1.0999999999999999E-2	4.8961000000000001E-5
-0.01	4.9005999999999998E-5
-8.9999999999999993E-3	4.9085999999999997E-5
-8.0000000000000002E-3	4.9067999999999998E-5
-7.0000000000000001E-3	4.9166999999999999E-5
-6.0000000000000001E-3	4.9336999999999999E-5
-5.0000000000000001E-3	4.9577999999999999E-5
-4.0000000000000001E-3	4.9444000000000003E-5
-3.0000000000000001E-3	4.9497999999999999E-5
-2E-3	4.9444000000000003E-5
-1E-3	4.9497999999999999E-5
0	4.9577999999999999E-5
1E-3	4.9641000000000001E-5
2E-3	4.9756999999999998E-5
3.0000000000000001E-3	4.9820000000000001E-5
4.0000000000000001E-3	4.9855000000000003E-5
5.0000000000000001E-3	4.9836999999999997E-5
6.0000000000000001E-3	4.9864000000000002E-5
7.0000000000000001E-3	4.9908999999999999E-5
8.0000000000000002E-3	4.9864000000000002E-5
8.9999999999999993E-3	5.0034000000000002E-5
0.01	5.0142000000000002E-5
1.0999999999999999E-2	5.0034000000000002E-5
1.2E-2	5.0167999999999998E-5
1.2999999999999999E-2	5.0275999999999998E-5
1.4E-2	5.0346999999999998E-5
1.4999999999999999E-2	5.0392000000000001E-5
1.6E-2	5.0454999999999997E-5
1.7000000000000001E-2	5.0445999999999998E-5
1.7999999999999999E-2	5.0553000000000002E-5
1.9E-2	5.058E-5
0.02	5.0544000000000003E-5
2.1000000000000001E-2	5.0571000000000001E-5
2.1999999999999999E-2	5.0741000000000001E-5
2.3E-2	5.0732000000000001E-5
2.4E-2	5.0714000000000003E-5
2.5000000000000001E-2	5.0865999999999997E-5
2.5999999999999999E-2	5.0946999999999999E-5
2.7E-2	5.0991E-5
2.8000000000000001E-2	5.1044999999999997E-5
2.9000000000000001E-2	5.1107999999999999E-5
0.03	5.1072000000000002E-5
3.1E-2	5.1196999999999998E-5
3.2000000000000001E-2	5.1242000000000002E-5
3.3000000000000002E-2	5.1125000000000003E-5
3.4000000000000002E-2	5.1286000000000003E-5
3.5000000000000003E-2	5.134E-5
3.5999999999999997E-2	5.1322000000000001E-5
3.6999999999999998E-2	5.1465000000000003E-5
3.7999999999999999E-2	5.1616999999999997E-5
3.9E-2	5.1635000000000003E-5
0.04	5.1662000000000001E-5
4.1000000000000002E-2	5.1761000000000001E-5
4.2000000000000003E-2	5.1814000000000002E-5
4.2999999999999997E-2	5.1786999999999997E-5
4.3999999999999997E-2	5.1823000000000002E-5
4.4999999999999998E-2	5.1956999999999997E-5
4.5999999999999999E-2	5.2117999999999998E-5
4.7E-2	5.2145000000000003E-5
4.8000000000000001E-2	5.2163000000000002E-5
4.9000000000000002E-2	5.2135999999999997E-5
0.05	5.2198999999999999E-5
5.0999999999999997E-2	5.2287999999999998E-5
5.1999999999999998E-2	5.2324000000000003E-5
5.2999999999999999E-2	5.2439999999999999E-5
5.3999999999999999E-2	5.2448999999999999E-5
5.5E-2	5.2475999999999997E-5
5.6000000000000001E-2	5.2583000000000001E-5
5.7000000000000002E-2	5.2664000000000003E-5
5.8000000000000003E-2	5.27E-5
5.8999999999999997E-2	5.2664000000000003E-5
0.06	5.2788999999999999E-5
6.0999999999999999E-2	5.2886999999999997E-5
6.2E-2	5.2914000000000002E-5
6.3E-2	5.2985999999999997E-5
6.4000000000000001E-2	5.3128999999999999E-5
6.5000000000000002E-2	5.3208999999999998E-5
6.6000000000000003E-2	5.3226999999999997E-5
6.7000000000000004E-2	5.3307999999999999E-5
6.8000000000000005E-2	5.3369999999999999E-5
6.9000000000000006E-2	5.3442000000000001E-5
7.0000000000000007E-2	5.3566999999999997E-5
7.0999999999999994E-2	5.3603000000000002E-5
7.1999999999999995E-2	5.3539999999999999E-5
7.2999999999999995E-2	5.3701E-5
7.3999999999999996E-2	5.3791E-5
7.4999999999999997E-2	5.3826999999999998E-5
7.5999999999999998E-2	5.3961000000000001E-5
7.6999999999999999E-2	5.4113000000000002E-5
7.8E-2	5.414E-5
7.9000000000000001E-2	5.4274000000000002E-5
0.08	5.4407999999999998E-5
8.1000000000000003E-2	5.4381E-5
8.2000000000000003E-2	5.4453000000000002E-5
8.3000000000000004E-2	5.4605000000000003E-5
8.4000000000000005E-2	5.4623000000000002E-5
8.5000000000000006E-2	5.4676000000000003E-5
8.5999999999999993E-2	5.4818999999999998E-5
8.6999999999999994E-2	5.49E-5
8.7999999999999995E-2	5.4988999999999998E-5
8.8999999999999996E-2	5.5176999999999997E-5
0.09	5.5266999999999998E-5
9.0999999999999998E-2	5.5266999999999998E-5
9.1999999999999998E-2	5.5374000000000002E-5
9.2999999999999999E-2	5.5553000000000002E-5
9.4E-2	5.5642E-5
9.5000000000000001E-2	5.5686999999999997E-5
9.6000000000000002E-2	5.5812E-5
9.7000000000000003E-2	5.6276999999999997E-5
9.8000000000000004E-2	5.6428999999999998E-5
9.9000000000000005E-2	5.6412000000000001E-5
0.1	5.6348999999999999E-5
0.10100000000000001	5.6412000000000001E-5
0.10199999999999999	5.6573000000000002E-5
0.10299999999999999	5.6777999999999997E-5
0.104	5.6805000000000002E-5
0.105	5.6938999999999998E-5
0.106	5.7082E-5
0.107	5.7172000000000001E-5
0.108	5.7243000000000001E-5
0.109	5.7457999999999998E-5
0.11	5.7538999999999999E-5
0.111	5.7547000000000003E-5
0.112	5.7788999999999998E-5
0.113	5.7914000000000002E-5
0.114	5.8093000000000001E-5
0.115	5.8298999999999999E-5
0.11600000000000001	5.8325999999999997E-5
0.11700000000000001	5.8424000000000002E-5
0.11799999999999999	5.8594000000000002E-5
0.11899999999999999	5.8853E-5
0.12	5.8987000000000003E-5
0.121	5.9104000000000002E-5
0.122	5.9256000000000003E-5
0.123	5.9265000000000003E-5
0.124	5.9444000000000002E-5
0.125	5.9809999999999998E-5
0.126	5.9891E-5
0.127	6.0061E-5
0.128	6.0302E-5
0.129	6.0454000000000001E-5
0.13	6.0633E-5
0.13100000000000001	6.0838999999999998E-5
0.13200000000000001	6.0999999999999999E-5
0.13300000000000001	6.1161000000000006E-5
0.13400000000000001	6.1358000000000004E-5
0.13500000000000001	6.1509999999999999E-5
0.13600000000000001	6.1554000000000001E-5
0.13700000000000001	6.1760000000000005E-5
0.13800000000000001	6.2001999999999994E-5
0.13900000000000001	6.2198000000000003E-5
0.14000000000000001	6.2466999999999997E-5
0.14099999999999999	6.2655000000000002E-5
0.14199999999999999	6.2806999999999997E-5
0.14299999999999999	6.3021000000000005E-5
0.14399999999999999	6.3200000000000005E-5
0.14499999999999999	6.3397000000000003E-5
0.14599999999999999	6.3621000000000006E-5
0.14699999999999999	6.3791E-5
0.14799999999999999	6.3898000000000004E-5
0.14899999999999999	6.4264999999999995E-5
0.15	6.4407999999999997E-5
0.151	6.4505999999999995E-5
0.152	6.4658000000000003E-5
0.153	6.5024999999999995E-5
0.154	6.5320000000000005E-5
0.155	6.5471999999999999E-5
0.156	6.5605999999999995E-5
0.157	6.5811999999999999E-5
0.158	6.5919000000000004E-5
0.159	6.6231999999999999E-5
0.16	6.6446999999999996E-5
0.161	6.6544999999999994E-5
0.16200000000000001	6.6687999999999996E-5
0.16300000000000001	6.6921000000000005E-5
0.16400000000000001	6.7100000000000005E-5
0.16500000000000001	6.7269999999999998E-5
0.16600000000000001	6.7546999999999996E-5
0.16700000000000001	6.7753E-5
0.16800000000000001	6.7949999999999998E-5
0.16900000000000001	6.8155000000000001E-5
0.17	6.8324999999999994E-5
0.17100000000000001	6.8433E-5
0.17199999999999999	6.8763999999999994E-5
0.17299999999999999	6.8968999999999996E-5
0.17399999999999999	6.8934000000000001E-5
0.17499999999999999	6.9059000000000004E-5
0.17599999999999999	6.9344999999999994E-5
0.17699999999999999	6.9461000000000005E-5
0.17799999999999999	6.9640000000000004E-5
0.17899999999999999	6.9819000000000004E-5
0.18	7.0034000000000001E-5
0.18099999999999999	7.0247999999999996E-5
0.182	7.0463000000000006E-5
0.183	7.0543000000000005E-5
0.184	7.0650999999999998E-5
0.185	7.0803000000000006E-5
0.186	7.1008999999999997E-5
0.187	7.1008999999999997E-5
0.188	7.1151999999999999E-5
0.189	7.1330999999999999E-5
0.19	7.1365999999999994E-5
0.191	7.1501000000000005E-5
0.192	7.1669999999999997E-5
0.193	7.1823000000000007E-5
0.19400000000000001	7.1983999999999994E-5
0.19500000000000001	7.2144000000000006E-5
0.19600000000000001	7.2216000000000001E-5
0.19700000000000001	7.2243000000000006E-5
0.19800000000000001	7.2367999999999996E-5
0.19900000000000001	7.2619000000000004E-5
0.2	7.3021000000000004E-5
0.20100000000000001	7.2993999999999999E-5
0.20200000000000001	7.2948999999999996E-5
0.20300000000000001	7.2914E-5
0.20399999999999999	7.3003000000000006E-5
0.20499999999999999	7.3109999999999996E-5
0.20599999999999999	7.3127999999999995E-5
0.20699999999999999	7.3236000000000002E-5
0.20799999999999999	7.3316000000000001E-5
0.20899999999999999	7.3361000000000005E-5
0.21	7.3397000000000002E-5
0.21099999999999999	7.3415000000000001E-5
0.21199999999999999	7.3415000000000001E-5
0.21299999999999999	7.3449999999999996E-5
0.214	7.3558000000000003E-5
0.215	7.3674E-5
0.216	7.3620000000000003E-5
0.217	7.3862000000000005E-5
0.218	7.3906999999999996E-5
0.219	7.3844000000000007E-5
0.22	7.3898000000000003E-5
0.221	7.4014E-5
0.222	7.3986999999999995E-5
0.223	7.4147999999999995E-5
0.224	7.4255E-5
0.22500000000000001	7.4085000000000006E-5
0.22600000000000001	7.4023000000000006E-5
0.22700000000000001	7.4121000000000004E-5
0.22800000000000001	7.4085000000000006E-5
0.22900000000000001	7.4129999999999997E-5
0.23	7.4220000000000004E-5
0.23100000000000001	7.4344999999999994E-5
0.23200000000000001	7.4344999999999994E-5
0.23300000000000001	7.4443000000000005E-5
0.23400000000000001	7.4515000000000001E-5
0.23499999999999999	7.4433999999999999E-5
0.23599999999999999	7.4479000000000003E-5
0.23699999999999999	7.4542000000000006E-5
0.23799999999999999	7.4461000000000004E-5
0.23899999999999999	7.4542000000000006E-5
0.24	7.4595E-5
0.24099999999999999	7.4577000000000001E-5
0.24199999999999999	7.4648999999999996E-5
0.24299999999999999	7.4819000000000003E-5
0.24399999999999999	7.4738000000000002E-5
0.245	7.4746999999999994E-5
0.246	7.4845999999999995E-5
0.247	7.4873E-5
0.248	7.4819000000000003E-5
0.249	7.4855000000000001E-5
0.25	7.4873E-5
0.251	7.4720000000000003E-5
0.252	7.4863999999999993E-5
0.253	7.4944000000000006E-5
0.254	7.4899000000000002E-5
0.255	7.5060000000000003E-5
0.25600000000000001	7.5185999999999995E-5
0.25700000000000001	7.5131999999999998E-5
0.25800000000000001	7.5292999999999999E-5
0.25900000000000001	7.5346999999999995E-5
0.26	7.5382000000000004E-5
0.26100000000000001	7.5354999999999999E-5
0.26200000000000001	7.5408999999999996E-5
0.26300000000000001	7.5436000000000001E-5
0.26400000000000001	7.5338000000000003E-5
0.26500000000000001	7.5525000000000006E-5
0.26600000000000001	7.5543000000000005E-5
0.26700000000000002	7.5561000000000004E-5
0.26800000000000002	7.5650999999999998E-5
0.26900000000000002	7.5704000000000006E-5
0.27	7.5704000000000006E-5
0.27100000000000002	7.5794E-5
0.27200000000000002	7.5945999999999994E-5
0.27300000000000002	7.5937000000000002E-5
0.27400000000000002	7.5955E-5
0.27500000000000002	7.6044000000000006E-5
0.27600000000000002	7.6017000000000001E-5
0.27700000000000002	7.5999000000000002E-5
0.27800000000000002	7.6168999999999995E-5
0.27900000000000003	7.6241000000000004E-5
0.28000000000000003	7.6267999999999996E-5
0.28100000000000003	7.6339000000000002E-5
0.28199999999999997	7.6402000000000005E-5
0.28299999999999997	7.6474E-5
0.28399999999999997	7.6563000000000005E-5
0.28499999999999998	7.6742000000000005E-5
0.28599999999999998	7.6687999999999995E-5
0.28699999999999998	7.6768999999999996E-5
0.28799999999999998	7.6812999999999998E-5
0.28899999999999998	7.6812999999999998E-5
0.28999999999999998	7.6911999999999998E-5
0.29099999999999998	7.7118000000000003E-5
0.29199999999999998	7.7198000000000002E-5
0.29299999999999998	7.7162000000000004E-5
0.29399999999999998	7.7349999999999996E-5
0.29499999999999998	7.7484000000000006E-5
0.29599999999999999	7.7538000000000002E-5
0.29699999999999999	7.7583000000000006E-5
0.29799999999999999	7.7663000000000005E-5
0.29899999999999999	7.7689999999999996E-5
0.3	7.7832999999999998E-5
0.30099999999999999	7.8029999999999997E-5
0.30199999999999999	7.8431999999999997E-5
0.30299999999999999	7.8512999999999999E-5
0.30399999999999999	7.8522000000000005E-5
0.30499999999999999	7.8495E-5
0.30599999999999999	7.8512999999999999E-5
0.307	7.8592999999999998E-5
0.308	7.8701000000000004E-5
0.309	7.8880000000000004E-5
0.31	7.8996000000000001E-5
0.311	7.9085000000000006E-5
0.312	7.9058000000000001E-5
0.313	7.9202000000000005E-5
0.314	7.9406999999999994E-5
0.315	7.9416E-5
0.316	7.9648999999999996E-5
0.317	7.9827999999999995E-5
0.318	7.9773999999999999E-5
0.31900000000000001	7.9998000000000002E-5
0.32	8.0193999999999998E-5
0.32100000000000001	8.0229999999999996E-5
0.32200000000000001	8.0481000000000004E-5
0.32300000000000001	8.0587999999999995E-5
0.32400000000000001	8.0597000000000001E-5
0.32500000000000001	8.0785000000000007E-5
0.32600000000000001	8.0981000000000003E-5
0.32700000000000001	8.1062000000000004E-5
0.32800000000000001	8.1142000000000003E-5
0.32900000000000001	8.1374999999999999E-5
0.33	8.1526999999999994E-5
0.33100000000000002	8.1633999999999998E-5
0.33200000000000002	8.1812999999999997E-5
0.33300000000000002	8.2064000000000006E-5
0.33400000000000002	8.2198000000000001E-5
0.33500000000000002	8.2341000000000003E-5
0.33600000000000002	8.2510999999999997E-5
0.33700000000000002	8.2502000000000004E-5
0.33800000000000002	8.2707999999999995E-5
0.33900000000000002	8.2896000000000001E-5
0.34	8.3039000000000002E-5
0.34100000000000003	8.3226000000000006E-5
0.34200000000000003	8.3423000000000004E-5
0.34300000000000003	8.3557E-5
0.34399999999999997	8.3718E-5
0.34499999999999997	8.3942000000000004E-5
0.34599999999999997	8.4191999999999996E-5
0.34699999999999998	8.4300000000000003E-5
0.34799999999999998	8.4497000000000001E-5
0.34899999999999998	8.4710999999999996E-5
0.35	8.4773999999999998E-5
0.35099999999999998	8.4987999999999993E-5
0.35199999999999998	8.5211999999999997E-5
0.35299999999999998	8.5372999999999997E-5
0.35399999999999998	8.5614999999999999E-5
0.35499999999999998	8.5828999999999994E-5
0.35599999999999998	8.5891999999999997E-5
0.35699999999999998	8.6088999999999995E-5
0.35799999999999998	8.6366000000000006E-5
0.35899999999999999	8.6500000000000002E-5
0.36	8.6724000000000005E-5
0.36099999999999999	8.6955999999999999E-5
0.36199999999999999	8.7117E-5
0.36299999999999999	8.7188999999999995E-5
0.36399999999999999	8.7439000000000001E-5
0.36499999999999999	8.7618E-5
0.36599999999999999	8.7733999999999997E-5
0.36699999999999999	8.8038E-5
0.36799999999999999	8.8199E-5
0.36899999999999999	8.8315999999999999E-5
0.37	8.8504000000000005E-5
0.371	8.8745000000000005E-5
0.372	8.8978000000000001E-5
0.373	8.9121000000000003E-5
0.374	8.9443000000000004E-5
0.375	8.9531999999999996E-5
0.376	8.9710999999999995E-5
0.377	8.9979E-5
0.378	9.0247999999999994E-5
0.379	9.0158E-5
0.38	9.0426999999999993E-5
0.38100000000000001	9.0694999999999998E-5
0.38200000000000001	9.0873999999999998E-5
0.38300000000000001	9.1052999999999997E-5
0.38400000000000001	9.1321000000000002E-5
0.38500000000000001	9.1500000000000001E-5
0.38600000000000001	9.1768000000000006E-5
0.38700000000000001	9.2037E-5
0.38800000000000001	9.2126000000000005E-5
0.38900000000000001	9.2214999999999997E-5
0.39	9.2484000000000004E-5
0.39100000000000001	9.2751999999999996E-5
0.39200000000000002	9.2930999999999995E-5
0.39300000000000002	9.3109999999999995E-5
0.39400000000000002	9.3377999999999999E-5
0.39500000000000002	9.3556999999999999E-5
0.39600000000000002	9.3735999999999998E-5
0.39700000000000002	9.4004000000000003E-5
0.39800000000000002	9.4183000000000003E-5
0.39900000000000002	9.4451999999999996E-5
0.4	9.4720000000000001E-5
0.40100000000000002	9.4809000000000007E-5
0.40200000000000002	9.5078E-5
0.40300000000000002	9.5346000000000005E-5
0.40400000000000003	9.5883000000000003E-5
0.40500000000000003	9.6329999999999994E-5
0.40600000000000003	9.6419E-5
0.40699999999999997	9.6597999999999999E-5
0.40799999999999997	9.6688000000000007E-5
0.40899999999999997	9.6866000000000004E-5
0.41	9.7134999999999997E-5
0.41099999999999998	9.7403000000000002E-5
0.41199999999999998	9.7670999999999994E-5
0.41299999999999998	9.7940000000000001E-5
0.41399999999999998	9.8208000000000006E-5
0.41499999999999998	9.8475999999999997E-5
0.41599999999999998	9.8833999999999996E-5
0.41699999999999998	9.8924000000000004E-5
0.41799999999999998	9.9191999999999995E-5
0.41899999999999998	9.9549999999999994E-5
0.42	9.9908000000000006E-5
0.42099999999999999	1.0018000000000001E-4
0.42199999999999999	1.0053E-4
0.42299999999999999	1.0089E-4
0.42399999999999999	1.0124999999999999E-4
0.42499999999999999	1.0143E-4
0.42599999999999999	1.0187999999999999E-4
0.42699999999999999	1.0213999999999999E-4
0.42799999999999999	1.025E-4
0.42899999999999999	1.0304E-4
0.43	1.0322E-4
0.43099999999999999	1.0349E-4
0.432	1.0375E-4
0.433	1.0411E-4
0.434	1.0446999999999999E-4
0.435	1.0501E-4
0.436	1.0545E-4
0.437	1.0581000000000001E-4
0.438	1.0626E-4
0.439	1.0671E-4
0.44	1.0697E-4
0.441	1.0751000000000001E-4
0.442	1.0796E-4
0.443	1.0832000000000001E-4
0.44400000000000001	1.0885E-4
0.44500000000000001	1.093E-4
0.44600000000000001	1.0966E-4
0.44700000000000001	1.1001E-4
0.44800000000000001	1.1064E-4
0.44900000000000001	1.1109E-4
0.45	1.1162000000000001E-4
0.45100000000000001	1.1207E-4
0.45200000000000001	1.1260999999999999E-4
0.45300000000000001	1.1306000000000001E-4
0.45400000000000001	1.1359E-4
0.45500000000000002	1.1422E-4
0.45600000000000002	1.1476000000000001E-4
0.45700000000000002	1.1529E-4
0.45800000000000002	1.1582999999999999E-4
0.45900000000000002	1.1628E-4
0.46	1.169E-4
0.46100000000000002	1.1752999999999999E-4
0.46200000000000002	1.1806E-4
0.46300000000000002	1.186E-4
0.46400000000000002	1.1923E-4
0.46500000000000002	1.1976000000000001E-4
0.46600000000000003	1.203E-4
0.46700000000000003	1.2093E-4
0.46800000000000003	1.2146000000000001E-4
0.46899999999999997	1.2208999999999999E-4
0.47	1.2271999999999999E-4
0.47099999999999997	1.2343E-4
0.47199999999999998	1.2406E-4
0.47299999999999998	1.2459E-4
0.47399999999999998	1.2522E-4
0.47499999999999998	1.2594E-4
0.47599999999999998	1.2664999999999999E-4
0.47699999999999998	1.2737E-4
0.47799999999999998	1.2789999999999999E-4
0.47899999999999998	1.2862E-4
0.48	1.2933000000000001E-4
0.48099999999999998	1.2987E-4
0.48199999999999998	1.305E-4
0.48299999999999998	1.3129999999999999E-4
0.48399999999999999	1.3192999999999999E-4
0.48499999999999999	1.3255E-4
0.48599999999999999	1.3327E-4
0.48699999999999999	1.3407E-4
0.48799999999999999	1.3469999999999999E-4
0.48899999999999999	1.3542E-4
0.49	1.3604000000000001E-4
0.49099999999999999	1.3667E-4
0.49199999999999999	1.3737999999999999E-4
0.49299999999999999	1.381E-4
0.49399999999999999	1.3863999999999999E-4
0.495	1.3925999999999999E-4
0.496	1.3998E-4
0.497	1.4069000000000001E-4
0.498	1.4132000000000001E-4
0.499	1.4203999999999999E-4
0.5	1.4275E-4
0.501	1.4347000000000001E-4
0.502	1.4417999999999999E-4
0.503	1.4472000000000001E-4
0.504	1.4525000000000001E-4
0.505	1.4596999999999999E-4
0.50600000000000001	1.4668999999999999E-4
0.50700000000000001	1.4757999999999999E-4
0.50800000000000001	1.4812000000000001E-4
0.50900000000000001	1.4873999999999999E-4
0.51	1.4909999999999999E-4
0.51100000000000001	1.4964000000000001E-4
0.51200000000000001	1.5025999999999999E-4
0.51300000000000001	1.5088999999999999E-4
0.51400000000000001	1.5134E-4
0.51500000000000001	1.5186999999999999E-4
0.51600000000000001	1.5241000000000001E-4
0.51700000000000002	1.5295E-4
0.51800000000000002	1.5348E-4
0.51900000000000002	1.5393000000000001E-4
0.52	1.5438E-4
0.52100000000000002	1.5490999999999999E-4
0.52200000000000002	1.5545000000000001E-4
0.52300000000000002	1.5589999999999999E-4
0.52400000000000002	1.5644000000000001E-4
0.52500000000000002	1.5697000000000001E-4
0.52600000000000002	1.5733000000000001E-4
0.52700000000000002	1.5787E-4
0.52800000000000002	1.5822000000000001E-4
0.52900000000000003	1.5849000000000001E-4
0.53	1.5885000000000001E-4
0.53100000000000003	1.593E-4
0.53200000000000003	1.5966E-4
0.53300000000000003	1.6001000000000001E-4
0.53400000000000003	1.6037000000000001E-4
0.53500000000000003	1.6064000000000001E-4
0.53600000000000003	1.6100000000000001E-4
0.53700000000000003	1.6134999999999999E-4
0.53800000000000003	1.6171E-4
0.53900000000000003	1.6197999999999999E-4
0.54	1.6225000000000001E-4
0.54100000000000004	1.6252000000000001E-4
0.54200000000000004	1.627E-4
0.54300000000000004	1.6296E-4
0.54400000000000004	1.6322999999999999E-4
0.54500000000000004	1.6341000000000001E-4
0.54600000000000004	1.6368E-4
0.54700000000000004	1.6395E-4
0.54800000000000004	1.6412999999999999E-4
0.54900000000000004	1.6422E-4
0.55000000000000004	1.6440000000000001E-4
0.55100000000000005	1.6466000000000001E-4
0.55200000000000005	1.6484E-4
0.55300000000000005	1.6501999999999999E-4
0.55400000000000005	1.652E-4
0.55500000000000005	1.6529000000000001E-4
0.55600000000000005	1.6547E-4
0.55700000000000005	1.6556000000000001E-4
0.55800000000000005	1.6556000000000001E-4
0.55900000000000005	1.6564999999999999E-4
0.56000000000000005	1.6592000000000001E-4
0.56100000000000005	1.6592000000000001E-4
0.56200000000000006	1.6600999999999999E-4
0.56299999999999994	1.6618000000000001E-4
0.56399999999999995	1.6618000000000001E-4
0.56499999999999995	1.6618000000000001E-4
0.56599999999999995	1.6636E-4
0.56699999999999995	1.6645000000000001E-4
0.56799999999999995	1.6636E-4
0.56899999999999995	1.6653999999999999E-4
0.56999999999999995	1.6653999999999999E-4
0.57099999999999995	1.6645000000000001E-4
0.57199999999999995	1.6653999999999999E-4
0.57299999999999995	1.6672E-4
0.57399999999999995	1.6681000000000001E-4
0.57499999999999996	1.6689999999999999E-4
0.57599999999999996	1.6689999999999999E-4
0.57699999999999996	1.6681000000000001E-4
0.57799999999999996	1.6689999999999999E-4
0.57899999999999996	1.6699E-4
0.57999999999999996	1.6708000000000001E-4
0.58099999999999996	1.6708000000000001E-4
0.58199999999999996	1.6716999999999999E-4
0.58299999999999996	1.6725999999999999E-4
0.58399999999999996	1.6708000000000001E-4
0.58499999999999996	1.6716999999999999E-4
0.58599999999999997	1.6735E-4
0.58699999999999997	1.6735E-4
0.58799999999999997	1.6752999999999999E-4
0.58899999999999997	1.6771000000000001E-4
0.59	1.6778999999999999E-4
0.59099999999999997	1.6788E-4
0.59199999999999997	1.6797000000000001E-4
0.59299999999999997	1.6797000000000001E-4
0.59399999999999997	1.6797000000000001E-4
0.59499999999999997	1.6814999999999999E-4
0.59599999999999997	1.6824E-4
0.59699999999999998	1.6824E-4
0.59799999999999998	1.6841999999999999E-4
0.59899999999999998	1.6869000000000001E-4
0.6	1.6869000000000001E-4
0.60099999999999998	1.6896000000000001E-4
0.60199999999999998	1.6914E-4
0.60299999999999998	1.6932000000000001E-4
0.60399999999999998	1.694E-4
0.60499999999999998	1.6958000000000001E-4
0.60599999999999998	1.6966999999999999E-4
0.60699999999999998	1.6993999999999999E-4
0.60799999999999998	1.7021000000000001E-4
0.60899999999999999	1.7066E-4
0.61	1.7092999999999999E-4
0.61099999999999999	1.7101E-4
0.61199999999999999	1.7110000000000001E-4
0.61299999999999999	1.7128E-4
0.61399999999999999	1.7145999999999999E-4
0.61499999999999999	1.7173000000000001E-4
0.61599999999999999	1.7200000000000001E-4
0.61699999999999999	1.7217999999999999E-4
0.61799999999999999	1.7244999999999999E-4
0.61899999999999999	1.7270999999999999E-4
0.62	1.7297999999999999E-4
0.621	1.7333999999999999E-4
0.622	1.7352000000000001E-4
0.623	1.7388000000000001E-4
0.624	1.7422999999999999E-4
0.625	1.7450000000000001E-4
0.626	1.7477000000000001E-4
0.627	1.7521999999999999E-4
0.628	1.7558E-4
0.629	1.7602000000000001E-4
0.63	1.7637999999999999E-4

*Figura 70 - Voltammogramma ciclico del polimero 3.2.c registrato a diverse velocità di scansione* Questo comportamento è chiaramente evidenziato dai voltammogrammi riportati in **Figura 70**. Analizzando i tracciati ottenuti a velocità di scansione crescenti, non solo si osserva la totale assenza di onde di scarica simmetriche durante la scansione di ritorno, ma si rileva anche una progressiva diminuzione dell'intensità delle onde faradiche. Questa perdita di segnale indica che la specie generata durante l’analisi non è limitata a una semplice irreversibilità del trasferimento di carica, ma risulta intrinsecamente instabile. Il calo della corrente registrata testimonia infatti una degradazione e una conseguente perdita di materiale elettroattivo utile all'interfaccia elettrodo-soluzione. Dal punto di vista chimico e fisico, questo profilo voltammetrico indica che il trasferimento elettronico all'interfaccia elettrodo-soluzione è strettamente accoppiato a fenomeni secondari che consumano o alterano irreversibilmente la specie generata elettronicamente. Quando il polimero neutro viene sottoposto a scansione anodica, ovvero ad un drogaggio elettrochimico di tipo p, la rimozione di elettroni dal sistema π-coniugato comporta la formazione di specie con carica positiva, definibili come polaroni, radicali cationi. Analogamente, ai potenziali catodici, attraverso un drogaggio di tipo n, l'iniezione di elettroni genera le rispettive specie radical-anioniche. La mancanza delle onde voltammetriche di ritorno conferma che queste macromolecole cariche risultano altamente instabili nelle condizioni sperimentali adottate. In un sistema ideale governato da un meccanismo di tipo E, puramente elettrochimico, la reazione si limiterebbe al solo trasferimento di elettroni: la specie ossidata o ridotta rimarrebbe stabile all'interfaccia elettrodo-soluzione e subirebbe il processo elettrochimico inverso in modo simmetrico una volta invertita la direzione della scansione del potenziale. Nei materiali in esame si instaura invece un meccanismo di tipo EC, elettrochimico-chimico, nel quale il trasferimento di carica iniziale (fase E) genera un intermedio altamente reattivo che viene immediatamente consumato da una reazione chimica secondaria (fase C) prima di poter restituire o accettare nuovamente l'elettrone scambiato. Tale instabilità si traduce tipicamente in reazioni chimiche irreversibili di degradazione del materiale, che possono includere reazioni di accoppiamento tra le catene polimeriche radicaliche, sovraossidazione o l'insorgenza di reazioni parassite. Di conseguenza, a causa del consumo chimico della specie elettroattiva transitoria, il materiale non è in grado di ripristinare il proprio stato neutro iniziale, come evidenziato dall'assoluta asimmetria dei cicli voltammetrici registrati. Oltre all'indagine qualitativa, i voltammogrammi sono stati sottoposti a un'elaborazione quantitativa finalizzata all'estrapolazione dei potenziali di _onset (Eonset). Infatti, a causa della marcata irreversibilità e dell'ampiezza delle onde faradiche descritte in precedenza, i potenziali di picco ( $E_{p}$ ) sono fortemente alterati dalla rapida degradazione delle specie cariche appena formate. Per questo motivo, non rappresentano un parametro affidabile per calcolare i veri livelli energetici del materiale. L'utilizzo del potenziale di _onset, al contrario, consente di approssimare con maggiore accuratezza la minima energia necessaria per innescare i primissimi trasferimenti elettronici all'interfaccia, correlandosi direttamente ai limiti di banda del materiale. La determinazione di questi valori è stata condotta applicando il metodo grafico dell'intersezione delle tangenti (**Figura 69**). La costruzione geometrica richiede innanzitutto di tracciare la linea di base che precede il picco (baseline). Questa retta modella la risposta del sistema in termini di pura corrente capacitiva, legata alla carica del doppio strato elettrico; essa viene registrata in un intervallo di potenziale in cui il polimero risulta ancora elettrochimicamente inerte, immediatamente prima dell'avvio delle reazioni redox. Successivamente, si procede delineando una seconda retta, tangente al punto di massima pendenza del fronte di salita dell'onda voltammetrica. Questa linea descrive il rapido incremento di corrente associato al vero e proprio processo faradico di drogaggio, ovvero il momento in cui l'iniezione o l'estrazione di elettroni diventa il processo predominante. Il potenziale di onset viene definito graficamente dal punto esatto di intersezione tra l'estrapolazione della corrente capacitiva precedente al picco e la tangente al processo faradico. Proiettando tale intersezione sull'asse delle ascisse, è possibile ricavare il valore in Volt: applicando la procedura all'onda anodica si ottiene il potenziale di onset di ossidazione ( $E_{onset}^{ox}$ ), mentre applicandola all'onda catodica si ricava il potenziale di onset di riduzione ( $E_{onset}^{red}$ ). Applicando sistematicamente questo metodo a tutti i tracciati sperimentali, è stato possibile escludere l'interferenza della corrente di fondo, individuando l'esatto potenziale redox di ciascun copolimero in modo chiaro e riproducibile. I valori di potenziale estratti graficamente sono quantità relative, strettamente dipendenti dalle caratteristiche specifiche dell'elettrodo di riferimento ad Ag/AgCl impiegato e dalle fluttuazioni termodinamiche del sistema solvente/elettrolita. Per convertire queste misure in parametri energetici assoluti, confrontabili con la letteratura, si rende indispensabile una calibrazione dell'asse dei potenziali. A tale scopo è stato impiegato il ferrocene come standard redox interno. Quest’ultimo costituisce il classico riferimento per le misurazioni elettrochimiche in solventi organici poiché presenta una coppia redox (Fc/Fc⁺) altamente reversibile, chimicamente stabile e il cui potenziale è ben noto. Dal punto di vista termodinamico, l'energia associata al processo di ossidazione del ferrocene è convenzionalmente posta a - 4.8 eV rispetto al livello energetico del vuoto. Registrando il voltammogramma del ferrocene al termine di ogni analisi e ricavandone il potenziale di semionda sperimentale, è stato possibile calibrare i dati prima della loro elaborazione grafica. L'asse delle ascisse dei voltammogrammi è stato normalizzato sottraendo il potenziale di semionda del ferrocene a tutti i valori di potenziale registrati, riferendo così i tracciati direttamente alla scala del Fc/Fc⁺. I potenziali di onset ricavati graficamente da questi voltammogrammi normalizzati sono stati quindi impiegati per calcolare i livelli energetici degli orbitali di frontiera HOMO e LUMO dei copolimeri, applicando le seguenti equazioni empiriche: $$ E_{HOMO}=-\left(E_{onset}^{ox}+4.8\right) eV E_{LUMO}=-\left(E_{onset}^{red}+4.8\right) eV $$ *Equazione 11 - calcolo dei livelli energetici HOMO e LUMO* Infine, la differenza tra il livello LUMO e il livello HOMO ha permesso di ricavare il bandgap elettrochimico ( $E_{g}$ ) per ciascun materiale sintetizzato: $$ E_{g}=E_{LUMO}-E_{HOMO} $$ *Equazione 12 - bandgap elettrochimico* L'applicazione sistematica di queste equazioni ha permesso di tradurre i dati voltammetrici normalizzati in un quadro quantitativo e completo delle proprietà optoelettroniche dei materiali. ### **4.4.3. Proprietà elettrochimiche dei copolimeri lienari** Definita la metodologia di indagine, l'analisi dei risultati è partita dallo studio dei copolimeri lineari precursori. L'analisi di questi precursori risulta di fondamentale importanza per valutare il comportamento redox dello scheletro coniugato puro, svincolando la lettura dei dati dalle potenziali variazioni conformazionali o dagli effetti di ingombro sterico indotti dai successivi passaggi di funzionalizzazione. L'obiettivo primario di questa sezione è, quindi, esaminare in modo sistematico come la frazione reale di unità DPP incorporate lungo la catena polimerica, moduli attivamente l'architettura energetica del sistema. Studiando la risposta voltammetrica di questa serie di copolimeri, è possibile tracciare in modo accurato l'evoluzione dei potenziali termodinamici di iniezione ed estrazione di carica, quantificando l'impatto strutturale del monomero sull'ampiezza del bandgap elettrochimico e sul posizionamento dei livelli HOMO e LUMO. I parametri termodinamici e i livelli energetici degli orbitali di frontiera, estratti dai voltammogrammi ciclici per tutti i copolimeri di partenza indagati, sono raccolti nella **Tabella 13**. Questa raccolta dati fornisce la base quantitativa essenziale per lo sviluppo delle successive correlazioni.

Polimero	% reale DPP	(V)	(V)	HOMO (eV)	LUMO (eV)	Bandgap (eV)
3a	25	0,238	-0,732	-5,038	-4,068	0,970
3b	32	0,054	-1,262	-4,854	-3,538	1,316
3c	35	0,0006	-1,372	-4,799	-3,428	1,371

*Tabella 13 – dati voltammetrici dei copolimeri sintetizzati* A partire dai dati raccolti, il primo parametro optoelettronico preso in esame è il bandgap elettrochimico ( $E_{g}$ ). Il grafico in **Figura 71** illustra la correlazione sperimentale tra l'ampiezza del bandgap e la frazione reale di unità DPP incorporate nello scheletro dei copolimeri lineari analizzati.

Frazione reale DPP	Series1
0.25	0.97
0.32	1.3158000000000001
0.35	1.3714000000000002

*Figura 71 - correlazione tra bandgap elettrochimico e frazione reale di DPP nei copolimeri sintetizzati* L'analisi del grafico evidenzia una chiara dipendenza tra le due variabili: all'aumentare del contenuto effettivo di dichetopirrolopirrolo lungo la catena polimerica, si osserva un allargamento progressivo del bandgap elettrochimico. Questa tendenza suggerisce che la variazione dell'energia di gap sia governata dalla composizione stechiometrica effettiva del materiale. La netta pendenza positiva della retta di interpolazione indica che il bandgap è fortemente sensibile alle variazioni di composizione: incrementi anche modesti nella percentuale di monomero DPP determinano un aumento significativo dell'energia richiesta per promuovere le transizioni elettroniche. Questo comportamento suggerisce che la presenza dell'unità DPP riduce la lunghezza di coniugazione effettiva del sistema, limitando la delocalizzazione $\pi$ e portando di conseguenza a una maggiore separazione energetica tra HOMO e LUMO. Questa correlazione dimostra la fattibilità di un controllo mirato del band gap attraverso la calibrazione del rapporto tra i due monomeri durante la sintesi. Proseguendo l'indagine sulle proprietà elettrochimiche, il grafico riportato illustra l'andamento dei potenziali di picco, sia per il processo di ossidazione che per quello di riduzione, in funzione della frazione reale di dichetopirrolopirrolo.

Frazione reale DPP	E picco anodico	E picco catodico
0.25	0.38200000000000001	-1.02
0.32	0.2	-1.8129999999999999
0.35	0.22800000000000001	-1.633

Figura 72 - correlazione tra E_picco e frazione reale di DPP nei copolimeri sintetizzati La variazione più marcata si osserva a carico del processo di riduzione (drogaggio di tipo n): all'aumentare della frazione di DPP, il potenziale di picco catodico subisce un drastico spostamento verso valori significativamente più negativi. Passando dal copolimero con il contenuto di DPP più basso (25%), con $E_{pc}$ a circa – 1 V, ai materiali con frazioni superiori (32-35%), il picco si sposta nella regione compresa tra – 1.6 V e – 1.8 V. Questa traslazione indica che il processo di inserzione di elettroni diventa termodinamicamente più sfavorito all'aumentare della percentuale di DPP, richiedendo sovratensioni progressivamente maggiori per innescare la formazione delle specie radical-anioniche. Per quanto riguarda il processo di ossidazione (drogaggio di tipo p), l'impatto del contenuto di DPP risulta meno drastico ma ugualmente rilevabile. Il potenziale di picco anodico ( $E_{pa}$ ) mostra un moderato spostamento verso valori meno positivi, passando da circa 0.4 V per il polimero a minor contenuto di DPP a valori stabilizzati attorno a 0.2/0.25 V per le frazioni maggiori. Analizzando il sistema nel suo complesso, l'effetto combinato di queste due traslazioni si traduce in un allargamento della separazione tra i picchi all'aumentare della percentuale di DPP incorporata. Questa divergenza progressiva tra i potenziali di picco è coerente con l'aumento lineare del band gap elettrochimico discusso precedentemente. Tuttavia, a causa dell'irreversibilità dei processi e delle cinetiche di degradazione associate ai potenziali di picco, un quadro energetico più accurato si ottiene esaminando i potenziali di onset, i quali rappresentano in modo più rigoroso i potenziali di attivazione termodinamica.

Frazione reale DPP	Eonset anodico	E onset catodico
0.25	0.23799999999999999	-0.73199999999999998
0.32	5.3800000000000001E-2	-1.262
0.35	-5.9999999999999995E-4	-1.3720000000000001

Figura 73 - correlazione tra E_onset e frazione reale di DPP nei copolimeri sintetizzati Come illustrato in **Figura 73**, l'andamento dei potenziali di onset in funzione della frazione di DPP rispecchia fedelmente le tendenze osservate per i potenziali di picco. Il potenziale di onset catodico ( $E_{onset}^{red}$ ), indicativo dell'energia del LUMO, mostra uno spostamento pronunciato verso valori più negativi, passando da circa – 0.75 V per il copolimero a basso contenuto di DPP a valori prossimi a – 1.4 V per le frazioni maggiori. Parallelamente, il potenziale di onset anodico ( $E_{onset}^{ox}$ ), correlato all'energia dell'HOMO, subisce una lieve traslazione verso potenziali meno positivi (da circa 0.25 V a quasi 0 V). La progressiva separazione tra $E_{onset}^{ox}$ ed $E_{onset}^{red}$ all'aumentare dell'unità DPP conferma l'allargamento del bandgap, dimostrando come la composizione macromolecolare agisca in modo sistematico sui livelli energetici di frontiera del materiale. A ulteriore conferma dell'impatto strutturale dell'unità dichetopirrolopirrolo, risulta logico un confronto con il comportamento elettrochimico del poli(3-esiltiofene) (P3HT) omopolimero. Il P3HT è un sistema marcatamente elettron-ricco che mostra un processo di ossidazione (p-doping) a potenziali accessibili, ma non presenta contributi faradici significativi a potenziali minori per quanto riguarda i processi di riduzione (n-doping) all'interno della consueta finestra di stabilità dei solventi organici. Al contrario, nei copolimeri qui sintetizzati, l'introduzione del DPP modifica radicalmente la risposta voltammetrica. Agendo da forte porzione elettron-attrattrice all'interno di un'architettura coniugata di tipo donatore-accettore, l'unità DPP stabilizza marcatamente il livello LUMO del sistema. Questa stabilizzazione rende termodinamicamente favorevole l'iniezione di elettroni, giustificando la comparsa delle evidenti onde catodiche a potenziali minori che risultano invece assenti nel P3HT puro. Tale marcato abbassamento del LUMO, accoppiato alla modulazione del livello HOMO governata principalmente dai segmenti di 3-esiltiofene, costituisce il fattore chiave che determina il restringimento del bandgap rispetto all'omopolimero di riferimento. Nel complesso, i risultati dell'indagine voltammetrica attestano la validità del design molecolare adottato: l'elevata sistematicità con cui la composizione influenza la risposta termodinamica convalida l'approccio sintetico come strumento efficace per l'ingegnerizzazione del materiale, definendo un protocollo per la sua ottimizzazione in vista di future applicazioni in ambito optoelettronico. ### **4.4.4. Effetto del design bottle brush** Dopo aver caratterizzato il comportamento optoelettronico dello scheletro coniugato di base, l'analisi è proseguita valutando l'impatto dell'architettura macromolecolare complessa. I parametri termodinamici ed energetici finali, calcolati per l'intera serie di composti sintetizzati, sono riassunti in modo sistematico nella **Tabella 14**.

Polimero	(V)	(V)	HOMO (eV)	LUMO (eV)	Bandgap (eV)
3.1.b	-0,183	-1,22	-4,617	-3,580	1,037
3.2.b	-0,175	-1,273	-4,625	-3,527	1,098
3.3.b	-0,17	-1,202	-4,630	-3,598	1,032
3.1.c	-0,0259	-1,547	-4,774	-3,253	1,521
3.2.c	-0,112	-1,531	-4,688	-3,269	1,419
3.3.c	-0,321	-1,25	-4,479	-3,550	0,929

*Tabella 14 - dati voltammetrici dei polimeri sintetizzati* Dal confronto tra questi dati e quelli dei precursori lineari discussi nel paragrafo XX (XX), è possibile valutare l'impatto dell'innesto delle catene laterali di policaprolattone (PCL) sulle proprietà optoelettroniche del materiale. Innanzitutto, l'analisi evidenzia che i copolimeri bottle-brush mantengono la caratteristica elettroattività dello scheletro coniugato. Questo comportamento dimostra che i processi di ossido-riduzione avvengono coerentemente a carico del core a base di DPP e 3HT, mentre i rami alifatici fungono da matrice dielettrica circostante. Tuttavia, la transizione verso un'architettura macromolecolare più complessa induce delle modulazioni evidenti nei livelli energetici di frontiera. Osservando i valori di HOMO e LUMO, l'introduzione delle ingombranti catene laterali modifica l'assetto energetico rispetto ai polimeri lineari di partenza. Questo effetto si riflette in modo diretto sull'ampiezza del bandgap elettrochimico finale. Tali variazioni possono essere attribuite agli effetti di ingombro sterico indotti dai rami di PCL: la loro presenza volumetrica influenza il grado di coplanarità locale dello scheletro coniugato, alterando di conseguenza l'estensione effettiva della delocalizzazione elettronica lungo la catena principale. Nonostante queste fluttuazioni conformazionali, i valori di bandgap dei copolimeri bottle-brush si attestano in un range compreso tra 0,929 eV e 1,521 eV. Il mantenimento di queste ampiezze conferma che l'ingegnerizzazione dell'architettura mediante PCL non compromette le spiccate potenzialità optoelettroniche del sistema coniugato originario. ## **4.5. Caratterizzazione spettroscopica allo stato solido** Lo studio delle proprietà ottiche allo stato solido rappresenta un passaggio fondamentale nella caratterizzazione dei materiali polimerici coniugati, specialmente in ottica di una possibile integrazione in dispositivi optoelettronici. Mentre le misurazioni effettuate in soluzione diluita permettono di indagare le proprietà fotofisiche della singola catena polimerica isolata e solvatata, l'analisi allo stato solido rivela il comportamento del materiale nelle sue condizioni operative. In questo stato, la vicinanza tra le macromolecole porta all'instaurarsi di forti interazioni intermolecolari, che alterano significativamente i livelli energetici di banda e, di conseguenza, i processi di assorbimento ed emissione fotonica. Negli spettri di assorbimento UV-Vis registrati allo stato solido, la limitata mobilità conformazionale e il forte impaccamento delle catene inducono generalmente una maggiore planarizzazione dello scheletro coniugato. Rispetto agli spettri in soluzione, questo fenomeno si traduce in una delocalizzazione elettronica più estesa lungo il backbone polimerico, portando a un aumento della lunghezza di coniugazione effettiva. Macroscopicamente, tale effetto genera un tipico spostamento batocromo del massimo di assorbimento e, in molti casi, la comparsa di una struttura vibronica più risolta, indice di un elevato grado di ordine strutturale locale. La tipologia di aggregazione supramolecolare detta le regole di transizione elettronica. Secondo la teoria dell'accoppiamento eccitonico di Kasha, l'impaccamento delle catene coniugate può avvenire prevalentemente secondo due geometrie: gli aggregati di tipo H (impaccamento face-to-face, in cui prevalgono le interazioni π-π laterali) e gli aggregati di tipo J (impaccamento head-to-tail). Nei polimeri coniugati, le forti interazioni π-π favoriscono frequentemente la formazione di aggregati H, i quali presentano una transizione otticamente permessa verso lo stato eccitonico a maggiore energia.⁵⁸ Queste dinamiche di aggregazione hanno ripercussioni molto evidenti sulle proprietà di emissione allo stato solido. Il fenomeno più comunemente osservato nei sistemi π-coniugati altamente planari è l'estinzione dell'emissione causata dall'aggregazione (ACQ). La forte vicinanza tra gli anelli aromatici e la formazione di aggregati H, favoriscono il rilassamento non radiativo degli eccitoni attraverso la formazione di eccimeri o il trasferimento di energia verso siti di smorzamento (difetti conformazionali o trappole energetiche). Di conseguenza, le rese quantiche di fluorescenza allo stato solido subiscono un drastico abbattimento rispetto a quelle misurate in soluzione.⁵⁹ Nei copolimeri alternati a donatore-accettore (D-A), la struttura è ulteriormente arricchita dalla presenza della banda di trasferimento di carica intramolecolare (ICT). L'impaccamento solido riduce le distanze intermolecolari, facilitando anche fenomeni di trasferimento di carica intermolecolare. In sistemi che presentano forti cromofori elettron-accettori e unità elettron-donatrici, come i derivati tiofenici, la tendenza all’impaccamento intermolecolare ed alla cristallizzazione è notevole. Per modulare questi effetti e prevenire un quenching della luminescenza, l'introduzione di ingombri sterici mirati, come catene alchiliche ramificate, innesti polimerici laterali o architetture bottle-brush, diventa una strategia cruciale. Tali modifiche strutturali agiscono da spaziatori fisici: pur mantenendo la coniugazione elettronica sul backbone principale, ostacolano l'eccessivo avvicinamento dei piani π, limitando la formazione di aggregati H non radiativi e preservando in parte le proprietà emissive del materiale. Al fine di indagare l'intricata correlazione tra la struttura supramolecolare e il comportamento fotofisico del sistema sintetizzato, è stata condotta un'analisi spettroscopica combinata in assorbimento UV-Vis e in emissione allo stato solido su uno dei campioni rappresentativi, il polimero bottle brush 3.2.b (**Figura 74**). ![](immagini/35b98a0a92f2091382ef285d4a9a446a02d3c0ccaff98eeb82d17f4db843ea23.png) *Figura 74 - confronto tra spettri UV-Vis (in nero) ed emissione (in rosso) del polimero 3.2.b in soluzione (linea continua) e allo stato solido (linea tratteggiata)* L'analisi comparativa delle proprietà ottiche in soluzione liquida (LS) e allo stato solido (SS) permette di evidenziare l'effetto dell'impaccamento macromolecolare sulle transizioni elettroniche del materiale sintetizzato. Osservando i profili di assorbimento, in soluzione il polimero presenta una banda principale con un massimo di assorbimento centrato a circa 550 nm. Passando allo stato solido, il profilo di assorbimento subisce un significativo allargamento e un marcato spostamento batocromo, riposizionando il massimo di transizione nell'intervallo tra 570 e 580 nm, unitamente a una variazione dell'intensità relativa della spalla vibronica a energie maggiori. Questo slittamento verso lunghezze d'onda superiori è attribuibile alla planarizzazione del backbone coniugato indotta dai vincoli conformazionali dello stato solido, la quale favorisce un'estensione della lunghezza di coniugazione effettiva rispetto alle catene solvatate. Le variazioni più drastiche si riscontrano tuttavia nei profili di emissione. Lo spettro di emissione in soluzione mostra una banda stretta e strutturata, con un massimo a circa 560-565 nm e un ridotto spostamento di Stokes, caratteristico del rilassamento radiativo da singola catena isolata. Al contrario, l'emissione allo stato solido si presenta notevolmente allargata e subisce un elevato red-shift, esibendo un massimo centrato intorno a 650-660 nm. Questo notevole incremento dello spostamento di Stokes tra l'assorbimento e l'emissione allo stato solido (circa 80-90 nm) è probabilmente legato a un maggiore ingombro delle catene polimeriche, che obbliga gli anelli aromatici ad assumere torsioni maggiori, e costituisce al contempo una chiara evidenza della forte aggregazione intermolecolare. Tali evidenze spettrali indicano che, a seguito della fotoeccitazione, l'energia migra efficientemente verso siti a minore energia generati dalla forte vicinanza tra i piani coniugati (interazioni π-π), portando al rilassamento radiativo prevalentemente da stati aggregati o specie eccimeriche, piuttosto che dalle singole catene polimeriche non interagenti. In conclusione, le marcate variazioni spettrali osservate confermano l'instaurarsi di un forte riarrangiamento strutturale allo stato solido, un aspetto determinante che definisce l'effettivo profilo fotofisico del materiale. # 5 **Conclusioni** Il presente lavoro di tesi si è prefissato l’obiettivo primario di progettare, sintetizzare e caratterizzare nuove architetture macromolecolari semiconduttrici ed emissive ad architettura a spazzola (bottle brush), al fine di superare una delle più gravicriticità dei materiali π-coniugati nell’ambito della soft optoelectronics: il fenomeno dello spegnimento dell'emissione indotto da aggregazione (Aggregation-Caused Quenching, ACQ). La naturale propensione dei sistemi planari coniugati a instaurare intense interazioni supramolecolari di π-π stacking porta infatti a una drastica dissipazione non radiativa dell’energia eccitonica allo stato solido. Per ovviare a questo limite, la strategia adottata si è basata sulla realizzazione di copolimeri bottle brush, nei quali l'accrescimento di catene polimeriche laterali flessibili lungo uno scheletro elettro- e fotoattivo è stato sfruttato come spaziatore sterico per modulare l'impaccamento intermolecolare, preservando al contempo le proprietà elettroniche del backbone. Dal punto di vista sintetico, il percorso intrapreso ha dimostrato la piena efficacia e riproducibilità di una strategia basata sull'impiego di monomeri ortogonali e multifunzionali derivati dal dichetopirrolopirrolo (DPP). In primo luogo, la reazione di ciclizzazione tra il **2**-cianotiofene e il diisopropil succinato ha consentito di isolare con successo il fluoroforo tetraciclico **1**. La successiva funzionalizzazione mediante $N$ -alchilazione nucleofila con 6-bromo-**1**-esanolo ha portato all’ottenimento del monomero chiave bis-alchilato (composto **2**), confermato per via spettroscopica (-NMR e FT-IR). Tale monomero ha esibito la duplice funzionalità ricercata: la presenza degli eterocicli tiofenici ha fornito i siti reattivi per l'accrescimento della catena principale semiconduttrice, mentre i gruppi ossidrilici primari terminali hanno svolto il ruolo di iniziatori indipendenti per la successiva fase di innesto. La sintesi dello scheletro polimerico coniugato è stata condotta mediante polimerizzazione ossidativa diretta mediata da cloruro ferrico in presenza di nitrometano, accoppiando il monomero di DPP con il 3-esiltiofene (3HT). Questo approccio si è rivelato particolarmente vantaggioso rispetto ai canonici accoppiamenti incrociati mediati da palladio, eliminando la necessità di stadi di pre-funzionalizzazione e operando in condizioni termodinamiche blande. La sintesi di tre differenti copolimeri statistici a rapporto co-monomerico variabile (**3a**, **3b** e **3c**) ha confermato la versatilità della metodica, permettendo di ottenere materiali processabili con pesi molecolari compresi tra circa 1400 e 2150 Da e un intervallo di lavorabilità termica adeguato, caratterizzato da transizioni vetrose intorno a – 10 °C e temperature di fusione superiori a 110 °C. L’accrescimento delle architetture bottle brush a partire dai macroiniziatori **3b** e **3c** è stato realizzato mediante polimerizzazione ad apertura d'anello (ROP) dell' $\varepsilon$ -caprolattone, catalizzata da ottanoato di stagno. Attraverso la modulazione del rapporto molare tra monomero ciclico e siti ossidrilici pendenti, sono state sintetizzate con successo due serie di copolimeri a spazzola con catene laterali di PCL a pesi molecolari nominali crescenti (1500, 5000 e 10000 Da). L'avvenuta reazione di innesto è stata verificata tramite FT-IR, registrando la completa scomparsa della banda associata agli ossidrili terminali e la concomitante comparsa dell'intenso assorbimento carbonilico estereo del PCL a circa $1720 cm^{-1}$ . L'indagine condotta mediante cromatografia a permeazione di gel (GPC) ha evidenziato indici di dispersità contenuti (1.23–1.52). Inoltre, la marcata contrazione del volume idrodinamico in soluzione rilevata rispetto ai pesi teorici lineari ha costituito una prova dell'ottenimento di macromolecole ramificate a densità elevata e struttura altamente compatta. Dal punto di vista termico, il comportamento dei sistemi bottle brush si è dimostrato governato dalla fase semicristallina dominante delle catene laterali di PCL, garantendo un profilo termico omogeneo e indipendente dalle minime oscillazioni della catena principale. La caratterizzazione ottica in soluzione ha evidenziato che la funzionalizzazione sterica non perturba l'integrità elettronica del core dichetopirrolopirrolico: i massimi di assorbimento (544–554 nm) e di emissione (557–564 nm), unitamente a valori di Stokes shift costantemente contenuti (8–14 nm), hanno confermato la conservazione dell'assetto planare del cromoforo e la minima riorganizzazione strutturale tra stato fondamentale ed eccitato. Al contrario, le indagini spettroscopiche condotte allo stato solido su film sottili (esemplificate sul campione 3.2b) hanno fornito indicazioni determinanti: lo spostamento batocromo dell'assorbimento (fino a 570–580 nm) e l'allargamento spettrale dell'emissione, con un marcato red-shift centrato a circa 650–660 nm, hanno dimostrato come l'impaccamento supramolecolare promuova la migrazione dell'eccitone verso stati aggregati a minore energia. Nonostante l'insorgenza di tali riarrangiamenti, l'architettura bottle brush ha consentito il mantenimento di un'apprezzabile emissione nel rosso, attenuando i percorsi di disattivazione non radiativa totale tipici dell'ACQ non controllato. Infine, l'approfondita indagine elettrochimica condotta mediante ciclovoltammetria ha fornito riscontri fondamentali circa le proprietà semiconduttrici e la struttura a bande dei materiali. Sebbene i polimeri esibiscano un meccanismo di trasferimento di carica irreversibile di tipo elettrochimico-chimico indotto dall'elevata reattività dei cationi e anioni radicalici all'interfaccia elettrodica, l'estrapolazione rigorosa dei potenziali di onset ha consentito di determinare con precisione la posizione dei livelli energetici HOMO e LUMO e l'ampiezza del bandgap elettrochimico. L'analisi comparativa ha evidenziato una correlazione lineare ( $R^{2}=0.9719$ ) tra la percentuale reale di DPP incorporata e l'allargamento del bandgap (da 3.42 eV a oltre 4.30 eV), guidata principalmente da uno spostamento del potenziale di riduzione catodica verso valori progressivamente più negativi. Tale sistematicità dimostra che la composizione monomerica funge da eccellente parametro di controllo per calibrare finemente i livelli elettronici di frontiera. In conclusione, i risultati conseguiti nel presente lavoro di tesi confermano la validità del design macromolecolare proposto: l'approccio ortogonale basato su scheletri semiconduttori DPP-3HT modificati mediante catene laterali di PCL consente di combinare proprietà elettrochimiche modulabili e capacità emissiva allo stato solido. **Bibliografia** 2. Shaikh, S. A. L. et al. A minireview on diketopyrrolopyrrole chemistry: Historical perspective and recent developments. Results Chem. 4, 100473 (2022). 3. Auwalu, M. A. & Cheng, S. Diketopyrrolopyrrole Fluorescent Probes, Photophysical and Biological Applications. Chemosensors 9, 44 (2021). 4. Zhang, B. et al. Diketopyrrolopyrrole-based fluorescent probe for visualizing over-expressed carboxylesterase in fever via ratiometric imaging. Talanta 266, 124971 (2024). 5. Iqbal, A. et al. The synthesis and properties of 1,4‐diketo‐pyrrolo[3,4‐C]pyrroles. Bull. Sociétés Chim. Belg. 97, 615–644 (1988). 6. Sprake, J. M. & Watson, K. D. Addition products of 2-(N-arylformimidoyl)pyridines and carbanions, and their reduction to octahydroindolizine derivatives. *J. Chem. Soc. Perkin 1* 5 (1976) doi:10.1039/p19760000005. 7. Grzybowski, M. & Gryko, D. T. Diketopyrrolopyrroles: Synthesis, Reactivity, and Optical Properties. Adv. Opt. Mater. 3, 280–320 (2015). 8. Closs, F. & Gompper, R. 2,5‐Diazapentalenes. Angew. Chem. Int. Ed. Engl. 26, 552–554 (1987). 9. Stas, S., Sergeyev, S. & Geerts, Y. Synthesis of diketopyrrolopyrrole (DPP) derivatives comprising bithiophene moieties. Tetrahedron 66, 1837–1845 (2010). 10. Avcıbaşi, N. et al. Synthesis and in vitro evaluation of dioxopyrrolopyrroles as potential low‐affinity fluorescent Ca²⁺ indicators. Int. J. Photoenergy 6, 159–167 (2004). 11. Riggs, R. L. et al. Synthetic studies related to diketopyrrolopyrrole (DPP) pigments. Part 3: Syntheses of tri- and tetra-aryl DPPs. Tetrahedron 61, 11230–11243 (2005). 12. Qian, G. & Wang, Z. Y. Near‐Infrared Thermochromic Diazapentalene Dyes. Adv. Mater. 24, 1582–1588 (2012). 13. Langhals, H., Grundei, T., Potrawa, T. & Polborn, K. Highly Photostable Organic Fluorescent Pigments – A Simple Synthesis of N ‐Arylpyrrolopyrrolediones (DPP). Liebigs Ann. 1996, 679–682 (1996). 14. De Luca, L., Giacomelli, G. & Porcheddu, A. A Mild and Efficient Alternative to the Classical Swern Oxidation. J. Org. Chem. 66, 7907–7909 (2001). 15. Harris, J. M., Liu, Y., Chai, S., Andrews, M. D. & Vederas, J. C. Modification of the Swern Oxidation: Use of a Soluble Polymer-Bound, Recyclable, and Odorless Sulfoxide. J. Org. Chem. 63, 2407–2409 (1998). 16. Mizuguchi, J., Grubenmann, A., Wooden, G. & Rihs, G. Structures of 3,6-diphenylpyrrolo[3,4- c ]pyrrole-1,4-dione and 2,5-dimethyl-3,6-diphenylpyrrolo[3,4- c ]pyrrole-1,4-dione. Acta Crystallogr. B 48, 696–700 (1992). 17. David, J., Weiter, M., Vala, M., Vyňuchal, J. & Kučerík, J. Stability and structural aspects of diketopyrrolopyrrole pigment and its N-alkyl derivatives. Dyes Pigments 89, 137–143 (2011). 18. Mizuguchi, J. & Wooden, G. A Large Bathochromic Shift from the Solution to the Solid State in 1,4‐Diketo‐3,6‐Diphenyl‐Pyrrolo‐[3,4‐c]‐Pyrrole. Berichte Bunsenges. Für Phys. Chem. 95, 1264–1274 (1991). 19. Luňák, S., Vyňuchal, J., Vala, M., Havel, L. & Hrdina, R. The synthesis, absorption and fluorescence of polar diketo-pyrrolo-pyrroles. Dyes Pigments 82, 102–108 (2009). 20. Lenz, R. DPP chemistry- Continuous innovation. 21. Colonna, G., Pilati, T., Rusconi, F. & Zecchi, G. Synthesis and properties of some new N,N′-disubstituted 2,5-dihydro-1,4-dioxo-3,6-diphenylpyrrolo[3,4-c]pyrroles. Dyes Pigments 75, 125–129 (2007). 22. Zambounis, J. S. & Iqbal, A. Pyrrolo(3,4-cipyrroles. 23. Yue, W., Suraru, S., Bialas, D., Müller, M. & Würthner, F. Synthesis and Properties of a New Class of Fully Conjugated Azahexacene Analogues. Angew. Chem. Int. Ed. 53, 6159–6162 (2014). 24. Zambounis, J. S., Hao, Z. & Iqbal, A. Latent pigments activated by heat. Nature 388, 131–132 (1997). 25. Tieke, B., Rabindranath, A. R., Zhang, K. & Zhu, Y. Conjugated polymers containing diketopyrrolopyrrole units in the main chain. Beilstein J. Org. Chem. 6, 830–845 (2010). 26. Li, Y., Sonar, P., Murphy, L. & Hong, W. High mobility diketopyrrolopyrrole (DPP)-based organic semiconductor materials for organic thin film transistors and photovoltaics. Energy Environ. Sci. 6, 1684 (2013). 27. McGlacken, G. P. & Bateman, L. M. Recent advances in aryl–aryl bond formation by direct arylation. Chem. Soc. Rev. 38, 2447 (2009). 28. Han, W. & Ofial, A. No Detours: Palladium-Catalyzed Oxidative C-H/C-H Cross-Couplings of Heteroarenes. Synlett 2011, 1951–1955 (2011). 29. Liu, S.-Y. et al. C–H activation: making diketopyrrolopyrrole derivatives easily accessible. J. Mater. Chem. A 1, 2795 (2013). 30. Hong, W. et al. A conjugated polyazine containing diketopyrrolopyrrole for ambipolar organic thin film transistors. Chem. Commun. 48, 8413 (2012). 31. Bürckstümmer, H., Weissenstein, A., Bialas, D. & Würthner, F. Synthesis and Characterization of Optical and Redox Properties of Bithiophene-Functionalized Diketopyrrolopyrrole Chromophores. J. Org. Chem. 76, 2426–2432 (2011). 32. Hu, X. et al. Incorporation of ester groups into low band-gap diketopyrrolopyrrole containing polymers for solar cell applications. J. Mater. Chem. 22, 15710 (2012). 33. Valeur, B. & Berberan-Santos, M. N. A Brief History of Fluorescence and Phosphorescence before the Emergence of Quantum Theory. J. Chem. Educ. 88, 731–738 (2011). 34. Lakowicz, J. R. Introduction to Fluorescence. in *Principles of Fluorescence Spectroscopy* (ed. Lakowicz, J. R.) 1–23 (Springer US, Boston, MA, 1999). doi:10.1007/978-1-4757-3061-6\_1. 35. Kasha, M. Characterization of electronic transitions in complex molecules. Discuss. Faraday Soc. 9, 14 (1950). 36. On the Change of Refrangibility of Light. By G. G. STOKES, ALA., F.R.S., Fellow of Pembroke College, and Lucasian Professor of -Mathematics in the University of Cambridge. 37. Prodi, L. & Credi, A. Spectrofluorimetry. in *The Exploration of Supramolecular Systems and Nanostructures by Photochemical Techniques* (ed. Ceroni, P.) vol. 78 97–129 (Springer Netherlands, Dordrecht, 2012). 38. Brouwer, A. M. Standards for photoluminescence quantum yield measurements in solution (IUPAC Technical Report). Pure Appl. Chem. 83, 2213–2228 (2011). 39. Weber, G. & Teale, F. W. J. Determination of the absolute quantum yield of fluorescent solutions. Trans. Faraday Soc. 53, 646 (1957). 40. Stoddart, J. F. Chapter 12. Host–guest chemistry. Annu. Rep. Sect. B Org. Chem. 85, 353–386 (1988). 41. Valdés, C., Toledo, L. M., Spitz, U. & Rebek, J. Structure and Selectivity of a Small Dimeric Encapsulating Assembly. Chem. – Eur. J. 2, 989–991 (1996). 42. Wang, K. et al. Highly fluorescent polycaprolactones decorated with di(thiophene‐2‐yl)‐diketopyrrolopyrrole: A covalent strategy of tuning fluorescence properties in solid states. J. Polym. Sci. Part Polym. Chem. 53, 1032–1042 (2015). 43. Lee, J.-K. et al. Light-emitting properties of PMMA-based new side chain polymers. Synth. Met. 111–112, 489–491 (2000). 44. Bao, W. W. et al. Diketopyrrolopyrrole (DPP)-Based Materials and Its Applications: A Review. Front. Chem. 8, 679 (2020). 45. Ostroverkhova, O. Organic Optoelectronic Materials: Mechanisms and Applications. Chem. Rev. 116, 13279–13412 (2016). 46. Nowsherwan, G. A. et al. Advances in Organic Materials for Next-Generation Optoelectronics: Potential and Challenges. Organics 5, 520–560 (2024). 47. Li, Y. Diketopyrrolopyrrole-Based Conjugated Polymers for Organic Electronics. https://doi.org/10.1021/ar500252u (2014) doi:10.1021/ar500252u. 48. Kroon, R. Small Bandgap Polymers for Organic Solar Cells (Polymer Material Development in the Last 5 Years). https://doi.org/10.1080/15583724.2015.1121853 doi:10.1080/15583724.2015.1121853. 49. Hendriks, K. H. Diketopyrrolopyrrole-Based Polymers for High-Efficiency Organic Solar Cells. https://doi.org/10.1039/c3ta11429c (2013) doi:10.1039/c3ta11429c. 50. Cardona, C. M., Li, W., Kaifer, A. E., Stockdale, D. & Bazan, G. C. Electrochemical Considerations for Determining Absolute Frontier Orbital Energy Levels of Conjugated Polymers for Solar Cell Applications. Adv. Mater. 23, 2367–2371 (2011). 51. Wang, L. et al. Robust singlet fission process in strong absorption π-expanded diketopyrrolopyrroles. Chem. Sci. 13, 13907–13913 (2022). 52. Abdel Aziz, I., Tullii, G., Antognazza, M. R. & Criado-Gonzalez, M. Poly(3-hexylthiophene) as a versatile semiconducting polymer for cutting-edge bioelectronics. Mater. Horiz. 12, 5570–5593 (2025). 53. Paganin, D. L., Bizzarri, P. C. & Lanzi, D. M. Sintesi e proprietà di nuovi polimeri tiofenici per applicazioni optoelettroniche. 54. Odian, G. G. *Principles of Polymerization*. (Wiley-Interscience, Hoboken, N.J, 2004). 55. Woodruff, M. A. & Hutmacher, D. W. The return of a forgotten polymer—Polycaprolactone in the 21st century. Prog. Polym. Sci. 35, 1217–1256 (2010). 56. Labet, M. & Thielemans, W. Synthesis of polycaprolactone: a review. Chem. Soc. Rev. 38, 3484 (2009). 57. Floyd, T. G. et al. Cationic Bottlebrush Copolymers from Partially Hydrolyzed Poly(oxazoline)s. Macromolecules 54, 9461–9473 (2021). 58. Kasha, M., Rawls, H. R. & Ashraf El-Bayoumi, M. The exciton model in molecular spectroscopy. Pure Appl. Chem. 11, 371–392 (1965). 59. Spano, F. C. & Silva, C. H- and J-Aggregate Behavior in Polymeric Semiconductors. Annu. Rev. Phys. Chem. 65, 477–500 (2014).